• Title/Summary/Keyword: Ni loss

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Electrodeposited Nano-flakes of Manganese Oxide on Macroporous Ni Electrode Exhibiting High Pseudocapacitance

  • Gobal, F.;Jafarzadeh, S.
    • Journal of Electrochemical Science and Technology
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    • v.3 no.4
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    • pp.178-184
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    • 2012
  • A porous nickel (P-Ni) substrate was prepared by selective leaching of zinc from pressed pellets containing powders of Ni & Zn in 4 M NaOH solution. Anodic deposition of manganese oxide onto the porous Ni substrate ($MnO_x$/P-Ni) formed nano-flakes of manganese oxide layers as revealed in SEM studies. Pseudocapacitance of this oxide electrode was evaluated by cyclic voltammetry (CV) and chronopotentiometry (CHP) in 2 M NaOH solution. The specific capacitance of the Mn oxide electrode was as high as 1515 F $g^{-1}$, which was ten times higher than Mn oxide deposited on a flat Ni-ribbon. 80% of capacity was retained after 200 charge/discharge cycles. The system showed no loss of activity in dry form over period of days. The impedance studies indicated highly conducting $MnO_x$/P-Ni substance and the obtained specific capacitance from impedance data showed good agreement with the charge/discharge measurements.

Magnetic Properties of Magnetic Core Materials for PLC as a Funtion to Additives (PLC용 자심재료의 협가제에 따른 자기적 특성의 변화)

  • An, Yong-Woon;Kim, Jong-Ryung;Oh, Young-Woo
    • Journal of the Korean Magnetics Society
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    • v.13 no.6
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    • pp.246-250
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    • 2003
  • The electromagnetic properties of Ni$\_$0.8/Zn$\_$0.2/Fe$_2$O$_4$ having stable characteristics in high frequency range were investigated as functions of Bi$_2$O$_3$, CaO contents. Power loss increased in proportion to the amount of Bi$_2$O$_3$ up to 0.3 wt% and decreased over 0.3 wt%. Also, permeability increased with Bi$_2$O$_3$ contents. The lowest power loss and highest resonance frequency were obtained to the specimens added Bi$_2$O$_3$ of 0.7wt% and CaO of 0.3 wt% due to creation of resistivity layers in the grain boundaries originated by the solid solution of Bi$_2$O$_3$ and CaO.

Physical Properties of Polycrystalline Mn2O3-Substituted LiNiBi Ferrite (Mn2O3가 LiNiBi Ferrite의 물리적 특성에 미치는 영향)

  • Koh Sae Gui
    • Korean Journal of Materials Research
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    • v.14 no.9
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    • pp.655-658
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    • 2004
  • Lithium ferrites are a low-cost material which have been prominent in the high frequency core industry because of their excellent temperature performance and high squareness ratio. In order to develope the lithium ferrites with the high squareness and low coercive force, the ferrites of $Li_{0.48}Bi_{0.02}Ni_{0.04}Fe_{2.46-x}O_4$ were investigated the by varying composition, temperature and frequency. Electric loss of the Li-ferrite was lowered with the substitution of $Mn_{2}O_3$. The addition of $Mn_{2}O_3$ increased the magnetic induction (Bm&Br) but decreased the coercive force (Hc) and the squareness ratio (R=Br/Bm). Also, the Br value was stable at environmental temperature variation.

The study on frequency characteristics of attenuator fabricated by Ni-Cr thin films (Ni-Cr 박막으로 제작한 attenuator에 대한 주파수 특성연구)

  • Kim, D.J.;Ryu, J.C.;Koo, B.K.;Kang, B.D.;Kim, K.T.;Song, Y.S.;Yu, K.M.;Kim, J.H.
    • Proceedings of the KIEE Conference
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    • 2000.07c
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    • pp.1637-1639
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    • 2000
  • Resister networks are used widely in many, high frequency applications for attenuators. In this paper we studied the frequency characteristics of attenuator using network analyzer and compared Ni-Cr thin film resistor with thick film resistor attenuator. Also from return loss, insertion loss and VSWR we obtained the maximum available frequency of these attenuators.

