• Textile Coloration and Finishing
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• v.9 no.6
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• pp.58-67
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• 1997

PTCA(1,2,3-propanetricarboxylic acid) and BTCA(1,2,3-butanetetracarboxylic acid) are selected as new nonformaldehyde agents for ester crosslinking of cotton cellulose to replace the traditional DMDHEU reagent. A goal of this research is to propose unknown ester mechanism of cotton cellulose by PTCA or BTCA using crystal structure model suggested by Meyer and Takahashi. In pursuit of these goals, we have treated 100% cotton broad cloth with PTCA or BTCA and different catalysts. They were used with $NaH_2PO_2,\;NaH_2PO_4,\;Na_2HPO_4,\;NaH_2PO_2,\;Na_3PO_4,$ catalysts to produce nonformaldehyde fabric finishes. Treatments were applied to all cotton fabrics using a pad-dry -cure process. The esterfication of cotton treated with BTCA or PTCA was investigated using Fourier transform infrared(FT-IR) spectra and the breaking strength, abrasion retention and discoloration properties were determined to prove the durable finished fabrics. Patterns with respect to abrasion resistance were more complex. Because PTCA and BTCA add-ons were comparable, the data suggest that the more effective catalysts, $NaH_2PO_2$ and mixed phosphate $NaH_2PO_2/NaH_2PO_4$) are effecting either a great number of crosslinks in the cotton or producing crosslinks that differ in actual structure.

• Journal of the Korean Magnetic Resonance Society
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• v.9 no.2
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• pp.103-109
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• 2005

New PVC plasticizer, 2,2,4-trimethyl-1,3-pentanediol-1-butyrate-3-isobutyrate was synthesized via simple esterification with butyric acid and Texanol(a trademark of Eastman Chemicals), the mixture of 2,2,4-trimethyl-1,3-pentanediol-3-isobutyrate and 2,2,4-trimethyl-1,3-pentanediol-1-isobutyrate. The analysis of $^1H-1D,\;^{13}C-1D$ NMR and HMBC spectra identified internal-ester-transfer of 2,2,4-trimethyl-1,3-pentanediol-1-isobutyrate during the reaction. 2,2,4-trimethyl-1,3-pentanediol-1-butyrate-3-isobutyrate gave better properties in PVC than 2,2,4-trimethyl-1,3-pentanediol diisobutyrate(TXIB, a trademark of Eastman Chemicals) such as lower viscosity, higher tensile strength and better elongation. In particular, remarkably reduced migration compared with TXIB suggested a reduced emission of VOC(volatile organic compound) from PVC.

• Bulletin of the Korean Chemical Society
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• v.14 no.1
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• pp.21-29
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• 1993

For the study of relaxation processes in complex spin system, a general master equation, which can be used to simulate a vast range of pulse experiments, has been formulated using the Liouville representation of quantum mechanics. The state of a nonequilibrium spin system in magnetic field is described by a density vector in Liouville space and the time evolution of the system is followed by the application of a linear master operator to the density vector in this Liouville space. In this master equation the nuclear spin relaxation due to intramolecular dipolar interaction or randomly fluctuating field interaction is explicitly implemented as a relaxation supermatrix for a strong coupled two-spin (1/2) system. The whole dynamic information inherent in the spin system is thus contained in the density vector and the master operator. The radiofrequency pulses are applied in the same space by corresponding unitary rotational supertransformations of the density vector. If the resulting FID is analytically Fourier transformed, it is possible to represent the final nonstationary spectrum using a frequency dependent spectral vector and intensity determining shape vector. The overall algorithm including relaxation interactions is then translated into an ANSIFORTRAN computer program, which can simulate a variety of two dimensional spectra. Furthermore a new strategy is tested by simulation of multiple quantum signals to differentiate the two relaxation interaction types.

• Korean Journal of Remote Sensing
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• v.23 no.1
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• pp.7-14
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• 2007

Atmospheric correction is one of critical procedures to extract quantitative information related to biophysical variables from hyperspectral imagery. Most atmospheric correction algorithms developed for hyperspectral data have been based upon atmospheric radiative transfer (RT) codes, such as MODTRAN. Because of the difficulty in acquisition of atmospheric data at the time of image capture, the complexity of RT model, and large volume of hyperspectral data, atmospheric correction can be very difficult and time-consuming processing. In this study, we attempted to develop an efficient method for the atmospheric correction of EO-1 Hyperion data. This method uses the pre-calculated look-up-table (LUT) for fast and simple processing. The pre-calculated LUT was generated by successive running of MODTRAN model with several input parameters related to solar and sensor geometry, radiometric specification of sensor, and atmospheric condition. Atmospheric water vapour contents image was generated directly from a few absorption bands of Hyperion data themselves and used one of input parameters. This new atmospheric correction method was tested on the Hyperion data acquired on June 3, 2001 over Seoul area. Reflectance spectra of several known targets corresponded with the typical pattern of spectral reflectance on the atmospherically corrected Hyperion image, although further improvement to reduce sensor noise is necessary.

• Bulletin of the Korean Chemical Society
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• v.22 no.7
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• pp.743-747
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• 2001

New azomethine metal complexes were synthesized systematically and characterized. Beryllium, magnesium, or zinc ions were used as a central metal cation and aromatic azomethines (L1-L4) were employed as a chelating anionic ligand. Emission peaks o f the complexes in both solution and solid states were observed mostly at the region of 400-500 nm in the luminescence spectra, where blue light was emitted. Three of them (BeL1 (Ⅰ), ZnL2 (Ⅱ), and ZnL3 (Ⅲ)) were sublimable and thus were applied to the organic light-emitting devices (OLED) as an emitting layer, respectively. The device including the emitting layer of Ⅰ exhibited white emission with the broad luminescence spectral range. The device with the emitting layer of Ⅱ showed blue luminescence with the maximum emission peak at 460 nm. Their ionization potentials, electron affinities, and electrochemical band gaps were investigated with cyclic voltammetry. The electrochemical gaps of 2.98 for I, 2.70 for Ⅱ, and 2.63 eV for Ⅲ were found to be consistent with their respective optical band gaps of 3.01, 2.95 and 2.61 eV within an experimental error. The structure of OLED manufactured in this study reveals that these complexes can work as electron transporting materials as well.

