• Journal of Welding and Joining
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• 제29권1호
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• pp.74-79
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• 2011

Three different welding wires were used to study the effects of Al content on weld metal toughness and porosity formation in self-shielded arc welding. Weld metal microstructure showed that while wire with 1.3% Al content contains coarse $\delta$-ferrite, wires with less than 0.5% Al content showed no such phase. In addition to the microstructural differences, cleanliness in weld metal was also different among wires. It showed that weld metal toughness was influenced by the $\delta$-ferrite formation, cleanliness and Ni addition. Even though wires with less than 0.5% Al content showed higher weld metal toughness, they showed relatively poor workability, forming porosities in weld bead in lower arc voltages.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.58-58
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• 2010

Reactive or unstable adsorbates are often difficult to study spectroscopically. They may have, for instance, resonance states lying close to the Fermi level, inducing them to desorb or decompose by the probe itself, low-energy tunneling electrons. In order to overcome this limitation, we developed a novel method, which we call x-ramp scan. The method sweeps the bias voltage, with the simutaneous scan along the imaging direction, in a constant current mode. This mapping yields the tip-height variation as a function of bias, or Z(V), at nominally always fresh surface. We applied this method to the investigation of methanol-induced molecular features, attributed to methoxy, found on NiAl(110) surface. These were produced by methanol molecules deposited by a pulse injection method onto the metallic surface. Our study shows adsorbed methoxy are very reactive to the bias voltage, rendering the standard spectroscopy useless. Our new x-ramp scan shows that the decomposition of adsorbates occurs at the sample bias of 3.63 V, and proceeds with the lifetime of a few milliseconds. The details of the method will be provided at the discussion.

• 한국재료학회지
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• 제13권6호
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• pp.365-368
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• 2003

Small amounts of additives such as mol % 0.13 NiO and mol % 0.01 $CaCO_3$were added to Cu-Zn-Mg ferrites. Basic composition of the Cu-Zn-Mg ferrites was $Cu_{Cu}$X/$Fe_{0.054}$ /$Zn_{0.486}$$Mg_{0.407}$ $Fe_{1.946}$ $O_4$(group A) and $Cu_{0.263}$$Fe_{0.027}$ $Zn_{0.503}$ $Mg_{0.262}$ $Fe_{1.973}$ $O_4$(group B). Specimens were sintered at different temperatures (1010, 1030, $1050^{\circ}C$) for 2 hours in air followed by an air cooling. Then, effects of various composition and sintering temperatures on the microstructure and the magnetic properties such as inductions, coercive forces, and initial permeabilities of the Cu-Zn-Mg ferrites were investigated. The average grain size increased with the increase of sintering temperature. The magnetic properties obtained from the aforementioned Cu-Zn-Mg ferrite specimens were 1,724 gauss for the maximum induction, 1.0 oersted for the coercive force, and 802 for the initial permeability. These magnetic properties indicated that the specimens could be utilized as the core of IFT (intermediate frequency transformer) and antenna in the amplitude modulation.

• 자원환경지질
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• 제26권4호
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• pp.465-472
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• 1993

The heavy metal contents are more abundant in stream waters, paddy soils and rice plants in the vicinity of abandoned mines compared to the surrounding areas in the Kyungpook province. However, these contents tend to decrease with distance from mines, and show some variation under different geological and geochemical environments. The Sin-stream waters have high contents of Cu=4.9 ppm, Pb=0.1 ppm, Zn=3.5 ppm and other heavy metals (Ni, Co, Cd) at Dalsung abandoned mine and low contents of Cu=0.4 ppm, Pb=0.1 ppm, Zn=0.1 ppm and other metals= 0.002 ppm in the surrounding area. The high contents decrease in the downstream in the area of calcareous sedimentary rocks. The paddy soils have high contents of approximately Cu=51 ppm, Pb=83 ppm, Zn=211 ppm, and Cd=11.3 ppm in the vicinity of Gunwi abandoned mine but low contents of Cu=4.5 ppm, Pb=2.9 ppm, Zn=60 ppm and Cd=0.4 ppm in the surrounding area. The Dadeog abandoned mine also shows similar trends to Gunwi mine. The contents of heavy metals of rice plants are high in the roots but trends to decrease through stem+leaf and become low in brown rices.

• 한국초전도ㆍ저온공학회논문지
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• 제14권3호
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• pp.53-59
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• 2012

Adiabatic demagnetization refrigerator (ADR) for hydrogen re-liquefaction operating between 24 K and 20 K has been designed. $Dy_{0.9}Gd_{0.1}Ni_2$, whose Curie temperature is 24 K, is selected as a magnetic refrigerant. The magnetic refrigerant powder is sintered with oxygen-free high purity copper (OFHC) powder to enhance its effective thermal conductivity as well as to achieve relatively high frequency. A perforated plate heat exchanger (PPHE) operated with forced convection is utilized as a heat switch. The forced convection heat switch is expected to have fast response relative to a conventional gas-gap heat switch. A conduction-cooled high Tc superconducting (HTS) magnet is employed to apply external magnetic field variation on a magnetic refrigerant. $2^{nd}$ generation GdBCO coated conductor HTS tape with Kapton$^{(R)}$ insulation (SUNAM Inc.) will be utilized for the HTS magnet. The magnetization and demagnetization processes are to be achieved by the AC operation of the HTS magnet. The designed magnetic field and target ramp rate of the HTS magnet are over 4 T with 180 A and 0.4 T/s, respectively. AC loss distribution on HTS magnet is theoretically estimated.