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Energy Band Structure, Electronic and Optical properties of Transparent Conducting Nickel Oxide Thin Films on $SiO_2$/Si substrate

  • Denny, Yus Rama;Lee, Sang-Su;Lee, Kang-Il;Lee, Sun-Young;Kang, Hee-Jae;Heo, Sung;Chung, Jae-Gwan;Lee, Jae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.347-347
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    • 2012
  • Nickel Oxide (NiO) is a transition metal oxide of the rock salt structure that has a wide band gap of 3.5 eV. It has a variety of specialized applications due to its excellent chemical stability, optical, electrical and magnetic properties. In this study, we concentrated on the application of NiO thin film for transparent conducting oxide. The energy band structure, electronic and optical properties of Nickel Oxide (NiO) thin films grown on Si by using electron beam evaporation were investigated by X-Ray Photoelectron Spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and UV-Spectrometer. The band gap of NiO thin films determined by REELS spectra was 3.53 eV for the primary energies of 1.5 keV. The valence-band offset (VBO) of NiO thin films investigated by XPS was 3.88 eV and the conduction-band offset (CBO) was 1.59 eV. The UV-spectra analysis showed that the optical transmittance of the NiO thin film was 84% in the visible light region within an error of ${\pm}1%$ and the optical band gap for indirect band gap was 3.53 eV which is well agreement with estimated by REELS. The dielectric function was determined using the REELS spectra in conjunction with the Quantitative Analysis of Electron Energy Loss Spectra (QUEELS)-${\varepsilon}({\kappa},{\omega})$-REELS software. The Energy Loss Function (ELF) appeared at 4.8, 8.2, 22.5, 38.6, and 67.0 eV. The results are in good agreement with the previous study [1]. The transmission coefficient of NiO thin films calculated by QUEELS-REELS was 85% in the visible region, we confirmed that the optical transmittance values obtained with UV-Spectrometer is the same as that of estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS within uncertainty. The inelastic mean free path (IMFP) estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS is consistent with the IMFP values determined by the Tanuma-Powell Penn (TPP2M) formula [2]. Our results showed that the IMFP of NiO thin films was increased with increasing primary energies. The quantitative analysis of REELS provides us with a straightforward way to determine the electronic and optical properties of transparent thin film materials.

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Electromagetic Wave Absorbing Properties of $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$(X=Cu, Mg, Mn)-Rubber Composite ($Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$(X=Cu, Mg, Mn)-Rubber Composite의 전파흡수특성에 관한 연구)

  • Im, Hui-Dae;Yun, Guk-Tae;Lee, Chan-Gyu
    • Korean Journal of Materials Research
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    • v.9 no.12
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    • pp.1234-1239
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    • 1999
  • Electromagnetic wave asorbing properties of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$, where X was replaced by substitution elements Cu, Mg, Mn, have been studied. The structure, shape, size and magnetic properties of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$ were analyzed by XRD, SEM, VSM. The relative complex permittivity, permeability, and electromagnetic wave absorbing properties were measured by Network Analyzer. The structure, shape, size and magnetization value of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$ were found to be similar in spite of substitution elements. The coercive force and hysteresis-loss showed maximum value when Mg was substituted for X. The dielectric loss(${\varepsilon}_r"/{\varepsilon}_r'$) was found to be maximum value when Mn was substituted for X. Also the magnetic loss(${\mu}_r"/{\mu}_r'$} was found to be maximum with Cu substitution. The electromagnetica wave absorbing property of the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$-Rubber composite with 4mm thickness was excellent as over - 40dB at 9GHz, and the $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$-Rubber composite with 8mm thickness was over-40dB at 2GHz. Those composites also showed superior microwave absorbing properties.

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Effects of Sheet Thickness on the Electromagnetic Wave Absorbing Characterization of Li0.375Ni0.375Zn0.25-Ferrite Composite as a Radiation Absorbent Material

  • Kim, Dong-Young;Yoon, Young-Ho;Jo, Kwan-Jun;Jung, Gil-Bong;An, Chong-Chul
    • Journal of electromagnetic engineering and science
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    • v.16 no.3
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    • pp.150-158
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    • 2016
  • This paper reports on a study of LiNiZn-ferrite composite as a radiation absorbent material (RAM). The electromagnetic (EM) wave absorbers are composed of an EM wave absorbing material and a polymeric binder. The surface morphology, chemical composition, weight percent of the ferrite composite of the toroid sample, magnetic properties, and return loss are investigated using field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), and network analyzer. For preparing the absorbing sheet, chlorinated polyethylene (CPE) is used as a polymeric binder. The EM wave absorption properties of the prepared samples were studied at 4 - 8 GHz. We can confirm the effects of the thickness of the samples for absorption properties. An absorption bandwidth of more than a 10-dB return loss shifts toward a lower frequency range along with an increase in the thickness of the absorber.

