• Resources Recycling
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• v.25 no.2
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• pp.10-16
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• 2016

In this study, the Ni base superalloy was recycled by Argon oxygen decarburization(AOD) process using an inconel 713C scrap. During AOD process, argon gas was continuously injected 1,000 sccm and oxygen gas was injected into 10, 20 and 30 minutes of 100, 250 and 500 sccm.. In early stage of oxygen injection, the oxygen dose increased with increasing Al, Cr, and Mo content and decreasing C content. And Al content was decreased by carburization with added elements in late stage Because of oxidation was occurred with Al, Cr etc. after the reaction of carbon has been finished. From the results, the ratio of ${\gamma}^{\prime}$ phase reduced due to decreasing of Al content for that reason Al is the main element to form the ${\gamma}^{\prime}$ phase. Also carbide reduced owing to decreasing of C content so the mechanical properties of the specimens excessively injected by excess $O_2$ gas were decreased.

• Nuclear Engineering and Technology
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• v.55 no.1
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• pp.156-168
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• 2023

This study investigates the high temperature oxidation behaviour of a Ni-20Cr-1.2Si (wt.%) alloy in steam from 1200 ℃ to 1350 ℃ by Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray Spectroscopy (EDS) and X-ray Diffraction (XRD). The results demonstrate that exposed Ni-based alloy developed a thin oxide scale, consisted mainly of Cr₂O₃. The oxidation kinetics obtained from the experimental results was applied to evaluate the hydrogen generation considering a simplified reactor core model with different cladding alloys following an unmitigated Loss-Of-Coolant Accident (LOCA) scenario in a hypothetical Small Modular Reactor (SMR). Overall, experimental data and simulations results show that both Fe-based and Ni-based alloys may enhance cladding survivability, delaying its melting, as well as reducing hydrogen generation under accident conditions compared to Zr-based alloys. However, a substantial neutron absorption occurs when Ni-based alloys are used as cladding for current uranium-dioxide fuel systems, even when compared to Fe-based alloys.

• Environmental Engineering Research
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• v.18 no.3
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• pp.177-189
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• 2013

Studies were carried out on the speciation of heavy metals (Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr) during rotary drum composting of water hyacinth (Eichhornia crassipes) for a period of 20 days. Five different proportions of cattle manure, water hyacinth and sawdust were prepared for composting. This study concluded that, rotary drum was very efficient for the degradation of organic matter as well as for the reduction of mobility and bioavailability of heavy metals during water hyacinth composting. The results from the sequential extraction procedure of heavy metals shows that rotary drum composting changed the distribution of five fractions of Zn, Cu, Mn, Fe, Ni, Pb, Cd, and Cr. The highest reduction in the bioavailability factors of Pb and Cd was observed during the process. The total concentration of Cu, Cr, and Cd was very low compared to the other metals (Zn, Mn, Fe, Ni, and Pb); however, the percentage of exchangeable and carbonate fractions of these metals was similar to other metals. These results confirmed that the bioavailability of metals does not depend on the total concentration of metals. From this study, it can be concluded that the addition of an appropriate proportion of cattle manure significantly reduced the mobile and easily available fractions (exchangeable and carbonate fractions) during water hyacinth composting in rotary drum.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.75-75
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• 2009

연성회로기판은 일반적으로 절연체를 이루는 폴리이미드와 전도체를 이루는 구리로 구성되어 있다. 폴리이미드는 뛰어난 열적 화학적 안정성, 기계적 특성, 공정성 등의 장점으로 인해 연성회로기판의 절연체로서 제안되었지만 전도체를 이루는 구리와의 접합 특성이 우수하지 않기 때문에 많은 연구가 현재까지 진행되고 있고, 그 결과 연성회로기판의 접합 특성에 많은 개선이 이루어짐과 동시에 다양한 공정 방법이 제안되고 있다. 하지만 고온다습한 환경에서 사용될 경우 폴리이미드의 높은 흡습성과, 구리와 seed layer의 산화 문제로 인해 접합 특성이 저하된다는 단점 또한 가지고 있다. 따라서 본 연구를 통해 고온다습한 조건하에서 seed layer가 80Ni/20Cr 합금으로 구성된 연성회로기판의 seed layer의 두께와 시효시간으로 인해 발생하는 접합 신뢰성의 차이를 관찰하였다. 본 연구에서는 두께 $25{\mu}m$의 폴리이미드 위에 각각 100, 200, $300{\AA}$ 두께의 80Ni/20Cr의 합금 조성을 가지는 seed layer를 스퍼터링 공정을 통해 형성한 후 전해도금법을 이용하여 $8{\mu}m$ 두께의 구리 전도층을 형성하였다. 접합 특성 평가를 위해 ICP 규격에 따라 전도층 패턴을 폭 3.2mm, 길이 230mm로 시편을 제작하여 50.8mm/min의 이송 속도로 각 시편당 8회의 $90^{\circ}$ peel test를 실시하였다. 또한 $85^{\circ}C$/85% 항온항습 조건하에서 각각 24, 72, 120, 168시간 동안 시효 처리 후 같은 방법으로 연성회로기판의 접합 특성을 평가하였다. 파면의 형상과 조성을 분석하기 위해 SEM (Scanning electron microscope)과 EDS (Energy-dispersive X-ray spectroscopy)를 사용하였으며, 파면의 조도 측정을 위해 AFM (Atomic force microscope)을 사용하였다. 또한 파면의 잔여물 분석을 위해 EPMA (Energy probe microanalysis)를 사용하였고 계면의 화학적 결합상태를 분석하기 위해 XPS (X-ray photoelectron spectroscopy)를 통해 파면을 분석하였다.

