• 제목/요약/키워드: Near-UV

검색결과 288건 처리시간 0.035초

스핀코팅 방법으로 제작된 ZnO 박막의 단계적 후열처리에 따른 구조적 및 광학적 특성

  • 문지윤;남기웅;박선희;박영빈;박형길;윤현식;김영규;지익수;김익현;김동완;김종수;김진수;임재영
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.290.1-290.1
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    • 2014
  • 스핀코팅방법으로 증착된 ZnO 박막의 단계적 후열처리에 따른 구조적, 광학적 특성에 관한 연구를 수행하였다. 일반적으로 ZnO 박막은 한 층을 증착한 후에, 유기물을 제거하기 위하여 전열처리를 수행한다. 본 연구에서는 ZnO 박막을 전열처리와 후열처리를 동시에 단계적으로 수행하였다. X-ray diffractometer, UV-visible spectrometer, photoluminescence를 이용하여 ZnO 박막의 구조적, 광학적 특성을 분석하였다. 모든 시료에서 표면은 직경이 약 20 nm인 둥근 입자들로 이루어져 있었다. X-ray diffraction 패턴은 $31^{\circ}$, $34^{\circ}$, $36^{\circ}$에서 나타났고, 이것은 각각 ZnO의 (100), (002), (101) 방향을 보여준다. 전열처리와 후열처리를 동시에 수행했을 경우, 자유엑시톤 재결합에 의해 3.2 eV에서 좁은 near-band-edge emission 피크가 나타났으며, 투과도 또한 향상되었다.

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Excitation Based Tunable Emissions from the Nanocrystalline $Ca_2Gd_8Si_6O_{26}$ : $Sm^{3+}/Tb^{3+}$ Phosphors for Novel Inorganic LEDs

  • Raju, G. Seeta Rama;Yu, Jae-Su
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.156-156
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    • 2011
  • Nanocrystalline $Ca_2Gd_8Si_6O_{26}$ (CGS) : $Sm^{3+}$ and CGS : $Tb^{3+}/Sm^{3+}$ phosphors were prepared by solvothermal reaction method for light emitting diode (LED) and field emission display (FED) applications. The XRD patterns of these phosphors confirmed their oxyapatite structure in the hexagonal lattice. The visible luminescence properties of these phosphors were investigated by exciting with ultraviolet (UV) or near-UV light and low voltage electron beam. The photoluminescence (PL) properties of $Ca_2Gd_8Si_6O_{26}$ (CGS) : $Sm^{3+}$ and CGS : $Tb^{3+}/Sm^{3+}$ phosphors were investigated as a function of $Sm^{3+}$ concentration. Cathodoluminescence (CL) properties were examined by changing the acceleration voltage. The CGS : $Sm^{3+}$ showed the dominant orange emission due to the $^4G_{5/2}{\rightarrow}^6H_{7/2}$ transition. The CGS : $Tb^{3+}/Sm^{3+}$ phosphor showed the green, white and orange emissions when excited with 275, 378, and 405 nm wavelengths, respectively. The chromaticity coordinates of these phosphors were comparable to or better than those of standard phosphors for LED or FED devices.

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과산화수소/자외선/산소 처리를 이용한 베르베린 염료 및 염직물의 퇴화거동 연구 (Study on the Degradation Behavior of Berberine Dye and Berberine Dyed Silk using Hydrogen Peroxide/UV/Oxygen Treatment)

  • 안춘순
    • 복식문화연구
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    • 제20권2호
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    • pp.238-250
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    • 2012
  • This study examined the degradation behavior of SB(standard berberine) dye and SB dyed silk using HPLC-MS instrument after degradation in the hydrogen peroxide/ultraviolet ray radiation/oxygen system up to 9 days and 40 hours respectively. In the degraded samples, berberine was detected at 5.2 min in the SB dye and 5.3 min in the SB dyed silk with its molecular ion=336 and the UV spectra of quaternary alkaloid. Degradation product 3(m/z=102) newly appeared after 5 day degradation treatment with continued increase till the end of degradation treatment. The amount of berberine in the degraded dye decreased with degradation progression. In the silk dyeings, berberine was detected only up to 21 hour degradation sample. The amount of berberine decreased dramatically during the first 6 hours of degradation treatment. The CIELAB color measurement of the silk dyeings showed dramatic change in the b* value, near zero in the 40 hour degraded silk. CIELAB and Munsell color measurements were in agreement with the HPLC-MS results of the dyed silk in the change of berberine content that the degraded silk became white and lost yellow color.

