• Title/Summary/Keyword: Natural soil

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Effects of Water Chemistry on Aggregation and Soil Adsorption of Silver Nanoparticles

  • Bae, Sujin;Hwang, Yu Sik;Lee, Yong-Ju;Lee, Sung-Kyu
    • Environmental Analysis Health and Toxicology
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    • v.28
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    • pp.6.1-6.7
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    • 2013
  • Objectives In this study, we investigated the influence of ionic strength and natural organic matter (NOM) on aggregation and soil adsorption of citrate-coated silver nanoparticles (AgNPs). Methods Time-resolved dynamic light scattering measurements and batch adsorption experiments were used to study their aggregation and soil adsorption behaviors, respectively. Results The aggregation rate of AgNPs increased with increasing ionic strength and decreasing NOM concentration. At higher ionic strength, the AgNPs were unstable, and thus tended to be adsorbed to the soil, while increased NOM concentration hindered soil adsorption. To understand the varying behaviors of AgNPs depending on the environmental factors, particle zeta potentials were also measured as a function of ionic strength and NOM concentration. The magnitude of particle zeta potential became more negative with decreasing ionic strength and increasing NOM concentration. These results imply that the aggregation and soil adsorption behavior of AgNPs were mainly controlled by electrical double-layer repulsion consistent with the Derjaguin-Landau-Verwey-Overbeek theory. Conclusions This study found that the aggregation and soil adsorption behavior of AgNPs are closely associated with environmental factors such as ionic strength and NOM and suggested that assessing the environmental fate and transport of nanoparticles requires a thorough understanding of particle-particle interaction mechanisms.

Effects of nonionic surfactants on the partitioning of naphthalene in soil/water system (토양과 수용액상에서 나프탈렌의 분배에 관한 비이온성 계면활성제의 영향)

  • 하동현;고석오;신원식;김영훈;전영웅;송동익
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.283-286
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    • 2002
  • Solubilization and partitioning of naphthalene was investigated in an aqueous system containing soils and surfactants. The environmental behavior of polycyclic aromatic hydrocarbons(PAHs) was mainly governed by their solubility and partitioning properties on soil media in a subsurface system. In surfactant-enhanced remediation systems, surfactants might be an additional variable. a natural soil ,silica and kaolinite were tested as soil media. two nonionic surfactants, Triton X-100 and Hydropropy1-$\beta$-cyclodextrin (HPCD) were employed for naphthalene solubilization. Naphthalene showed linear on natural soil while non-linear sorption on silica and kaolinite. Soils have higher sorption capacity for Triton X-100 than HPCD indicating Triton X-100 formed ad-micelle on the soil surface. Desorption study showed a hysterysis and reversible desorption. The partitioning coefficient(K$_{D}$) of naphthalene was increased as the concentration of surfactant was increased. (below CMC), however, the coefficient was decreased above CMC. This indicates that naphthalene is partitioned into the micelles and the partition occurs competitively on both ad-micelle and free micelles as surfactant concentration increases. Therefore, the target compounds to be dissolved into aqueous phase in a surfactant enhanced remediation system might be highly partitioned on to the ad-micelle resulting in an adverse effect rather increased solubilization would be achieved.d.

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Future Directions and Perspectives on Soil Environmental Researches (토양환경분야 연구동향 및 전망)

  • Yang, Jae-E.;Ok, Yong-Sik;Chung, Doug-Young
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1286-1294
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    • 2011
  • This paper reviews the future directions and perspectives on the soil environmental researches in the 21 century. Previously, the principal emphasis of soil environmental researches had put on the enhancement of food and fiber productions. Beside the basic function of soil, however, the societal needs on soil resources in the 21st century have demands for several environmental and social challenges, occurring regionally or globally. Typical global issues with which soil science should deal include food security with increasing agronomic production to meet the exploding world population growth, adaptation and mitigation of climate change, increase of the carbon sequestration, supply of the biomass and bioenergy, securing the water resource and quality, protection of environmental pollution, enhancing the biodiversity and ecosystem health, and developing the sustainable farming/cropping system that improve the use efficiency of water and agricultural resources. These challenges can be solved through the sustainable crop production intensification (SCPI) or plant welfare concept in which soil plays a key role in solving the abovementioned global issues. Through implementation of either concept, soil science can fulfill the goal of the modern agriculture which is the sustainable production of crops while maintaining or enhancing the ecosystem function, quality and health. Therefore, directions of the future soil environmental researches should lie on valuing soil as an ecosystem services, translating research across both temporal and spatial scales, sharing and using data already available for other purposes, incorporating existing and new technologies from other disciplines, collaborating across discipline, and translating soil research into information for stakeholders and end users. Through the outcomes of these approaches, soil can enhance the productivity from the same confined land, increase profitability, conserve natural resource, reduce the negative impact on environment, enhance human nutrition and health, and enhance natural capital and the flow of ecosystem services. Soil is the central dogma, final frontier and new engine for the era of sustainability development in the $21^{st}$ century and thus soil environmental researches should be carried according to this main theme.

