• Title/Summary/Keyword: Ni loss

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Microwave dielectric properties of Forsterite based Ceramics (포스테라이트계 유전체의 마이크로파 유전특성)

  • Kim, Dong-Young;Lee, Hong-Yeol;Jun, Dong-Suk;Lee, Sang-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.279-282
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    • 2003
  • For the millimeter-wave dielectrics, Forsterite-based ceramics were produced. Pure forsterite ceramics($Mg_2SiO_4$) shows porous micro-structure and very low Q*f values, which is not suitable for the dielectrics for the millimeter-wave band. Several sintering aids including $Al_2O_3$, $Li_2CO_3$, $Li_2SiO_4$, were added to the forsterite ceramics in order to produce dense low-loss dielectrics. Among these additives, $Li_2CO_3$ is the most effective sintering aids. Several sub-components including NiO, ZnO, $SnO_2$, $TiO_2$, were added to enhance the microwave dielectric properties. $TiO_2$ is the most effective additive to enhance the dielectric properties at microwave bands. The simultaneous addition of $TiO_2$ and $Li_2CO_3$ increases Q*f value over 170,000, which can be used as dielectrics in millimeter-wave bands.

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A Study on the Cyclic Oxidation Properties of Aluminum Diffusion Coated Materials (알루미늄 확산코팅재료의 주기산화 특성에 관한 연구)

  • 강석철;민경만;김길무
    • Journal of the Korean institute of surface engineering
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    • v.32 no.1
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    • pp.49-60
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    • 1999
  • The protective oxide scales and coatings formed on high temperature materials must be preserved in high temperature atmosphere. And the thermal stresses induced by thermal cycling and the growth stresses by the formation of oxide scales can cause the loss of adherence and spalling of the oxide scales and coated layers. Among the coating processes Al diffusion coating is favored due to thermochemical stability and superior adherence in an hostile atmosphere. In this study, protective oxide forming element, Al was coated on Ni, Inconel 600 and 690 by diffusion coating process varying coating temperature and time. And the surface stability and adherence of oxide scales formed on those Al diffusion coated materials were evaluated by thermal cycling test. Al diffusion coated specimens showed superior cyclic oxidation resistance compared to bare ones and specimens coated for longer period had better cyclic oxidation resistance, due to the abundant amount of Al in the coated layer. Meanwhile Al diffusion coated Inconel 600 and 690 showed improved cyclic oxidation resistance by the effect of Al in the coated layer and Cr in the substrate. Comparing both Al diffusion coated Inconel 600 and 690, Al diffusion coated Inconel 690 maintained better adhesion between coated layer and substrate by virtue of the bridging effect resulting from the segregation of Cr in the interdiffusion zone.

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Cavitation-Erosion Characteristics of the Stainless Steel with Adding Ti Stabilizer Element in Sea Water (안정화 원소 Ti 첨가에 따른 스테인리스강의 해수 내 캐비테이션-침식 특성)

  • Choi, Yong-Won;Yang, Ye-Jin;Kim, Seong-Jong
    • Journal of the Korean institute of surface engineering
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    • v.49 no.4
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    • pp.344-348
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    • 2016
  • Stainless steel is widely applied in many industrial fields due to its excellent anti-corrosion and durability characteristics. However, stainless steel is very vulnerable to cavitation attack caused by high speed flow of fluid in the chloride environments such as marine environment. These conditions promote intergranular corrosion and cavitation-erosion, leading to degradation of the structural integrity and service life. In order to prevent these problems, the stabilized stainless steel is applied to the offshore and shipbuilding industries. In this study, Ti was added to 19%Cr-9%Ni as the stabilizer element with different concentrations (0.26%, 0.71%), and their durabilities were evaluated with cavitation-erosion experiment by a modified ASTM G32 method. The microstructural change was observed with the stabilizer element contents. The result of the observation indicated that the amount of carbide precipitation was decreased and its size became finer with increasing Ti content. In the cavitation-erosion experiment, both weight loss and surface damage depth represented an inverse proportional relationship with the amount of Ti element. Consequently, the stainless steel containing 0.71% of Ti had excellent durability characteristics.

