• Title/Summary/Keyword: Nb addition

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Fabrication and Characteristics of Ti-Nb-Mo-CPP Composite Fabricated by High Energy Mechanical Milling and Spark Plasma Sintering (고에너지밀링과 스파크플라즈마소결을 이용한 Ti-Nb-Mo-CPP 생체복합재료의 제조 및 특성)

  • Park, Sang-Hoon;Woo, Kee-Do;Kim, Ji-Young;Kim, Sang-Mi
    • Korean Journal of Metals and Materials
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    • v.50 no.6
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    • pp.469-475
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    • 2012
  • A high-energy mechanical milling (HEMM) process was introduced to improve sinter-ability, and rapid sintering of spark plasma sintering (SPS) under pressure was used to make ultra fine grain (UFG) of Ti-Nb-Mo-CPP composites, which have bio-attractive elements, for increasing mechanical properties. Ti-Nb-Mo-CPP composites were successfully fabricated by SPS at $1000^{\circ}C$ within 5 minutes under 70 MPa using HEMMed powders. The Vickers hardness of the composites increased with increased milling time and addition of CPP contents. Biocompatibility and corrosion resistance of the Ti-Nb-Mo alloys were improved by addition of CPP, and the Ti-35%Nb-10%Mo-10%CPP alloy had better biocompatibility and corrosion resistance than the Ti-6Al-4V ELI alloy.

Electrical Properties of Piezoceramic PZT with $Nb_2O_5$ Dopant ($Nb_2O_5$를 첨가한 압전 세라믹 PZT의 전기적 특성)

  • Park, J.H.;Choi, H.I.;SaGong, G.
    • Proceedings of the KIEE Conference
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    • 1991.11a
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    • pp.336-338
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    • 1991
  • Effects of $Nb_2O_5$ addition ranged from 0.0 to 0.75(wt%) on the microstructure and electrical porperties of PZT ceramics have been investigated. The Pb vacancy concentration increases with increasing NbO content. However, the experimental results show the resistivity increases with increasing $Nb^{5+}$ content. This behavior can be explained as a compensation effect and $Nb^{5+}$ can serve as a donar and contribute electrons to the conduction process. According to the law of mass action, this result may reduce the total charge carrier:thus the resistivity increase with NbO content in PZT.

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The Effects of Niobium on Sliding Wear Characteristics of High Speed Steel by Powder Metallurgy (분말고속도공구강의 미끄럼마모특성에 미치는 Nb의 영향)

  • 이한영;배종수;김용진
    • Tribology and Lubricants
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    • v.16 no.3
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    • pp.194-200
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    • 2000
  • In order to evaluate the effect of Nb on wear properties of high speed steel(HSS) by powder metallurgy, niobium-alloyed HSS have been prepared by adding 0%, 1%, 3% and 5%Nb to HSS of 6%W-5%Mo-4 %Cr-5%V-5%Co. Sliding wear tests were conducted at various sliding speed conditions under the constant pressure using a pin-on-disc type machine. The results of this study show that the wear resistance of HSS by powder metallurgy was increased by the addition of Nb within the range of sliding speed used in this experimental study. However, the amount of Nb did not improve the wear resistance. It may be due to the thermal stability of carbide and high temperature properties of the matrix containing Nb comparing to that without Nb.

Study on the Reaction Characteristics of Self-reducing $Nb_2O_5$ Briquettes (자기 환원성 $Nb_2O_5$ 브리켓의 반응특성 연구)

  • Kim M. S.;You B. D.;Wi C. H.;Yun D. J.;Choi S. O.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.333-336
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    • 2005
  • The reduction behavior of $Nb_2O_5$ in aluminum containing self-reducing briquettes(SRNB) was investigated. The time required for slag/metal equilibrium was estimated as about 20 minutes from the addition of SRNB on to the surface of molten steel. The maximum yield of Nb was expected with the slag composition of $60\%CaO-40\%Al_2O_3$. When $CaCO_3$ was used as a flux, the oxidation loss of Al by $CO_2$ should be compensated, and the chemical equivalent ratio of Al to $Nb_2O_5$ of about 1.43 was required to maximize the yield of Nb.

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Ag(100) 기판위에 증착된 Nb Cluster에 관한 STM연구

  • 윤홍식;유미애;한권환;이준희;양경득;여인환
    • Proceedings of the Korean Vacuum Society Conference
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    • 2000.02a
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    • pp.140-140
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    • 2000
  • The initial growth mode of Nb on Ag(11) in sub-monolayer regime and the influence of subsequent 520K annealing are studied using UHV Scanning Tunneling Microscopy. E-beam evaporated Nb is deposited onto the substrate at RT, and STM measurements are carried out at RT and 78 K. With Nb being immiscible in bulk Ag, 3D islands formation begins at early stage and no particular ordered structure is found. After annealing to 520K, most of islands are disappeared from terrace. There exist 2 possibilities. : (1) Diffusion of Nb into the 2nd or 3rd layer of Ag substrate or (2) agglomeration of Nb on Ag at higher temperature. A model will be given to explain the evidence. In addition, we investigated the change of STM image according to bias voltage depending on island size. Possible physical mechanism responsible for such behavior together with interaction between Nb islands and reactive gases will be also discussed.

