• Title/Summary/Keyword: New spectra

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New red light-emitting copolymer based on polyfluorene

  • Cho, Nam-Sung;Hwang, Do-Hoon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.721-723
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    • 2002
  • We report a new red light emitting fluorene-based copolymer, poly{9,9-bis(2'-ethylhexyl)fluorene-2,7-diyl-co-2, 5-bis(2-thienyl-1-cyanovinyl}-1-(2'-ethylhexyloxy)-4methoxybenzene-5",5'''-diyl} (PFTCVB). The synthesized copolymers showed the absorption maxima at about 380 nm and the absorption between 425 and 600 nm increased as the fraction of the thiophene-containing monomer (BTCVB) increased. In PL, the emission maxima of the copolymers were red-shifted as the fraction of BTCVB increased, despite the similar absorption characteristics were shown in the UV-visible spectra. The copolymer containing 15 mol% of BTCVB showed a maximum PL and EL emission at 620 and 630 nm.

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Reduction of Audible Switching Acoustic Noise in Motor Drives by a New Two Phase Random Pulse Position PWM Scheme (새로운 2상 랜덤 펄스 위치 PWM기법에 의한 모터 구동 시스템의 가청 스위칭 소음 저감)

  • Wi, Seog-Oh;Lim, Young-Cheol;Na, Seok-Hwan;Jung, Young-Gook
    • Proceedings of the KIEE Conference
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    • 2002.04a
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    • pp.82-89
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    • 2002
  • In this paper, a new two-phase space vector RPWM(Random PWM) is proposed. In the proposed RPWM, each of two-phase PWM pulses is located randomly in each switching interval. Based on the space vector modulation technique, the duty ratio of the pulses is calculated. Along with the randomization of the PWM pulses, we can obtain the effects of spread spectra of inverter output voltage, d.c link current and audible switching acoustic noise as in the case of randomly changed switching frequency. To verify the validity of the proposed two-phase RPWM scheme, the experiment based on the C167 micro-controller was executed. The performance of the proposed scheme was compared with traditional PWM schemes experimentally.

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Elastic Wave Resonance Scattering from a Fluid-filled Cylindrical Cavity (유체가 채워진 실린더형 공동에 의한 탄성파 공명 산란 해석)

  • Huinam Rhee;Park, Youngjin
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.208-213
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    • 2002
  • A new method is presented for the isolation of resonances from scattered waves for elastic wave resonance scattering problems. The resonance scattering function consisting purely of resonance information is defined. Elastic wave resonance scattering from a water-filled cylindrical cavity imbedded in an aluminum matrix is numerically analyzed. The classical resonance scattering theory and the new method compute different magnitudes and phases of the resonances from each partial wave, and therefore. their total resonance spectra are quite different. The exact $\pi$ - radians phase shifts through the resonance and anti-resonance frequencies show that the proposed method properly extracts the vibrational resonance information of the scatterer compared to resonance scattering theory.

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Novel Antioxidants, Stc-l and Stc-2, from Stereum ostrea

  • Kim, Young-Hee;Yun, Bong-Sik;Kim, Jong-Pyong;Moon, Suk-Sik;Yoo, Ick-Dong
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1998.11a
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    • pp.131-131
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    • 1998
  • In the course of screening for new natural compounds having antioxidant activity from microbials, mushrooms as well as plants. We have isolated novel sesquiterpenoid and officinalic acid from methanolic extracts of Stereum ostrea. The dried fruit body( 450 g) of Stereum ostrea was extracted with methanol, then methanolic extract was partitioned between water and hexane, chloroform, and ethyl acetate, subsequently. The chloroform extract was subjected on silica gel, Sephadex LH-20 and RP-18 column chromatography, successively. And two compounds were isolated and identified as new triterpenoids and officinalic acid using $^1$H - NMR, $\^$13/C - NMR as well as Mass spectra.

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Study of 4-Nitroazoxybenzenes (Part Ⅰ) Separation of the Isomers of 4-Nitroazoxybenzenes and their Structure Study by U.V. Spectrophotometry (4-Nitroazoxybenzene 에 關한 硏究 (第1報) 4-Nitroazoxybenzene 의 $\{alpha}$- 및 ${\beta}$- 異性體의 分離와 U.V. Spectrophotometry에 의한 그 構造硏究)

  • Chi Sun Hahn;Byung Hi Yun;Hyuk Koo Lee
    • Journal of the Korean Chemical Society
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    • v.7 no.3
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    • pp.197-202
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    • 1963
  • The ${\alpha}-and\;{\beta}$-isomer of 4-nitroazoxybenzenes have been separated by liquid chromatography and their U.V. spectra were examined. The n${\to}{\pi}^{\ast}$ transition band of the compounds did not appear, likewise the cases of other compounds of the series. Transition band of the new isomer were as usual as those of other azoxy-compounds, whereas the ${\pi}{\to}{\pi}^{\ast}$ transition band of the other isomer which is reported in the literature shown peculier hypochromic shift and hypochromic effect. From the spectroscopic point of view it is very likely that the new isomer (m.p. $184-5^{\circ}C$) is ${\alpha}$-isomer and the other one (m.p. $152^{circ}C$) is ${\beta}$-isomer contrary to the literature.

