• Title/Summary/Keyword: Ni Content

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Effect of Ni Content in Cuunderlayer on the Magnetoresistance of Co/Cu Artificial Superlattice (Co/Cu 인공초격자에서 구리기저층에 첨가된 니켈의 양이 자기저항에 미치는 영향)

  • 민경익;송용진;주승기
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.310-313
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    • 1993
  • The effect of Ni content in Cu underlayer on the magnetoresistance of Cu/Co artificial superlattice has been investigated. As the content of Ni increased, the preferred orientation of artificial superlattice changed from fec (100) to fcc (111) due to the change of the preferred orientation of the underlayer. When the content of Ni was 6 %, 26.7 % of magnetoresistance with 175 Oe of saturation field could be obtained in ${[Cu(19\AA)/Co(30\AA)]}_{20}|Cu-6%Ni(200\AA)/Si$.

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Structural Analysis of Zn-Ni electrodeposition (Zn-Ni 도금강판의 도금층 구조 분석)

  • Lee, D.H.;Park, S.H.
    • Analytical Science and Technology
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    • v.12 no.1
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    • pp.40-46
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    • 1999
  • Zn-Ni alloy electrodeposition on steel has been examined by means of X-ray diffraction and scanning electron microscopy. The effect of current density, $Ni^{2+}$ ion concentration, and $Cl^-$ ion concentration on the structure as well as morphology of the electrodeposit have been studied. The Ni content of the electrodeposit increased with decreasing current density in the range studied in this work. The Ni content of the electrodeposit also increased with increasing $Ni^{2+}$ ion and $Cl^-$ ion concentrations. The structure change of the electrodeposit was closely related to the Ni content. In fact, the mixture phase of ${\eta}$ and ${\gamma}$ was found below 10 wt.% of Ni while the ${\gamma}$ phase only was observed above 10 wt.% of Ni. In addition, the lattice parameter, a, of then phase structure increased and the lattice parameter, c, of it decreased as the Ni content of the electrodeposit increased. The morphology of the electrodeposit varied from the plate-like shape to the fine granular shape depending upon the change in composition and structure of the electrodeposit.

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Effect of the Cu Composition Ratio on the Phase Transformation in Low Ni Austenite Cast Iron, Fe-3%C-16%(Ni+Mn+Cu) (Fe-3%C-16%(Ni+Mn+Cu) 주철에서 상변태에 미치는 Cu 조성비의 영향)

  • Park, Gi-Deok;Heo, Hoe-Jun;Na, He-Sung;Kang, Chung-Yun
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.419-425
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    • 2012
  • The purpose of this research was to develop a low Ni austenitic cast iron through replacing Ni by Cu and Mn because they are cheaper than Ni. The effect of the Cu content (6-12 wt%) on the microstructure characteristics was investigated in Fe-3%C-16%(Ni+Cu+Mn) cast iron. Contrary to general effect of the Cu on cast iron, the result of the microstructure analysis indicated that bainite and cementite were formed in high Cu content (>8 wt%Cu). A crystallized Cu-solution (Cu-Mn) phase and MnS in the Cu-solution were formed. The quantity of those phases increased as the Cu content increased. Consequently, the high Cu content in the composition ratio (Ni+Cu+Mn=16%) caused the formation of Cu-Mn/MnS and those phases decreased the effect of Cu and Mn on austenite formation. For this reason, bainite and cementite were formed in high Cu content.

