• Title/Summary/Keyword: New spectra

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Room-temperature Ferromagnetism in Fe-doped Reduced TiO2-δ (산소 결핍에 따른 Fe가 도핑된 TiO2-δ의 상온 강자성 현상에 관한 연구)

  • Lee, H.M.;Kim, C.S.;Uhm, Y.R.;Rhee, C.K.
    • Journal of Powder Materials
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    • v.13 no.6 s.59
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    • pp.401-407
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    • 2006
  • Effects of oxygen deficiency on the room temperature ferromagnetism in Fe-doped reduced $TiO_2$ have been investigated by comparing the air-annealed $Ti_{0.97}Fe_{0.03}O_2$ compound with secondly post-annealed one in vacuum ambience. The air-annealed sample showed a paramagnetic behavior at room temperature. However, when the sample was further annealed in vacuum, a strongly enhanced ferromagnetic behavior was observed at same temperature. $M{\"{o}}ssbauer$ spectra of air-annealed sample at 295K showed a single doublet of $Fe^{3+}$, suggesting that the Fe ions are paramagnetic. On the other hand, the absorption spectra after vacuum-annealing exhibited two doublets, in which one is the same component with air-annealed sample and the other is new doublet corresponding to $Fe^{2+}$ state. This result suggests that the occurrence of ferromagnetism in reduced sample may be interpreted as the contribution of unquenched orbital moment of $Fe^{2+}$ ions.

Classification of Hyperspectral Images Using Spectral Mutual Information (분광 상호정보를 이용한 하이퍼스펙트럴 영상분류)

  • Byun, Young-Gi;Eo, Yang-Dam;Yu, Ki-Yun
    • Journal of Korean Society for Geospatial Information Science
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    • v.15 no.3
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    • pp.33-39
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    • 2007
  • Hyperspectral remote sensing data contain plenty of information about objects, which makes object classification more precise. In this paper, we proposed a new spectral similarity measure, called Spectral Mutual Information (SMI) for hyperspectral image classification problem. It is derived from the concept of mutual information arising in information theory and can be used to measure the statistical dependency between spectra. SMI views each pixel spectrum as a random variable and classifies image by measuring the similarity between two spectra form analogy mutual information. The proposed SMI was tested to evaluate its effectiveness. The evaluation was done by comparing the results of preexisting classification method (SAM, SSV). The evaluation results showed the proposed approach has a good potential in the classification of hyperspectral images.

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Investigation on Effective Peak Ground Accelerations Based on the Gyeongju Earthquake Records (경주지진 관측자료에 기반한 유효최대지반가속도 분석)

  • Shin, Dong Hyeon;Hong, Suk-Jae;Kim, Hyung-Joon
    • Journal of the Earthquake Engineering Society of Korea
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    • v.20 no.7_spc
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    • pp.425-434
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    • 2016
  • This study investigates important parameters used to determine an effective peak ground acceleration (EPGA) based on the characteristics of response spectra of historical earthquakes occurred at Korean peninsula. EPGAs are very important since they are implemented in the Korean Building Code for the seismic design of new structures. Recently, the Gyeongju earthquakes with the largest magnitude in earthquakes measured at Korea took place and resulted in non-structural and structural damage, which their EPGAs should need to be evaluated. This paper first describes the basic concepts on EPGAs and the EPGAs of the Gyeongju earthquakes are then evaluated and compared according to epicentral distances, site classes and directions of seismic waves. The EPGAs are dependant on normalizing factors and ranges of period on response spectrum constructed with the Gyeongju earthquake records. Using the normalizing factors and the ranges of period determined based on the characteristics of domestic response spectra, this paper draw a conclusion that the EPGAs are estimated to be about 30 % of the measured peak ground accelerations (PGA).

Synthesis of Novel D-Glucose-derived Benzyl and Alkyl 1,2,3-Triazoles as Potential Antifungal and Antibacterial Agents

