• 한국자기학회:학술대회 개요집
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• 한국자기학회 2001년도 춘계연구발표회 논문개요집
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• pp.70-71
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• 2001

• 대한치과보철학회지
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• 제44권5호
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• pp.628-641
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• 2006

Statement of problem: Dental magnetic materials have been applied to removable prosthetic appliances, maxillofacial prostheses, obturator and dental implant but they still have some problems such as low corrosion resistance in oral environments. Purpose: To increase the corrosion resistance of dental magnetic materials, surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels. Materials and methods : Surfaces of Sm-Co and Nd-Fe-B based magnetic materials were plated with TiN and sealed with stainless steels, and then three kinds of electrochemical corrosion test were performed in 0.9% NaCl solution; potentiodynamic, potentiostatic, and electrochemical impedance test. From this study, corrosion behavior, amount of elements released, mean average surface roughness values, the changing of retention force, and magnetic force values were measured comparing with control group of non-coated magnetic materials. Results: The values of surface roughness of TiN coated Sm-Co and TiN coated Nd-Fe-B based magnetic materials were lower than those of non coated Sm-Co and Nd-Fe-B alloy. From results of potentiodynamic test, the passive current density of TiN coated Sm-Co alloy were smaller than those of TiN coated Nd-Fe-B alloy and non coated alloys in 0.9% NaCl solution. From results of potentiostatic and electrochemical impedance test, the surface stability of the TiN coated Sm-Co alloy was more drastically increased than that of the TiN coated Nd-Fe-B alloy and non-coated alloy. The retention and magnetic force after and before corrosion test did not change in the case of TiN coated magnetic alloy sealed with stainless steel. Conclusion: It is considered that the corrosion problem and improvement for surface stability of dental magnetic materials could be solved by ion plating with TiN on the surface of dental magnetic materials and by sealing with stainless steels.

• 한국자기학회지
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• 제1권2호
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• pp.55-59
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• 1991

희토류-3d 천이원소인 비정질${[{(Fe_{80}CO_{20})}_{0.98}RE_{0.02}]}_{80}B_{20}(RE=Nd,\;Sm,\;Gd,\;Tb)$ 합금 리본시료에 대한 자기적 성질을 조사하기 위하여 시료진동형 자력계(vibrating sample magnetometor)를 이용하여 77 K부터 900 K까지의 온도 영역에서 포화자화 값을 온도의 함수로 측정 한후, Curie 온도 ($T_{c}$)와 Bloch 상수등을 추정하였다. 이들로 부터 spin wave stiffness 상수, 교환상호작용(exchange interaction)의 범위와 평균자승거리($$)등을 계산하였으며 각 희토류 원소에 대한 치환효과를 비교 분석하였다.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2002년도 동계연구발표회 논문개요집
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• pp.232-233
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• 2002

Nanostructed high energy Nd-Fe-B based bulk magnet can be prepared by hot-working process (hot press and die-upset) from melt-spun amorphous or nanocrystalline powder.[1] Recently, we have investigated a modified method, current-applied pressure-assisted (CAPA) process, to produce nanocrystalline isotropic and anisotropic NdFeB magnets. The process consists of current-applied pressing the melt-spun powders to obtain isotropic precursor subsequent current-applied deforming the precursor to obtain textured magnet.[2-3] (omitted)

• Journal of Magnetics
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• 제4권2호
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• pp.46-51
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• 1999

A solid-HDDR characteristics of the Nd-Fe-B-type alloys magnetic properties of the solid-HDDR treated materials have been investigated using three types of alloys; $Nd_{15}Fe_{77}B_8 (alloy A), Nd_{16}Fe_{75.9}B_8Zr_{0.1}(alloy B), and Nd_{12.6}Fe_{68.7}Co_{11.6}B_8Ga_{1.0}Zr_{0.1} $(alloy C). It has been found that the four-components alloy B and six-components alloy C have showed higher hydrogenation temperatures than the ternary alloy A. The alloys A and B appeared to absorb more hydrogen gas more rapidly as well compared to the alloy C. The disproportionation temperature of hydrogenated materials was exhibited no significant difference among the alloys. The thermal stability of the hydrided materials of the three types of alloys was found to become more stable in order of number of components. The disproportionation and the recombination kinetics were significantly sluggish in the solid-HDDR manner with respect to the conventional manner. Some degree of anisotropic nature was found to exist in the ingot and this anisotropic nature was retained even after the solid-HDDR treatment. It was suggested the solid-HDDR treatment may possibly be used for a preparation of an isotropic or anisotropic Nd-Fe-B-type cast magnets.