• Korean Journal of Environmental Agriculture
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• v.22 no.2
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• pp.118-123
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• 2003

This study was carried out to examine the heavy metal concentrations in soils under roadside trees and tree ring layers, and to investigate the relationship between heavy metal concentrations and tree ring growth of roadside trees in Seoul. Soil samples at $0{\sim}20\;cm$ depth and tree line were collected from Platanus occidentalis and Ginkgo biloba at nine streets, and pH and heavy Metal concentrations were analyzed. Soil pH ranged from 6.62 to 8.01 and soil heavy metal concentrations under roadside trees were higher (Zn 109.03, Pb 26.49 and Cu 44.98 mg/kg) compared with those of the referred forest soils. Soils at Cheonggye2ga street showed the highest heavy metal concentrations, and seemed to be related to heavy traffic and dense hardware stores. Tree ring width significantly decreased from 1979 through 2000 for both species. There were positive correlations between Cr, Pb and Cu concentrations in soils and tree ring layers for P. occidentalis and Ni for G. biloba. However, there were negative correlations between Cr concentration in tree ring layers and tree ring width for P. occidentalis, and Ni and Cu for G. biloba. Also there were no significant correlations between climatic factors in Seoul and tree ring width.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.2
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• pp.349-356
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• 2002

For two kinds of 25Cr-20Ni stainless steels, STS310J1TB and STS310S with and without a small amount of Nb and N, creep behavior has been studied in a stress and temperature range from 147 to 392 MPa and from 923 to 773 K with a special reference to tertiary creep. The average creep life of STS310J1TB was about 100 times longer than that of the STS310S. The apparent activation energy for the initial creep rate was 330 kJ/mol in STS310J1TB, while that of the STS310S was 274kJ/mol in a power law creep region and 478 kJ/mol in a region of power law breakdown (PLB). The activation energy for STS310S below PLB is close to the for self-diffusion. When compensating for the temperature dependence of the Young's modulus and the omega value, it was found that the apparent activation energy for STS310J1TB was reduced to the activation energy for diffusion of chromium atom in gamma steel. The stress exponent of STS310S was about 12.3 above PLB and 5.1 in a power law creep region. Notwithstanding that the creep condition for STS310J1TB was in a power law creep region, its stress exponent was 7.9 larger than that of STS310S corresponding to the same creep conditions. This was ascribed to the presence of fine precipitates in STS310J1TB.

• Proceedings of the KSME Conference
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• 2001.11a
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• pp.117-122
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• 2001

For two kinds of 25Cr-20Ni stainless steels, SUS310J1TB TB and SUS310S with and without a small amount of Nb and N, creep behavior has been studied in a stress and temperature range from 147 to 392MPa and from 923 to 973K with a special reference to tertiary creep. The average creep life of SUS310J1TB was about 100 times longer than that of the SUS310S. The apparent activation energy for the initial creep rate was 330 kJ/mol in SUS310J1TB, while that of the SUS310S was 274 kJ/mol in a power law creep region and 478 kJ/mol in a region of power law breakdown (PLB). The activation energy for SUS310S below PLB is close to the that for self-diffusion. When compensating for the temperature dependence of the Young's modulus and the omega value, it was found that the apparent activation energy for SUS310J1TB was reduced to the activation energy for diffusion of chromium atom in a gamma steel. The stress exponent of SUS310S was about 12 above PLB and 5.1 in a power law creep region. Notwithstanding that the creep condition for SUS310J1TB was in a power law creep region, its stress exponent was 8.3 larger than that of SUS310S corresponding to the same creep conditions. This was ascribed to the presence of fine precipitates in SUS310J1TB.

