• Title/Summary/Keyword: Ni(II)

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Effect of Estrogen on the Gestational Profiles in Gene Expression of Placental Lactogen I, II and Pit-i in the Rat Placenta (흰쥐 태반에서 Placental Lactogen I과 II 그리고 Pit-1의 유전자 발현에 미치는 에스트로겐의 영향)

  • 정진권;강성구;강해묵;이병주
    • The Korean Journal of Zoology
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    • v.39 no.1
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    • pp.115-121
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    • 1996
  • To investigate gestational profiles in gene expression of placental lactogen I fpL4), PL-lI and Pit-1, RNA samples were extracted from the placentas of pregnant day 12 to 20 at 2 day intervals. Northern blots showed changes in gene expression of PL4, - 11 and Pit-i. Sizes of PL-l and -II mRNA were changed and amounts of PL-I, -H and Pit-1 mRNA increased during progress of gestation. To examine the effect of estrogen on the gene expression of PL-I, -Il and Pit-1, pregnant female rats were ovariectomized (OVX) and daily injected with estradiol (OVX + E). OVX markedly lowered the amount of PL4 and 41 mRNA, and shifted niRNA size from 1 kb to i 3 kb in PL-l mRNA and 0.6 kb to i kb in PL-ll mRNA, respectively. OVX had no effect on the mRNA size of Pit-1, but markedly attenuated Pit-1 mRNA level. Estrogen injection reversed the effect of OVX on the size-shift but not on the amount of PL4 and -Il mRNA. Replacement of E partially recovered OVX-induced inhibition of Pit-i mRNA level. Present results suggest that estrogen may play a pivotal role on the gene expression of PL-l and -Il such as alternative RNA splicing and/or polyadenylation, and Pit-1 may be involved in the gene expression of PL-l and 41 by estrogen.

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Cyanide- and Phenoxo-Bridged Heterobimetallic Fe(III)-Mn(III) Coordination Polymer: Synthesis, Crystal Structures and Magnetic Properties

  • Zhang, Daopeng;Kong, Lingqian;Li, Yueyun;Wang, Ping;Chen, Xia
    • Bulletin of the Korean Chemical Society
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    • v.35 no.9
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    • pp.2684-2688
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    • 2014
  • Two two-dimensional cyanide- and phenoxo-bridged heterometallic M(II)-Mn(III) (M = Ni, Pd) coordination polymers $\{[Mn(saltmen)]_4[Ni(CN)_4]\}(ClO_4)_2{\cdot}CH_3OH{\cdot}H_2O$ (1) and $\{[Mn(saltmen)]_4[Pd(CN)_4]\}(ClO_4)_2{\cdot}CH_3CN{\cdot}H_2O$ (2) ($saltmen^{2-}$ = N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneaminato)dianion) have been obtained by using $K_2[M(CN)_4]$ as building blocks and a salen-tpye Schiff-base manganese(III) compound as assembling segment. Single X-ray analysis reveals their isostrutural cyanide-bridged $MMn_4$ pentanuclear cationic structure. The four Schiff base manganese units of the pentanuclear entity are self-complementary through the phenoxo oxygen atoms from the neighboring complex, therefore forming cyanide- and phenoxo-bridged 2D sheet-like structure. Investigation over magnetic susceptibilities reveals the overall ferromagnetic coupling between the adjacent Mn(III) ions bridged by the phenoxo oxygen atoms with J = 2.13 and $2.21cm^{-1}$ for complexes 1 and 2, respectively.

Numerically integrated modified virtual crack closure integral technique for 2-D crack problems

  • Palani, G.S.;Dattaguru, B.;Iyer, Nagesh R.
    • Structural Engineering and Mechanics
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    • v.18 no.6
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    • pp.731-744
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    • 2004
  • Modified virtual crack closure integral (MVCCI) technique has become very popular for computation of strain energy release rate (SERR) and stress intensity factor (SIF) for 2-D crack problems. The objective of this paper is to propose a numerical integration procedure for MVCCI so as to generalize the technique and make its application much wider. This new procedure called as numerically integrated MVCCI (NI-MVCCI) will remove the dependence of MVCCI equations on the type of finite element employed in the basic stress analysis. Numerical studies on fracture analysis of 2-D crack (mode I and II) problems have been conducted by employing 4-noded, 8-noded (regular & quarter-point), 9-noded and 12-noded finite elements. For non-singular (regular) elements at crack tip, NI-MVCCI technique generates the same results as MVCCI, but the advantage for higher order regular and singular elements is that complex equations for MVCCI need not be derived. Gauss numerical integration rule to be employed for 8-noded singular (quarter-point) element for accurate computation of SERR and SIF has been recommended based on the numerical studies.