Dependence of the physical properties for magnetic core materials on the concentrations of $Bi_2O_3$ and CaO ($Bi_2O_3$와 CaO 첨가에 따른 PLC용 자심 재료의 물성)

  • An, Y.W.;Lee, H.Y.;Kim, J.R.;Kim, H.S.;Oh, Y.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.04a
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    • pp.64-67
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    • 2002
  • The Physical and magnetic properties such as microstructure, permeability and power loss of Ni-Zn ferrite with composition of $Ni_{0.8}Zn_{0.2}Fe_2O_4$, were investigated as the function of $Bi_2O_3$ and CaO contents. The power loss increased in proportion to the amount of $Bi_2O_3$ up to 0.3 wt% but it decreased over than 0.3 wt% addition. The highest permeability of 134 was obtained to the specimen added 1.0 wt% $Bi_2O_3$ since $Bi_2O_3$ contents were strongly dominant to grain growth and size than that of CaO. $Bi_2O_3$ liquid phase created during sintering process promoted sintering and grain growth so that grain size and permeability increased compared to that of the specimens which were sintered with free-additive and CaO. Also, lots of pores existed in the specimen which was added $Bi_2O_3$ wt% with the biggest grain size.

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THE INVESTIGATION OF PSEUDOELASTIC NITI WIRES FOR DAMPING USES

  • Pan, Qiang;Cho, Chong-Du;Lu, Sheng
    • Proceedings of the KSME Conference
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    • 2007.05a
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    • pp.154-159
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    • 2007
  • Some shape memory alloys like NiTi show noticeable high damping property in pseudoelastic range. Due to its instinct characteristics, a NiTi alloy is commonly used for passive damping applications, in which the energy may be dissipated by the conversion from mechanical to thermal energy. Previous researches found the NiTi wires own higher damping property than the bars; therefore the wire form is adopted in this study. A loss factor is introduced for measuring the damping property of the NiTi wires. The experimental observation shows the mechanical behaviors of NiTi wires are dependent on temperature, strain rate and strain amplitude. Moreover, it is found the first several decades of loading-unloading cycles can obviously influence the property of NiTi wires under the same working conditions.

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Effects of Heat-treatments on Discharge Characteristics of TiFe1-xNix Alloy Electrodes for Ni/MH Secondary Battery (Ni/MH 2차전지용 TiFe1-xNix 합금전극의 방전특성에 대한 열처리의 영향)

  • Joung, Soon-dol;Joung, Sang-sik;Ahn, Hyo-jun;Kim, Ki-won
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.4
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    • pp.135-141
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    • 1998
  • The effects of heat-treatment on discharge characteristics of $TiFe_{1-x}Ni_x$ alloy were investigated. The content of Ni in alloy was varied from x = 0.1 to 0.6 by each 0.1 increment. Discharge capacity change of each alloy with C/D cycles was measured. With increasing Ni-content initial discharge capacity was increased. but at x = 0.6 it was deceased again. With increasing C/D cycles discharge capacity was rapidly decreased in the alloy of high Ni-content. In order to investigate the effects of heat-treatment on cycle life, $TiFe_{0.5}Ni_{0.5}$ alloy having maximum initial discharge capacity was heat-treated at various temperatures in the range of $700{\sim}900^{\circ}C$ and tested. The loss of initial discharge capacity was appeared at all temperatures. but cycle characteristics of the alloy was improved. The electrodes heat-treated for 1 hour in the range of $700{\sim}850^{\circ}C$ showed good recovery of discharge capacities through repeated cycles, and from SEM observation results these were considered as 1 hour in the range of $700{\sim}850^{\circ}C$ showed good recovery of discharge capacities through repeated cycles, and from SEM observation results these were considered asbeing due to increased electrode strength and small loss of porosity during heat-treatment. The electrode heat-treated for 1 hour at $900^{\circ}C$ showed poor discharge characteristics because of low porosity.

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