• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2000년도 춘계학술강연 및 발표대회 강연 및 발표논문 초록집
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• pp.11-11
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• 2000

Large-size ceramic/metal bulk FGMs have been fabricated on a recently developed and the world's largest Spark Plasma Sintering(SPS) systems, As a part of the development program for practical production processes and machines for FGMs by SPS, the processes, mechanical properties, dimensional size and shape effects, and production machine systems were investigated. In the past, $ZrO_{2}$/TiAI, $ZrO_{2}$/Ni, $Al_{2}O_{3}$/Ti, WC/Co, WC/Co/Steel, A1/P, Polymide, Cu/Polymide, nano-composites, porous and other combinations of bulk FGMs have already been processed using SPS. However, most of the specimen sizes were small, in a range of 20 to 30mm in diameter. Recently disk-shape sintered compacts with diameters of 100 and 150 mm, and thickness of approximately 15 and 17 mm, $ZrO_{2}$(3Y)/ stainless steel FGMs were homogenous consolidated in a shorter sintering time, while maintaining high quality and repeatability by utilizing a temperature gradient sintering method. The SPS heating up and holding time totaled less than one hour. Therefore, the SPS process in expected to find increased use in the fabrication of large-size FGMs as a new industrial processing technology. This paper introduces SPS systems, the processing principles, features and the characteristies of ceramic/metal bulk FGM.

• 한국결정성장학회지
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• 제9권5호
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• pp.475-479
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• 1999

Langasite ($La_{3}Ga_{5}SiO_{14}$) was found to have wide application as a promising piezoelectric material. It has high thermal stability of the frequency and large electromechanical coupling factor. For the further development of new compounds with langasite type structure, powders in the La-Al-Si-O system were synthesized by a modified Pechini process. The evolution of the crystalline phase during calcination was studied using TG-DTA, XRD and TEM for the precursor powders. Decomposition proceeded via dehydration and removal of excess solvents at low temperatures ($T<500^{\circ}C$), followed by the crystallization of lanthanum aluminum silicate ($T>800^{\circ}C$) and phase transformation to $LaAlO_{3}$ phase ($T>1200^{\circ}C$). Transmission electron microscopy (TEM) of the calcined powders showed diffuse hollow rings corresponding to an amorphous phase at $800^{\circ}C$ and clear diffraction patterns corresponding to a crystalline phase from the P321 space group ($T<1200^{\circ}C$) and the R3m ($T<1200^{\circ}C$).

• Journal of Ceramic Processing Research
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• 제13권spc2호
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• pp.428-432
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• 2012

Polyamidimide (PAI)-colloidal silica (CS) nanohybrid films were synthesized by an advanced sol-gel process. The synthesized PAI-CS hybrid films have a uniform and stable chemical bonding and there is no interfacial defects observed by TEM. The thermal degradation ratio of PAI-CS (10 wt%) hybrid films is delayed by 100 ℃ compared with pure PAI sample determined by on set temperature range in TGA. The dielectric constant of PAI-CS (10 wt%) hybrid films decreases with increasing CS content up to about 5 wt% but increases at higher CS content, which is not explained simply by effective medium therories (EMT). The duration time of PAI-CS (10 wt%) hybrid coil is 38 sec, which is very longer than that of pure PAI coil sample. The PAI-CS (10 wt%) hybrid film has a higher breakdown voltage resistance than the pure PAI film at surge environment and exhibits superior heat resistance. The PAI-CS (10 wt%) sample shows the advanced and stable thermal emission properties in transformer module compared with the pure PAI sample. This result illustrates that the advanced thermal conductivity and expansion properties of PAI-CS sample in the case of appropriate sol-gel processes brings the stable thermal emission in transformer system. Therefore, new PAI-CS hybrid samples with such stable thermal emission properties are expected to be used as a high functional coating application in ET, IT and electric power products.

