• Title/Summary/Keyword: NbR

Search Result 345, Processing Time 0.031 seconds

DNA Dynamics: a Fluorescence Resonance Energy Transfer Study Using a Long-Lifetime Metal-Ligand Complex

  • Kang, Jung-Sook;Lakowicz, Joseph-R.;Piszczek, Grzegorz
    • Archives of Pharmacal Research
    • /
    • v.25 no.2
    • /
    • pp.143-150
    • /
    • 2002
  • Fluorescent probes bound to DNA typically display nanosecond decay times and reveal only nanosecond motions. We extend the time range of measurable DNA dynamics using $[Ru(pby)_2(dppz)]^{2+}$ (bpy=2.2'-bipyridine, dppz=dipyrido[3,2-a2',3'-c]phenazine) (RuBD) which displays a mean lifetime near 90 ns. To test the usefulness of RuBD as a probe for diffusive processes in calf thymus DNA, we compared the efficiencies of fluorescence resonance energy transfer (FRET) using three donors which display lifetimes near 5 ns for acridine orange (AO), 22 ns for ethidum bromide (EB) and 92 ns for RuBD, with nile blue (NB) as the acceptor. The F rster distances for AO-NB, EB-NB and RuBD-NB donor-acceptor pairs were 42.3, 52.3, and $30.6{\;}{\AA}$, respectively. All three donors showed dramatic decreases in fluorescence intensities and more rapid intensity decays with increasing NB concentrations. The intensity decays of AO and EB in the presence of varying concentrations of NB were satisfactorily described by the one-dimensional FRET model without diffusion (Blumen and Manz, 1979). In the case of the long-lifetime donor RuBD, the experimental phase and modulation somewhat deviated from the recovered values computed from this model. The recovered NB concentrations and FRET efficiencies from the model were slightly larger than the expected values, however, the recovered and expected values did not show a significant difference. Thus, it is suggested that the lifetime of RuBD is too short to measure diffusive processes in calf thymus DNA.

Influence of $TiO_2$ on the dielectric properties of $Bi(Nb_{0.7}Ta_{0.3})O_4$ ceramics for low-firing (저온소결용 $Bi(Nb_{0.7}Ta_{0.3})O_4$ 세라믹스의 유전특성에 미치는 $TiO_2$ 영향)

  • Kim, Dae-Min;Yoon, Sang-Ok;Kim, Kwan-Soo;Kim, Shin;Kim, Jae-Chan;Kim, Kyung-Joo;Park, Jong-Guk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2007.06a
    • /
    • pp.298-298
    • /
    • 2007
  • Influence of $TiO_2$ on the dielectric properties of the $Bi(Nb_{0.7}Ta_{0.3})O_4$ ceramic with 7 wt% zinc borosilicate(ZBS) glass was investigated as a function of the $TiO_2$ contents with a view to applying this system to LTCC technology. The $Bi(Nb_{0.7}Ta_{0.3})O_4$ ceramic addition of 7 wt% ZBS glass ensured successful sintering below $900^{\circ}C$. But, TCF of $Bi(Nb_{0.7}Ta_{0.3})O_4$ ceramic is large negative values, respectively, it is necessary to adjust to zero TCF for practical applications Therefore, the addition of materials having positive TCF, such as $TiO_2$, might be an effective method for the improvement. In general, increasing addition of $TiO_2$ increased dielectric constant and TCF but it decreased the sinterability and $Q{\tiems}f$ value significantly due to the dielectric property and high sintering temperature of $TiO_2$. $Bi(Nb_{0.7}Ta_{0.3})O_4$ ceramic with 7 wt% ZBS glass and then addition 0.5 wt% $TiO_2$ sintered at $900^{\circ}C$ demonstrated 42 in the dielectric constant(${\varepsilon}_r$), 1,000 GHz in the $Q{\times}f$ value, and $10{\pm}5\;ppm/^{\circ}C$ in the temperature coefficient of resonant frequency(${\tau}_f$).