Growth and Characterization of Lithium Potassium Phthalate (LiKP) Single Crystals for Third Order Nonlinear Optical Applications

  • Sivakumar, B.;Raj, S. Gokul;Kumar, G. Ramesh;Mohan, R.
    • Bulletin of the Korean Chemical Society
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    • 제33권11호
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    • pp.3755-3760
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    • 2012
  • Single crystals of lithium potassium phthalate (LiKP) were successfully grown from aqueous solution by solvent evaporation technique. The grown crystals were characterized by single crystal X-ray diffraction. The lithium potassium phthalate $C_{16}\;H_{12}\;K\;Li_3\;O_{11}$ belongs to triclinic system with the following unit-cell dimensions at 298(2) K;$a=7.405(5){\AA}$;$b=9.878(5){\AA}$;$c=13.396(5){\AA}$;${\alpha}=71.778(5)^{\circ}$;${\beta}=87.300(5)^{\circ}$;${\gamma}=85.405(5)^{\circ}$; having a space group P1. Mass spectrometric analysis provides the molecular weight of the compound and possible ways of fragmentations occurs in the compound. Thermal stability of the crystal was also studied by both simultaneous TGA/DTA analyses. The UV-Vis-NIR spectrum shows a good transparency in the whole of Visible and as well as in the near IR range. Third order nonlinear optical studies have also been studied by Z-scan technique. Nonlinear absorption and nonlinear refractive index were found out and the third order bulk susceptibility of compound was also estimated. The results have been discussed in detail.

$RuO_2$ Related Schottky contact for GaN/AlGaN device

  • Jung, Byung-Kwon;Kim, Jung-Kyu;Lee, Jung-Hee;Hahm, Sung-Ho
    • 한국반도체및디스플레이장비학회:학술대회논문집
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    • 한국반도체및디스플레이장비학회 2002년도 추계학술대회 발표 논문집
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    • pp.85-90
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    • 2002
  • $RuO_2$/GaN and related contacts were investigated for Schottky contacts in GaN-Based optical and electronic devices. We demonstrated that an $RuO_2$ film forms a stable Schottky contact on a GaN layer with a barrier height (${\Phi}_B$) of 1.46 eV and transmittance of 70% in the visible and near UV region. $RuO_2$/GaN Schottky diode showed a breakdown at over -50V and leakage current of only 0.3 nA at -5V. The $RuO_2$/GaN Schottky type photodetector had the UV/Visible rejection ratio of over $10^5$ and the responsivity of 0.23 A/W at 330 nm. The $RuO_2$ gate AlGaN/GaN EFET exhibited high drain current ($I_d$) of 689.3 mA/mm and high transconductance ($g_m$) of 197.4 mS/mm. Cut-Off frequency ($f_t$) and maximum operating frequency ($f_{max}$) were measured as 27.0 GHz and 45.5 GHz, respectively.

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ON THE IMPORTANCE OF USING APPROPRIATE SPECTRAL MODELS TO DERIVE PHYSICAL PROPERTIES OF GALAXIES

  • PACIFICI, CAMILLA;DA CUNHA, ELISABETE;CHARLOT, STEPHANE;YI, SUKYOUNG
    • 천문학논총
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    • 제30권2호
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    • pp.535-537
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    • 2015
  • Interpreting ultraviolet-to-infrared (UV-to-IR) observations of galaxies in terms of constraints on physical parameters-such as stellar mass ($M_{\ast}$) and star formation rate (SFR)-requires spectral synthesis modelling. We investigate how increasing the level of sophistication of the standard simplifying assumptions of such models can improve estimates of galaxy physical parameters. To achieve this, we compile a sample of 1048 galaxies at redshifts 0.7 < z < 2.8 with accurate photometry at rest-frame UV to near-IR wavelengths from the 3D-HST Survey. We compare the spectral energy distributions of these galaxies with those from different model spectral libraries to derive estimates of the physical parameters. We find that spectral libraries including sophisticated descriptions of galaxy star formation histories (SFHs) and prescriptions for attenuation by dust and nebular emission provide a much better representation of the observations than 'classical' spectral libraries, in which galaxy SFHs are assumed to be exponentially declining functions of time, associated with a simple prescription for dust attenuation free of nebular emission. As a result, for the galaxies in our sample, $M_{\ast}$ derived using classical spectral libraries tends to be systematically overestimated and SFRs systematically underestimated relative to the values derived adopting a more realistic spectral library. We conclude that the sophisticated approach considered here is required to reliably interpret fundamental diagnostics of galaxy evolution.

Color Enhancement of Natural Sapphires by High Pressure High Temperature Process

  • Song, Jeongho;Noh, Yunyoung;Song, Ohsung
    • 한국세라믹학회지
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    • 제52권2호
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    • pp.165-170
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    • 2015
  • We employed the high-pressure high temperature (HPHT) process to enhance the colors of natural sapphires to obtain a vivid blue. First, we analyze the content of the coloring agent $Fe_2O_3$ using the wavelength dispersive X-ray fluorescence (WD-XRF) method. The HPHT procedure operates under 1 GPa at various temperatures of 1700, 1750, and $1800^{\circ}C$ for 5 minutes using a cubic press. We determine the color changes using the optical microscopic images, UV-VIS near-infrared (NIR) spectra, micro-Raman spectra, and Fourier transform-infrared (FT-IR) spectra for all sapphire samples before and after the treatment. The optical microscopic results indicate that the HPHT process can enhance the sapphire color to a vivid blue at temperatures above $1750^{\circ}C$. The UV-VIS-NIR spectra identify the color changes explicitly and quantitatively through providing the Lab color scales and color differences. Both results demonstrate that the colors of natural sapphires can be enhanced to a vivid blue using the HPHT process above $1750^{\circ}C$ under 1 GPa for 5 minutes.

