• Bulletin of the Korean Chemical Society
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• 제23권11호
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• pp.1604-1610
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• 2002

In the present work, we studied thiram on silver surface by SERS. Investigations of disulfides with SERS revealed that the molecules undergo a surface reaction on silver, namely easy cleavage of the S-S bond. We believe that the two S atoms of resonance formed from the thiram may be chemisorbed strongly on Ag sol. This resonance form adheres perpendicularly to the Ag surface via the two S atoms, since the ${\delta}(CH3)$ and n (CN) mode perpendicular to the surface showed strong enhancement. The important roles of halide anion adsorption have been discussed and the pH effects of thiram on Ag sol in acidic, neutral, and alkaline conditions were examined.

• Parasites, Hosts and Diseases
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• 제28권3호
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• pp.155-160
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• 1990

우리 나라에서만 인체 감염이 확인된 장흡충 Fibricole seoulensis의 특징적 구조인 tribocytic organ의 기능을 파악하는 연구의 일환으로, 이 구조물과 표피의 조직화학적 성질을 밝히기 위해 특수 염색을 시행하였다. 충체 의 단면을 H&E 염색, 탄수화물, mucosubstance, amylo:임 및 교원질에 대한 특수 염색 및 alkaline phospha- tase에 대한 면역 조직화학 염색을 시행, 관찰하였다. Tribocytic organ의 표피, 분비물 및 선세포는 PAS 및 double bridge PAP에 양성이었다. 충체의 표피 역시 같은 염색에 양성이었다. 그러므로 F. seoulensis에서 tribocytic organ의 표피, 분비물 및 선세포와 충체의 표피는 neutral mucopolysaccharide를 함유하고 있으며 tribocytic organ의 표피, 분비물 및 충체의 표피는 alkaline phosphatase 활성도가 있음을 알 수 있었다. 이러한 구조들은 충체의 분비 기능 및 숙주 점막에의 부착 등에 관여할 것으로 생각된다.

• Steel and Composite Structures
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• 제48권2호
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• pp.113-130
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• 2023

The present manuscript aims to investigate the deviation between the middle surface (MS) and neutral surface (NS) formulations on the static response of bi-directionally functionally graded (BDFG) porous plate. The higher order shear deformation plate theory with a four variable is exploited to define the displacement field of BDFG plate. The displacement field variables based on both NS and on MS are presented in detail. These relations tend to get and derive a new set of boundary conditions (BCs). The porosity distribution is portrayed by cosine function including three different configurations, center, bottom, and top distributions. The elastic foundation including shear and normal stiffnesses by Winkler-Pasternak model is included. The equilibrium equations based on MS and NS are derived by using Hamilton's principles and expressed by variable coefficient partial differential equations. The numerical differential quadrature method (DQM) is adopted to solve the derived partial differential equations with variable coefficient. Rigidities coefficients and stress resultants for both MS and NS formulations are derived. The mathematical formulation is proved with previous published work. Additional numerical and parametric results are developed to present the influences of modified boundary conditions, NS and MS formulations, gradation parameters, elastic foundations coefficients, porosity type and porosity coefficient on the static response of BDFG porous plate. The following model can be used in design and analysis of BDFG structure used in aerospace, vehicle, dental, bio-structure, civil and nuclear structures.

• 대한기계학회논문집
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• 제15권2호
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• pp.630-643
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• 1991

The hydrodynamic stability equations are formulated for buoyancy-induced flows adjacent to a vertical, planar, isothermal surface in cold pure water. The resulting stability equations, when reduced to ordinary differential equation by a similarity transformation, constitute a two-point boundary-value(eigenvalue) problem, which was numerically solved for various values of the density extremum parameter R=( $T_{m}$ - $T_.inf./) / ( $T_{o}$ - $T_.inf./). These stability equations have been solved using a computer code designed to accurately solve two-point boundary-value problems. The present numerical study includes neutral stability results for the region of the flows corresponding to 0.0.leq. R. leq.0.15, where the outside buoyancy force reversals arise. The results show that a small amount of outside buoyancy force reversal causes the critical Grashof number $G^*/ to increase significantly. A further increase of the outside buoyancy force reversal causes the critical Grashof number to decrease. But the dimensionless frequency parameter $B^*/ at $G^*/ is systematically decreased. When the stability results of the present work are compared to the experimental data, the numerical results agree in a qualitative way with the experimental data.erimental data.

• 대한기계학회논문집B
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• 제29권2호
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• pp.189-196
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• 2005

The physical model considered here is a horizontal layer of fluid heated below and cold above with a conducting body placed at the center of the layer. The body has dimensionless thermal conductivities to the fluid of 0.1, 1 and 50. Two-dimensional solution for unsteady natural convection is obtained using an accurate and efficient Chebyshev spectral methodology for different Rayleigh numbers. Multi-domain technique is used to handle a square-shaped conducting body. The results for the case of a conducting body are also compared to those of adiabatic and neutral isothermal bodies. When the dimensionless thermal conductivity is 0.1, a pattern of fluid flow and isotherms and the corresponding time-averaged surface Nusselt number are almost the same as the case of an adiabatic body. When the dimensionless thermal conductivity is 50, a pattern of flow and isotherm and the corresponding surface and time-averaged Nusselt number are similar to those of neutral body. The results for the case of dimensionless thermal conductivity of unity are also compared to those of pure natural convection.