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Effect of $Nb_2O_5$ Addition on the Dielectric Properties of $(Sr_{1-x}{\cdot}Ca_x)TiO_3$ Ceramic ($(Sr_{1-x}{\cdot}Ca_x)TiO_3$세라믹의 유전특성에 미치는 $Nb_2O_5$ 첨가영향)

  • 김진사;정익형;최운식;김중혁;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1996.11a
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    • pp.256-259
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    • 1996
  • $(Sr_{1-x}{\cdot}Ca_x)TiO_3+yNb_2O_5$($0.05{\leq}x{\leq}0.2$, 0.004$1350[^{\circ}C]$ in a reducing atmosphere($N_2$ gas). Dielectric propertries were investigated with contents of $Nb_2O_5$. The grain size and dielectric constant increase with increase $Nb_2O_5$, but decrease in $Nb_2O_5$ exceed($Nb_2O_5=0.6[mol%]$). Also, the temperature characteristics of the dielectric loss factor exhibited a stable value within 0.5[%]. The capacitance characteristics appeals a stab]e value in ${\pm}10[%]$.

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Study on Microstructure and Corrosion Characteristics of Zr-0.8Sn-xNb Ternary Alloys (Nb 첨가량에 따른 Zr-0.8Sn-xNb 3원계 합금의 미세조직 및 부식특성 연구)

  • Kim, Hyeon-Gil;Jeong, Yong-Hwan;Wi, Myeong-Yong
    • Korean Journal of Materials Research
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    • v.9 no.5
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    • pp.452-459
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    • 1999
  • To develop advanced cladding materials, the effect of Nb addition on the microstructure and corrosion characteristics of Zr-0.8Sn-xNb alloys was investigated. As the Nb content increased, the grain size decreased and the volume fraction of precipitates increased. It was observed from the corrosion test at $360^{\circ}C$ that the corrosion resistance increased with decreasing Nb content. The best corrosion resistance was obtained in Zr-0.8Sn-0.2Nb alloy with high volume fraction of tetra-$ZrO_2$in the oxide. Therefore, it is suggested that Nb in theZr-0.85Sn-xNb system should be added within the solubility limit of Nb from the viewpoint of alloy design.

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Piezoelectric and Dielectric Properties of (Na,K)(Nb,Sb)$O_3$ Ceramics According to the Amount of $Bi_2O_3$ Addition ($Bi_2O_3$ 첨가에 따른 (Na,K)(Nb,Sb)$O_3$ 세라믹스의 압전 및 유전 특성)

  • Lee, Sang-Ho;Yoo, Ju-Hyun;Jeong, Yeong-Ho;Park, Yong-Wook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.305-305
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    • 2010
  • In this study, in order to develop excellent lead free piezoelectric ceramics for piezoelectric transformer application (Na,K)(Nb,Sb)$O_3$ ceramics were fabricated using conventional oxides mixed method and their piezoelectric and dielectric characteristics were investigated according to the amount of $Bi_2O_3$ addition.

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Influence of BaTiO3 Content and Firing Temperature on the Dielectric Properties of Pb(Mg1/3Nb2/3)O3 Ceramics (Pb(Mg1/3Nb2/3)O3계의 유전성에 미치는 BaTiO3첨가량 및 열처리 온도의 영향 (PMN-BaTiO3계 세라믹스의 합성 및 유전성))

  • 윤기현;강동헌
    • Journal of the Korean Ceramic Society
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    • v.26 no.2
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    • pp.249-257
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    • 1989
  • Dielectric properties and the stability of the perovskite phase in the Pb(Mg1/3Nb2/3)O3 system have been investigated as a function of amount of BaTiO3 and firing temperature. In the specimens fired at 120$0^{\circ}C$, the pyrochlore phase was eliminated by the addition of 10-15m/o BaTiO3 and also the dielectric constant increased. However, the dielectric constant decreased with further addition of BaTiO3 even though no pyrochlore phase was found to be present. The reducing tendency of the pyrochlore phase decreased with lowering the firing temperature in the system of Pb(Mg1/3Nb2/3)O3 with BaTiO3. Dielectric properties in PMN ceramics were affected by the character of the BaTiO3 rather than the pyrochlore phase.

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The Microwave Dielectric Properties of $BiNbO_4$ as The Addition of $MoO_3$ ($MoO_3$첨가에 따른 $BiNbO_4$의 마이크로파 유전특성)

  • 박영순;김덕규;김규도;박춘배
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.232-235
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    • 1999
  • In this paper, We described the effect of $MoO_3$ Addition and firing temperature on the microwave dielectric properties of $BiNb0_4$ ceramics. The specimens prepared by conventional mixed method was addicted by 0 - 0.03 wt% $MoO_3$ and fired at 860 - $950^{\circ}$ for 3hr. Density increased when $MoO_3$ is below O.Olwt% but decreased when over O.Olwt%. $BiNb0_4$ ceramics addicted with CuO 0.03wt % and $MoO_3$ 0.01 wt% showed microwave dielectric properties, Dielectric constant 37.5, Quality factor[Qx$f_0$]5500, Temperature coefficient of resonance frequency 15ppm/$^{\circ}$

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