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Preparation and Structure Determination of a New Glycoside, (20E)-Ginsenoside $Rh_3$, and its isomer from Diol-type Ginseng Saponins (인삼의 diol계 사포닌으로부터 새로운 배당체 (20E)-Ginsenoside $Rh_3$ 및 그의 입체이성체의 제조와 구조결정)

  • 김동선;백남인;박종대;이유희;정소영;이천배;김신일
    • YAKHAK HOEJI
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    • v.39 no.1
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    • pp.85-93
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    • 1995
  • Acidic and alkaline hydrolysis of diol-type ginseng saponins produced a new glycoside, (20E)-ginsenoside Rh$_{3}$, and its stereoisomer (20Z)-, which were further subjected to alkaline by drolysis to give their aglycones, (20E)- and (20Z)-3$\beta$, 12$\beta$-dihydroxy-dammar-20(22),24-diene. The ratio of stereoisomeric mixtures was estimated to be ca. 5:1 from intensities of the peaks in $^{1}$H- and $^{13}$C-NMR spectra. The $^{1}$H- and $^{13}$C-NMR signals of ginsenoside Rh$_{3}$, which have remained unclarified, were completely assigned by the extensive application of modern NMR techniques.

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Syntheses and Antibacterial Activities of New Quinolones Containing cis- or trans-3-Amino-4-methylthiomethylpyrrolidino Moiety (시스 또는 트란스-3-아미노-4-메틸티오메틸피롤리디닐기를 포함하는 퀴놀론 항균물질의 합성과 효능검색)

  • Lee, Jae-Wook;Lim, Gui-Taek
    • Journal of Life Science
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    • v.13 no.6
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    • pp.943-949
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    • 2003
  • New quinolone derivatives of 7-(cis- or trans-3-amino-4-mehtylthiomethylpyrrolidinyl) quinolone-3-carboxylic acids were synthesized by condensation of 7-halo substituted quinolone-3-carboxylic acids with cis- or trans-3-amino-4-mehtylthiomethylpyrrolidine. Some of these compounds showed broad spectra of antibacterial activities against Gram-positive and Gram-negative organisms except Pseudomonas aeruginosa, and exhibited much stronger activity against MRSA.

Generating of the same hue population using hue angle and chroma vector (색상각와 채도벡터를 이용한 동일색상의 분광반사 모집단 생성)

  • 유미옥;서봉우;안석출
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.2
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    • pp.1-12
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    • 2000
  • This paper proposes a new algorithm classifing same hues in order toe estimate the spectral reflectance of object from 3 band color image information. To estimate the spectral reflectance of object, the conventional estimation methods are required of 5 or 9 band digital color values. The 5 or 9 band image acquisition systems are required of 5 or 3 times same work for color image acquisition process. To solve the above problems, we propose a new method that can be estimated spectra reflectance estimation of object. The proposed method is to classify same hues corresponding a color stimulus, by using hue angle and chroma vector of a color stimulus. The classified same hues are used as the population corresponding a color stimulus. The range of same hue is estimated by the cumulative proportional ration according to the number of basis function.

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A New Space Vector Random Position PWM Scheme (새로운 공간벡터 Random Position PWM기법)

  • Kim, Hoe-Geun;Lim, Young-Cheol;Na, Seok-Hwan;Jung, Young-Gook
    • Proceedings of the KIEE Conference
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    • 2001.10a
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    • pp.168-174
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    • 2001
  • In this paper, a new space vector RPPWM (Random Position PWM) is proposed. In the proposed RPPWM, each of three phase pulses is located randomly in each switching interval. Based on the space vector modulation technique, the duty ratio of the pulses is calculated. Along with the randomization of the PWM pulses, we can obtain the effects of spread spectra of voltage, current as in the case of randomly changed switching frequency. To verify the validity of the proposed RPPWM, simulation study was tried using Matlab/simulink. The main model described in Simulink block diagrams includes the space vector modulation block, pulse position randomization block, inverter block, 3 phase induction motor block, and so on. By the simulation study, the harmonics of the output voltage, and the current of inverter are predicted in different PWM methods- SVPWM, LLPWM, proposed RPPWM.

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In-line (α,n) source sampling methodology for monte carlo radiation transport simulations

  • Griesheimer, David P.;Pavlou, Andrew T.;Thompson, Jason T.;Holmes, Jesse C.;Zerkle, Michael L.;Caro, Edmund;Joo, Hansem
    • Nuclear Engineering and Technology
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    • v.49 no.6
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    • pp.1199-1210
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    • 2017
  • A new in-line method for sampling neutrons emitted in (${\alpha}$,n) reactions based on alpha particle source information has been developed for continuous-energy Monte Carlo simulations. The new method uses a continuous-slowing-down model coupled with (${\alpha}$,n) cross section data to precompute the expected neutron yield over the alpha particle lifetime. This eliminates the complexity and computational cost associated with explicit charged particle transport. When combined with an integrated alpha particle decay source sampling capability, the proposed method provides an efficient and accurate method for sampling (${\alpha}$,n) neutrons based solely on nuclide inventories in the problem, with no additional user input required. Results from several example calculations show that the proposed method reproduces the (${\alpha}$,n) neutron yields and energy spectra from reference experiments and calculations.