• Food Science and Industry
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• v.51 no.2
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• pp.114-126
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• 2018

The production of high quality oil to meet new standard needs a 'next generation' innovative oil refining tool in paradigm shift. 'Nanoneutralization' using controlled hydrodynamic cavitation-assisted Nanoreactor is successfully being introduced and commercialized into edible oil industry and it plays a key driver for sustainable development of food processing. This emerging technology using bubble dynamics as a consequence of Bernoulli's principle by hydrodynamic cavitation in Venturi-designed multi-flow through cell is radically changing the conventionally chemical-oriented neutralization. Nanoneutralization derived by the creation of nanometer-sized bubbles formed through scientifically structured geometric channels under high pressure has been proven to improve mass transfer and reaction rate so substantially reduce the chemicals required for refined vegetable oil and to increase oil yield while even improving oil quality. More researches on science behind this revolutionary technology will help usto better understand the principle and process hence makes its potential applications expandable in extraction, refining and modification of fats and oils processing.

• Journal of the Korean Chemical Society
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• v.64 no.3
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• pp.175-188
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• 2020

The purpose of this study was to analyze chemistry textbooks and teachers' guidebooks from the perspective of 'Ignorance', one of the important features of model. This is because the emphasis is on developing modeling capabilities for students in the 2015 Revised Curriculum. For this, Arrhenius model and Brønsted-Lowry model were selected as acid and base models in neutralization reaction which are important contents in chemistry curriculum. The analysis criteria of this study were extracted by analyzing previous studies and four general chemistry textbooks dealing with 'Ignorance' related to acid and base neutralization reaction. Based on the analysis criteria, we analyzed nine chemistry I textbooks and teacher's guides and six chemistry II textbooks and teacher's guides of the 2015 revised curriculum. In addition, we analyzed contents of four chemistry I textbooks and teacher's guides and three chemistry II textbooks and teacher's guides in the 2009 revised curriculum for comparison according to revised curriculums. We analyzed the contents related to the concept of 'neutralization reaction', 'neutrality', 'quantitative relation of neutralization reaction', 'degree of ionization', and 'ionization constant'. Based on the results of this study, we proposed a way to present 'Ignorance' of the models in teachers' guidebooks that chemistry teachers can understand 'Ignorance' of model and teach modeling capabilities for students.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.06a
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• pp.99-105
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• 2000

Greases composed of base oil and thickener are widely used in the purpose of lubrication and anti-corrosion of machinery. However, greases are sometimes oxidized and decomposed by heat of friction, and produced organic acid. And the greases leaked out ordinary spot make the concrete structures weaken. In this study, the chemical effects of the greases with the concrete structures were investigated through oxidation reaction under pressure and oxygen, and evaluated by the analysis of TAN, Ca content, FT-IR and XRD of grease and cement powder after the oxidation reaction. As the results, TAN value decreased with the increase of the content of cement because of neutralization of organic acid produced by the oxidation of grease with calcium contained in the cement. The content of calcium linearly increased with the increase of cement due to calcium salt by neutralization of acid. Also, according to XRD results of the cement powder oxidized at 99 $^{\circ}C$, the diffraction peak due to calcium hydroxide decreased in comparison with that at room temperature because of the reaction of calcium and organic acid.

• Economic and Environmental Geology
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• v.51 no.4
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• pp.359-370
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• 2018

The batch and column experiments were performed to overcome the limitation of the neutralization process using the $scCO_2$-water-recycled aggregate, reducing its treatment time to 3 hour. The waste cement mortar and two kinds of recycled aggregate were used for the experiment. In the extraction batch experiment, three different types of waste mortar were reacted with water and $scCO_2$ for 1 ~ 24 hour and the pH of extracted solution from the treated waste mortar was measured to determine the minimum reaction time maintaining below 9.8 of pH. The continuous column experiment was also performed to identify the pH reduction effect of the neutralization process for the massive recycled aggregate, considering the non-equilibrium reaction in the field. Thirty five gram of waste mortar was mixed with 70 mL of distilled water in a high pressurized stainless steel cell at 100 bar and $50^{\circ}C$ for 1 ~ 24 hour as the neutralization process. The dried waste mortar was mixed with water at 150 rpm for 10 min. and the pH of water was measured for 15 days. The XRD and TG/DTA analyses for the waste mortar before and after the reaction were performed to identify the mineralogical change during the neutralization process. The acryl column (16 cm in diameter, 1 m in length) was packed with 3 hour treated (or untreated) recycled aggregate and 220 liter of distilled water was flushed down into the column. The pH and $Ca^{2+}$ concentration of the effluent from the column were measured at the certain time interval. The pH of extracted water from 3 hour treated waste mortar (10 ~ 13 mm in diameter) maintained below 9.8 (the legal limit). From XRD and TG/DTA analyses, the amount of portlandite in the waste mortar decreased after the neutralization process but the calcite was created as the secondary mineral. From the column experiment, the pH of the effluent from the column packed with 3 hour treated recycled aggregate kept below 9.8 regardless of their sizes, identifying that the recycled aggregate with 3 hour $scCO_2$ treatment can be reused in real construction sites.

• Korean Security Journal
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• no.14
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• pp.311-336
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• 2007

This study examines the concepts of counter-act against the Bio-terrorism and the reaction system in advanced countries, thereby to find out reaction system necessary to Korea. Acts on anti-Bio-terrorism is divided to detection stage, protection stage, diagnosis stage and detoxication and neutralization stage according to flow of event occurrence. As for detection stage, Korea is developing it as contact type, while advanced countries are under development of the devices that may detect the terrorism from the remote distance. It is necessary for Korea to develop the remote-distant detection system as well as the contact type of device that may promptly operate. Among the protection gears, the quality of Korea's gas mask is recognized worldwide, but that of other outfits should be improved by applying the state-of-art science technology. The diagnosis device also should be developed to the extent that the dispatched initial action team may make immediate decisions necessary in the field. As the current trends for detoxication materials worldwide require the improvement to new materials harmless to human body and equipment, Korea is also required to acquire those materials. The technology for neutralization means the development of vaccine and antibiotics and it requires the development made by shared efforts worldwide. For this purpose, it is necessary to further develop Korea's medical technology. In addition, the further efforts are required in terms of reaction manual, training model, public communication efforts and preparation for trauma syndrome.