  • Wei, Jin-Jian;Jin, Lei;Wan, Kun;Zhou, Cheng-He
    • Bulletin of the Korean Chemical Society
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    • v.32 no.1
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    • pp.229-238
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    • 2011
  • A series of novel glucose derived benzyl and alkyl 1,2,3-triazoles and their hydrochlorides have been synthesized via Cu(I)-catalyzed 1,3-dipolar cycloaddition. All the new compounds were characterized by MS, IR and NMR spectra. The DEPT, APT, $^1H$-$^1H$ and $^1H-^{13}C$ 2D NMR spectra for some compounds were also recorded. These compounds were evaluated for their in vitro antibacterial activities against Staphylococcus aureus ATCC 29213, Bacillus subtilis, Bacillus proteus, Pseudomonas aeruginosa, Escherichia coli ATCC 25922, and antifungal activities against Candida albicans and Aspergillus fumigatus. The bioactive data revealed that (3R,4S,5S,6S)-2-(hydroxymethyl)-6-methoxy-4,5-bis((1-octyl-1H-1,2,3-triazol-4-yl)methoxy)-tetrahydro-2H-pyran-3-ol 8a exhibited excellent antifungal activity against A. fumigatus with an MIC value of 0.055 mM compared to Fluconazole. It also showed broad inhibitory efficacy against tested bacterial strains with MIC values ranging from 0.049 mM to 0.39 mM.

A Novel Spectral Analysis of Ultrashort Pulse Transmission Using the Pulse-Ordering Concept

  • Jae-hong;Hi-chang Chung;Jin-sung Jun;Yong-sun Oh
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.7A
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    • pp.986-993
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    • 2000
  • In this paper, we analyze transmission characteristics of ultrashort laser pulses using the properties of high-order pulses which are systematically obtained following their orders. The high-order pulses are easily derived from a modified PRS system model. But we make clear they are very useful to cover wider area and to show more accurate transmission characteristics of ultrashort pulses than Gaussian or Sech pulse approximations used conventionally. These are based on the fact that the spectra and bandwidths of the high-order pulses are geautifully related to their orders. First modifying the generalized PRS system model, we propose a new model for deriving any type of high-order pulse. And we offer a novel analysis method of ultrashort pulse transmission varying the order of the pulse from n=1 to n=100, we obtain spectra of ultrashort pulses with 1(ps)∼150(fs) FWHM's, which are widely used in optical pulse communications. One-step further, we derive PSD's of their pulse-tr ins when they are applied to Unipolar signaling scheme. These PSD's are decided in the range of possible pulse intervals. All of these results are not only coincided with some conventional experimental works but will be applied to any pioneering ultrashort pulse in the future.

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A Tumor Growth Inhibitory Substance Isolated from Panax ginseng (고려홍삼분말중의 항종양 활성물질)

  • Katano Mitsuo;Yamamoto Hiroshi;Matsunaga Hisashi
    • Proceedings of the Ginseng society Conference
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    • 1988.08a
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    • pp.33-35
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    • 1988
  • During a series of studies aimed at isolation of the tumor growth inhibitory substance from Panax ginseng. we found a new type of antitumor substance. The substance was isolated from a powder of the root of Panax ginseng C.A. Meyer. which is commonly used for various diseases as a commercial medical drug by the name of Korean Red Ginseng Powder in Japan. Data from infrared spectra proton and carbon-13 nuclear magnetic resonance. and high resolution mass spectra were identical with those of panaxytriol. Panaxytriol isolated from Korean Red Ginseng Powder (Nikkan Korai Ninjin Co.. Ltd.. Japan) inhibited the growth of several kinds of human and murine malignant cells in vitro. Although the detailed mechanism of cell growth inhibition by panaxytriol is yet to he elucidated. panaxytriol's action appeares to be more dose-dependent than time-dependent.

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New parametric approach to decomposition of disk averaged spectra of potential extra terrestrial planet I. Surface type ratio of the Earth

  • Ryu, Dong-Ok;Seong, Se-Hyun;Yu, Jin-Hee;Oh, Eun-Song;Ahn, Ki-Beom;Hong, Jin-Suk;Lee, Jae-Min;Kim, Suk-Whan
    • Bulletin of the Korean Space Science Society
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    • 2010.04a
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    • pp.34.2-34.2
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    • 2010
  • We built 7 potential extra-terrestrial planets including the full 3D Earth model with various surface types and 6 planet models, each with uniform surface characteristics. The surface types include ice, tundra, forest, grass, ground and ocean. We then imported these 7 planets into integrated ray tracing(IRT) model to compute their disk averaged spectra and to understand the spectral behavior depending on the geometrical view, illumination phase and seasonal change. The IRT computation show that the 6 planets with uniform surfaces exhibit clear spectral differences from that of the Earth. We then built a phase and seasonal DAS database for the 6 uniform surface planets and used them for parametric spectral decomposition technique to derive the Earth DAS. This computation resulted in the first potential solution to the surface type ratio of the Earth compared to the measured earth surface type ratio. The computational details and the implications are discussed.

