• 제목/요약/키워드: New spectra

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Panaxyne epoxide, A New Cytotoxic Polyyne from Panax ginseng Root against L210 Cells

  • Kim, Shin-Il;Kang, Kyu-Sang;Lee, You-Hui
    • Archives of Pharmacal Research
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    • v.12 no.1
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    • pp.48-51
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    • 1989
  • A new polyacetylene compound with cytotoxic activity against L1210 cells having diyne-ene and epoxy moiety, named panaxyne epoxide, was isolated from Panax ginseng C.A. Meyer. The chemical structure of the polyacetylene was determined to be tetradeca-13-ene-1,3-diyne-6,7-epoxide by UV, IR, $^1H-NMR,\;^{l3}$C-NMR and mass spectra.

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A NEW CATALOG OF AGB STARS BASED ON INFRARED TWO-COLOR DIAGRAMS

  • Suh, Kyung-Won;Hong, Jinju
    • Journal of The Korean Astronomical Society
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    • v.50 no.4
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    • pp.131-138
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    • 2017
  • We present a new catalog of AGB stars based on infrared two-color diagrams (2CDs) and known properties of the pulsations and spectra. We exclude some misclassified objects from previous catalogs. We identify color areas in two IR 2CDs where most O-rich and C-rich objects listed in previous catalogs of AGB stars are found. By collecting new objects in these color selection areas in the two IR 2CDs, we find candidate objects for AGB stars. By using the color selection method, we identify 3996 new objects in the O-rich areas, 1487 new objects in the C-rich areas, and 295 new objects in the overlap areas of the two 2CDs simultaneously. We have found that 470 O-rich and 9 C-rich objects are Mira variables with positive spectral identification and they are newly identified AGB stars. We present a new catalog of 3828 O-rich AGB stars and 1168 C-rich AGB stars excluding misclassified objects and adding newly identified objects.

Silver Nanoparticles Effect on Antimicrobial and Antifungal Activity of New Heterocycles

  • Kandile, Nadia G.;Zaky, Howida T.;Mohamed, Mansoura I.;Mohamed, Hemat M.
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3530-3538
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    • 2010
  • In this study 1-[4-(2-methoxy benzyl)-6-aryl-pyridazin-3(2H)-ylidene] hydrazines were used for the synthesis of new heterocyclic systems such as thiazolidine, phthalazine, pyrazolo, tetrazolo, hydrazide and new pyridazine derivatives to explore the effect of silver nanoparticles on their biological activity efficiency. Structures of the new heterocycles were characterized by the aid of several analytical techniques including; $^1H$-NMR, FTIR and mass spectra. Silver nanoparticles were synthesized by a simple methodology and the formation of silver nanoparticles was confirmed by transmission electron microscopy (TEM) and UV studies. Most of the new prepared heterocycles were evaluated in vitro as new antimicrobial agents. Combination effects of the silver nanoparticles on the antimicrobial activity of the new heterocycles were investigated using the disk diffusion method. Compound 10a exhibited the strongest enhancing effect of silver nanoparticles solution against Aspergillus flavus and Candida albicans.

Highly Luminescent Aniline and TiO2 Composite: The Effect of Weight Ratio of Aniline and TiO2

  • Kim, Byoung-Ju;Park, Eun-Hye;Kang, Kwang-Sun
    • Current Photovoltaic Research
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    • v.4 no.1
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    • pp.8-11
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    • 2016
  • Strong deep ultraviolet emitting aniline and $TiO_2$ composite has been synthesized via hydrolysis and condensation reactions of titaniumisopropoxide ($Ti(OPr)_4$), aniline, and acetic anhydride. Three different weight ratios of aniline and $Ti(OPr)_4$ including 3:1 ($TiO_2An-A$), 2:1 ($TiO_2An-B$), and 1:1 ($TiO_2An-C$) were synthesized and characterized their optical properties. The FTIR spectra of the $TiO_2An-A$, -B, and -C showed the absorption intensities of the benzene ring stretching and bending vibrations, and benzene ring -CH stretching, bending, and deformation vibrations increased with the increase of the amount of aniline. The UV-visible absorption spectra showed that the UV region absorption was slightly increased with the increase of the amount of aniline. The photoluminescence (PL) intensities were exponentially increased with the increase the excitation wavelength from 307 to 317 nm, steadily increased from 300 to 313 nm and slowly increased from 302 to 308 nm for $TiO_2An-A$, -B, and -C, respectively and decreased thereafter. Therefore, the PL intensity is strongly dependent on the weight ratio of $Ti(OPr)_4$ and aniline.

Correlation of elastic input energy equivalent velocity spectral values

  • Cheng, Yin;Lucchini, Andrea;Mollaioli, Fabrizio
    • Earthquakes and Structures
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    • v.8 no.5
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    • pp.957-976
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    • 2015
  • Recently, two energy-based response parameters, i.e., the absolute and the relative elastic input energy equivalent velocity, have been receiving a lot of research attention. Several studies, in fact, have demonstrated the potential of these intensity measures in the prediction of the seismic structural response. Although some ground motion prediction equations have been developed for these parameters, they only provide marginal distributions without information about the joint occurrence of the spectral values at different periods. In order to build new prediction models for the two equivalent velocities, a large set of ground motion records is used to calculate the correlation coefficients between the response spectral values corresponding to different periods and components of the ground motion. Then, functional forms adopted in models from the literature are calibrated to fit the obtained data. A new functional form is proposed to improve the predictions of the considered models from the literature. The components of the ground motion considered in this study are the two horizontal ones only. Potential uses of the proposed equations in addition to the prediction of the correlation coefficients of the equivalent velocity spectral values are shown, such as the prediction of derived intensity measures and the development of conditional mean spectra.