Effects of Pulse-Reverse Current on Purity of Deposit in Electrowinning of Cobalt (코발트 전해채취 시 전착물 순도에 미치는 Pulse-Reverse Current의 영향)

  • Han, Jung Min;Lee, Jung Hoon;Kim, Yong Hwan;Jung, Uoo Chang;Chung, Won Sub
    • Korean Journal of Metals and Materials
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    • v.48 no.11
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    • pp.1014-1020
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    • 2010
  • In order to improve the purity on deposit in cobalt electrowining, a fundamental study using Pulse-Reverse Current (PRC) was carried out. Based on a sulfate solution, Cu, Ni, and Fe as impurities were added during cobalt electrowinning. There were four reverse waveforms and frequency conditions from 1 Hz to 10 kHz, and the purity of each condition was compared with the Direct Current (DC) purity. From the results, it was found that the anodic potential induced by reverse current affects selective dissolution of impurities. In this work, the case of the highest reverse peak current density ($I_r$) with a short reverse time ($t_r$) at 100 Hz showed a higher purity than that of the DC. This PRC condition also showed only a 4% low current efficiency comparable to the DC. We concluded that an optimized PRC for cobalt electrowinning could improve the purity with little loss of current efficiency.

Electrochemical Corrosion Damage Characteristics of Austenite Stainless Steel and Nickel Alloy with Various Seawater Concentrations (오스테나이트계 스테인리스강과 니켈합금의 해수 농도 변화에 따른 전기화학적 부식 손상 특성)

  • Heo, Ho-Seong;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.281-288
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    • 2021
  • Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10-4 mA/cm2 and 1.11 × 10-4 mA/cm2 and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

Review on sodium corrosion evolution of nuclear-grade 316 stainless steel for sodium-cooled fast reactor applications

  • Dai, Yaonan;Zheng, Xiaotao;Ding, Peishan
    • Nuclear Engineering and Technology
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    • v.53 no.11
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    • pp.3474-3490
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    • 2021
  • Sodium-cooled fast reactor (SFR) is the preferred technology of the generation-IV fast neutron reactor, and its core body mainly uses nuclear-grade 316 stainless steel. In order to prolong the design life of SFRs to 60 years and more, it is necessary to summarize and analyze the anti-corrosion effect of nuclear grade 316 stainless steel in high temperature sodium environment. The research on sodium corrosion of nuclear grade 316 stainless steel is mainly composed of several important factors, including the microstructure of stainless steel (ferrite layer, degradation layer, etc.), the trace chemical elements of stainless steel (Cr, Ni and Mo, etc) and liquid impurity elements in sodium (O, C and N, etc), carburization and mechanical properties of stainless steel, etc. Through summarizing and constructing the sodium corrosion rate equations of nuclear grade 316 stainless steel, the stainless steel loss of thickness can be predicted. By analyzing the effects of temperature, oxygen content in sodium and velocity of sodium on corrosion rate, the basis for establishing integrity evaluation standard of SFR core components with sodium corrosion is provided.

Development of Hardware and Monitoring Software for Stable Operation of Fire Pumps (소방펌프의 안정적 운영을 위한 하드웨어 및 모니터링 소프트웨어 개발)

  • Ku, Bonhyu;Kim, Doo-Hyun;Kim, Sung-Chul
    • Journal of the Korean Society of Safety
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    • v.37 no.4
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    • pp.28-35
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    • 2022
  • This study is aimed to develop a safety diagnosis system for fire pumps that detects normal and abnormal signals for the stable operation of the system. Hence, the following activities were carried out: first, a threshold value was identified for the normal operation and six abnormal operations (adherence of impeller, absence of water source, separation of pump and motor, run-stop operation, air inflow into the casing, and reverse-phase loss of the power line) reflecting changes in the current, flow and pressure of fire pumps; secondly, based on the identified signals, an algorithm capable of detecting three abnormal signals was developed and in terms of hardware, a current, pressure and flow sensor suitable for the analogue input values of NI-6009 was designed and installed. This combination of the hardware and software is applicable as a diagnosis system to ensure the stable operation of fire pumps.

