• Title/Summary/Keyword: Ni variation

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Synthesis and Surface Characterization of Carbon Nanotubes by Hot-Filament Plasma Enhanced Chemical Vapor Deposition (Hot-filament 화학기상 증착법에 의한 탄소나노튜브의 성장 및 표면 특성)

  • Choi, Eun-Chang;Kim, Jung-Tae;Park, Yong-Seob;Choi, Won-Seok;Hong, Byung-You
    • Journal of the Korean Vacuum Society
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    • v.16 no.3
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    • pp.187-191
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    • 2007
  • In this paper, the catalyst layer is deposited on silicon substrate using magnetron sputtering system and carbon nanotubes(CNTs) were grown in $NH_3\;and\; C_2H_2$ gas by hot-filament plasma enhanced chemical vapor deposition (HFPECVD) system. A growth temperature of carbon nanotubes was changed from $350^{\circ}C\;to\;650^{\circ}C\;by\;100^{\circ}C$. We observed the shape of CNTs by a field-emission scanning electron microscope(FE-SEM) measurement and analyzed the surface characteristic of CNTs layer by contact angle measurement. That is, the growth temperature of CNTs is the important factor leads to the variation of the properties.

Study on the Chemical Characteristics of $PM_{10}$ at Background Area in Korean Peninsula (한반도 서해안 배경지역 미세입자의 화학적 특성 연구)

  • Bang So-Young;Baek Kwang-Wook;Chung Jin-Do;Nam Jae-Cheol
    • Journal of Environmental Health Sciences
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    • v.30 no.5 s.81
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    • pp.455-468
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    • 2004
  • The purpose of this paper is to understand the time series and origin of a chemical component and to compare the difference during yellow sand episodes for analysis $PM_{10}$ chemical components in the region of west in Korean Peninsula, 1999-2001. An annual mean concentration of $PM_{10}$ is $29.1\;{\mu}g/m^3$. A monthly mean and standard deviation of $PM_{10}$ concentration are very high in spring but there is no remarkably seasonal variation. Also, water soluble ionic component of $PM_{10}$ be influenced by double more total anion than total cation, be included $NO_{3}^-\;and\;SO_{4}^{2-}$ for the source of acidity and $NH_{4}^+$ to neutralize. Tracer metals of $PM_{10}$ slowly increases caused by emitted for soil and ocean (Fe, Al, Ca, Mg, Na) and Zn, Pb, Cu, Mn for anthropogenic source. According to method of enrichment factor (E.F) and statistics, assuming that the origin of metal component in $PM_{10}$ most of element in the Earth's crust e.g. Mg, Ca, Fe originates soil and Cu, Zn, Cd, Pb derives from anthropogenic sources. The ionic component for $Na^{+}\;Cl^-,\;Mg^{2+}\;and\;Ca^{2+}$ and Mg, Al, Ca, Fe originated by soil component largely increase during yellow sand period and then tracer metal component as Pb, Cd, Zn decrease. According to factor analysis, the first group is ionic component ($Na^+,\;Mg^{2+},\;Ca^{2+}$) and metal component (Na, Fe, Mn and Ni) be influenced by soil. The second group, Mg, Cr also be influenced by soil particle.

Long-term Characteristics of PM2.5 and Its Metallic Components in Chuncheon, Korea (춘천시 대기 중 PM2.5 및 금속성분의 장기간 농도 특성)