사출성형 조건 변화에 따른 도광판의 황화현산에 관한 연구 (A study on yellowing property of LGP under various injection molding conditions)

  • 이성준;민인기;김종선;이성희;윤경환
    • Design & Manufacturing
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    • 제9권2호
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    • pp.20-24
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    • 2015
  • Recently, the light guide plate (LGP), a component of the BLU, becomes thinner and larger than ever. In industrial field, specialized injection molding technique is applied to mold the ultra-thin LGP such as a ultra-high speed injection molding. Usually very high melt temperature is used for low viscosity. High injection speed and melt temperature lead to yellowing of LGP. In the present paper a series of injection molding experiment was performed under various injection molding conditions. Yellow index, CIE xy, spectral transmittance of sample were measured using the UV-Visible spectrophotometer. Systematic decrease of spectral transmittance in UV-B range was found as the melt temperature was higher. Yellow index and CIE xy were became higher near the gate location in LGP. From the result of analysis of variance, the main factor to affect for yellow index was mold temperature and that for spectral transmittance(at 315 nm) was melt temperature.

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GLI 자료를 이용한 생체 소각 에어러솔 측정에 대한 연구 (The Measurements of Biomass Burning Aerosols from GLI Data)

  • 이현진;;하경자;김재환
    • 대한원격탐사학회지
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    • 제21권4호
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    • pp.273-285
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    • 2005
  • 본 연구에서는 GLI 센서의 자외선인 380nm, 가시광선 영 역의 400nm와 412nm, 가시광선의 푸른 파장영역인 460nm와 490nm, 근파장 적외선인 2100nm를 비교 분석하여 생체 소각 에어러솔 탐지에 효과적인 파장을 살펴보고자 하였다. 자외선 파장이 지표 반사도가 낮고 BRDF 효과도 작게 나타나므로 에어러솔 추정시 효과적이라고 알려져 있으나 412nm를 제외한 400nm, 460nm, 490nm에서 380nm와 비슷한 지표 반사도를 보였다. 지표 반사도 대비 방법을 2003년 5월에 적용해 에어러솔 반사도를 산출하였을때 460nm의 에어러솔 반사도가 380nm 보다 민감하게 나타났다. GLI의 두파장을 이용해 TOMS 에어러솔 지수를 산출하였을 때 생체 소각 에어러솔은 흡수성 에어러솔로 나타났으며 380nm와 460nm를 이용한 TOMS 에어러솔 지수가 AERONET의 에어러솔 광학 두께와 높은 상관관계를 보이며 에어러솔의 광학 두께에 민감하게 반응하고 있다. 그러므로 생체소각 에어러솔을 탐지할 때에는 가시광선의 푸른색 영역의 파장대가 효과적일 것으로 사료된다.

2003년 5월 러시아지역에서 발생한 산불로 인한 스모크 에어로졸 플룸의 영향 (Impact of the Smoke Aerosol from Russian Forest Fires on the Atmospheric Environment over Korea during May 2003)

  • 이권호;김정은;김영준;김준
    • 한국대기환경학회지
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    • 제20권5호
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    • pp.603-613
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    • 2004
  • Extensive forest fires occurred across the border in Russia. particularly east of Lake Baikal between the Amur and Lena rivers in May 2003. These forest fires released large amounts of particulates and gases into the atmosphere. resulting in adverse effects on regional air quality and the global radiation budget. Smoke pollution from the Russian fires near Lake Baikal was sometimes transported to Korea through Mongolia and eastern China. In this study ground based radiation (visible and UV-B) data measured during May 2003 at Seoul and Kwangju were analyzed to estimate smoke aerosol impacts on solar radiation. Surface criteria air pollutants ($PM_{10}$, CO, $O_3$) data were also obtained from National Institute of Environmental Research (NIER) during smoke aerosol event period (19 May~24 May 2003). Large Aerosol Optical Depth (AOD) 1.0~3.0 was observed during this period due to the influence of the long range transport of smoke aerosol plume from the Russian fires, resulting in short-wavelength direct aerosol radiative forcing of -90~ -200W/$m^2$. These smoke aerosol plume caused decrease in surface UV-B radiation up to 80% and increase in PM_(10) concentration up to 200${\mu}g/m^3$ exceeding the 24 hour ambient air quality standard.