• Title/Summary/Keyword: Nd:glass

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Crystallization in Li20-A1203-Si02 Glass induced by 355nm Nd:YAG Laser Irradiation

  • Lee, Yong-Su;Kang, Won-Ho;Song, Sun-Dal
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2000.04a
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    • pp.112-117
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    • 2000
  • Nd:YAG laser of 355nm wavelength, which amounts to 3.5eV, produced by a harmonic generator was used to create Ag metallic particles as seeds for nucleation in photosensitive glass containing Ag+ and Ce3+. The pulse widths and frequency of the laser were 8ns and 10Hz, respectively. For crystalline growth, heat-treatment following laser irradiation was carried out at $570^{\circ}C$ fur 1h. Then, the LiAlSi3O8. crystal phase appeared in the laser irradiated lithium aluminum silicate glass. We present the effect of laser-induced nucleation compared with spontaneous nucleation by heat treatment for crystallization in the glass.

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Sintering and Dielectric Properties of BaO-Nd2O3-TiO2 Microwave Ceramics with Glass-Ceramics (결정화유리의 첨가에 의한 BNT계 세라믹스의 저온소결 및 마이크로파 유전특성)

  • ;;;;Futoshi Ustuno
    • Journal of the Korean Ceramic Society
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    • v.41 no.6
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    • pp.444-449
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    • 2004
  • The microwave dielectric properties of low temperature sintered BaO-Nd$_2$O$_3$-TiO$_2$ (here after BNT) with a Pb-based glass-ceramics were studied in order to investigate their applicability to Low Temperature Co-fired Ceramics (LTCC) for fabrication of multilayered Radio Frequency (RF) passive components module. The BNT ceramics, with 5∼30 wt% of PbO-TiO$_2$-A1$_2$O$_3$-SiO$_2$ based glass-ceramics, were sintered at 105$0^{\circ}C$, which is lower than 130$0^{\circ}C$, sintering temperature of pure BNT ceramics. With increasing the amount of the glass-ceramics, sintering rate of the ceramics become activated due to the softening of glass, resulting in low-temperature densification. BaO-Nd$_2$O$_3$-TiO$_2$ microwave ceramics with 20 wt% glass-ceramics exhibit sintered relative densities over 95% and dielectric constant of 72, quality factor of 1500, and temperature coefficient of frequency of +22 ppm/$^{\circ}C$. This enhanced dielectric properties are attributed to mainly the presence of crystalline phases PbTiO$_3$ within the Pb-based glass.

Properties of Phosphate Glasses - $BaO-Nd_{2}O_3-TiO_2$ Ceramic Composites for Using Dielectric Materials Having Low Temperature Cofired Ceramic(LTCC) (저온동시소성 유전체 재료용 인산염계 유리-$BaO-Nd_{2}O_3-TiO_2$계 세라믹 복합체의 특성)

  • Lee Hoi Kwan;Lee Yong Su;Hwang Sheng-Jian;Kang Won Ho;Kim Hyung Sun
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.2 s.31
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    • pp.17-22
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    • 2004
  • In this study, BNT($BaO-Nd_{2}O_3-TiO_2$) and $70P_{2}O_5-5B_{2}O_3-(25-x)BaO-xNa_{2}O$ glass-ceramic composites were fabricated and investigated in order to apply for low temperature cofired ceramic. The prepared BNT based glass-ceramic composites were sintered at $800{\sim}950^{\circ}C$ with the glass fit contents ranging from 10 to $15\;wt\%$. The properties such as sintering and dielectric property were investigated in the ceramic compositions according to the phosphate glass frit. The dielectric constant was varied between 10 to 40 and shrinkage rate was increased according to increasing glass frit.

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Characteristics of the Nd:YAG laser Spot Welding in $Cu_{54}Ni_{6}Zr_{22}Ti_{18}$ Bulk Metallic Glass Alloy ($Cu_{54}Ni_{6}Zr_{22}Ti_{18}$ 벌크비정질 합금의 Nd:YAG 레이저 점용접 특성)

  • Kim, J.H.;Lee, J.H.;Shin, S.Y.;Bae, J.C.;Lee, C.H.
    • Laser Solutions
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    • v.8 no.2
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    • pp.13-20
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    • 2005
  • Weldability is largely dependent on the phase evolution and the microstructure of the weld. For the weldability of the $Cu_{54}Ni_6Zr_{22}Ti_{18}$ bulk metallic glass, the crystallization affects the sensitivity of the weld to the brittle failure. In order to suppress the irreversible crystallization, Nd:YAG laser welding was chosen. The pulsed Nd:YAG laser was irradiated onto the BMG plate and the effects of the pulse shape [peak power intensity and pulse duration time] on the crystallinity were evaluated.