Enhanced Electrocatalytic Activity of Low Ni Content Nano Structured NiPd Electrocatalysts Prepared by Electrodeposition Method for Borohydride Oxidation

  • Zolfaghari, Mahdieh;Arab, Ali;Asghari, Alireza
    • Journal of Electrochemical Science and Technology
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    • v.11 no.3
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    • pp.238-247
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    • 2020
  • Some nano structured bimetallic NiPd electrocatalysts were electrodeposited on glassy carbon electrodes using a double potential step chronoamperometry. The morphology of the electrodeposited samples was investigated by field emission-scanning electron microscopy, while their compositions were evaluated using energy dispersive X-ray spectroscopy. It was observed that the electrodeposited samples contained a low Ni content, in the range of 0.80 - 7.10%. The electrodeposited samples were employed as the anode electro-catalysts for the oxidation of sodium borohydride in NaOH solution (1.0 M) using cyclic voltammetry, chronoamperometry, rotating disk electrode, and impedance spectroscopy. The number of exchanged electrons, charge transfer resistances, apparent rate constants, and double layer capacitances were calculated for the oxidation of borohydride on the prepared catalysts. According to the results obtained, the NiPd-2 sample with the lowest Ni content (0.80%), presented the highest catalytic activity for borohydride oxidation compared with the other NiPd samples as well as the pure Pd sample. The anodic peak current density was obtained to be about 1.3 times higher on the NiPd-2 sample compared with that for the Pd sample.

Preparation of Ni-PTFE Electrode using Nickel Plating for Alkaline Fuel Cell (니켈도금기술을 이용만 알칼리형 연료전지용 Ni-PTFE전극의 개발)

  • Kim, Jae-Ho;Lee, Young-Seak
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.4
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    • pp.291-299
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    • 2009
  • Ni-plated polytetrafluoroethylene(Ni-PTFE) particles($25{\mu}m$, $500{\mu}m$) were prepared by using nickel electroless plating. The Ni content in Ni-PTFE particles increased with increasing the amount of reduction agent. At about 53 wt% Ni content, $25{\mu}m$ Ni-PTFE particles showed conductivity of 320S/m. The Ni-PTFE particles were formed into the Ni-PTFE plate using heat treatment at $350^{\circ}C$ under $10{\sim}1000kg/cm^2$. The Ni-PTFE plate displayed the high conductivity of 5100S/m due to the formation of 3-dimentional Ni network. The plate was used as an electrode in an alkaline fuel cell(AFC). In terms of the current density, the Ni-PTFE electrode having higher Ni content(53 wt%) showed improved performance.

Composition, preferred orientation and magnetic properties of Ni-Fe-Co alloy electrodeposits (Ni-Fe-Co 박막도금층의 조성, 우선배향 및 자기적 성질)

  • 예길촌;김선윤;문근호;김용웅
    • Journal of the Korean institute of surface engineering
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    • v.28 no.6
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    • pp.352-360
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    • 1995
  • The effect of electrolysis conditions on the composition, the magnetic properties and the preferred orientation of Ni-Fe-Co alloy deposits was investigated using the sulfate-chloride bath paddle agitated. Cathode current efficiency increases with the current density, showing the different tendency of the variation from that of the Ni-Fe electrodeposits. The Co content of the deposits decreases with increasing current density, while the content of Ni and Fe is shown to be minimum or maximum at 3A/$dm^2$ respectively. The Ni/Fe ratio of the alloy deposits is lower than that of Ni-Fe deposits. The coercive force($H_c$) of the deposits increases with the Co content in deposit, showing the relatively low value in the range of 1.8~5.0Wt.% Co. The anisotropy field ($H_k$) of the deposits is higher than that of Ni-Fe alloy deposits, The preferred orientation of the deposits is generally (200), but the orientation factor(R) changes with both the increase of current density and the magnetic field applied during deposition.

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A Study of the Characteristics of Cast Ni-Ti Alloy for Biomaterial with Compositional Change (정밀 주조한 생체용 Ni-Ti합금의 조성변화에 따른 특성 연구)

  • 권오원;김교한
    • Journal of Biomedical Engineering Research
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    • v.14 no.3
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    • pp.283-290
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    • 1993
  • In thls study, the effects of the composltional change of cast Ni-Ti alloys on its characteristics including mechanical properties, phase transformation temperature, and ion releasing rate were investigated. brittle:behavior was shown in the stress-strain curve of the alloy containing low Ti content (Ni-44.0%Ti). By increasing the Ti content, the trend in stress-strain curves changed from that of superelasticity to that of shape memory effect(Ni-44.4%Ti, Ni-45.1%Ti, Ni-45, 5%Ti). Phase transformation temperature ($A_f, {\;}M_5$ point) increased with increasing the Ti content. lon releasing rate of four types of Mi-Ti alloys was very low compared to that of the dental commerical Ni-Cr alloy.