Recent Studies on Area Selective Atomic Layer Deposition of Elemental Metals (단일 원소 금속의 영역 선택적 원자층 증착법 연구 동향)

  • Min Gyoo Cho;Jae Hee Go;Byung Joon Choi
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.156-168
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    • 2023
  • The semiconductor industry faces physical limitations due to its top-down manufacturing processes. High cost of EUV equipment, time loss during tens or hundreds of photolithography steps, overlay, etch process errors, and contamination issues owing to photolithography still exist and may become more serious with the miniaturization of semiconductor devices. Therefore, a bottom-up approach is required to overcome these issues. The key technology that enables bottom-up semiconductor manufacturing is area-selective atomic layer deposition (ASALD). Here, various ASALD processes for elemental metals, such as Co, Cu, Ir, Ni, Pt, and Ru, are reviewed. Surface treatments using chemical species, such as self-assembled monolayers and small-molecule inhibitors, to control the hydrophilicity of the surface have been introduced. Finally, we discuss the future applications of metal ASALD processes.

The effects of the scattering opacity and the color temperature on numerically modelling of the first peak of type IIb supernovae

  • Park, Seong Hyun;Yoon, Sung-Chul
    • The Bulletin of The Korean Astronomical Society
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    • v.45 no.1
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    • pp.70.1-70.1
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    • 2020
  • A type IIb supernova (SN IIb) is the result of core-collapse of a massive star which lost most of its hydrogen-rich envelope during its evolution. The pre-SN progenitor properties, such as the total radius and the mass of the hydrogen-rich envelope, can widely vary due to the mass-loss history of the progenitors. Optical light curves of SNe IIb are dominated by energy released by the hydrogen recombination and the radioactive decay of 56Ni in the early and late epochs respectively. This may result in distinctive double peaked light curves like the one observed in SN 1993J. The first peak, caused by the hydrogen recombination, can be modelled with numerical simulations providing information on the pre-SN progenitor properties. We compare two radiation-hydrodynamics codes, STELLA and SNEC, that are frequently used in SNe modelling, and investigate the effect of opacity treatment on the temporal evolution of the color temperature of SNe and eventually on the optical light curves. We find that with a proper treatment of the scattering opacity, SNe IIb models exploded from the progenitor models evolved with latest stellar evolution model hardly match the observational data. We also discuss the smaller scale features found in the models during hydrogen recombination phase.

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Geochemical Characteristics and Heavy Metal Pollutions in the Surface Sediments of Oyster Farms in Goseong Bay, Korea (고성만 굴 양식장 표층퇴적물의 지화학적특성과 중금속 오염에 관한 연구)

  • Kang, Ju-Hyun;Lee, Sang-Jun;Jeong, Woo-Geon;Cho, Sang-Man
    • The Korean Journal of Malacology
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    • v.28 no.3
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    • pp.233-244
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    • 2012
  • Goseong bay, located in southeast sea of Korea with an area of 2,100 ha, is a semi-enclosed bay well-known for oyster farming cultured in an extended range of 148 ha. The objective of this study is to provide the fundamental data in order to manage the effective sea area. A total 26 of surface sediment were collected from Goseong bay to evaluate their sedimentary environment and heavy metals. The loss on Ignition (LOI), C/N ratio, acid volatile sulfide (AVS) and heavy metals were analyzed. loss on ignition (LOI) of surface sediment range from 1.00% to 3.03% (average 2.00%). The carbonate content ranges from 0.52% to 4.29% (average 2.37%). C/N ratio of organic matter showed that most part of organic matter comes from neighboring continent. Acid volatile sulfide (AVS) value of surface sediment from 0.02 mg/g to 1.43 mg/g (average 0.24 mg/g). A ten element of surface sediments (Al, As, Cd, Cr, Cu, Hg, Ni, Pb, V, Zn) were calculated by enrichment factor (Ef) and the results show that some areas are highly polluted with respect Cu and Hg. The correlation matrix displays the existence of remarkable levels of correlation with both positive and negative values among different variable pairs. LOI and AVS showed both positive values. LOI and AVS values falls under 2% and 1%. Therefore, Goseong bay showed good in quality of sediment.