• Corrosion Science and Technology
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• 제15권6호
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• pp.271-280
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• 2016

An approach to achieving the ambitious goal of cost effectively extending the safe operation life of energy pipeline to 100 years is the application of health monitoring and life prediction tools that are able to provide both long-term remnant pipeline life prediction and in-situ pipeline condition monitoring. A critical step is the enhancement of technological capabilities that are required for understanding and quantifying the effects of key factors influencing buried steel pipeline corrosion and environmentally assisted materials degradation, and the development of condition monitoring technologies that are able to provide in-situ monitoring and site-specific warning of pipeline damage. This paper provides an overview of our current research aimed at developing new sensors and electrochemical cells for monitoring, categorising and quantifying the level and nature of external pipeline and coating damages under the combined effects of various inter-related variables and processes such as localised corrosion, coating cracking and disbondment, cathodic shielding, transit loss of cathodic protection.

• Advanced Composite Materials
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• 제17권1호
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• pp.75-87
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• 2008

Aerospace structural applications, along with high performance marine and automotive applications, require high-strength efficiency, which can be achieved using metal matrix composites (MMCs). Rotating components, such as jet-engine blades and gas turbine parts, require materials that maximize strength efficiency and metallurgical stability at elevated temperatures. Titanium matrix composites (TMCs) are well suited in such applications, since they offer an enhanced resistance to temperature effects as well as corrosion resistance, in addition to optimum strength efficiency. The overall behavior of the composite system largly depends on the properties of the interface between fiber and matrix. Characterization of the fiber.matrix interface at operating temperatures is therefore essential for the developemt of these materials. The fiber fragmentation test shows good reproducibility of results in determining interface properties. This paper deals with the evaluation of fiber fragmentation characteristics in TMCs at elevated temperature and the results are compared with tests at ambient temperature. It was observed that tensile testing at $650^{\circ}C$ of single-fiber TMCs led to limited fiber fragmentation behavior. This indicates that the load transfer from the matrix to the fiber occurs due to interfacial friction, arising predominantly from mechanical clamping of the fiber by radial compressive residual and Poisson stresses. The present work also demonstrates that composite processing conditions can significantly affect the nature of the fiber.matrix interface and the resulting fragmentation of the fiber.

• Bulletin of the Korean Chemical Society
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• 제30권1호
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• pp.92-96
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• 2009

A new precursor [$Zr(acac)_{3}(H_{2}O)_{2}$] was synthesized by Sonochemical technique and used to deposit thin $ZrO_{2}$ film on quartz and ceramic substrate via ultrasonic aerosol assisted chemical vapour deposition (UAACVD) at 300 ${^{\circ}C}$ in oxygen environment followed by annealing of the sample for 2-3 minutes at 500 ${^{\circ}C}$ in nitrogen ambient. The molecular structure of the precursor determined by single crystal X-ray analysis revealed that the molecules are linked through intermolecular hydrogen bonds forming pseudo six and eight membered rings. DSC and TGA/FTIR techniques were used to determine thermal behavior and decomposition temperature of the precursor and nature of evolved gas products. The optical measurement of annealed $ZrO_{2}$ film with tetragonal phase shows optical energy band gap of 5.01 eV. The particle size, morphology, surface structure and composition of deposited films were investigated by XRD, SEM and EDX.

• Bulletin of the Korean Chemical Society
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• 제28권11호
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• pp.2009-2014
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• 2007

The aminolysis of diphenyl thiophosphinic chloride (2) with substituted anilines in acetonitrile at 55.0 oC is investigated kinetically. Kinetic results yield large Hammett ρX (ρnuc = ?3.97) and Bronsted βX (βnuc = 1.40) values. A concerted mechanism involving a partial frontside nucleophilic attack through a hydrogen-bonded, four-center type transition state is proposed on the basis of the primary normal kinetic isotope effects (kH/kD = 1.0-1.1) with deuterated aniline (XC6H4ND2) nucleophiles. The natural bond order charges on P and the degrees of distortion of 42 compounds: chlorophosphates [(R1O)(R2O)P(=O)Cl], chlorothiophosphates [(R1O)(R2O)P(=S)Cl], phosphonochloridates [(R1O)R2P(=O)Cl], phosphonochlorothioates [(R1O)R2P(=S)Cl], chlorophosphinates [R1R2P(=O)Cl], and chlorothiophosphinates [R1R2P(=S)Cl] are calculated at the B3LYP/ 6-311+G(d,p) level in the gas phase.

• 천문학회지
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• 제41권4호
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• pp.83-98
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• 2008

In an attempt of clarifying the connection between the photospheric abundance anomalies and the stellar rotation as well as of exploring the nature of "normal A" stars, the abundances of seven elements (C, O, Si, Ca, Ti, Fe, and Ba) and the projected rotational velocity for 46 A-type field stars were determined by applying the spectrum-fitting method to the high-dispersion spectral data obtained with BOES at BOAO. We found that the peculiarities(underabundances of C, O, and Ca; an overabundance of Ba) seen in slow rotators efficiently decrease with an increase of rotation, which almost disappear at $v_esin\;i{\gtrsim}100km\;s^{-1}$. This further suggests that stars with sufficiently large rotational velocity may retain the original composition at the surface without being altered. Considering the subsolar tendency(by several tenths dex below) exhibited by the elemental abundances of such rapidly-rotating (supposedly normal) A stars, we suspect that the gas metallicity may have decreased since our Sun was born, contrary to the common picture of galactic chemical evolution.