  • PDF

Effect of V and Nb on Mechanical Properties of Non-Heattreated Hot Forging Steels (열간단조용 비조질강의 기계적 성질에 미치는 V, Nb의 영향)

  • Wee, Kyeom-Bok;Jeong, Woon-Tae;Lee, Kyeong-Seop;Wang, Seong-Do
    • Korean Journal of Materials Research
    • /
    • v.2 no.1
    • /
    • pp.65-75
    • /
    • 1992
  • 0.4wt%C steel added with V and/or Nb were forged and followed by air cooling. The structure-property relationships were examined and multiple regression analysis was conducted to quantify the magnitudes of effects of microalloying elements on the properties of the steels. All material's tensile strength are greater than $70kg/\textrm{mm}^2$, so they are equal to or superior to Q/T material's(S45C). Their impact energies are less than 40J, so they are 50% of Q/T material's. Increasing the content of V from 0.10 to 0.15 wt% had brought improvement in UTS about 20% but with some sacrifice of impact energy. These were the results from the precipitation strengthening by fine dispersion of VC in ferrite, increment of pearlite volume fraction and decrement of pearlite interlamellar spacings. However, increasing the content of Nb from 0.05 to 0.l0wt % slightly improved UTS and impact energy. NbC precipitates were more effective in suppression of austenite grain coarsening than VC precipitates. Combined additions of V+Nb were more effective to bring impact toughness than sole addition. Optimum combination of strength and toughness was accomplished wish 0.4C-1. 19Mn-0.05S-0.12V-0.07Nb steel.

  • PDF

Estimation of Gene Effects in Four Bivoltine Silkworm (Bombyx mori L.) Crosses

  • Malik, G.N.;Singh, T.P.;Rufaie, S.Z.Haque;Aijaz, M.;Dar, H.U.
    • International Journal of Industrial Entomology and Biomaterials
    • /
    • v.8 no.1
    • /
    • pp.113-115
    • /
    • 2004
  • Six generations (P$_1$, P$_2$, F$_1$, BC$_1$, BC$_2$ and F$_2$) of four bivoltine silkworm crosses (SKAU-R-1 ${\times}$ Yakwei, SKAU-R-6 ${\times}$ Yakwei, CSR$_2$ ${\times}$ CSR$_4$ and SH$_{6}$${\times}$ NB$_4$D$_2$) were evaluated in a completely randomized block design with 5 replications for each treatment. The generation mean 2 in respect of 3 metric traits (single cocoon weight, single shell weight, and shell ratio %), were subjected to Cavallis joint scaling test. Additive dominance model was found to be adequate in CSR$_2$${\times}$CSR$_4$ and SH$_{6}$${\times}$ NB$_4$D$_2$ for single cocoon weight and shell weight and SKAU-R-6 ${\times}$ Yakwei for shell ratio(%). Whereas, in rest of the crosses epistasis was evident in the traits under investigation. Magnitude of additive gene effect (d) was greater than dominance(h) in SH$_{6}$${\times}$NB$_4$D$_2$ and SKUA-R-6${\times}$Yakwei for shell ratio (%) and in CSR$_2$${\times}$ CSR$_4$ for shell weight. Thus selection for these traits in early segregating generations of these crosses would be effective for obtaining considerable genetic gain. gain.

Cyclic Deformation Behaviors under Isothermal and Thermomechanical Fatigue Conditions in Nb and Mo Added 15Cr Ferritic Stainless Steel (Nb 및 Mo 첨가 페라이트계 스테인리스강의 등온 저주기 및 열기계적 피로에 따른 변형거동)

  • Jung, Jae Gyu;Oh, Seung Taik;Choi, Won Doo;Lee, Doo Hwan;Lim, Jong Dae;Oh, Yong Jun
    • Korean Journal of Metals and Materials
    • /
    • v.47 no.11
    • /
    • pp.707-715
    • /
    • 2009
  • This paper deals with cyclic stress and strain responses during isothermal low cycle fatigue (LCF) and thermo-mechanical fatigue (TMF) loadings on Nb and Mo containing 15Cr stainless steel, which is used for exhaust manifolds in automobiles. The test temperatures ($T_{i}$) of the isothermal LCF were 600 and $800^{\circ}C$. The minimum temperature of the TMF test was $100^{\circ}C$ and the maximum temperaures ($T_{p}$) were varied between 500 and $800^{\circ}C$. In both loading conditions, weak cyclic softening is observed at $T_{i}=T_{p}=800^{\circ}C$, but the transition to strong cyclic hardening is completed with the temperature decrease below $T_i=600{\sim}700^{\circ}C$ for LCF and $T_{p}=500{\sim}600^{\circ}C$ for TMF. The stress-strain hysteresis loops in the TMF loading show a significant stress relaxation during compressive (heating) half cycle at $T_{p}>500^{\circ}C$, which develops tensile mean stress during cycling. Due to the stress relaxation, the TMF test sample reveals much lower dislocation density than the isothermally fatigued sample at the same temperature with $T_{p}$. A detailed correlation between fatigue microstructure and cycling deformation behavior is discussed.