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Photodetection Mechanism in Mid/Far-Infrared Dual-Band InAs/GaSb Type-II Strained-Layer Superlattice

  • No, Sam-Gyu;Lee, Sang-Jun;Krishna, Sanjay
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.127-127
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    • 2010
  • Owing to many advantages on indirect intersubband absorption from the hole miniband to the electron miniband based on the type-II band alignment in InAs/GaSb strained-layer superlattice (SLS), InAs/GaSb SLS infrared photodetector (SLIP) has emerged as a promising system to realize high-detectivity quantum photodetector operating up to room temperature in the spectral range of mid-infrared (MIR) to far-infrared (FIR). In particular, n-barrier-n (n-B-n) structure designed for blocking the majority-carrier dark current makes it possible for MIR/FIR dual-band SLIP whose photoresponse (PR) band can be exclusively selected by the bias polarity. In this study, we present the MIR and FIR photoresponse (PR) mechanism identified by dual-band PR spectra and photoluminescence (PL) profiles taken from InAs/GaSb SLIP. In the MIR/FIR PR spectra measured by changing bias polarity, each spectrum individually shows a series of distinctive peaks related to the transitions from the hole subbands to the conduction one. The PR mechanism at each polarity is discussed in terms of diffusion current, and a superposition of MIR-PR in the FIR-PR spectrum is explained by tunnelling of electrons activated in MIR-SLS. The effective FIR-PR spectrum decomposed into three curves for HH1, LH1, and HH2 has revealed the edge energies of 120, 170, and 220 meV, respectively, and the temperature variation of the MIR-PR edge energies shows that the temperature behavior of the SLS systems can be approximately expressed by the Varshni empirical equation.

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Assignment of ¹H and $^{13}C$ Nuclear Magnetic Resonances of Ganglioside $G_{A1}$

  • 이경익;전길자;류경임;방은정;최병석;김양미
    • Bulletin of the Korean Chemical Society
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    • v.16 no.9
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    • pp.864-869
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    • 1995
  • Investigation of the structures of the gangliosides has proven to be very important in the understanding of their biological roles such as regulation of differentiation and growth of cells. We used nuclear magnetic resonance spectros-copy in order to investigate the structure of GA1. In order to do this, the assignment of spectra is a prerequisite. Since GA1 does not have polar sialic acid, the spectral overlap is severe. In order to solve this problem, we use 2D NMR spectroscopy and heteronuclear 1H/13C correlated spectroscopy in this study. Here, we report the complete assignment of the proton and the carbon spectra of the GA1 in DMSO-d6-D20 (98:2, v/v). These assignments will be useful for interpreting 1H and 13C NMR data from uncharacterized oligosaccharides and for determining the linkage position, the number of sugar rings, and the sequence of new ganglioside. Amide proton in ring Ⅲ shows many interring nOes and has intramolecular hydrogen bonding. This appears to be an important factor in tertiary folding of GA1. Based on this assignment, determination of three dimensional structure of GA1 will be carried out. Studies on the conformational properties of GA1 may lead to a better understanding of the molecular basis of its functions.

Synthesis of LaMnO3-Diamond Composites and Their Photocatalytic Activity in the Degradation of Weak Acid Red C-3GN

  • Huang, Hao;Lu, Benqian;Liu, Yuanyuan;Wang, Xeuqian;Hu, Jie
    • Nano
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    • v.13 no.10
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    • pp.1850121.1-1850121.11
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    • 2018
  • In this study, a series of $LaMnO_3$-diamond composites with varied $LaMnO_3$ mass contents supported on micro-diamond have been synthesized using a sol-gel method. The as-prepared composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy and the Fourier transform infrared spectra (FTIR). Meanwhile, the photocatalytic performances were also tested by photoluminescence (PL) spectroscopy, ultraviolet-visible diffuse reflection spectra (UV-Vis DRS) and the degradation of weak acid red C-3GN (RC-3GN). Results show that the peak position of $LaMnO_3$ is shifted to low angle after the introduction of diamond, and perovskite particles uniformly distributed on the surface of diamond, forming a network structure, which can increase the active sites and the absorption of dye molecules. When the mass ratio of $LaMnO_3$ and diamond is 1:2 (LMO-Dia-2), the composite shows the most excellent photocatalytic activity. This result offers a sample route to enlarge the range of the application of micro-diamond and provide a new carrier for perovskite photocatalysts.