• Title/Summary/Keyword: Nb substitution

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Influence on Dielectric Properties and Evaporation of PbO According to Substituting $Nd^{3+}$ for $Pb^{2+}$ in $Pb(Mg_{1/3}Nb_{2/3})O_3$ System ($Pb(Mg_{1/3}Nb_{2/3})O_3$계 세라믹스의 $Pb^{2+}$$Nd^{3+}$로 치환함에 따른 유전특성 및 PbO 휘발에 관한 연구)

  • 김성열;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.175-180
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    • 1993
  • Influence of Nd3+ substitution for Pb2+ on the dielectric properties and the PbO evaporation according to substituting Nd3+ for Pb2+ in Pb(Mg1/3Nb2/3)O3 system ceramics have been investigated. The dielectric constant at the curie temperature and evaporation of PbO were decreased with increase of Nd3+ amounts. The percentage of PbO evaporation was 2.5wt% in the PMN system substituted Nd3+ for Pb2+, while it was 3.7wt% in the PMN system.

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Effects of $PbTiO_3$ Addition on Dielectric Properties and Extent of PbO Loss in Nd-Doped $Pb(Mg^{1/3}Nb^{2/3})O_3$ System ($Nd^{3+}$로 치환된 $Pb(Mg^{1/3}Nb^{2/3})O_3$$PbTiO_3$ 첨가에 따른 유전특성과 PbO 휘발)

  • 김성열;이응상
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.671-677
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    • 1993
  • Effects of PbTiO3 addition on dielectric properties and extent of PbO loss in Nd-doped Pb(Mg1/3Nb2/3)O3 system were investigated. As the proportion of dopping increased, the phase transition temperature shifted to low region, and the dielectric constant at room temperature decreased rapidly. But as the proportion of PbTiO3 increased, the phase transition temperature shifted to high retion, and the dielectric constant at room temperature increased. The substitution of Nd3+ for Pb2+ decreased the amount of PbO evaporation, therefore the sample sintered well in case of only 1 mole% adding excess PbO.

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Dielectric Properties of Pb($Fe_{1/2}Nb_{1/2}$)$O_3$ with $MnO_2$ Prepared by Molten Salt Synthesis Method (용융염 합성법에 의한 $MnO_2$가 첨가된 Pb($Fe_{1/2}Nb_{1/2}$)$O_3$의 유전성)

  • 박경봉;윤기현
    • Journal of the Korean Ceramic Society
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    • v.28 no.1
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    • pp.79-85
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    • 1991
  • The effects of MnO2 on the microstructure and dielectric properties of Pb(Fe1/2Nb1/2)O3 ceramics prepared by KCl-NaCl molten salt synthesis(MSS) method have been investigated. As the amount of MnO2 increased up to 0.25wt%, the density increased and the grain size decreased, while above 0.25wt%, the density decreased with the grain growth. Dielectric constant increased with increasing the amount of MnO2, and dielectric loss decreased up to 0.25wt% and then increased. This is due to the compensation effect by the substitution of Mn4+ to Fe3+ and the appearance of the second phase.

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Field-Induced Strains and Polarization Switching Mechanisms in La-Modified $Pb(Sc_{1/2}Nb_{1/2})O_3-PbTiO_3$ Ceramics (La 변성 $Pb(Sc_{1/2}Nb_{1/2})O_3-PbTiO_3$계 요업체의 전계유기변위와 분극특성)

  • 장명철
    • Journal of the Korean Ceramic Society
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    • v.37 no.1
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    • pp.63-69
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    • 2000
  • Electrically-induced strain(S) and polarization(P) for Pb(Sc1/2Nb1/2)O3-PbTiO3(1-x)PSN-xPT) crystalline solutions were studied. From the compositional dependence of S and P we could observe two maximum values at x=0.10 and x=0.425. It is considered that PSNT10(x=0.10) composition is the structural phase boundary to indicate the variable order-disorder[VOD] region. PSNT(x=0.425) composition is the morphotropic phase boundary[MPB] to indicate the rhombohedral to tetragonal phase transition. Higher S (0.437%) and P (0.3974$\mu$C/$\textrm{cm}^2$) values were attained by the La substitution (5 wt%) at Pb site in the MPB composition of 57.5PSN-42.5PT.

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A study on Dielectric Properties using PMN Ceramics with La substitution (La치환된 PMN계 세라믹스의 유전특성에 관한 연구)

  • Ji, S.H.;Lee, N.H.;Kim, Y.H.;Kim, J.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1242-1244
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    • 1995
  • The dielectric and polarizable properties of $0.9Pb_{1-x}La_x({Mg}_{1/3}Nb_{2/3})O_3-0.1PbTiO_3$ (x=0,1,2,3,4,5) have been investigated. The temperature-dependant electrostictive characteristics of 0.9PMN-0.1PT relaxor ferroelectric system were improved by enhencing the extent of the diffuse phase transition(DPT). This was achieved using PMN-PTceramics by the partial substitution of La at the Pb site. The curie temperature and the maximum dielectric permittivity decreased by substituting La and the electric field-related hysteresis phenomena decreased with increasing La substitution amount.