  • Byun, Jin-Yeo;Cho, Sung-Hwan;Kim, Hyun-Woong;Han, Young-Ji
    • Journal of Korean Society for Atmospheric Environment
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    • v.34 no.3
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    • pp.406-417
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    • 2018
  • In this study, $PM_{2.5}$ samples were collected during approximately 3 years in Chuncheon, a small residential and tourist city, in Korea. The average $PM_{2.5}$ concentration was $26.9{\mu}g/m^3$, exceeding the annual national air quality standard. $PM_{2.5}$ showed typical seasonal variation, having higher concentration in winter and lower concentration in summer. Sixteen metallic elements in $PM_{2.5}$ were also analyzed, and K was the highest contributor especially in late fall and winter. In addition, K considerably increased for the top 10% of $PM_{2.5}$ samples and showed the highest correlation coefficient with $PM_{2.5}$ among all other metallic elements. These results suggest that the combustion of agricultural residue and other biomass, the major source of K was likely to be important to high $PM_{2.5}$ concentration events in this city. Crustal elements including Al, Fe, Si, Ti, Mg showed high concentration in spring while Cr, Cu and Ni were relatively consistent throughout a year. Principal component analysis was used to trace the sources, and soil re-suspension, combustion of biomass and fossil fuels, and asphalt concrete production were identified as the main sources of $PM_{2.5}$.

Variability of measured modal frequencies of a cable-stayed bridge under different wind conditions

  • Ni, Y.Q.;Ko, J.M.;Hua, X.G.;Zhou, H.F.
    • Smart Structures and Systems
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    • v.3 no.3
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    • pp.341-356
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    • 2007
  • A good understanding of normal modal variability of civil structures due to varying environmental conditions such as temperature and wind is important for reliable performance of vibration-based damage detection methods. This paper addresses the quantification of wind-induced modal variability of a cable-stayed bridge making use of one-year monitoring data. In order to discriminate the wind-induced modal variability from the temperature-induced modal variability, the one-year monitoring data are divided into two sets: the first set includes the data obtained under weak wind conditions (hourly-average wind speed less than 2 m/s) during all four seasons, and the second set includes the data obtained under both weak and strong (typhoon) wind conditions during the summer only. The measured modal frequencies and temperatures of the bridge obtained from the first set of data are used to formulate temperature-frequency correlation models by means of artificial neural network technique. Before the second set of data is utilized to quantify the wind-induced modal variability, the effect of temperature on the measured modal frequencies is first eliminated by normalizing these modal frequencies to a reference temperature with the use of the temperature-frequency correlation models. Then the wind-induced modal variability is quantitatively evaluated by correlating the normalized modal frequencies for each mode with the wind speed measurement data. It is revealed that in contrast to the dependence of modal frequencies on temperature, there is no explicit correlation between the modal frequencies and wind intensity. For most of the measured modes, the modal frequencies exhibit a slightly increasing trend with the increase of wind speed in statistical sense. The relative variation of the modal frequencies arising from wind effect (with the maximum hourly-average wind speed up to 17.6 m/s) is estimated to range from 1.61% to 7.87% for the measured 8 modes of the bridge, being notably less than the modal variability caused by temperature effect.

Optical Transmittance Variation to Thickness of Nickel Thin Films (니켈박막의 두께에 따른 광투과율변화)

  • Yang, Ki-Won;Son, Jeong-Sik;Kwak, Ho-Weon;Lee, Haeng Ki;Park, Sang Chul
    • Journal of Korean Ophthalmic Optics Society
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    • v.13 no.1
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    • pp.49-52
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    • 2008
  • To study the optical transmittance through nickel thin films with various thicknesses. Methods: We measured the optical transmittance through thin nickel film with various thicknesses. Results: The thickness dependence of the optical transmittance through nickel thin films deposited by thermal evaporation had been investigated. The optical transmittance rapidly decreased with the Ni film thickness less than 70 nm while it slightly decreased with the thickness more than 70 nm. In the experiment of optical dispersion, most of the light transmitted in the incidence direction. The result of experiment showed that optical dispersion was negligibly. Conclusions: Optical transmittance exponentially decreased as nickel thin film thickness increased.

