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http://dx.doi.org/10.5012/bkcs.2014.35.9.2684

Cyanide- and Phenoxo-Bridged Heterobimetallic Fe(III)-Mn(III) Coordination Polymer: Synthesis, Crystal Structures and Magnetic Properties  

Zhang, Daopeng (College of Chemical Engineering, Shandong University of Technology)
Kong, Lingqian (Dongchang College, Liaocheng University)
Li, Yueyun (College of Chemical Engineering, Shandong University of Technology)
Wang, Ping (College of Chemical Engineering, Shandong University of Technology)
Chen, Xia (College of Chemical Engineering, Shandong University of Technology)
Publication Information
Bulletin of the Korean Chemical Society / v.35, no.9, 2014 , pp. 2684-2688 More about this Journal
Abstract
Two two-dimensional cyanide- and phenoxo-bridged heterometallic M(II)-Mn(III) (M = Ni, Pd) coordination polymers $\{[Mn(saltmen)]_4[Ni(CN)_4]\}(ClO_4)_2{\cdot}CH_3OH{\cdot}H_2O$ (1) and $\{[Mn(saltmen)]_4[Pd(CN)_4]\}(ClO_4)_2{\cdot}CH_3CN{\cdot}H_2O$ (2) ($saltmen^{2-}$ = N,N'-(1,1,2,2-tetramethylethylene)bis(salicylideneaminato)dianion) have been obtained by using $K_2[M(CN)_4]$ as building blocks and a salen-tpye Schiff-base manganese(III) compound as assembling segment. Single X-ray analysis reveals their isostrutural cyanide-bridged $MMn_4$ pentanuclear cationic structure. The four Schiff base manganese units of the pentanuclear entity are self-complementary through the phenoxo oxygen atoms from the neighboring complex, therefore forming cyanide- and phenoxo-bridged 2D sheet-like structure. Investigation over magnetic susceptibilities reveals the overall ferromagnetic coupling between the adjacent Mn(III) ions bridged by the phenoxo oxygen atoms with J = 2.13 and $2.21cm^{-1}$ for complexes 1 and 2, respectively.
Keywords
Cyanide-bridged; Heterometallic; Crystal structure; Magnetic property;
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