• 한국전기전자재료학회논문지
• /
• 제17권1호
• /
• pp.7-15
• /
• 2004

The ferroelectric SBT thin films as a material of capacitors for non-volatile FRAMs have some problems that its remanent polarization value is relatively low and the crystallization temperature is quite high abovc 80$0^{\circ}C$. Therefore, in this paper, SBTN solution with S $r_{0.9}$B $i_{2.1}$T $a_{1.8}$N $b_{0.2}$$O_{9}$ composition was synthesized by sol-gel method. Sr(O $C_2$ $H_{5}$)$_2$, Bi(TMHD)$_3$, Ta(O $C_2$ $H_{5}$)$_{5}$and Nb(O $C_2$ $H_{5}$)$_{5}$ were used as precursors, which were dissolved in 2-methoxyethanol. SBTN thin films with 200 nm thickness were deposited on Pt/Ti $O_2$/ $SiO_2$/Si substrates by spin-coating. UV-irradiation in a power of 200 W for 10 min and rapid thermal annealing in a 5-Torr-oxygen ambient at 76$0^{\circ}C$ for 60 sec were used to promote crystallization. The films were well crystallized and fine-grained after annealing at $650^{\circ}C$ in oxygen ambient. The electrical characteristics of 2Pr=11.94 $\mu$C/$\textrm{cm}^2$, Ps＋/Pr＋=0.54 at the applied voltage of 5 V were obtained for a 200-nm-thick SBTN films. This results show that 2Pr values of the UV irradiated and rapid thermal annealed SBTN thin films at the applied voltage of 5 V were about 57% higher than those of no additional processed SBTN thin films. thin films.lms.s.s.

• 한국재료학회지
• /
• 제11권5호
• /
• pp.367-371
• /
• 2001

RF magnetron sputtering 법으로 T $a_2$ $O_{5}$ 세라믹 타겟과 S $r_2$N $b_2$ $O_{7}$ 세라믹 타겟을 동시 sputtering하여 저유전율 S $r_2$(T $a_{1-x}$ , N $b_{x}$)$_2$ $O_{7}$(STNO) 박막을 p-type Si (100) 기판 위에 증착하여 NDRO 강유전체 메모리 (Non-destructive read out ferro-electric random access memory)에 사용되는 Pt/STNO/Si (MFS) 구조의 응용 가능성을 확인하였다. Sr$_2$Nb$_2$ $O_{7} (SN O)$ 타겟과 T $a_2$ $O_{5}$ 타겟의 출력의 비를 100w/100w, 70w/100w, 그리고 50w/100w로 조절하면서 x 값을 달리하여 조성을 변화시켰다. 성장된 박막을 8$50^{\circ}C$, 90$0^{\circ}C$, 그리고 9$50^{\circ}C$에서 1시간 동안 산소 분위기에서 열처리하였다. 조성과 열처리 온도에 따른 구조적 특징을 XRD에 의해 관찰하였으며 표면특성은 FE-SBM에 의해 관찰하였고, C-V 측정과 I-V 측정으로 박막의 전기적 특성을 조사하였다. SNO 타겟과 T $a_2$ $O_{5}$ 타켓의 출력비에 따른 STNO 박막의 성장 결과 70W/170W의 출력비에서 성장된 STNO박막에서 Ta의 양이 상대적 맡은 x=0.4였으며 가장 우수한 C-V 특성 및 누설 전류 특성을 보였다. 이 조성에서 성장된 STNO박막은 3-9V외 인가전압에서 메모리 윈도우 갑이 0.5-8.3V였고 누설전류밀도는 -6V의 인가전압에서 7.9$\times$10$_{-8}$A /$\textrm{cm}^2$였다.