부산지역 강우의 화학적 특성 II. 중금속의 공급원과 습성침적 플럭스

  • Jun, Eun-Joo;Yang, Han-Soeb;Ok, Gon;Kim, Young-Seup
    • Journal of Environmental Science International
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    • v.7 no.5
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    • pp.717-723
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    • 1998
  • The concentrations and wet deposition flux into the sea of heavy metals of precipitation in Pusan area were measured and estimated. The samples were collected by polyethylene bottle(30ι) from January to November in 1996, and heavy metals were analyzed by atomic absorption spectrometer. The concentration order of heavy metals was Al >Fe >Zn >Pb >Mn >Cu >Ni >Cd >Co, and they were high at inland sites and low at coastal sites. The enrichment factors for some metals(Zn, Cu, Pb, Cd), based on crustal Al, were significantly greater than unity, and the order was Cd > Pb > Zn > Cu. This evidence suggests Cd and Pb are derived predominantly from non-crustal sources. Al, Fe and Mn contents showed good correlation with each other. Therefore this enrichment factor indicates similar geochemical behavior of these elements. The annual wet depositional flux(mg/ $m^2$ /yr) from Pl site was as follows: Al(121.1). Fe,(177.2), Zn(12.9), Mn(6.19), Pb(14.4), Cu(0.64), Ni(1.03), Cd(1.02) and Co(1.01).

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Preventive Effect of Ebelactone B, an Esterase Inhibitor on Rice Sheath Blight Caused by Rhizoctonia solani

  • Chun, Hyo-Kon;Ko, Hack-Ryong;Moon, Hang-Sick;Kho, Yung-Hee
    • Journal of Microbiology and Biotechnology
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    • v.5 no.6
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    • pp.335-340
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    • 1995
  • Two types of Rhizoctonia solani esterases induced by cutin hydrolysate were partially purified by ammonium sulfate precipitation and gel filtration. The esterase I with hydrolyzing activity toward both ${\rho}-ni-trophenyl$ butyrate and ${\rho}-nitrophenyl$ palmitate and the esterase II with hydrolyzing activity toward only ${\rho}-ni-trophenyl$ butyrate were inhibited by ebelactone B, an esterase inhibitor produced by actinomycetes with $IC_{50}$ values of 0.01 and $0.09{\;}\mu\textrm{g}/l$, respectively. Spraying on rice seedling with ebelactone B at a concentration of $30{\;}\mu\textrm{g}/ml$ completely suppressed infection by R. solani. Ebelactone B could not protect the wounded rice seedling and did not show any inhibitory effect on the mycelial growth at a concentration of 1 mg/ml. These results indicate that ebelactone B, an esterase inhibitor protects rice plants from infection with R. solani by inhibition of penetration, not through fungitoxic or fungicidal effect.

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A Study on the joining of $Al_2O_3$ to STS 304 with using Cu-7.5wt% Zr Insert metal (Cu-7.5wt% Zr 삽입 금속을 이용한 $Al_2O_3$-STS 304 접합체 계면 조직에 관한 연구)

  • 김병무;한원진;강정윤;이상래
    • Journal of Welding and Joining
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    • v.11 no.1
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    • pp.62-72
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    • 1993
  • Recently there is an increased interest in joining of ceramics to metals and brazing now an accepted method of joining for a wide variety of ceramic to metal combination. The present research work is aimed at establishing the basis of the metal-ceramic joining of $Al_{2}$O$_{3}$ to STS 304 with using Cu-7.5wt% Zr insert metals. Also the microstructures of the brazed joints were observed by using optical microscope and SEM and the reaction products were analyzed by using EDX, WDX and XRD. As a result, the following findings were obtained. The reaction layers of the brazed joints of $Al_{2}$O$_{3}$ to STS 304 are composed of four layers at the bonded interlayer. Double reaction layers are formed at the interface of $Al_{2}$O$_{3}$ insert metal. Layer I was composed of ZrO$_{2}$ particles, Fe-Cr-Ni compounds in Cu matrix, while layer II ZrO$_{2}$ band phase containing Fe-Cr-Ni compounds.

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Highly Selective Derivative Spectrophotometry for Determination of Nickel Using 1-(2-Pyridylazo)-2-naphthol in Tween 80 Micellar Solutions

  • Eskandari, Habibollah
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1137-1142
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    • 2004
  • A spectrophotometric and first derivative spectrophotometric method was developed in aquatic Tween 80 micellar solutions for selective determination of nickel without using any pre-separation step. 1-(2-Pyridylazo)-2-naphthol (PAN), as a sensitive chromogenic complexing agent formed a red-colored Ni(II)-PAN complex in Tween 80 media with satisfactory solubility and stability. Conditions such as pH, PAN concentration, type and concentration of micellizing agent were optimized. Molar absorptivity of Ni-PAN complex was found $4.62\;{\times}\;10^4L\;cm^{?1}\;mol^{?1}$ at 569 nm, under the optimum condition. Calibration graphs were derived by zero, first and second derivative spectrophotometry at maximum wavelengths of 569, 578 and 571 nm with linear ranges of 30-1800, 20-2500 and 30-2000 ng $mL^{?1}$ , respectively. Precision as standard deviation as well as accuracy as recovery percent were in the range of 1-20 ng $mL^{?1}$, and 93.3-103.3%, respectively, for the entire of the linear ranges. Spectrophotometric detection limit was 3 ng $mL^{?1}$ and effects of diverse ions on the first derivative determination of nickel were studied to investigate selectivity of the method. Interferences of cobalt and copper on the nickel determination were prevented using o-phenanthroline as masking agent. The recommended procedures were applied to the various synthetic and stainless steel alloys, tea leaves and human hair, with satisfactory results.