• Wind and Structures
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• v.18 no.4
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• pp.391-422
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• 2014

The high frequency force balance (HFFB) technique provides convenient measurements of integrated forces on rigid building models in terms of base bending moments and torque and/or base shear forces. These base moments or forces are then used to approximately estimate the generalized forces of building fundamental modes with mode shape corrections. This paper presents an analysis framework for coupled dynamic response of tall buildings with HFFB technique. The empirical mode shape corrections for generalized forces with coupled mode shapes are validated using measurements of synchronous pressures on a square building surface from a wind tunnel. An alternative approach for estimating the mean and background response components directly using HFFB measurements without mode shape corrections is introduced with a discussion on higher mode contributions. The uncertainty in the mode shape corrections and its influence on predicted responses of buildings with both uncoupled and coupled modal shapes are examined. Furthermore, this paper presents a comparison of aerodynamic base moment spectra with available data sets for various tall building configurations. Finally, e-technology aspects in conjunction with HFFB technique such as web-based on-line analysis framework for buildings with uncoupled mode shapes used in NALD (NatHaz Aerodynamic Loads Database) is discussed, which facilitates the use of HFFB data for preliminary design stages of tall buildings subject to wind loads.

• Korean Journal of Optics and Photonics
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• v.14 no.6
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• pp.674-679
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• 2003

We fabricated erbium-doped fiber ring laser with a new structure that can operate in C- & L-band wavelength region. The wave-length of the laser can be tuned continuously over 102 nm between 1510.4-1612.6 nm by insertion of the fiber Fabry-Perot tunable filter (FFP-TF) in the ring cavity. By use of the wavelength tunable characteristics of our fiber laser, we measured absorption spectra of more than fifty transition lines of the acetylene ($^{13}$ C$_2$H$_2$) molecule with high signal to noise ratio (SNR).

• Natural Product Sciences
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• v.27 no.3
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• pp.172-175
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• 2021

Sesbagrandiflorain F (1), a novel 2-arylbenzofuran, and two more 2-arylbenzofurans (2-3), were isolated from the stem bark of Sesbania grandiflora L. Based on information HRESIMS data, 1D, and 2D NMR spectra, the structure of 1 was fully assigned. Compounds 1-3 were tested for cytotoxicity in MCF-7 and HeLa cells. Compounds 1 and 3 showed moderate activity against MCF-7 cells with an IC₅₀ value of 2.68 and 4.08 ㎍/mL, respectively. Conversely, all of the isolates were inactive towards HeLa cells.

• Journal of Astronomy and Space Sciences
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• v.35 no.4
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• pp.211-218
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• 2018

Solar microwave bursts carry information about the magnetic field in the emitting region as well as about electrons accelerated during solar flares. While this sensitivity to the coronal magnetic field must be a unique advantage of solar microwave burst observations, it also adds a complexity to spectral analysis targeted to electron diagnostics. This paper introduces a new spectral analysis procedure in which the cross-section and thickness of a microwave source are expressed as power-law functions of the magnetic field so that the degree of magnetic inhomogeneity can systematically be derived. We applied this spectral analysis tool to two contrasting events observed by the Owens Valley Solar Array: the SOL2003-04-04T20:55 flare with a steep microwave spectrum and the SOL2003-10-19T16:50 flare with a broader spectrum. Our analysis shows that the strong flare with the broader microwave spectrum occurred in a region of highly inhomogeneous magnetic field and vice versa. We further demonstrate that such source properties are consistent with the magnetic field observations from the Michelson Doppler Imager instrument onboard the Solar and Heliospheric Observatory (SOHO) spacecraft and the extreme ultraviolet imaging observations from the SOHO extreme ultraviolet imaging telescope. This spectral inversion tool is particularly useful for analyzing microwave flux spectra of strong flares from magnetically complex systems.

• The Bulletin of The Korean Astronomical Society
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• v.43 no.2
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• pp.59.2-59.2
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• 2018

We introduce a new project of constructing a large spectro-photometric samples of metal-poor (i.e. [Fe/H] < -1.0) subdwarfs in the Galactic halo. The sample is collected from a compilation of the stellar objects that are cross-identified both in the Sloan Digital Sky Survey (SDSS) and recently published data from GAIA mission. The color range of the selected stars covers 0.0 < (g-r) < 2.0; thus the spectral types of our sample span from early F- through late K-type stars on the metal-poor main sequence (i.e. the local subdwarf sequence). We scrutinized the physical, chemical, and kinematical properties of our samples using their SDSS medium-resolution (R ~ 2000) spectra, combined with accurately measured proper motions from GAIA satellite. Our study will provide useful information on the global trend in the various properties (e.g. abundance pattern as a function of the galactocentric distance; rotational velocity vs [Fe/H] ${\cdots}$ etc) of the metal-poor subdwarf populations in the Galactic halo, which is ultimately important to better understand metal-poor stellar evolutionary models and chemical evolution of the Milky Way halo in the early phase of its formation. Further our comprehensive catalog of the Galactic field halo subdwarfs collected in this study will serve a solid groundwork for future follow-up high resolution spectroscopic observations on many interesting individual targets.