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Sintering and Dielectric Properties of K2O-CaO-P2O5 Glasses-BNT(BaO-Nd2O3-TiO2) Ceramic Composites (K2O-CaO-P2O5계 유리-BNT(BaO-Nd2O3-TiO2)계 세라믹 복합체의 소결 및 유전특성)

  • 오영석;이용수;강원호;정병해;김형순
    • Journal of the Korean Ceramic Society
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    • v.40 no.10
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    • pp.954-960
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    • 2003
  • To develop mobile phone antenna modules, glass-ceramics composites that are 20∼80 dielectric constant materials which has been fabricated. The glass-ceramics composites were based in the BNT (BaO-Nd$_2$O$_3$-TiO$_2$), and properties-a sintering and dielectric property-were investigated in its composites according to the $K_2$O-CaO-P$_2$O$_{5}$ system glass frits. The prepared ceramics were sintered at 900∼120$0^{\circ}C$ with the glass frit contents ranging from 10 to 40 wt%. The shrinkage and relative density grew into increasing glass frits and sintering temperature. Sintered composites showed the tendency that the dielectric constant ($\varepsilon$$_{r}$) and quality factor (Q${\times}$f) decreased in increasing glass frits and sintering temperature.

Optimum Gain Distribution of the Ampilfiers in High Power YLF($Nd^{3+}$)-Phosphate Glass($Nd^{3+}$) Laser System

  • CHi, Kyeong-Koo
    • Proceedings of the Optical Society of Korea Conference
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    • 1989.02a
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    • pp.20-25
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    • 1989
  • The nonlinear, time dependent photon transport equations of Frantz and Nodvik, which describe the amplification of an optical pulse in an active medium, are modified to a simpler equation which describes only the amplification of energy. with this equation, the output energy of the high power YLF(Nd3+)-Phosphate Glass(Nd3+) Laser System is calculated. When the stored energy density Est is 0.10J/㎤, 0.16J/㎤, 0.228J/㎤, and 0.50J/㎤, and with the assumption of uniform population inversion density, the final output energy of this laser system is 5.38J, 176J, 317J, and 283J, respectively. The gain saturation causes distortion of the output beam. This phenomenon is described in detail at the first three rod amplifier systems in the case of E=0.228J/㎤. The peak current and decay time constant of the flashlamps, which are used to obtain population inversion in the active medium, are investigated. The flashlamp driving circuit which has optimum operational performance should have {{{{ SQRT { LC} }} time about 100$\mu$sec.

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The Effect of Glass Addition on the Sintering and Dielectric Properties of BaO-Nd2O3-TiO2 Microwave Ceramics (Glass첨가에 의한 BaO-Nd2O3-TiO2계 세라믹스의 저온소결과 마이크로파 유전특성)

  • Shin, Dong-Soon;Choi, Young-Jin;Park, Jae-Hwan;Nahm, Sahn;Park, Jae-Gwan
    • Journal of the Korean Ceramic Society
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    • v.40 no.1
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    • pp.98-103
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    • 2003
  • The effect of glass addition on the low-temperature sintering and microwave dielectric properties in $BaO-Nd_2O_3-TiO_2$ dielectric ceramics were studied. When 10~30 wt% of alkali lithium borosilicate glass was added, the sintering temperature decreases from $1300^{\circ}C$;to;1000^{\circ}C$ and the relative density more than 95% was obtained. When the added amount of glass increased above 10 wt%, the density as well as dielectric properties changed, which was attributed to the second phase formation. When the sample was sintered at 100$0^{\circ}C$ with l0wt% of glass, the dielectric properties of $Qxf_o{ge}2800,;{varepsilon}_r{ge}65;and;{ au_f=+55 ppm/^{\circ}C$ were obtained.