• Title/Summary/Keyword: Neutralization

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Electrodialysis of metal plating wastewater with neutralization pretreatment: Separation efficiency and organic removal

  • Park, Yong-Min;Choi, Su-Young;Park, Ki-Young;Kweon, Jihyang
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.179-187
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    • 2020
  • Electrodialysis has been applied for treatment of industrial wastewater including metal electroplating. The wastewater from metal plating industries contains high concentrations of inorganics such as copper, nickel, and sodium. The ions in the feed were separated due to the electrical forces in the electrodialysis. The concentrate compartment is exposed to the elevated concentrations of the ions and yielded inorganic precipitations on the cation exchange membranes. The presence of organic matter in the metal plating wastewater affects complex interfacial reactions, which determines characteristics of inorganic scale fouling. The wastewater from a metal plating industry in practice was collected and the inorganic and organic compositions of the wastewater were analyzed. The performance of electrodialysis of the raw wastewater was evaluated and the effects of adjusting pH of the raw water were also measured. The integrated processes with neutralization and electrodialysis showed great removal of heavy metals sufficient to discharge to aquatic ecosystem. The organic matter in the raw water was also reduced by the neutralization, which might enhance removal performance and alleviate organic fouling in the integrated system.

Interference Neutralization for Small-Cell Wireless Networks (스몰셀 무선망 간섭 상쇄 기법 연구)

  • Jeon, Sang-Woon;Jung, Bang Chul
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.38A no.12
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    • pp.1117-1124
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    • 2013
  • As the recently soaring wireless traffic, small-cell techniques have been actively studied in order to support such a wireless demand for cellular wireless networks. This paper focuses on the inter-cell interference neutralization to resolve the main barrier for implementing small-cell cellular networks. Assuming that each message is delivered to the final destination by the help of base stations or relays, ergodic interference neutralization is proposed, which exploits the time-varying nature of wireless channels. The previous approach based on amplify-and-forward (AF) suffers from severe performance degradation in the low signal-to-noise (SNR) regime due to noise amplification. On the other hand, the proposed interference neutralization based on recently developed compute-and-forward (CF) fixes such a problem and improves the performance in the low SNR regime.

An Analysis and Improvement of the Experiment of the Acid-Base Neutralization Reaction (산-염기 중화반응 실험의 문제점 분석 및 개선 방안)

  • Jeon, Yeong-Hwa;Hong, Lan-Sun;Kang, Young-Jin;Kang, Seong-Joo
    • Journal of the Korean Chemical Society
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    • v.48 no.2
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    • pp.189-194
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    • 2004
  • The aim of this study is to analyze and improve the experiment of the acid-base neutralization reaction described in science textbooks. The problems in the neutralization reaction of NaOH-HCl solution were following; 1) the decoloration of phenolphthalein solution, 2) the color change of the titrated solution during condensation for the confirmation of the salt crystals, 3) the difficulty for the confirmation of the salt crystals. These problems are explained by the structure change of phenolphthalein and the improved experiment is proposed.

Detection of antibodies against infectious Borna disease virus -a comparison of three serological methods- (보르나병 바이러스 항체검출을 위한 연구 -세 가지 혈청진단법의 비교-)

  • Lee, Du-sik
    • Korean Journal of Veterinary Research
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    • v.32 no.1
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    • pp.57-61
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    • 1992
  • To determin the accuracy of serological methods in detecting Borna-disease(BD) viral antibodies, 273 experimentally infected rabbit sera were compared by using indirect immunofluorescence antibody test(IFA), serum neutralization test(SN) and enzyme-linked immunosorbent assay(ELISA). One hundred twenty-three serum samples had BD viral antibodies detected by IFA. CELISA antibodies to BD virus were also present in the same one hundred twenty-three serum samples. However, neutralization test antibodies to BD virus were present in 27 of the in rabbit serum samples. Neutralization test was sensitive in comparison with KFA and CELISA. In comparison with IFA, CELISA was both sensitive and specific in detecting BD viral antibodies. These results extend observations made with laboratory animals to the diagnosis of naturally infected animals.