• 한국응용과학기술학회지
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• 제10권2호
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• pp.57-63
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• 1993

This study investigated the reaction and variation of fatty acid composition of soybean oil when it is partially hydrogenated until its iodine value(IV) shifts from 134 to 110. Experment was conducted under he outlined reactiion conditions of temperatures(170, 190 and $210^{\circ}C$), pressure(1.3, 2.8 and 4.2atm) and nickel(Ni) catalyst concentraons(0.005, 0.01, 0.05, and 0.1%) with a fixed agitation(350rpm). Further investigation was also made to see the effect of added lecithin on hydrogenation. When reaction temperature was gradually raised and catalyst concentration increased, the content of linolenic acid progressively decreased while the increase amount of stearic acid reduced(P<0.05). On he other hand when pressure gradually increased, the contents of stearic acid and linolenic acid increased(P<0.05). Meanwhile when lecithin was added, reaction time increased by two to six times more than when no addition was made.

• 한국표면공학회지
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• 제30권5호
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• pp.333-346
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• 1997

Plasma spray processes for functional coatings of tubular SOFC ( Soild oxide Fuel Cell).consisting of air electrode, oxide electrolyte, an fuel electrode, are optimized by fully saturated fractional factorial testing. Material and electric characteristics of each coating are analtsed by the implementation of SEM and optical microscope for evaluating microstructure and porosity, X-ray diffraction method for investigating compositional change between raw powder and sprayed coating, and Van der Pauw method for measuring electrical conductivity. LSM ($La_{0.65}Sr_{0.35}MnO_3$air electrode and Ni-YSL fuel electrode coatings have porosities of around 23~30% sufficient for effective fuel and oxidant gas supply to electrochemical reaction interfaces and electrical conductivities of around 90 S/cm and 1000 S/cm, respectively, enough for acting as current collecting electrodes. YSZ($ZrO_2-8mol%Y_2O_3$) electrolyte film has a high ionic conductivities of 0.05~0.07 S/cm at $1000^{\circ}C$ in air atmosphere, but appears to be somewhat too porous to reduce the thickness. for enhancing the cell efficiency. A unit tubular SOFC has beem fabricated by the optimized plasma spray processes for each functional coating and the cell. Its electrochemical chracteristics are investigated by measuring voltage-current and power density with variation of operationg temperature, radio of fuel to air gas flowrates, and total gas flowrate of reactants.

• 마이크로전자및패키징학회지
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• 제20권1호
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• pp.39-43
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• 2013

전기도금법을 이용한 인바합금의 전착시도금층의물성에 외부 작동변수가 미치는 영향을 알아보기 위해 전류밀도, duty cycle, pH, 온도를 변화시켜 도금을실시 한 후 도금층의 조성 변화 등을 분석하였다. 전류밀도와 온도의 변화에 따라 도금층의 조성이 변하였지만 duty cycle, pH, 온도의 변화는 도금층의 조성변화에 거의 영향을 미치지 않는다. 하지만 duty cycle 증가 시에는도금층의 미세구조가 변화하고 경도가 감소하는 경향이 관찰되었다.

• 한국수소및신에너지학회논문집
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• 제22권5호
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• pp.641-648
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• 2011

KEPRI (KEPCO Research Institute) designed and operated the lab-scale high temperature electrolysis (HTE) system for hydrogen production with $10{\times}10cm^2$ 5-cell stack at $750^{\circ}C$. The electrolysis cell consists of Ni-YSZ steam/hydrogen electrode, YSZ electrolyte and LSCF based perovskite as air side electrode. The active area of one cell is 92.16 $cm^2$. The hydrogen production system was operated for 2664 hours and the performance of electrolysis stack was measured by means of current variation with from 6 A to 28 A. The maximum hydrogen production rate and current efficiency was 47.33 NL/hr and 80.90% at 28 A, respectively. As the applied current increased, hydrogen production rate, current efficiency and the degradation rate of stack were increased respectively. From the result of stack performance, optimum operation current of this system was 24 A, considering current efficiencies and cell degradations.

• 한국자기학회지
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• 제10권1호
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• pp.1-6
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• 2000

단롤법으로 제조된 비정질 F $e_{79.7}$ S $i_{9.3}$ $B_{9.7}$N $i_{1.4}$ 합금 리본의 직류중첩특성을 향상시키기 위하여 46$0^{\circ}C$에서 열처리 시간에 따른 자기적 특성과 미세구조의 변화를 조사하였다. 직류중첩특성은 미세구조의 변화와 밀접한 연관성이 있음이 관찰되었다. $\alpha$-Fe 결정립의 크기가 200~300 nm일 경우 가장 효과적으로 자벽 이동을 방해하여 최대 직류중첩특성을 나타내었다. 수지상정의 성장 형태와 분포는 2개의 영역으로 분리되어 나타나며, 이는 리본 제조 시 발생하는 리본 내 과냉도의 차이에 기인한 것이다.한 것이다.