• 천문학회보
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• 제37권2호
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• pp.67-67
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• 2012

Exploring the distant universe by observing various astronomical objects and extending knowledge on the cosmos by applying human intuition and reasoning to observations are astronomers' professional activity. Astronomers are the people born under a lucky star since this elegant and beautiful job is their the only duty. Being in the 21st century we astronomers now know that galaxies are holding evolving stars and gas, and distribute in the infinite spacetime in an interesting way revealing the secrets of the beginning of the universe. Cosmic structures such as galaxies, large-scale structures, and cosmic microwave background fluctuations are also the tracers of the expansion of space and the invisible components of the energy contents of the universe. Unlike the past century we are in a situation where integral knowledge on various cosmic structures as well as that on a variety of observational and analysis tools are available to everyone and often required for our special mission. However, my experience made me think that accumulating critical questions on nature driven by curiosity is vital for researchers and far more important than absorbing knowledge from others and books. Transforming one's own question marks to acclamation marks is the reward of our life. That is THE fun.

• 한국환경과학회지
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• 제5권1호
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• pp.71-81
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• 1996

Direct Sky Blue-5B is an Azo dye known as general for staining of textile and leather, etc., and as materials which are difficult to be biodegraded in nature. The bacterium strain which could degrade direct Sky Blue-5B was isolated from activated sludge of dyeing factory and identified as Proteus sp. by experiment on morphological, cultural and biochemical characteristics, and so named Proteus sp. ST-1. The optimum condition of the strain for degradation of Sky Blue-5B were at about 35$^{\circ}C$ and PH 7~8. The strain had been capable of degradation with organic nitrogen effectively and had completely degraded 200mg/1 of the dye within 12hrs at 37$^{\circ}C$. The enzyme system related to degradation of Azo dye may be intracellular, and so degraded the dye after absorption into cell. The degradation products of Sky Blue-5B by Proton sp. 57-1 were analyzed by Gas Chromatography /Mass Spectrometry and Spectrophotomer, from this observation, it may be infered that the strain degraded the dye directly without any mediate.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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• pp.2223-2225
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• 2005

In this work, experimental investigation has been mainly done. For this purpose, UHF sensor has been designed and fabricated to detect the partial discharges produced from the 10 artificial defects introduced into the real scale 70kV GIS mock-up under the high voltage at the well shielded room. And also, in order to verify the applicability of the proposed method at the site, the proposed CAPD (chaos analysis of partial discharge) is combined with spectral analysis method in order to identify the nature of the above 10 defects. The PD pattern recognition of each defect has been fulfilled by applying self developed artificial neural network soft ware. The result shows that the recognition rate is reached to be 80% by newly proposed method while the traditional PRPD analysis method leads us to obtain 41%. In consequence, it can be pointed out that the proposed method seems likely to be applicable to the real GIS at the site.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.45-48
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• 2000

High dielectric (Ba,Sr)TiO$_3$ thin films were etched in an inductively coupled plasma (ICP) as a function of C1$_2$/Ar gas mixing ratio. Under Cl$_2$(20)/Ar(80), the maximum etch rate of the BST films was 400$\AA$/min and selectivities of BST to Pt and PR were obtained 0.4 and 0.2, respectively. We investigated the etched surface of BST by x-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM) and x-ray diffraction (XRD). From the result of XPS analysis, we found that residues of Ba-Cl and Ti-Cl bonds remained on the surface of the etched BST for high boiling point. The surface roughness decreased as Cl$_2$ increases in Cl$_2$/Ar plasma because of non-volatile etching products. This changed the nature of the crystallinity of BST. From the result of XRD analysis, the crystalliility of etched BST film maintained as similar to as-deposited BST under Ar only and Cl$_2$(20)/Ar(80). However, (100) orientation intensity of etched BST film abruptly decreased at Cl$_2$ only plasma. It was caused that Cl compounds were redeposited on the etched BST surface and damaged to crystallinity of BST film during the etch process.

• 한국태양광발전학회지
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• 제3권2호
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• pp.48-54
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• 2017

Nowadays Viet Nam's energy supply which is mainly produced by fossil fuels energy such as coal, gas, and oil. However, the operation of fossil fuel power plants is one of the major causes of environmental pollution and climate change as well. It has a serious impact on the survival of human beings in general. As can be seen, the manufacturing industry is strongly invested, the demand for energy is also increasing. As traditional fossil fuels are being depleted and to minimize environmental pollution, renewable energy is the solution widely used by many countries in the world. Therefore, renewable energy has a significant role in maintaining the sustainability of world economy. Renewable energy sources such as solar energy, wind energy, biomass energy, geothermal energy can supply clean and nature-sourced energy to replace fossil fuels. Encouraging development of renewables is a general trend in the world today, which is also a common goal of COP21 commitment on global GHG reduction. The objective of this study is to assess the opportunities and challenges for renewable energy development in Vietnam, particularly for solar power. This study also discusses policies to promote the development of solar energy in Vietnam. While solar power provides ecological, economic and social benefits, it is exploited very modestly in Vietnam, where there are many barriers to slow down the development of renewable energy.