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Control of pH Neutralization Process using Simulation Based Dynamic Programming (ICCAS 2003)

  • Kim, Dong-Kyu;Yang, Dae-Ryook
    • 제어로봇시스템학회:학술대회논문집
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    • 2003.10a
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    • pp.2617-2622
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    • 2003
  • The pH neutralization process has long been taken as a representative benchmark problem of nonlinear chemical process control due to its nonlinearity and time-varying nature. For general nonlinear processes, it is difficult to control with a linear model-based control method so nonlinear controls must be considered. Among the numerous approaches suggested, the most rigorous approach is the dynamic optimization. However, as the size of the problem grows, the dynamic programming approach is suffered from the curse of dimensionality. In order to avoid this problem, the Neuro-Dynamic Programming (NDP) approach was proposed by Bertsekas and Tsitsiklis (1996). The NDP approach is to utilize all the data collected to generate an approximation of optimal cost-to-go function which was used to find the optimal input movement in real time control. The approximation could be any type of function such as polynomials, neural networks and etc. In this study, an algorithm using NDP approach was applied to a pH neutralization process to investigate the feasibility of the NDP algorithm and to deepen the understanding of the basic characteristics of this algorithm. As the global approximator, the neural network which requires training and k-nearest neighbor method which requires querying instead of training are investigated. The global approximator requires optimal control strategy. If the optimal control strategy is not available, suboptimal control strategy can be used even though the laborious Bellman iterations are necessary. For pH neutralization process it is rather easy to devise an optimal control strategy. Thus, we used an optimal control strategy and did not perform the Bellman iteration. Also, the effects of constraints on control moves are studied. From the simulations, the NDP method outperforms the conventional PID control.

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College Students' Misconception about the Volume Change of Solution during Acid/Base Titration: Partial Molar Volume of Salt (산·염기 적정에서 용액의 부피 변화에 대한 대학생들의 오개념 연구)

  • Jang, Nak Han
    • Journal of Science Education
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    • v.33 no.2
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    • pp.317-320
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    • 2009
  • I investigated Korean college students' conception about the volume change of solution when they detected the equivalence point during acid/base titration experiment using method of volume measurement. According to this study, most college students had a misconception that the volume increment was due to the formation of water by neutralization during acid/base titration. However, this is not enough to explain the volume change, neglecting contribution of a salt in solution. I calculated the partial molar volume of NaCl formed to explain the volume increment of solution during HCl/NaOH neutralization. Comparing the result of experiment with the calculation of partial molar volume, I elucidated that the main effect of volume increment was due to the partial molar volume of NaCl formed during HCl/NaOH neutralization. Here I propose to introduce college students to the concept of partial molar volume of the salt formed to reduce misconception about the volume change of solution during acid/base neutralization.

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A Study on the Improvement of MIMO Antenna Isolation for Mobile Applications (휴대 단말기용 MIMO 안테나의 격리도 향상에 관한 연구)

  • Yoon, In-Seop;Yan, Xiao-Jia;Kim, Sang-Uk;Jo, Yun-Hyun;Park, Hyo-Dal
    • The Journal of the Korea institute of electronic communication sciences
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    • v.10 no.9
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    • pp.987-992
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    • 2015
  • In this paper, neutralization line structure have been employed to improve the isolation between the MIMO antenna system. The proposed MIMO antenna size is $116mm{\times}64mm{\times}5mm$ and designed on FR-4(${\varepsilon}r=4.4$) ground substrate. Neutralization line was applied to enhance isolation between the each antenna elements. The fabricated antenna satisfied a VSWR below 3 in LTE band B13 and the isolation between the MIMO antenna system is presented below -15dB. On the H-plane, antenna shows an omnidirectional pattern. In LTE band B13, the antenna presents a gain of a -2.6dBi ~-1.18dBi and radiation efficiency of 33.49% ~ 46.45%. Comparing measurement result with the outcome of simulation, the proposed MIMO antenna is expected to be applied for mobile application.