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Metal Concentrations in some Brown Seaweeds from Kongsfjorden on Spitsbergen, Svalbard Islands (스발바드군도 스피츠베르겐섬 콩스피요르드에 서식하는 갈조류의 중금속 농도)

  • Ahn, In-Young;Choi, Hee-Seon;Ji, Jung-Youn;Chung, Ho-Sung;Kim, Ji-Hee
    • Ocean and Polar Research
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    • v.26 no.2
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    • pp.121-132
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    • 2004
  • Concentrations of Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb, Zn were determined in four arctic brown algae (Laminaria saccharina, L. digitata, Alaria esculenta, Desmarestia aculeata) in an attempt to examine for their metal accumulation capacity and also to assess their contamination levels. Macroalgae were collected from shallow subtidal waters (<20m) of Kongsfjorden (Kings Bay) on Spitsbergen during the period of the late July to early August 2003. Metal concentrations highly varied between sampling sites, species and tissue parts. Input of melt-water laden with terrigenous sediment particles seemed to have a large influence on baseline accumulations of some metals (Al, Fe, Mn, Pb etc.) in the macroalgae, causing a significant spatial variation. There were also significant concentration differences between the young and old tissue parts in L. saccharina, L. digitata and A. esculenta. While Al, Fe, Mn, Pb were higher in the perennial parts (stipes and holdfast below meristematic region), Cd and As concentrations were significantly higher in the young blades above the meristematic region. Zn and Cr, on the other hand, showed little differences between the tissue parts. The highest metal concentrations were found in D. aculeata, which seems to be due to its filamentous fine branches leading to high surface/volume ratios. The lowest concentrations were found in the two Laminaria spp., the blades of which are thicker than D. aculeata and A. esculenta. No distinct signs of contamination were detected in the brown algal species analyzed. Added to this, the results of the present studies suggest the potential utility of L. saccharina, L. digitata and A. esculenta as biomonitors for metal pollution monitoring in this area.

Variability of Surface Chlorophyll Concentration in the Northwest Pacific Ocean (북서태평양의 표층엽록소 변동성)

  • Park, Ji-Soo;Suk, Moon-Sik;Yoon, Suk;Yoo, Sin-Jae
    • Ocean and Polar Research
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    • v.30 no.3
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    • pp.277-287
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    • 2008
  • We collected information on seasonal and interannual variability of surface chlorophyll a concentration between 1997-2007 from the Northwest Pacific Ocean. Satellite data were used to acquire chlorophyll a and sea surface temperature from six regions: East Sea/Ulleung Basin, East China Sea, Philippin Sea, Warm Pool region, Warm Pool North region, and Warm Pool East region. Mixed layer depth (MLD) was calculated from temperature profiles of ARGO floats data in four of the six regions during 2002-2007. In the East Sea/Ulleung Basin, seasonal variability of chlorophyll a concentration was attributed to seasonal change of MLD, while there was no significant relationship between chlorophyll a concentration and MLD in the Warm Pool region. Interannual anomaly in sea surface temperature were similar among the East Sea, East China Sea, Philippin Sea, and Warm Pool North region. The anomaly pattern was reversed in the Warm Pool East region. However, the anomaly pattern in the Warm Pool region was intermediate of the two patterns. In relation to chlorophyll a, there was a reversed interannual anomaly pattern between Warm Pool North and Warm Pool East, while the anomaly pattern in the Warm Pool region was similar to that of Warm Pool North except for the El $Ni\tilde{n}o$ years (1997/1998, 2002/2003, 2006/2007). However, there was no distinct relationship among other seas. Interestingly, in the Warm Pool and Warm Pool East regions, sea surface temperature showed a pronounced inverse pattern with chlorophyll a. This indicates a strong interrelationship among sea surface temperature-MLD-chlorophyll a in the regions. In the Warm Pool and Warm Pool East, zonal distribution of chlorophyll a concentration within the past 10 years has shown a good relationship with sea surface temperature which reflects ENSO variability.