• 한국자기학회지
• /
• 제16권6호
• /
• pp.300-304
• /
• 2006

저손실 고투자율 특성을 가지는 Fe-Si-B-Nb-Ci계 나노결정립 재료로 ${\alpha}-Fe$ 나노결정 자심재료를 제조하기 위한 열처리 온도 변화에서, $510^{\circ}C$의 열처리 조건에서 가장 높은 투자율과 가장 낮은 코어손실 특성을 나타내었다. 제조된 자심재료를 이용한 비접촉식 커플러 제조에서, 저주파 대역에서의 신호전송 특성은 자심재료의 자기적 특성에 지배적인 영향을 받는데 열처리 온도에 따른 투자율 변화의 결과와 일치하는 결과를 나타내었으며, 고주파 대역의 신호전송 특성은 임피던스 매칭으로 향상시킬 수 있었다. 그리고 300 A의 고전류가 흐르는 지중선로에서 자기적 포화 없이 안정적인 특성을 발휘하기 위해서는 $500{\mu}m$ 이상의 에어-갭이 필요하였다. 또한 나노 결정질 자심재료 제조에 대한 연구결과를 통해 5dB 이하의 삽입손실을 나타내는 전력선 통신용 비접촉식 커플러를 제조할 수 있었다.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2003년도 하계학술연구발표회 및 한.일 공동심포지엄
• /
• pp.88-89
• /
• 2003

During the past decade, giant magnetotransport phenomena such as giant magetoresistance (GMR) in thin films and in manganese perovskites, and, giant magnetoimpedance (GMI) in soft magnetic amorphous ribbons, have brought much interest in the basic physical understanding and their applications as magnetic recording heads and in magnetic sensors technology. Among the parameters required for the quality of a magnetic sensor, temperature dependences of GMR and GMI profiles are playing an important role. In the present work, we have studied temperature dependences of the longitudinal permeability and giant magnetoimpedance effect in $Co_{70}$F $e_{5}$S $i_{15}$ N $b_{2.2}$C $u_{0.8}$ $B_{7}$ amorphous ribbons expecting as a promising candidate in the domain of magnetic sensors.rs.rs.rs.s.

• 암석학회지
• /
• 제27권1호
• /
• pp.37-47
• /
• 2018

백두산에서 역사시대에 분화한 화산재의 시료에 대하여 다양한 방법으로 주성분과 미량성분을 분석하였다. 화산재의 주성분 원소 함량은 $SiO_2$ 58.8~71.1 wt.%, $Al_2O_3$ 9.6~16.8 wt.%, ${Fe_2O_3}^T$ 4.5~6.9 wt.%, MgO 0.1~1.7 wt.%, CaO 0.3~1.6 wt.%, $Na_2O$ 5.2~6.3 wt.%, $K_2O$ 4.3~5.9 wt.% 그리고 $TiO_2$ 1.2 wt.%이하로 분석되었다. Ba, Cu, Cr. Co, Ni, Sr, V, Zn와 Zr을 포함하는 32개 미량원소가 분석되었는데, 이들 화산재는 일부 미량원소와 경희토류 원소의 부화정도에 따라 두 그룹(그룹 A, 그룹 B)으로 구분되며, 그룹 A에는 1천년 전의 밀레니엄 분화물, 1668년과 1903년 분화물이, 그룹 B에는 1702년 분화물이 해당된다. 중금속원소인 Cu, Co, Zn, Mn 등은 소량 함유되어 나타난다. 백두산 화산재는, 섭입대 기원의 일본 사쿠라지마 화산의 화산재와 비교하여, 미량성분원소 중 Y, Nb, Pb, U, Sc, V, Ni 그리고 Cu 함량은 낮게 나타나며, Zr, Ba, Hf, Cr, Co, Zn 그리고 희토류(Eu제외) 등은 높은 함량을 나타낸다.

• Journal of Magnetics
• /
• 제11권1호
• /
• pp.36-42
• /
• 2006

In this report, we demonstrate a comprehensive analysis of the effects of Au addition on the microstructure and magnetic properties of $Fe_{73.5}Si_{13.5}B_{9}Nb_{3}Au_1$ Finemet-type alloy. It was found that the as-quenched alloys were the amorphous state and turned into nanocrystalline state under heat treatments. The DSC analysis indicates that the sharply exothermal peak corresponding to the crystallization of the $\alpha-Fe(Si)$ was observed at $547-579^{\circ}C$ depending on the heating rates, which is little higher than that of original Finemet (542-$570{^{\circ}C}$, respectively). Besides, the thermomagnetic result confirmed that the full substitution of Cu by Au with the single phase structure in the M(T) curve along cooling cycle. Ultrasoft magnetic properties of the nanocrystallized samples were significantly enhanced by the proper annealing such as the increase of permeability and the decrease of the coercivity. The optimum annealing condition was found at the annealing temperature of $540^{\circ}C$ and the increase of the annealing time up to 90 min.