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Electrode Characteristics of the (Mm)Ni5-Based Hydrogen Storage Alloys ((Mm)Ni5계 수소저장합금의 전극 특성)

  • Han, D.S.;Choi, S.J.;Chang, M.H.;Choi, J.;Park, C.N.
    • Transactions of the Korean hydrogen and new energy society
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    • v.6 no.1
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    • pp.35-41
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    • 1995
  • The MmNi-based alloy electrode was studied for use as a negative electrode in Ni-MH battery. Alloys with $MmNi_5-_xM_x$(M=Co,Al,Mn) composition were synthesized, and their electrode charateristics of activation rate, temperature dependence, electrode capacity and cycle life were investigated. With increasing Al content and decreasing Mn content in the alloys, the discharge capacity increased while the cycle life decreased. As x in $MmNi_5-_xM_x$ increased from 1.5 to 2.0, decreasing the Ni content, the discharge capacity, the low temperature property and the rate capability decreased. However its cycle life was improved. Increasing Co content resulted in a prolonged cycle life and decrease of high rate discharge capacity. It can be concluded that the most promising alloy in view of discharge capacity and cycle life is $MmNi_{3.5}Co_{0.7}Al_{0.5}Mn_{0.3}$.

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A study on the tensile property and corrosion resistance of austenitic stainless base and weld metal (오스테나이트계 스테인리스강 모재 및 용접부의 인장특성과 내식성에 관한 연구)

  • 정호신;김조권;엄동석
    • Journal of Welding and Joining
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    • v.14 no.4
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    • pp.71-78
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    • 1996
  • The effect of chemical composition on mechanical properry and corrosion resistance of austenitic stainless steel was investigated. The main results obtained were as follows : 1. There was a linear relationship between the tensile strength of stainless steel and the $Cr_{eq}/Ni_{eq}$. The larger the $Cr_{eq}/Ni_{eq}$ was the higher the tensile strength of stainless steel. 2. There was a good correlationship between $Cr_{eq}/Ni_{eq}$ and intergranular, gerneral corrsion rate. 3. Intergranular corrosion rate decreased linearly with increasing Cr content. 4. General corrosion rate decreased linearly with increasing Ni content. 5. Logarithm corrosion rate of intergranular and general corrosion has a linear relationship with all of the factor of $Cr_{eq}/Ni_{eq}$, Cr and Ni content.

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Composition and Coercivity of Fe-Co-Ni Alloy Electrodeposits (Fe-Co-Ni합금박막의 조성 및 자기적 성질)

  • 예길촌;김용웅;문근호
    • Journal of the Korean institute of surface engineering
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    • v.29 no.3
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    • pp.195-202
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    • 1996
  • The composition, the microstructure and the magnetic properties(HC and Hk) of Fe-Co-Ni alloy electrodeposits were investigated according to the electrolysis conditions using sulfate bath paddle agitated. The current efficiency of the alloys electrodeposition was considerably low in the range of 16∼50%. The Fe content(wt.%) of the alloy increased from 20% to 57% with current density, while Ni content of them decreased in the range of 70∼24% respectively, and Co content was nearly constant. As a result, Fe/Ni ratio of the alloy increased from 0.3 to 2.0 showing the anomalous codeposition. The structure of the alloy changed from fcc to the mixed one of fcc+bcc with the increase of Fe/Ni ratio. The preferred orientation of the alloy with fcc and bcc structure were (220) and (110) respectively. The alloy with Fe/Ni ratio(0.3∼l.2) had the lowest coercivity of 0.4∼0.8 Oe.

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