The Partial Full Duplex Relay Scheme for Cell ID Detection of Type 1 Relay in 3GPP LTE-Advanced System (3GPP LTE-Advanced 시스템에서 Type 1 relay의 셀 ID 검출을 위한 부분 전이중 relay 기법)

  • Min, Young-Il;Jang, Jun-Hee;Choi, Hyung-Jin
    • The Journal of Korean Institute of Communications and Information Sciences
    • /
    • v.36 no.6A
    • /
    • pp.558-567
    • /
    • 2011
  • In this paper, we propose a partial full duplex relay scheme for 3GPP (3rd Generation Partnership Project) LTE (Long Term Evolution)-Advanced system using a Type 1 relay. The Type 1 relay as inband relay is prohibited to transmit and receive simultaneously because of self-interference. Therefore, the Type 1 relay cannot receive synchronization signals which are transmitted to eNB. To overcoming this problem, we propose the partial full duplex relay scheme which transmits to R-UE (Relay-User Equipment) and receives from eNB (evolved NodeB) simultaneously when eNB and the Type 1 relay transmit subframes which have synchronization signals. Additionally, for solving self-interference, the Type 1 relay transmitter and receiver antennas are sufficiently sufficiently isolated and self-interference cancellation is applied for the self-interference signal from the relay transmitter. Thus, the partial full duplex relay scheme can receive synchronization signals from eNB and solve the problems of conventional solutions and we propose the partial channel estimation scheme for partial full duplex relay scheme using SCI. By extensive computer simulation, we verify that the partial full duplex relay scheme is attractive and suitable for the Type 1 relay system.

Improvement of Hydrogen Storage Properties of Mg by Addition of NbF5 via Mechanical Milling under H2

  • Kwak, Young Jun;Song, Jiyoung;Mumm, Daniel R.
    • Korean Journal of Materials Research
    • /
    • v.23 no.10
    • /
    • pp.562-567
    • /
    • 2013
  • A 90 wt% Mg-10 wt% $NbF_5$ sample was prepared by mechanical milling under $H_2$ (reactive mechanical grinding). Its hydriding and dehydriding properties were then examined. Activation of the 90 wt% Mg-10 wt% $NbF_5$ sample was not required. At n=1, the sample absorbed 3.11 wt% H for 2.5 min, 3.55 wt% H for 5 min, 3.86 wt% H for 10 min, and 4.23 wt% H for 30 min at 593K under 12 bar $H_2$. At n=1, the sample desorbed 0.17 wt% H for 5 min, 0.74 wt% H for 10 min, 2.03 wt% H for 30 min, and 2.81 wt% H for 60 min at 593K under 1.0 bar $H_2$. The XRD pattern of the 90 wt% Mg-10 wt% $NbF_5$ after reactive mechanical grinding showed Mg, ${\beta}-MgH_2$ and small amounts of ${\gamma}-MgH_2$, $NbH_2$, $MgF_2$ and $NbF_3$. The XRD pattern of the 90 wt% Mg-10 wt% $NbF_5$ dehydrided at n=3 revealed Mg, ${\beta}-MgH_2$, a small amount of MgO and very small amounts of $MgH_2$ and $NbH_2$. The 90 wt% Mg-10 wt% $NbF_5$ had a higher initial hydriding rate and a larger quantity of hydrogen absorbed for 60 min than the 90 wt% Mg-10 wt% MnO and the 90 wt% Mg-10 wt% $Fe_2O_3$, which were reported to have quite high hydriding rates and/or dehydriding rates. The 90 wt% Mg-10 wt% $NbF_5$ had a higher initial dehydriding rate (after an incubation period) and a larger quantity of hydrogen desorbed for 60 min than the 90 wt% Mg-10 wt% MnO and the 90 wt% Mg-10 wt% $Fe_2O_3$.

