• Title/Summary/Keyword: Ni addition

Search Result 1,051, Processing Time 0.03 seconds

Development of cube textured Ni-W alloy substrates for YBCO coated conductor (YBCO Coated Conductor를 위한 Cube texture Ni-W 합금 기판의 제작 및 특성평가)

  • 김규태;임준형;장석헌;김정호;주진호;김호진;지봉기;전병혁;김찬중
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
    • /
    • 2003.10a
    • /
    • pp.106-108
    • /
    • 2003
  • We fabricated Ni and Ni-W alloys for use as a substrate in YBCO coated conductor applications and evaluated the effect of W in Ni on texture, microstructure and surface morphology, and hardness of substrate. Pure Ni, Ni-2 at.%W, and Ni-5at.%W alloy substrates were prepared by plasma arc melting, cold rolling, and the recrystallization heat treatment at various temperature (700- 130$0^{\circ}C$). It was observed that Ni-W alloy substrates had stronger cube texture and maintained it at higher annealing temperature, compared to pure Ni substrate : The full-width at half- maximums of in-plane texture was 13.40$^{\circ}$ for Ni substrate and 4.42$^{\circ}$-5.57$^{\circ}$ for Ni-W substrate annealed at 100$0^{\circ}C$. In addition, it was observed that the Ni-W substrate had smaller grain size, shallower boundary depth, and higher hardness, compared to those of pure Ni substrate.

  • PDF

Effect of Surface Treatment on Bioactivity of Ti-Ni Shape Memory Alloys (Ti-Ni형상기억합금의 생체활성에 미치는 표면처리의 영향)

  • Choi, Mi-Seon;Nam, Tae-Hyun
    • Korean Journal of Metals and Materials
    • /
    • v.47 no.12
    • /
    • pp.881-886
    • /
    • 2009
  • Research into the replacement of injured systems and tissue in the human body is advancing rapidly. Recently, Ti-Ni shape memory alloys have shown excellent biofunctionality related to their shape memory effect and superelasticity. In this study, the effect of an acid or an alkali treatment on the bioactivity in 49Ti-Ni and 51.5Ti-48.5Ni alloys is investigated in an effort to utilize Ti-Ni alloy as a biomaterial. In addition, the biocompatibility in a SBF solution is assessed through in vitro testing. A porous surface was formed on the surface of both alloys after a chemical treatment. According to the in vitro test, apatite formed on the surfaces of both alloys. The forming rate of apatite in the Ti-rich alloy was faster that in the Ni-rich alloy. The formation of apatite provided proof of the bioactivity of the Ti-Ni alloy. A small quantity of Ni was eluted at the initial stage, whereas Ni was not found for 12 days in the Ti-rich alloy and for 8 days in the Ni-rich alloy. In the case of the treated 51.5Ti-Ni alloy, the shape memory property was worsened but the biocompatibility was improved.

Effects of F-treatment on the Degradation of $Mg_2$Ni type Hydrogen Storage Alloy Electrode ($Mg_2$Ni계 수소저장합금전극의 퇴화거동에 미치는 불화 처리 영향)

  • Kim, Jun-Seong;Choe, Jae-Ung;Lee, Chang-Rae;Gang, Seong-Gun
    • Korean Journal of Materials Research
    • /
    • v.11 no.4
    • /
    • pp.294-299
    • /
    • 2001
  • Effects of the surface fluorination on the electrochemical charge-discharge properties of $Mg_2$Ni electrode in Ni-MH batteries fabricated by mechanical alloying were investigated. After 20h ball milling, Mg and Ni powder formed nanocrystalline $Mg_2$Ni. Discharge capacity of this alloy increased greatly at first one cycle, but due to the formation of Mg(OH)$_2$ passive layer, it showed a rapid degradation in alkaline solution within 10cyc1es. In case of 6N KOH +xN KF electrolyte (x = 0.5, 1, 2), a continuous and stable fluorinated layer formed by adding excess F$^{[-10]}$ ion, increased durability of $Mg_2$Ni electrode greatly and high rate discharge capability(90-100mAh/g). 2N KF addition led to the highest durability of all tested here. The reason of the improvement is due to thin MgF$_2$, which can prevent the $Mg_2$Ni electrode from forming Mg(OH)$_2$layer that is the main cause of degradation.