DEPENDENCE OF METAL CONCENTRATIONS OF METAL-TREATED ANTIBACTERIAL ACTIVATED CARBON FIBER AND THEIR APPLICATION (금속 처리된 항균성 활성탄소 섬유의 금속 농도의 의존성과 그의 응용)

  • Oh, Won-Chun;Kim, Bum-Soo;Jang, Won-Cheoul;Rheem, In-Soo;Kim, Jong-Wan
    • Proceedings of the KAIS Fall Conference
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    • 2000.10a
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    • pp.55-60
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    • 2000
  • The adsorption isotherms can be assigned to typical Type I for Ag and Cu-treated ACFs and Type I and Type II for Ni-treated ACFs. From the DSC analysis, A $g_{0.9}$-ACF occurs only exothermic curve at the temperature of $203^{\circ}C$, and relatively stable composition curves were formed. But C $u_{0.3}$-ACF and C $u_{0.4}$-ACF occur endothermic curves at the temperature of 57.26, 107.02 and $215.87^{\circ}C$. N $i_{1.0}$-ACF occurs large endothermic curves at 59.26, 98.40 and $208.89^{\circ}C$ and N $i_{0.8}$-ACF are shown endothermic curves at 59.26 and $157.77^{\circ}C$. From the biological results, the percentages of the antibacterial effects were 96.5-100 for Ag-ACFs, 92.3-99.8 for Cu-ACFs and 95.5-100 for Ni-ACFs, respectivelylyvelylyly

Study on (n,p) reactions of 58Ni, 99Tc, 99Ru, 131Xe, 133Cs and 186Os radioisotopes used in medicine

  • Hallo M. Abdullah;Ali H. Ahmed
    • Nuclear Engineering and Technology
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    • v.55 no.1
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    • pp.304-309
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    • 2023
  • In the last decade, nuclear medicine appears to be a good choice of medicine. 58Co, 99Mo, 99Tc, 99Re, 133Xe and 186Re are very important radionuclides for nuclear medicine. In this study, the excitation functions of 58Ni (n, p) 58Co, 99Tc (n, p) 99Mo, 99Ru (n, p) 99Tc, 131Xe (n, p) 131I, 133Cs (n, p) 133Xe and 186Os (n, p) 186Re nuclear reactions were calculated at neutron energies between 1 and 20 MeV using TALYS 1.95 and EMPIRE 3.2 nuclear codes. Furthermore, the cross sections were calculated with the empirical formula derived in our past study at 14-15 MeV. The obtained results were compared with the measured values in EXFOR library, and with the evaluated data of (JENDL-4.0/HE, JEFF-3.3, TENDL-2019, ENDF/B-VIII.0, IRDFF-II, JENDL/ImPACT-18). The results are in good agreement with those of the evaluated data libraries and experimental results and indicates that these radioisotopes can be produced by smaller cyclotrons.

First Report of Xenoroussoella triseptata Isolated from Soil in Korea

  • Jung-Joo Ryu;Seung-Yeol Lee;In-Kyu Kang;Leonid N. Ten;Hee-Young Jung
    • The Korean Journal of Mycology
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    • v.50 no.3
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    • pp.195-204
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    • 2022
  • A fungal strain, designated KNUF-20-NI009, was isolated from soil collected from Gunsan-si, Jeollabuk-do, Korea. The isolate showed cultural features typical of the genus Xenoroussoella. Colonies cultivated on malt extract agar were olivaceous-brown to pale olivaceous-white at the margins, with undersides of dark olivaceous to olivaceous-brown and a white margin. The conidia, with a size range of 2.7-5.1×1.6-3.3 ㎛ ($\bar{x}=3.6\times2.6{\mu}m$, n=50), were globoid to ellipsoid in shape, hyaline when immature, becoming light brown to golden-brown when mature, and characterized by 1 or 2 guttules. Multi-locus sequence analysis based on a combined dataset of internal transcribed spacer regions (ITS), large subunit rDNA (LSU), small subunit rDNA (SSU), translation elongation factor 1-alpha (TEF1α), and RNA polymerase II largest subunit (RPB2) sequences revealed KNUF-20-NI009 to be a strain of Xenoroussoella triseptata. This is the first report of this species in Korea.