Hall Effect and Resistivity of Amorphous $Fe_{83-x}Zr_{7}B_{10}Nb_{x}$ Alloys

  • Lee, Soo-Hyung;Yu, Seong-Cho;Xu, Jun-Hau;Rao, K.V.;Noh, Tae-Hwan;Kang, Il-Koo;Rhie, Kungwon
    • Journal of the Korean Magnetics Society
    • /
    • v.5 no.5
    • /
    • pp.841-845
    • /
    • 1995
  • The effect of small addition of Nb on the electrical resistivity and Hall coeffcient of the amorphous $Fe_{83}Zr_{7}B_{10}$ alloy and annealed ones ones below the crystallization temperature were investigated, which has been considered to be suitable for high frequency core material. At room temperature, their resistivities $\rho$ and the spontaneous Hall coeffcients $R_{s}$ are $~1.6\;{\mu}{\Omega}m$ and $~3{\times}10^{-8}m^{3}/As$, respectively. $R_{s}$ and $\rho$ are decreased with increasing temperature from 100 K to room temperature. Side-jump effect was adopted to analyze the effect of the small variation of conentration and annealing. The quantity of $R_{s}/{\rho}^{2}$ at room temperature, which is directly related to the electronic structure of the mother alloy, remained almost a constant except as quenched one as it can be predicted from the side-jump effect. The unexpected temperature dependence of $R_{s}/{\rho}^{2}$ measured at low fields much below Tc is left as a question.

  • PDF

HALL EFFECT AND RESISTIVITY OF AMORPHOUS $Fe_{83-x}Zr_{7}B_{10}Nb_{x}$ ALLOYS

  • Lee, Soo-Hyung;Yu, Seong-Cho;Xu, Jun-Hau;Rao, K.V.;Noh, Tae-Hwan;Kang, Il-Koo;Rhie, Kungwon
    • Journal of the Korean Magnetics Society
    • /
    • v.5 no.5
    • /
    • pp.772-777
    • /
    • 1995
  • The effect of small addition of Nb on the electrical resistivity and Hall coefficient of the amorphous $Fe_{83}Zr_{7}B_{10}$ alloy and annealed ones below the crystallization temperature were investigated, which has been considered to be suitable for high frequency core material. At room temperature, their resistivities $\rho$ and the spontaneous Hall coefficients $R_{s}$ are $~1.6\;{\mu}{\Omega}m$ and $~3{\times}10^{-8}m^{3}/As$, respectively. $R_{s}$ and $\rho$ are decreased with increasing temperature from 100 K to room temperature. Side-jump effect was adopted to analyze the effect of the small variation of concentration and annealing. The quantity of $R_{s}/{\rho}^{2}$ at room temperature, which is directly related to the electronic structure of the mother alloy, remained almost a constant except as quenched one as it can be predicted from the side-jump effect. We suggested the temperature dependence of $R_{s}/{\rho}^{2}$ can be compared to Ms{T}.

  • PDF

Microwave Dielectric Properties of Donor doped Zr0.8Sn0.2TiO4 Ceramics (Donor Dopant 첨가 Zr0.8Sn0.2TiO4 세라믹스의 마이크로파 유전특성)

  • 김윤호
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.2 no.2
    • /
    • pp.31-40
    • /
    • 1995
  • Donor dopant로 WO3, Ta2O5 및 Nb2O5를 첨가한 Zr0.8Sn0.2TiO4 세라믹스의 유전상수 $\varepsilon$r 품 질계수 Q 및 공진주파수의 온도계수 rf에 대하여 연구하였다. 139$0^{\circ}C$에서 32시간 소결시 donor dopant 첨가량에 따른 ZST의 유전상수는 소결밀도의 변화 거동과 잘 일치하였다. 5.5 GHz에서 측정 한 ZST의 품질계수 Q는 ~0.5 mol% WO3 Ta2O5 및 Nb2O5 첨가에 의해 6800에서 8500 정도로 증가 하였다. ZST의 $\tau$f는 0.3 mol%까지의 WO3 첨가량 증가에 따라 0 ppm/$^{\circ}C$에서 -4.6 ppm/$^{\circ}C$까지 음 의 값으로 직선적으로 감소하였으며 0.4 mol% 범위의 Ta2O5 및 Nb2O5 첨가에 의해 -7 ppm/$^{\circ}C$ 까지 직선적으로 감소하였다.