• 한국자기학회지
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• 제5권5호
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• pp.408-411
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• 1995

Microstructure and magnetic properties of $Fe-Nd_{13.5}-Co_{15}-B_{6-8}Ga_{0-1}-Zr_{0.2-1}$ alloys during HDDR process were studied. $ZrB_{2}$ phase was detected and identified by X-Ray diffraction. Influence of Ga, Zr and Ga+Zr additions on phase relations at different stages of HDDR process was studied by X-ray diffraction and magnetic measurements.

• 한국전기전자재료학회논문지
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• 제30권1호
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• pp.27-31
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• 2017

In this study, the effect of Tb inward diffusion on the magnetic properties of the Nd-Fe-B sintered magnets was studied. After sintering of the magnets, $TbF_3$ slurries were dip-coated on the surface of the samples, then heat-treatment was followed for $TbF_3$ diffusion. The element distribution in the magnets and the diffusion profiles of Tb ions were analyzed by an EPMA (electron probe micro-analyzer). Prolonged heat treatment resulted in a deeper diffusion length of Tb ions. Coercivity of the $1^{st}$ heat-treated sample showed 21.86 kOe, while that of the $1^{st}$, $2^{nd}$ heat-treated and annealed sample revealed 34 kOe.

• E2M - 전기 전자와 첨단 소재
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• 제8권6호
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• pp.811-815
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• 1995

회토류계 영구자석은 종래의 Ferrite계나 Alnico계와 비교해서 대단히 강하여, 전기전자부품의 소형화에 크게 기여하고 있다. 최근에는, 전자기기산업 이외의 분야에 있어서도 그의 응용이 확대되어가고 있는 추세로 자성재료의 생산액은 매년 증가하고 있다. 회토류계 영구자석재료의 연구는 1960년대에 시작되어 Sm $Co_{5}$, Sm$_{2}$ $Co_{17}$ 화합물의 등장을 거쳐 현재는 1982년데 Sagawa 및 Croat가 독자적으로 발견한 Nd$_{2}$ Fe$_{14}$B 자석이 주류로 되고 있다. 그렇지만 이 화합물에는 다른 영구자석에 비하여 큐리온도가 낮은 결점이 있어서, 아직도 새로운 화합물의 탐색이 계속되고 있다. 그 중에서도, 1990년대에 Coey에 의해서 최초로 학회지에 보고되어진 Sm$_{2}$Fe$_{17}$N$_{x}$는, Nd$_{2}$Fe$_{14}$B와 같은 정도의 이론 최대에너지급, Sm $Co_{5}$에 대등한 거대한 이방성자장, 750K에 달하는 큐리온도등의 우수한 성질을 갖고 있어 Nd$_{2}$Fe$_{14}$B를 극복하는 자성재료로서 큰 기대가 되어진다. 되어진다.진다.

• 한국분말야금학회:학술대회논문집
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• 한국분말야금학회 2005년도 춘계학술강연 및 발표대회강연 및 발표논문 초록집
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• pp.72-72
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• 2005

• 한국자기학회지
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• 제3권1호
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• pp.34-40
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• 1993

급속냉각기술로 제조된 $Nd_{10.5}Fe_{79}Co_{2}Zr_{1.5}B_{7}$ 합금분말을 사용하여 사출성형용 자성 펠렛을 제조하였다. 입도분포가 다른 두 종류의 분말($38~75\;\mu\textrm{m}$ 및 $75~50\;\mu\textrm{m}$)을 사용하여 열가소성(Nylon 6) 펠렛을 제조한 후 자성분말의 임계분율(critical volume fraction) 을 결정하고 수지자석의 성형밀도에 따른 자기특성을 고찰하였다. Nylon 6 수지를 사용한 Nd-Fe-Co-Zr-B계 펠렛은 분말입도가 $38~75\;\mu\textrm{m}$인 경우 임계 부피분율은 70%로 나타났고, 그때의 성형밀도는 이론밀도 의 90%를 상회 했으나 $75~150\;\mu\textrm{m}$ 분말의 경우는 같은 분율에서 이론밀도의 87% 수준에 머물렀다. 최적의 자기특성은 분말에 윤활제로서 silicone oil만을 0.5wt.% 첨가한 경우이며 이때의 자기특성으로, $(BH)_{max}=5.2\;MGOe,\;B_{r}=5.1\;kG$ 그리고 $_{i}H_{c}=8.8\;kOe$의 높은 수준을 보였다. Nylon 6수지자석의 성형밀도를 예측할 수 있는 경험식으로서, ${\rho}(g/cm^{3})=1.1+K.V_{s}$을 얻었으며 K(5.3~5.6)는 자성분말 입도에 따른 기울기 상수이고 $V_{s}$는 분말의 부피분율이다.