  • PDF

Pyroelectricity of Ni-doped PMNT Ferroelectric for Pyroelectric Detector

  • Kim, Yeon Jung
    • Applied Science and Convergence Technology
    • /
    • v.24 no.6
    • /
    • pp.215-218
    • /
    • 2015
  • A pyroelctric properties of Ni(x)-doped PMNT systems were analyzed. Modified PMNT samples were prepared using the columbite structure method. Pyroelectric current, polarization, dielectric constant and dissipation factor of Ni-doped PMNT samples were measured as a function of temperature. By adding a small amount of NiO, pyroelectricity of PMNT is increased. Unlike the normal $ABO_3$ ferroelectric, Ni-doped PMNT showed properties for relaxor ferroelectric of causing the successive phase transition over a wide temperature. The optimum conditions for obtaining compositions with improvement ferroelectric properties are a nominal addition of 0.02 mole% Ni. Also, Ni-doped PMNT ferroelectric showed excellent pyroelectric figures of merit in the vicinity of room temperature. The pyroelectric coefficient ($0.00524C/m^2K$ at $25^{\circ}C$) and figures of merit ($F_v{\sim}0.039m^2/C$ and $F_d{\sim}0.664{\times}10^{-4}Pa^{-1/2}$) of composition PMNT with 0.02 mole% Ni are comparable to the earlier reports on lead-type pyroelectrics.

Remarkable Stability of Graphene/Ni-Al Layered Double Hydroxide Hybrid Composites for Electrochemical Capacitor Electrodes

  • Lee, Jeong Woo;In, Su-Il;Kim, Jong-Duk
    • Journal of Electrochemical Science and Technology
    • /
    • v.4 no.1
    • /
    • pp.19-26
    • /
    • 2013
  • Graphene/Ni-Al layered double hydroxide (LDH) hybrid materials were synthesized by a hydrothermal reaction. Hexagonal Ni-Al LDH particles nucleated and grew on graphene sheets, thus preventing restacking of the graphene sheets and aggregation of the Ni-Al LDH nanoparticles upon drying. Electrode made from the graphene/Ni-Al LDH hybrid materials showed a substantial improvement in electrochemical capacitance relative to those made with pure Ni-Al LDH nanoparticles. In addition, the graphene/Ni-Al LDH hybrid composite materials showed remarkable stability after 4000 cycles with over 100% capacitance retention. These materials are thus very promising for use in electrochemical capacitor electrodes.

The Effect of B addition on the High Temperature Behavior of Low Thermal Expansion Fe-29%Ni-17%Co Kovar Alloy (저열팽창성 Fe-29%Ni-17%Co 코바 합금의 고온 변형 거동에 미치는 B 첨가의 영향)

  • Kwon, S.H.;Park, J.H.;Kim, M.C.;Lee, K.A.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
    • /
    • 2008.05a
    • /
    • pp.491-492
    • /
    • 2008
  • The effect of B on the hot ductility of Fe-29Ni-17Co Kovar alloy and the mechanism of high temperature deformation behavior were investigated. Hot-tensile test was carried out at the temperature range of $900^{\circ}C-1200^{\circ}C$. Optical microscopy and scanning electron microscopy were used to investigate the microstructure and fracture during hot deformation. The hot ductility of Kovar alloy was drastically increased with the addition of Boron. The improvement of hot ductility results from the grain boundary migration mainly due to the dynamic recrystallization at lower temperature range($900^{\circ}C$).