Studies on the Decomposition of Leaf Litter Containing Heavy Metals in Andong Serpentine Area, Korea I. Microcosm Experiment (사문암지대의 중금속 함유 낙엽의 분해에 관한 연구 I. Microcosm 실험)

  • Ryou, Sae-Han;Kim, Jeong-Myeong;Shim, Jae-Kuk
    • Korean Journal of Environmental Biology
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    • v.27 no.4
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    • pp.353-362
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    • 2009
  • This study attempted to compare the litter decomposition rate of Arundinella hirta and Miscanthus sinensis var. purpurascens which collected from serpentine soil acting potentially toxic concentration of heavy metals and non-serpentine soil by using the microcosm method for 192 days under constant humidity and $23^{\circ}C$. The contents of Ni, Fe, Mg and Cr in the serpentine and nonserpentine soil originated litter showed high differences between them. The litter samples from serpentine site have lower C/N than non-serpentine litter, but the soluble carbohydrate content was shown almost similar between two plant litter. The mass loss rates of leaf litter from serpentine area were slower than those from non-serpentine site. During the experimental period, the remained dry weight of A. hirta and M. sinensis var. purpurascens litter collected from serpentine site were 64.7%, 65.0% of initial dry weight and litter samples from non-serpentine site showed 54.2%, 50.7%, respectively. K and Na were leached rapidly at the initial decomposition periods, but Ca showed immobilization and other metal elements reserved at the decomposing litter for a long time. The decomposing A. hirta litter from non-serpentine soil showed higher values of $CO_2$ evolution, microbial biomass-C, and microbial biomass-N than those in serpentine soil originated litter acting nutrient stresses and exhibited rapid decay rate. The microbial biomass and microbial respiration of decaying litter were positively correlated with litter decomposition rate, and these relationships showed more rapid slope in non-serpentine soil originated litter than that in serpentine soil.

Physical properties of granitic weathered soil on natural terrain around Seoul city (서울주변에 분포한 화강암류 풍화토층의 물리적 성질)

  • Kim, Kyeong-Su
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09a
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    • pp.1122-1129
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    • 2010
  • Various soil tests were performed in the laboratory after soil samples were obtained from natural terrains distributed on the granitic rocks where are located in Mt. Bukhan, Mt. Surak and Mt. Gwanak around Seoul. Through the comparison of soil properties in each mountain, the difference of soil properties in a similar geological condition was investigated. According to the result of soil test, the soils were generally classified into calyey and silty sands with a well grade. Soil densities are ranged from $2.62kg/cm^3$ to $2.67kg/cm^3$, and water contents of soils are ranged from 3.77% to 31.12%. These values are not sorted locally. The wet unit weights of soils are ranged from $1.092kg/cm^3$ to $1.814kg/cm^3$. It has a big difference between the average values because that of Mt. Bukhan is $1.604kg/cm^3$ and those of Mt. Surak and Mt. Gwanak are $1.500kg/cm^3$ and $1.331kg/cm^3$, respectively. The internal friction angles are ranged from $31^{\circ}$ to $39^{\circ}$ and the cohesions are ranged from 1.57kPa to 8.63kPa. The shear strengths are too high and similar in all regions. The coefficients of permeability are ranged from $3.07{\times}10^{-3}cm/sec$ to $4.61{\times}10^{-2}cm/sec$. So, these soils are evaluated as a middle to high permeable ground. On average, the value of Mt. Bukhan is $1.47{\times}10^{-2}cm/sec$ and the values of Mt. Surak and Mt. Kwanak are $1.29{\times}10^{-2}cm/sec$ and $1.66{\times}10^{-2}cm/sec$, respectively.

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Physicochemical Properties of Depth-based Soil on the Reclaimed Dredging Area (임해준설매립지 토양의 깊이별 이화학적 특성)

  • Nam, Woong;Kwak, Young-Se;Jeong, In-Ho;Lee, Deok-Beom;Lee, Sang-Suk
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.11 no.5
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    • pp.60-71
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    • 2008
  • Through analyzing the specific physicochemical alterations in depth-based soil at reclaimed dredging area, the baseline data were provided for developing the reclaimed dredging area as natural landscape planting sites and ecological-landscape sites based on the soil improvement technology. There was no physical disturbance for 15 to 20 years in Gwangyang Bay reclaimed dredging area after reclamation. Physicochemical examinations of the soil were performed based on the vertical depth. Results of physicochemical analysis such as pH, electric conductivity, total salt contents, silt, clay contents, available phosphorus, calcium, magnesium, sodium, chlorine, and sodium-adsorption ratio showed increasing patterns with the depth while total organic contents, total nitrogen, and sand showed decreasing patterns. Potassium as an exchangeable cation, showed similar distribution patterns between the shallow and deep soil. This result strongly implied that long-term exposure to natural rainfall in reclaimed dredging area altered soil characteristics related to salinity. This research demonstrated that there were no remarkable differences in physicochemical characteristics at soil depth and groundwater table height, suggesting a baseline data for developing reclaimed dredging area. Additional investigation is required for different reclaimed dredging areas. Also, additional monitoring and examination are need on plant communities and time variable alteration in the soil to test the feasibility of reclaimed dredging areas as natural landscape planting sites and ecological-landscape sites.