• Journal of Magnetics
• /
• 제11권1호
• /
• pp.30-35
• /
• 2006

A thorough study about the influences of Mn substitution for Fe on the microstructure and magnetic characteristics of $Fe_{73.5-x}Mn-{x}Si_{13.5}B_{9}Nb_{3}Cu_1$ (x = 1, 3, 5) alloys prepared by the melt-spinning technique has been performed. Nanocomposites composed of nanoscale $(Fe,Mn)_{3}Si$ magnetic phase embedded in an amorphous matrix were obtained by annealing their amorphous alloys at $535^{\circ}C$ for 1 hour. The addition of Mn causes a slight increase in the mean grain size. The Curie temperatures of the initial amorphous phase and of the nanocrystals phase decreased, while the Curie temperature of the remaining amorphous phase remained nearly constant with increasing Mn content. Soft magnetic properties of the crystallized samples have been significantly improved by a proper thermal treatment. Accordingly, the giant magnetoimpedance effect is observed and ascribed to the increase of the magnetic permeability, and the decrease of the coercivity of the samples. The increased magnetic permeability is resulted from a decrease in the magnetocrystalline anisotropy and saturation magnetostriction.

• 한국분말재료학회지
• /
• 제16권6호
• /
• pp.424-430
• /
• 2009

Electromagnetic wave energies are consumed in the form of thermal energy, which is mainly caused by magnetic loss, dielectric loss and conductive loss. In this study, CNT was added to the nanocrystalline soft magnetic materials inducing a high magnetic loss, in order to improve the dielectric loss of the EM wave absorption sheet. Generally, the aspect ratio and the dispersion state of CNT can be changed by the pre-ball milling process, which affects the absorbing properties. After the various ball-milling processes, 1wt% of CNTs were mixed with the nanocrystalline $Fe_{73}Si_{16}B_7Nb_{3}Cu_1$ base powder, and then further processed to make EM absorption sheets. As a result, the addition of CNT to Fe-based nanocrystalline materials improved the absorption properties. However, the increase of ball-milling time for more than 1h was not desirable for the powder mixture, because the ballmilling caused the shortening of CNT length and the agglomeration of the CNT flakes.

• Progress in Superconductivity
• /
• 제14권2호
• /
• pp.102-105
• /
• 2012

We are developing meander-shaped metallic magnetic calorimeters using micro-fabrication methods. A planar Nb coil in a meander shape was fabricated on a Si substrate. The coil was designed to have a persistent current using a metal heater evaporated on a part of the coil. A paramagnetic sensor, $5{\mu}m$ thick Au:Er foil, was glued on top of the meander structure with epoxy. The magnetization and heat capacity were measured at different temperatures, and applied field currents matched well with expected values. The detector showed an energy resolution of 4 keV FWHM for the 5.5 MeV alpha particles.

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
• /
• pp.788-789
• /
• 2006

Microstructure and soft magnetic properties of bulk amorphous and/or nanocrystalline $Fe_{73.5}Cu_1Nb_3Si_{13.5}B_9$ alloys prepared by consolidation at 5.5GPa were investigated. The relative density of the bulk sample 1 (from amorphous powders) was 98.5% and the grain sizes were about 10.6nm. While the relative density and grain sizes of bulk sample 2 (from nanocrystalline powders) are 98% and 20.1nm, respectively. Particularly, the bulk samples exhibited a good combined magnetic property: for Sample1, $M_s=125emu/g$ and $H_c=1.5Oe;$ for Sample2, $M_s=129emu/g$ and $H_c=3.3Oe$. The success of synthesizing the nanocrystalline Fe-based bulk alloys will be encouraging for the future development of bulk nanocrystalline soft magnetic alloys.