• Journal of Veterinary Clinics
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• v.34 no.3
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• pp.197-199
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• 2017

A 14-year-old castrated male ShihTzu diagnosed with chronic kidney disease (CKD) 6 months prior was referred to our clinic. The patient had been experiencing symptoms such as vomiting, poor appetite and hind limbs weakness. Hematology tests showed that he had a non-regenerative anemia. With aggressive treatment, the patient's state had gotten worse. He showed ragged breath, vomiting blood and loss of consciousness temporarily. Hematocrit maintained low level. Gastric hemorrhage was strongly suspected by hematemesis. Whole blood transfusion was performed and heparin was used as an anticoagulant. Prior to transfusion, the blood cross matching between donor and patient was performed and the result was compatible. After the transfusion was stabilized, 1 mg of protamine sulfate for each 100 units of heparin was prepared and given intravenously over 3 minutes to reverse the effects of heparin. Immediately after protamine injection, the patient conducted severe anaphylactic shock. Protamine sulfate is used to reverse the anticoagulant action of heparin in dogs and humans. The adverse reaction of protamine sulfate range from mild reaction to fetal cardiac arrest. When using protamine sulfate as heparin neutralization, it can lead to the death of a patient cause of anaphylactic shock. For this reason, the protamine sulfate should be injected slowly with antihistamine and the clinician should carefully monitor patients.

• Resources Recycling
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• v.10 no.6
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• pp.15-21
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• 2001

Shape-controlled copper oxides have been recovered from copper-containing waste etchant by neutralization with alkalihydroxide. Large amount of copper-containing waste etchant is generated from Printed Circuit Board industry. In an environmental and economic point of view, retrieve of the valuable natural resource from the waste is important. In recycling process of copper oxide from the waste etchant, reaction temperature controls shapes and sizes of the products. Copper oxide recovered below reaction temperature $40^{\circ}C$ was of a needle shape, while copper oxide comes in a platy shape above $40 ^{\circ}C$ . Physical properties of samples have been characterized using SEM, XRD, TGA and Atomic absorption spectroscopy.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.11 no.5
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• pp.185-189
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• 2001

Amorphous aluminium phosphate powders were synthesized as a single phase by neutralization reaction of a stoichiometric mixture of $Al_2(SO_4)_3$ and $H_3PO_4$ using the NaOH or KOH solution and subsequently by the hydrothermal precipitation method. The synthesis conditions were as follows : starting materials; $Al_2(SO_4)_3$ and $H_3PO_4$,pH ranges of neutralization reaction; between 5.6 and 6.0, temperature ranges of hydrothermal reaction; between 170 and $180^{\circ}C$,time ranges of hydrothermal reaction; between 4 and 5hs. Under such synthesis conditions, the products are obtained as amorphous aluminium phosphate powders of 0.1~0.3$\mu\textrm{m}$ in size and are Eitted to USP (United Standard Pharmacopoeia) test.

• Journal of the Korea Institute of Building Construction
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• v.12 no.5
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• pp.490-502
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• 2012

The use of recycled aggregate, even for low-performance concrete, has been very limited because recycled aggregate, which contains a large amount of old mortar, is very low in quality. To produce a high-quality recycled aggregate, removing the paste that adheres to the recycled aggregate is very important. We have conducted research on a complex abrasion method, which removes the component of cement paste from recycled fine aggregate by using both a low-speed wet abrasion crusher as a mechanical process and neutralization as chemical processes, and well as research on the optimal manufacturing condition of recycled fine aggregates. Subsequently, we evaluated the quality of recycled fine aggregate manufactured using these methods, and tested the specimen made by this aggregate. As a result, it was found that recycled fine aggregates produced by considering the aforementioned optimal abrasion condition with the use of sulfuric acid as reactant showed excellent quality, recording a dry density of 2.4 and an absorption ratio of 2.94. Furthermore, it was discovered that gypsum, which is a reaction product occurring in the process, did not significantly affect the quality of aggregates. Furthermore, the test of mortar using this aggregate, when gypsum was included as a reaction product, showed no obvious retarding effect. However, the test sample containing gypsum recorded a long-term strength of 25.7MPa, whereas the test sample that did not contain gypsum posted a long-term strength of 29.4MPa. Thus, it is thought to be necessary to conduct additional research into the soundness and durability because it showed a clear reduction of strength.

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.46 no.3
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• pp.37-43
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• 2014

Kinetics of holocellulose hydrolysis in concentrated sulfuric acid was analyzed using $^1H$-NMR spectroscopy with different reaction time, temperature and acid concentration in secondary hydrolysis. In this work, reaction condition of secondary hydrolysis was similar to concentrated sulfuric acid process with electrodialysis or simulated moving bed chromatography process for sulfuric acid recycling. By $^1H$-NMR spectroscopy, acid hydrolyzates from higher secondary acid hydrolysis (25-35% acid concentration) was successfully analyzed without any difficulties in neutralization or adsorption of acid hydrolyzate to solid salt. Higher acid concentration, higher temperature and longer reaction time led to more cellulose for glucose conversion but accompanied with glucose to galactose isomerization, glucose to unknown compounds and degradation of glucose to organic acid via furans.