• 대한한의학회지
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• 제26권3호
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• pp.215-227
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• 2005

Objectives : This study was carried out to investigate the effects of Pyungjintang on indomethacin-induced gastric mucosal lesions of mire. Methods : Experimental mice were classified into not-treated group (NOR group), gastro-inflammation elicitated group (CON group), misoprostol-administered group after gastro-inflammation elicitation (MA group), and Pyungjintang-administered group after gastro-inflammation elicitation (PA group). This study examined the morphological change, distribution of mast cells, mucus surface cells, neutral mucus secreting cells, acid mucus secreting cells, PNA reaction, angiogenesis (MIP-2), COX-1, Hsp70, NF-kB p50, COX-2IL-12B, ICAM-1, BrdU and apoptotic cells of gastric mucosa. Results : 1. The scars of diapedesis, dilatation of right gastric artery and the hemorrhagic erosions of gastric mucosa were reduced in the MA and PA groups. 2. Gastric perforation was observed in the gastro-inflammation elicitated group, but not in the MA and PA groups. 3. The COX-1 positive cellsl, cell proliferation of gastric mucosa, neutral mucus secreting ce31s, acid mucus secreting cells and PNA positive reaction of surface mucus cells were increased in the MA and PA groups. 4. The distribution of apoptotic cells, mast cells, MIP-2, Hsp70, NF-kB p50, COX-2, IL-l2B and ICAM-1 were decreased in the MA and PA groups. Conclusions : Pyungjintang had excellent effects on indomethacin-induced gastric mucosal lesions in mice.

• 한국염색가공학회지
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• 제13권2호
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• pp.114-119
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• 2001

Four kinds of neutral sodium salts with different anions, NaF, NaCl, NaBr, and NaI, were added to the dye bath to accurately understand the effect of anions on the reactive dyeing of silk with C. I. Reactive Black 5. The sodium cation towered the negative surface potential of the silk and increased the dye-uptake on fille fabric as reported previously. However, because of the discrepancy in the anions'inhibition power from cation's lowering: the surface negative potential the amount of the dye on the silk fiber was different from each other in the order of $F^->Cl^-> Br^-I^-$. The activation energy(E$_{a}$) lot the dyeing was in the order of $F^->Cl^-> Br^-I^-$ but the dye-uptake on the fabric and the activation free energy$(\Delta{G}^*)$, the real energy barrier fort the reaction, were in the order of $F^->Cl^-> Br^-I^-$ because the strength of the interaction of the anions with sodium cations was the salute as the order of the latter. In other words F$^{[-1000]}$ exerted the weakest electrostatic force on $Na^+$ and competed with the dyestuff anions least of all. The decrease in $\Delta{S}^*$ may be due to the looesly bonded activated complex of dyestuff anions, sodium cations and fiber molecules at transition state. It was clarified from the Brёnsted equation that sodium salts with different anions also had fille ionic strength effect and the specific salt effect on the reactive dyeing.g.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2012년도 추계총회 및 학술대회 논문집
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• pp.131-133
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• 2012

The photoluminescence (PT) properties of Al-doped ZnO thin films grown by the sol-gel dip-coating method have been investigated. At 12 K, nine distinct PL peaks were observed at 2.037, 2.592, 2.832, 3.027, 3.177, 3.216, 3.260, 3.303, and 3.354 eV. The deep-level emissions (2.037, 2.592, 2.832, and 3.027 eV) were attributed to native defects. The near-band-edge (NBE) emission peaks at 3.354, 3.303, 3.260, 3.216, and 3.177 eV were attributed to the emission of the neutral-donor-bound excitons (D0X), two-electron satellite (TES), free-to-neutral-acceptors (e,A0), donor-acceptor pairs (DAP), and second-order longitudinal optical (2LO) phonon replicas of the TES (TES-2LO), respectively. According to Haynes' empirical rule, we calculated the energy of a free exciton (FX) to be 3.374 eV. The thermal activation energy for D0X in the nanocrystalline ZnO thin film was found to be ~25 meV, corresponding to the thermal dissociation energy required for D0X transitions.

• Earthquakes and Structures
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• 제10권6호
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• pp.1429-1449
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• 2016

The effect of porosity on bending and free vibration behavior of simply supported functionally graded plate reposed on the Winkler-Pasternak foundation is investigated analytically in the present paper. The modified rule of mixture covering porosity phases is used to describe and approximate material properties of the FGM plates with porosity phases. The effect due to transverse shear is included by using a new refined shear deformation theory. The number of unknown functions involved in the present theory is only four as against five or more in case of other shear deformation theories. The Poisson ratio is held constant. Based on the sinusoidal shear deformation theory, the position of neutral surface is determined and the equation of motion for FG rectangular plates resting on elastic foundation based on neutral surface is obtained through the minimum total potential energy and Hamilton's principle. The convergence of the method is demonstrated and to validate the results, comparisons are made with the available solutions for both isotropic and functionally graded material (FGM). The effect of porosity volume fraction on Al/Al2O3 and Ti-6Al-4V/Aluminum oxide plates are presented in graphical forms. The roles played by the constituent volume fraction index, the foundation stiffness parameters and the geometry of the plate is also studied.

• Steel and Composite Structures
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• 제18권3호
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• pp.793-809
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• 2015

In this scientific work, constructing of a novel shear deformation beam model including the stretching effect is of concern for flexural and free vibration responses of functionally graded beams. The particularity of this model is that, in addition to considering the transverse shear deformation and the stretching effect, the zero transverse shear stress condition on the beam surface is assured without introducing the shear correction parameter. By employing the Hamilton's principle together with the concept of the neutral axe's position for such beams, the equations of motion are obtained. Some examples are performed to demonstrate the effects of changing gradients, thickness stretching, and thickness to length ratios on the bending and vibration of functionally graded beams.