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The effect of PCN substitution on dielectric and piezoelectric properties of PMN-PZT Ceramics (PCN 치환이 PMN-PZT 세라믹스에 유전 및 압전특성에 미치는 영향)

  • Nam, Seung-Hyon;Yoo, Ju-Hyun;Lee, Su-Ho;Jeong, Yeong-Ho;Park, Chang-Yub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.161-164
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    • 2004
  • In this study, to develop the composition ceramics for the Ultrasonic vibrator, $Pb(Mn_{1/3}Nb_{2/3})O_3Pb(Zr.Ti)O_3$ system ceramics were manufactured as a function of PCN substitution. Its dielectric and piezoelectric characteristics were investigated. With increasing the amount of PCN substitution, electromechanical coupling factor(kp) were increased until 3mol% PCN and that after decreased. mechanical quality factor(Qm) showed the maxinum value at 2mol% PCN. Eletromechanical coupling factor, mechanical quality factor and dielectric constant were showed optimum value at PCN 2mol% as 0.58, 1630 and 1407, respectively for ultrasonic vibrator applications.

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Magnetic Characteristics of CoNbZr amorphous Films with Pd addition

  • Song, J.S.;Wee, S.B.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05d
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    • pp.90-95
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    • 2003
  • The present paper is to investigate the phase stability and soft magnetic properties of amorphous CoNbZr films when Pd is added as a substitution for CoNbZr alloys. The films were prepared by a RF magnetron sputtering method. The CoNbZrPd films deposited on Si wafers exhibited amorphous structures being independent upon the amount of Pd added in the films. On the addition of 4.34% Pd, the excellent soft magnetic characteristics of the films were observed with a coercive force of 0.54 Oe and an anisotropy field of 11 Oe, whereas a coercive force of 1 Oe and an anisotropy field of 3.5 Oe were shown in the film without the addition of Pd. The increased anisotropy field and low coercive force of the films may be attributed to the occupancy of Pd in the preferred sites parallel to the external magnetic field applied on the deposition process. A permeability of about 1100 was kept constant in the operation frequency ranging up to 100 MHz, which can be explained by the Landau-Lifshitz formula.

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Electrical and Optical Properties of Grain-Oriented (Pb, Ba, La) $Nb_2O_6$ Piezoelectric Ceramics (입자배향(Pb, Ba, La) $Nb_2O_6$ 압전세라믹스의 제작 및 그 전기적.광학적 특성)

  • 남효덕;조상희;영전방유
    • Journal of the Korean Ceramic Society
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    • v.25 no.3
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    • pp.268-276
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    • 1988
  • Ba or La-Substituted lead niobate $(Pb_{1-x}Ba_x)_{1-y}La_{2y/3}Nb_2O_6$(PBLN), powders having needle shape are prepared by flux method using KCl and the effect of Ba or La substitution on morphology of obtained powders is examined. From these needle shape powders, grain-oriented ceramics are made by doctor-blade method and two-stage hot-pressing technique. The dielectric, piezoelectric and optical properties of the ceramics are also investigaated. Heating condition and the amount of substituted Ba or La have remarkable effects have large anisotropy in both permittivity and coupling factor depending on the pressing direction.

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The effect of annealing for dielectric properties of Ti doped $K(Ta,Nb)O_3$ thin film using PLD (PLD를 사용하여 Ti doped K(Ta,Nb)O3 thin film의 유전특성을 위한 annealing 효과)

  • Koo, Ja-Yl;Yi, Chong-Ho;Bae, Hyung-Jin;Lee, Won-Suk
    • Proceedings of the IEEK Conference
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    • 2006.06a
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    • pp.985-986
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    • 2006
  • The epitaxial $KTa_{0.524}Nb_{0.446}Ti_{0.03}O_3$ films with 3% Ti were investigated. Titanium (+4) substitution on the Nb/Ta site should reduce dielectric losses of KTN: Ti film by introducing an acceptor state. This acceptor state traps electrons due to oxygen vacancies that form during oxide film growth. KTN:Ti films were grown using pulsed laser deposition, and then annealed at different temperatures in oxygen ambient. The crystallinity, and surface morphology of KTN:Ti film were investigated using x-ray diffraction, and atomic force microscopy. The dielectric properties of Ti doped KTN films measured for unannealed and annealed films will be reported. Tunability and dielectric loss of as-deposited KTN:Ti film were determined to be 10% and 0.0134, respectively. For films annealed at $800^{\circ}C$ and $900^{\circ}C$, the dielectric loss decreased but with a decrease in tunability as well.

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Soft Magnetic Properties of CoNbZr amorphous Films with Pd addition

  • Song, J.S,;Wee, S.B,
    • Proceedings of the Korean Society Of Semiconductor Equipment Technology
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    • 2002.11a
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    • pp.54-58
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    • 2002
  • The present paper is to investigate the phase stability and soft magnetic properties of amorphous CoNbZr films when Pd is added as a substitution for CoNbZr alloys. The films were prepared by a RF magnetron sputtering method. The CoNbZrPd films deposited on Si wafers exhibited amorphous structures being independent upon the amount of Pd added in the films. On the addition of 4.34% Pd, the excellent soft magnetic characteristics of the films were observed with a coercive force of 0.54 Oe and an anisotropy field of 11 Oe, whereas a coercive force of 1 Oe and an anisotropy field of 3.5 Oe were shown in the film without the addition of Pd. The increased anisotropy field and low coercive force of the films may be attributed to the occupancy of Pd in the preferred sites parallel to the external magnetic field applied on the deposition process. A permeability of about 1100 was kept constant in the operation frequency ranging up to 100 MHz, which can be explained by the Landau-Lifshitz formula.

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