• Journal of the Korean Chemical Society
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• v.20 no.6
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• pp.494-499
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• 1976

The extraction-polarographic method applied to the determination of micro amount of chromium (Ⅵ). Chromium(Ⅵ) was extracted into methylisobuthylketone(MIBK) layer containing diethyldithiocarbamate(DDTC) as Cr(Ⅲ)-DDTC complex from acetate buffered aqueous, solution of pH 5.4 and the direct current polarogram for the extract was recorded after addition of sodium perchlorate as supporting electrolyte. The reduction current was diffusion controlled. And the half wave potential of this reduction wave was -0.81 volt vs. SCE. The diffusion current was proportional to the chromium concentraticn in aqueous solution in the range of 8∼160 ppm. And the chromium(Ⅵ) could be selectively determined in the presence of chromium(Ⅲ), since the chromium(Ⅲ) did not interfere up to twice the amount of chromium(Ⅵ). Many of other metals such as Mn(Ⅱ), Cu(Ⅲ), Zn(Ⅱ), Mg(Ⅱ), Ni(Ⅱ) and Ag(Ⅰ) were found to have no effect even when present in 1000 times the amount of chromium (Ⅵ).

• Korean Journal of Materials Research
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• v.30 no.9
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• pp.465-473
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• 2020

For surface hardening of a continuous casting mold component, a fundamental metallurgical investigation on dissimilar laser clads (Cu-NiCrBSi) is performed. In particular, variation behavior of microstructures and mechanical properties (hardness and wear resistance) of dissimilar clads during long-term service is clarified by performing high-temperature post-clad heat treatment (temperature range: 500 ~ 1,000 ℃ and isothermal holding time: 20 ~ 500 min). The microstructures of clad metals (as-clads) consist of fine dendrite morphologies and severe microsegregations of the alloying elements (Cr and Si); substrate material (Cu) is clearly confirmed. During the post-clad heat treatment, the microsegregations are totally homogenized, and secondary phases (Cr-based borides and carbides) precipitated during the short-term heat treatment are also almost dissolved, especially at the heat treatment conditions of 950 ℃ for 500 min. Owing to these microstructural homogenization behaviors, an opposite tendency of the surface mechanical properties can be confirmed. In other words, the wear resistance (wear rate) improves from 4.1 × 10^-2 ㎣/Nm (as-clad condition) to 1.4 × 10^-2 ㎣/Nm (heat-treated at 950 ℃ for 500 min), whereas the hardness decreases from 453 HV (as-clad condition) to 142 HV (heat-treated at 950 ℃ for 500 min).

• Journal of Dental Rehabilitation and Applied Science
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• v.33 no.2
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• pp.71-79
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• 2017

Purpose: Ni-Cr alloy does not contain Beryllium, causing the metal compound to form oxides in the furnace but by using Titanium as a chemical catalyst the forming of the oxides can be controlled, and by controlling the impurities formed on the metal surface, the possibility of the Ni-Cr alloy bond strength being increased can be analysed. Materials and Methods: Titanium was used as a chemical catalyst in the porcelain for the oxidation of beryllium-free metal (Ni-Cr) alloy. The T1 group, which does not use Titanium power as a chemical catalyst is a reference model for comparison. The T2 group and T3 group used 10 g and 20 g of Titanium power, respectively. They are fabricated to observe the shear bond strength and surface properties. There was no significance when One-way ANOVA analysis/Tukey Honestly Significant Difference Test was conducted for statistical analysis among groups (P > 0.05). Results: Results of measuring the three-point flexural bond strength of the Ni-Cr alloy and thickness of the oxide film. Experiment T3 using 20 g Titanium chemical catalyst: $39.22{\pm}3.41MPa$ and $6.66{\mu}m$, having the highest bond strength and thinness of oxide film. Experiment T2 using 10 g Titanium chemical catalyst: $34.65{\pm}1.39MPa$ and $13.22{\mu}m$. Experiment T1 using no Titanium chemical catalyst: $32.37{\pm}1.91MPa$ and $22.22{\mu}m$. Conclusion: The T2 and T3 experiments using Titanium chemical catalyst showed higher bond strength for the Ni-Cr alloy and lower thickness of oxide film than experiment T1, and the titanium catalyst being able to increase bond strength was observed.