Ginseng Conservation Program in Russian Primorye: Genetic Structure of Natural and Cultivated Populations

  • Yu.N. Zhuravlev;O.G. Koren;G.D. Reunova;E.V Artyukova;M.M. Kozyrenko;T.I. Muzarok;I.L. Kats
    • Proceedings of the Ginseng society Conference
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    • 2002.10a
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    • pp.509-521
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    • 2002
  • 'The Regional complex long-term program of restoration (reintroduction) of Primoryes ginseng population up to 2005' elaborated by Primorye governor administration, Regional Committee of Natural Resources and Russian Academy of Sciences operates in Russian Primorye. The Institute of Biology and Soil Science (IBSS) provides the scientific implementation of this program including the genetic analysis of extant ginseng populations, plant reproduction and offspring identification. According to our investigations, the genetic resource of P. ginseng in Primorye is represented by three populations of wild-growing ginseng and a few private plantations. The results obtained by RAPD allowed concluding that this resource is dispersed among the wild and cultivated ginseng sub-populations in such a way that each of sub-populations studied has to be represented in living plant collection as a stock material to maintain species genetic variability. The allozyme analyses also showed that the small sub-populations of natural ginseng are characterized by unique genetic diversity and, therefore, they all need to be represented in reintroduction centers. Additionally the allozyme analysis discovered that the Blue Mountain and Khasan populations possess the most genetic diversity. So, at least one more reproductive ginseng unit has to be created besides two already existing reintroduction centers representing the Sikhote-Alin and the Blue Mountain populations.

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Assessment of Natural Attenuation Processes in the Groundwater Contaminated with Trichloroethylene (TCE) Using Multi-Species Reactive Transport Modeling (다성분 반응 이동 모델링을 이용한 트리클로로에틸렌(TCE)으로 오염된 지하수에서의 자연저감 평가)

  • Jeen, Sung-Wook;Jun, Seong-Chun;Kim, Rak-Hyeon;Hwang, Hyoun-Tae
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.101-113
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    • 2016
  • To properly manage and remediate groundwater contaminated with chlorinated hydrocarbons such as trichloroethylene (TCE), it is necessary to assess natural attenuation processes of contaminants in the aquifer along with investigation of contamination history and aquifer characterization. This study evaluated natural attenuation processes of TCE at an industrial site in Korea by delineating hydrogeochemical characteristics along the flow path of contaminated groundwater, by calculating reaction rate constants for TCE and its degradation products, and by using geochemical and reactive transport modeling. The monitoring data showed that TCE tended to be transformed to cis-1,2-dichloroethene (cis-1,2-DCE) and further to vinyl chloride (VC) via microbial reductive dechlorination, although the degree was not too significant. According to our modeling results, the temporal and spatial distribution of the TCE plume suggested the dominant role of biodegradation in attenuation processes. This study can provide a useful method for assessing natural attenuation processes in the aquifer contaminated with chlorinated hydrocarbons and can be applied to other sites with similar hydrological, microbiological, and geochemical settings.

An Improved Selective Isolation of Rare Actinomycetes from Forest Soil

  • Seong, Chi-Nam;Park, Ji-Heok;Baik, Keun-Shik
    • Journal of Microbiology
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    • v.39 no.1
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    • pp.17-23
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    • 2001
  • Various pretreatment procedures and selective media were applied to assess the optimal conditions for the isolation of rare actinomycetes from soil. Pretreatment of wet-heating for 15 min at 70$^{\circ}C$ and phenol treatment of soil suspension were the most effective methods for the isolation of these microorganisms. Hair hydrolysate vitamin agar (HHVA) was the most suitable medium for the recovery of rare actinomycetes. Thirty-five rare actinomycete strains were chosen using selective isolation approaches, then morphological and chemical properties of the isolates were determined. The isolates belonged to one of the following genus, Micromonospora, Microbispora, Actinoplanes and Streptosporangium.

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Frost Heaving in Artificial Ground Freezing

  • 생뢰효박
    • Proceedings of the Korean Geotechical Society Conference
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    • 1994.03b
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    • pp.13-46
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    • 1994
  • Artificial ground freezing methods have been applied to geotechnical construction projects for stabilizing earth materials and controlling water seepage into the ground. However, this can result in frost heaving and causes the same engineering problems as encountered with the natural freezing of soil. In natural freezing, the ground freezes from the surface downward. When artificial ground freezing is applied at a deep location, however, freezing is limited locally. The soil condition differs between them as follows: Natural freezing - unsaturated and without overburden pressure. Artificial freezing -- saturated and under overburden pressure. The authors investigated the practical application of artificial ground freezing and examined the frost behaviour of a saturated soil under overburden pressure. This paper presents the results obtained from experiments concerning frost heaving and discusses frost heaving at the freezing site.

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