  • PDF

Study of Thermal Stability of Ni Silicide using Ni-V Alloy

  • Zhong, Zhun;Oh, Soon-Young;Lee, Won-Jae;Zhang, Ying-Ying;Jung, Soon-Yen;Li, Shi-Guang;Lee, Ga-Won;Wang, Jin-Suk;Lee, Hi-Deok;Kim, Yeong-Cheol
    • Transactions on Electrical and Electronic Materials
    • /
    • v.9 no.2
    • /
    • pp.47-51
    • /
    • 2008
  • In this paper, thermal stability of Nickel silicide formed on p-type silicon wafer using Ni-V alloy film was studied. As compared with pure Ni, Ni-V shows better thermal stability. The addition of Vanadium suppresses the phase transition of NiSi to $NiSi_2$ effectively. Ni-V single structure shows the best thermal stability compared with the other Ni-silicide using TiN and Co/TiN capping layers. To enhance the thermal stability up to $650^{\circ}C$ and find out the optimal thickness of Ni silicide, different thickness of Ni-V was also investigated in this work.

Effect of Excess PbO Addition on Sintering and Piezoelectric Characteristics in Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3 System (PbO 과잉량이 Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3계의 소결 및 압전특성에 미치는 영향)

  • 전구락;김정주;조상희;김도연
    • Journal of the Korean Ceramic Society
    • /
    • v.26 no.4
    • /
    • pp.568-574
    • /
    • 1989
  • Effect of PbO addition on sintering and piezoelectric properties at 0.45Pb(Ni1/3Nb2/3)O3-0.40PbTiO3-0.15PbZrO3 composition which is tetragonal phase was investigated. In this composition, Porosity and dielectric constant were increased with excess PbO addition, but Kp and d31 was not changed. These variation of physical properties could be interpreted as composition change of solid grains from tetragonal to MPB region due to amount of PbO-rich liquid changing.

  • PDF

Formation of a Core/Rim Structure in Ti(C, N)-based Cermets (Ti(C, N)계 써메트의 유심구조 형성거동)

  • Kim, Suk-Hwan
    • Journal of Powder Materials
    • /
    • v.13 no.1 s.54
    • /
    • pp.10-17
    • /
    • 2006
  • Model experiment was introduced to obtain the formation of a core/rim structure by only liquid phase reaction in Ti(C, N)-based cermet alloys. Infiltrated Ti(C, N)-Ni, $MO_2C-Ni$, and TaC-Ni cermets were bonded to sandwiched specimen by heat treatment $1450^{\circ}C$ for 5hr. With nitrogen addition, both (Ti, Mo) (C, N) and (Ti, Ta) (C, N) rim structure was nucleated around comer of cuboidal Ti(C, N) core. However, equilibrium shapes of(Ti, Mo) (C, N) and (Ti, Ta) (C, N) rim were different possibly due to the effect of interface energy. The core/rim and rim! binder interfaces were parallel to each other with TaC addition, while rotated to each other with $MO_2C$ addition.

Effect of Nickel Addition in Hot Dip Galvanizing of Mini-mill Steels Containing Silicon (실리콘을 함유한 미니밀 소재의 용융아연도금성에 미치는 니켈첨가의 영향)

  • Lee, H.J.;Kim, J.S.;Chung, J.H.
    • Journal of the Korean institute of surface engineering
    • /
    • v.32 no.2
    • /
    • pp.157-164
    • /
    • 1999
  • In this study the effect of nickel addition on the coating weight of mini-mill steels containing silicon has been studied. It is shown that the pure zinc accelerated growth of the alloy layers occurred by a rapid growth of the zeta phase at 0.06%Si. The addition of 0.06%Ni to a pure zinc bath was found to be very effective in reducing the coating weight and promoting preferential development of the delta phase. The coating obtained by immersion in the Zn-Ni bath shows the presence of a nickel-rich region between the zeta phase and the eta phase. It is suggested that nickel prevents the rapid growth of the zeta phase due to the formation of the Zn-Ni-Fe ternary compound, which may act as a barrier to inward diffusion of zinc or iron at the zeta-eta boundary.

  • PDF