Bonding And Anti-bonding Nature of Magnetic Semiconductor Thin Film of Fe(TCNQ:tetracyanoquinodimethane)

  • Jo, Junhyeon;Jin, Mi-jin;Park, Jungmin;Modepalli, Vijayakumar;Yoo, Jung-Woo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.294-294
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    • 2014
  • Developing magnetic thin films with desirable physical properties is a key step to promote research in spintronics. Organic-based magnetic material is a relatively new kind of materials which has magnetic properties in a molecular and microscopic level. These materials have been constructed by the coordination between 3d transition metal and organic materials producing long-range magnetic orders with a relatively high transition temperature. However, these materials were mostly synthesized as a form of powder, which is difficult to study for their physical properties as well as apply for electronic/spintronic devices. In this study, we have employed physical vapor deposition (PVD) to develop a new organic-based hybrid magnetic film that is achieved by the coordination of Fe and tetracyanoquinodimethane (TCNQ). The IR spectra of the grown film show modified CN vibration modes in TCNQ, which suggest a strong bonding between Fe and TCNQ. The thin film has both ferromagnetic and semiconducting behaviors, which is suitable for molecular spintronic applications. The high resolution photoemission (HRPES) spectra also show shift of 1s peak point of nitrogen and the carbon 1s peaks display traces of charge transfer from Fe to TCNQ as well as shake-up features, which suggest strong bonding and anti-bonding nature of coordination between Fe and TCNQ.

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Study on Optimal Coefficients of Line Broadening Function for Performance Enhancements of CT-TDLAS (CT-레이저흡수분광법(TDLAS) 성능향상을 위한 레이저 선폭확장 함수 최적 계수 선정에 관한 연구)

  • CHOI, DOOWON;CHO, GYONGRAE;DEGUCHI, YOSHIHIRO;BAEK, TAESIL;DOH, DEOGHEE
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.6
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    • pp.773-782
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    • 2016
  • The performance of the CT-TDLAS (computed tomography-tunable diode laser absorption spectroscopy) is strongly dependent upon the line broadening functions. The line of the laser beam used in the TDLAS is scattered by the natural broadening, the collisional broadening and the doppler broadening. The influence of the natural broadening to the experimental spectra obtained in the TDLAS is negligible. The influences of the collisional broadening and the doppler broadening to the experimental spectra are relatively large, in high pressure gas flows and in high temperature low pressure gas flows, respectively. In this study, optimal coefficients are proposed for the doppler broadening function by using the experimental data obtained in a flat burner test. The optimal coefficients were ${\gamma}_j=0.16$ and n=0.37. Using these coefficients, the temperature and concentration distributions at the engine exhaust gas pipe have been calculated showing their validities.

Evaluation of pulse effect on frequency content of ground motions and definition of a new characteristic period

  • Yaghmaei-Sabegh, Saman
    • Earthquakes and Structures
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    • v.20 no.4
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    • pp.457-471
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    • 2021
  • This study aims at providing a simple and effective methodology to define a meaningful characteristic period for special class of earthquake records named "pulse-like ground motions". In the proposed method, continuous wavelet transform is employed to extract the large pulse of ground motions. Then, Fourier amplitude spectra obtained from the original ground motion and the residual motion is simply compared. This comparison permits to define a threshold pulse-period (Tp∗) as the threshold period above which the pulse component has negligible contributions to the Fourier amplitude spectrum. The effect of pulse on frequency content of motions was discussed on the light of this definition. The advantage and superior features of the new definition were related to the inelastic displacement ratio (IDR) for single-degree-of-freedom systems with period equal to one half of the threshold period. Analyses performed for the proposed period at three ductility levels u=2,4,6 were compared with the results obtained at half of pulse period derived from wavelet analysis, peak-point method and the peak of product of the velocity and the displacement response spectra (Sv x Sd). According to the results, pulse effects on inelastic displacement ratio seem to be more important when $\frac{T_p^*}{T}=2$ (T is the fundamental vibration period of system). The results showed that utilizing of the proposed definition could facilitate an enhanced understanding of pulse-like records features.

Retrofit Yield Spectra-a practical device in seismic rehabilitation

  • Thermou, G.E.;Elnashai, A.S.;Pantazopoulou, S.J.
    • Earthquakes and Structures
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    • v.3 no.2
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    • pp.141-168
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    • 2012
  • The Retrofit Yield Spectrum (RYS) is a new spectrum-based device that relates seismic demand of a retrofitted structure with the fundamental design parameters of the retrofit. This is obtained from superposition of Yield Point Spectra with design charts that summarize in pertinent spectrum-compatible coordinates the attributes of a number of alternative retrofit scenarios. Therefore, once the requirements for upgrading a given structure have been determined, the RYS enable direct insight of the sensitivity of the seismic response of the upgraded structure to the preliminary design decisions made while establishing the retrofit plan. By virtue of their spectrum-based origin, RYS are derived with reference to a single mode of structural vibration; a primary objective is to control the contribution of this mode in the retrofit design so as to produce a desirable distribution of damage at the ultimate limit state by removing soft storey formations and engaging the maximum number of structural members in deformation, in response to the input motion. Calculations are performed with reference to the yield-point, where secant stiffness is proportional to the flexural strength of reinforced concrete members. Derivation and use of the Retrofit Yield Spectra (RYS) refers to the seismic demand expressed either in terms of spectral acceleration, spectral displacement or interstory drift, at yield of the first storey. A reinforced concrete building that has been tested in full scale to a sequence of simulated earthquake excitations is used in the paper as a demonstration case study to examine the effectiveness of the proposed methodology.