• 한국세라믹학회지
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• 제37권2호
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• pp.181-185
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• 2000

A new technique capable of accelerating the crystallization of ferrite powder at low temperature is developed. Effects of the ultrasonic waves on the crystallization were studied for ferrite powders prepared using the co-precipitation method. The crystallization of the ferrite powders exposed to the ultrasonic waves were characterized by the XRD. The amorphous ferrite powders prepared using the co-precipitation method were crystallized as a result of the exposure to the ultrasonic waves for 5h and the crystallization of the ferrite powders became more enhanced in proportion to the time exposed. The ferrite powder exposed to the ultrasonic waves for 25h had higher crystallinity a larger specific surface area than the ferrite powder calcined at 500$^{\circ}C$ for 2h.

• 한국세라믹학회지
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• 제46권4호
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• pp.345-349
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• 2009

In Part II, the paper will describe a three-phase alumina-based nanoceramic composite demonstrating superplasticity at a surprisingly lower temperature and higher strain rate. One important factor in the processing of these nanocomposites was the use of the electrical field assisted sintering method, SPS. These improvements in mechanical properties were briefly discussed in the context of the results from the microstructural investigations. SPS forming approach provides a new route for low temperature and high-strain-rate superplasticity for nanostructured materials and should impact and interest a broad range of scientists in materials research and superplastic forming technology.

• 한국세라믹학회지
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• 제45권4호
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• pp.204-207
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• 2008

This paper presents a new process for producing SiC fiber-SiC matrix(SiC/SiC) composites by reaction sintering. The processing strategy for the fabrication of the SiC/SiC composites involves the following: (1) infiltration of the SiC fiber fabric using a slurry consisting of Si and C precursors, (2) stacking the slurry-infiltrated SiC fiber fabric at room temperature, (3) cross-linking the stacked composites, (4) pyrolysis of the stacked composites, and (5) hot-pressing of the pyrolyzed composites. It was possible to obtain dense SiC/SiC composites with relative densities of >96% and a typical flexural strength of ${\sim}400$ MPa.

• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2003년도 춘계학술대회 논문집
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• pp.107-112
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• 2003

The recent machine tools are requested so high-quality processing and productivity increasing. Therefore, it is so necessary to develop technology for high-speed and high-precision. This thesis touches on the development of high speed and intellectual line center. At first, the line center is necessary that strong structure, compact structure and light weight design for high-speed processing and transfer. So, it is necessary that examination of new materials and structures for light-weight and control devices for precision processing. So, it is going to make mention of the process of 1st model production for the above-mentioned based on test model production and evaluation.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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• pp.1088-1090
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• 2002

In this study, a new processing route of barrier ribs for the plasma display panels was attempted. A slurry containing ceramic powders for the barrier ribs, binder, hardener, and other additives, was molded into a PDMS mold by capillary infiltration process. The molded slurry was cured prior to mold removal. It was demonstrated that the process can fabricate successfully the cell type barrier ribs of PDP.

• 한국세라믹학회지
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• 제53권3호
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• pp.317-324
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• 2016

Continued miniaturization and increasingly exact requirements for thin film deposition in the semiconductor industry is driving the search for new effective, efficient, selective precursors and processes. The requirements of defect-free, conformal films, and precise thickness control have focused attention on atomic layer deposition (ALD). ALD precursors so far have been developed through a trial-and-error experimental approach, leveraging the expertise and tribal knowledge of individual research groups. Precursors can show significant variation in performance, depending on specific choice of co-reactant, deposition stage, and processing conditions. The chemical design space for reactive thin film precursors is enormous and there is urgent need for the development of computational approaches to help identify new ligand-metal architectures and functional co-reactants that deliver the required surface activity for next-generation thin-film deposition processes. In this paper we discuss quantum mechanical simulation (e.g. density functional theory, DFT) applied to ALD precursor reactivity and state-of-the-art automated screening approaches to assist experimental efforts leading toward optimized precursors for next-generation ALD processes.

• 세라미스트
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• 제10권3호
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• pp.91-97
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• 2007

Femtosecond laser micro-processing received much attention in the past decade. The nature of ultra-short light-matter interaction permits femtosecond laser to overcome the diffraction limit and realize precise micro-processing. The ultrahigh light intensity of the femtosecond laser allows sapece-selective microscopic modifications to materials based on multiphoton processes. In this paper, we review our recent research development on space-selective precipitation and control of functional crystals in glasses by an infrared femtosecond laser. The technique will open new possibilities in the fabrication of micro-optical components with various optical functions.