Design for Wastewater Neutralization Network in Yeosu Petrochemical Complex by Multi-Criteria Decision Making Strategy (다중척도 의사결정 전략을 이용한 여수 석유화학단지의 폐수 중화망 설계)

  • Lee, Tai-Yong
    • Clean Technology
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    • v.17 no.2
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    • pp.175-180
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    • 2011
  • A novel multi-criteria decision making strategy is developed for the construction of industrial symbiosis network in eco-industrial park and the strategy is applied to the construction of acid/alkali wastewater neutralization network in Yeosu industrial complex. Acid (or alkali) wastewater is commonly generated in chemical industries, and it can be used as neutralizing agent for alkali (or acid) wastewater generated from another source. As a consequence, a large-scale industrial symbiosis network for wastewater neutralization can be constructed in petrochemical complexes where a large amount of acid/alkali wastewater is generated. In this study, substance flow model is constructed which describes the wastewater neutralization network and multi-criteria decision making strategy is applied to find a few candidate for industrial symbiosis network.

Hybrid neutralization and membrane process for fluoride removal from an industrial effluent

  • Meftah, Nouha;Ezzeddine, Abdessalem;Bedoui, Ahmed;Hannachi, Ahmed
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.303-312
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    • 2020
  • This study aims to investigate at a laboratory scale fluorides removal from an industrial wastewater having excessive F- concentration through a hybrid process combining neutralization and membrane separation. For the membrane separation operation, both Reverse Osmosis (RO) and Nanofiltration (NF) were investigated and confronted. The optimized neutralization step with hydrated lime allowed reaching fluoride removal rates of 99.1± 0.4 %. To simulate continuous process, consecutive batch treatments with full recirculation of membrane process brines were conducted. Despite the relatively high super saturations with respect to CaF2, no membrane cloaking was observed. The RO polishing treatment allowed decreasing the permeate fluoride concentration to 0.9± 0.3 mg/L with a fluoride rejection rate of 93± 2% at the optimal transmembrane pressure of around 100 psi. When NF membrane was used to treat neutralization filtrate, the permeate fluoride concentration dropped to 1.1± 0.4 mg/L with a fluoride rejection rate of 88± 5% at the optimal pressure of around 80 psi. Thus, with respect to RO, NF allowed roughly 20% decrease of the driving pressure at the expense of only 5% drop of rejection rate. Both NF and RO permeates at optimal operating transmembrane pressures respect environmental regulations for reject streams discharge into the environment.

Permeation Property of Ionomer Film with New Multifunctional Ionic Site (다관능기를 도입한 아이오노머 필름의 기체투과 특성)

  • Lee, Bo-Mi;Jeong, Sam-Bong;Nam, Sang-Yong
    • Korean Journal of Materials Research
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    • v.22 no.5
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    • pp.227-236
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    • 2012
  • Ionomer is a thermoplastic that is composed of covalent bonds and ionic bonds. It is possible to use this material in processes such as injection molding or extrusion molding due to the material's high oil resistance, weatherproof characteristics, and shock resistance. In this study, a new ionomer having a multifunctional group was prepared by a stepwise neutralization system with the addition of acidic and salt additives. In step I, to increase the contents of the multifunctional group and the acid degree in ethylene acrylic acid (EAA), MGA was added to the ionomer resin (EAA). A new ionomer was prepared via the traditional preparation method of the ionic cross-linking process. In step II, metal salt was added to the mixture of EAA and MGA. The extrusion process was performed using a twin extruder (L/D = 40, size : ${\varphi}30$). Ionomer film was prepared for evaluation of gas permeability by using the compression molding process. The degree of neutralized and ionic cross-linked new ionomer was confirmed by FT-IR and XRD analysis. In order to estimate the neutralization of the new ionomer film, various properties such as gas permeation and mechanical properties were measured. The physical strength and anti-scratch property of the new ionomer were improved with increase of the neutralization degree. The gas barrier property of the new ionomer was improved through the introduction of an ionic site. Also, the ionic degree of cross-linking and gas barrier property of the ionomer membrane prepared by stepwise neutralization were increased.