Modeling of temperature distribution in a reinforced concrete supertall structure based on structural health monitoring data

  • Ni, Y.Q.;Ye, X.W.;Lin, K.C.;Liao, W.Y.
    • Computers and Concrete
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    • v.8 no.3
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    • pp.293-309
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    • 2011
  • A long-term structural health monitoring (SHM) system comprising over 700 sensors of sixteen types has been implemented on the Guangzhou Television and Sightseeing Tower (GTST) of 610 m high for real-time monitoring of the structure at both construction and service stages. As part of this sophisticated SHM system, 48 temperature sensors have been deployed at 12 cross-sections of the reinforced concrete inner structure of the GTST to provide on-line monitoring via a wireless data transmission system. In this paper, the differential temperature profiles in the reinforced concrete inner structure of the GTST, which are mainly caused by solar radiation, are recognized from the monitoring data with the purpose of understanding the temperature-induced structural internal forces and deformations. After a careful examination of the pre-classified temperature measurement data obtained under sunny days and non-sunny days, common characteristic of the daily temperature variation is observed from the data acquired in sunny days. Making use of 60-day temperature measurement data obtained in sunny days, statistical patterns of the daily rising temperature and daily descending temperature are synthesized, and temperature distribution models of the reinforced concrete inner structure of the GTST are formulated using linear regression analysis. The developed monitoring-based temperature distribution models will serve as a reliable input for numerical prediction of the temperature-induced deformations and provide a robust basis to facilitate the design and construction of similar structures in consideration of thermal effects.

Characteristics of Reliability for Flip Chip Package with Non-conductive paste (비전도성 접착제가 사용된 플립칩 패키지의 신뢰성에 관한 연구)

  • Noh, Bo-In;Lee, Jong-Bum;Won, Sung-Ho;Jung, Seung-Boo
    • Journal of the Microelectronics and Packaging Society
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    • v.14 no.4
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    • pp.9-14
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    • 2007
  • In this study, the thermal reliability on flip chip package with non-conductive pastes (NCPs) was evaluated under accelerated conditions. As the number of thermal shock cycle and the dwell time of temperature and humidity condition increased, the electrical resistance of the flip chip package with NCPs increased. These phenomenon was occurred by the crack between Au bump and Au bump and the delamination between chip or substrate and NCPs during the thermal shock and temperature and humidity tests. And the variation of electrical resistance during temperature and humidity test was larger than that during thermal shock test. Therefore it was identified that the flip chip package with NCPs was sensitive to environment with moisture.

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Ionic and Elemental Compositions of PM2.5 at the 1,100 m-Highland of Mt. Hallasan in Jeju Island (한라산 1,100 m 지역의 대기 중 PM2.5에 함유된 이온 및 원소 성분의 조성특성)

  • Lee, Ki-Ho;Hu, Chul-Goo
    • Journal of Environmental Science International
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    • v.25 no.6
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    • pp.865-875
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    • 2016
  • In this study, mass concentrations and chemical compositions of $PM_{2.5}$, including water-soluble ions and elements were determined at the 1,100 m-highland of Mt. Hallasan in Jeju Island across four seasons from August 2013 to August 2014. The average mass concentration of $PM_{2.5}$ was $12.5{\pm}8.41{\mu}g/m^3$ with 45.8% of the contribution from eight water-soluble ionic species. Three ionic species ($SO{_4}^{2-}$, $NH{_4}^+$, and $NO{_3}^-$) comprised 96.2% of the total concentration of ions contained in $PM_{2.5}$ and were the dominant ions, accounting for 43.5% of the $PM_{2.5}$ mass at Mt. Hallasan. On the basis of the mass concentration level, seasonal variation, enrichment factor, and relationship among elements, we can presume that Mg, K, Ca, Mn, Fe, Co, Sr, Ba, Nd, and Dy originated mainly from crust or soil and that V, Cr, Ni, Cu, Zn, As, Cd, and Pb were significantly enriched in $PM_{2.5}$ owing to the effects of the anthropogenic emissions. These results and the local distribution of emission sources and topographic characteristics near this sampling site suggest that the compositions of $PM_{2.5}$ collected at the 1100 m-highland of Mt. Hallasan were largely influenced by inflow from outside of Jeju Island.