• Title/Summary/Keyword: Natural reduction

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Reduction of cement consumption by producing smart green concretes with natural zeolites

  • Trung, Nguyen Thoi;Alemi, Nima;Haido, James H.;Shariati, Mahdi;Baradaran, Seyedata;Yousif, Salim T.
    • Smart Structures and Systems
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    • v.24 no.3
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    • pp.415-425
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    • 2019
  • This study was carried out to evaluate the natural zeolite in producing green concrete as an effort to prevent global warming and environmental impact problems of cement industries. To achieve this target, two types of natural zeolites applied to study physical, chemical and compressive strength of concrete containing different percentages of zeolites. The results in comparison with control samples indicate that compressive strength of zeolites mixes increases with the 15% replacement of zeolite instead of cement in all types of samples. In the water-cement ratio of 0.6, results showed an increase in the compressive strength of all percentages of replacement. This results indicate that using natural zeolites could be produced a green concrete by a huge reduction and saving in the consumption of cement.

Effects of Natural Organic Matter (NOM) on Cr(Ⅵ) reduction by Fe(II) (Fe(II)을 이용한 Cr(Ⅵ) 환원시 천연유기물의 영향)

  • 한인섭
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1999.10a
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    • pp.81-84
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    • 1999
  • The aqueous geochemical characteristics of Cr(III) and Cr(Ⅵ) in environmental systems are very different from one another: Cr(Ⅵ) is highly soluble, mobile and toxic relative to Cr(III) Reduction of Cr(Ⅵ) to Cr(III) are beneficial in aquatic systems because of the transformation of a highly mobile and toxic species to one having a low solubility in water, thus simultaneously decreasing chromium mobility and toxicity. Fe(II) species are excellent reductants for transforming Cr(Ⅵ) to Cr(III), and in addition, keeping Cr(III) concentrations below the drinking water standard of 52 ppb at pH values between 5 and 11. Investigations of the effects of NOM on Cr(Ⅵ) reduction are for examining the feasibility of using ferrous iron to reduce hexavalent chromium in subsurface environments. Experiments in the presence of soils, however, showed that the solid phase consumes some of the reducing capacity of Fe(II) and makes the overall reduction kinetics slower. The soil components bring about consumption of the ferrous iron reductant. Particular attention is devoted to the complexation of Fe(II) by NOM and the subsequent effect on Cr(Ⅵ) reduction. Cr(Ⅵ) reduction rate by Fe(II) was affected by the presence of NOM (humic acid), The effects of humic acid was different from the solution pH values and the concentration of humic acid. It was probably due to the reactions between humic acid and Cr(Ⅵ), humic acid and Fe(II), and between Cr(Ⅵ) and Fe(II), at each pH.

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Damage Detection of Beam by Using the Reduction Ratio of Natural Frequency and the Neural Network (고유진동수의 감소율과 신경망을 이용한 보의 손상평가)

  • Ghoi, Hyuk;Lee, Gyu-Won
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.2
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    • pp.153-165
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    • 2006
  • A damage in a structure changes its dynamic characteristics such as natural frequencies, damping ratios, and the mode shapes. In this paper the effort has been spent in obtaining the characteristics of the reduction ratio in natural frequencies and the damage detection is performed using the reduction ratios. Most of the emphasis has been on using the artificial neural network to determine the location and the extent of the damage as well as the existence of the damage. The data for learning and verifying neural network were obtained from the analytical analysis. The data have no errors. Considering the real measurements the data including errors which are difference this study between other studies also were used for neural network. The position and extent of the damage can be detected using the neural network trained by reduction ratios of natural frequencies.

Aging Characteristics of NOx Storage and Reduction Catalyst for Lean-bum Natural Gas Vehicles (린번 천연가스자동차용 NOx 흡장촉매의 열화특성)

  • Choi, Byung-Chul;Lee, Choon-Hee
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.3
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    • pp.147-152
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    • 2007
  • This study investigates the aging characteristics of NOx storage and reduction(NSR) catalyst on the emission conditions of lean burn natural gas vehicles. We designed various NSR catalysts using by the double-layer washcoat technology to increase of a surface area and a thermal durability performance of the catalysts. The experiments were conducted with 3 kinds of the NSR catalysts, which were manufactured using by a honeycomb cordierite substrate. It was found that Ba is weak in the thermal aging because it has lower melting temperature than that of precious metals (PMs). The suitable loading amount of Ba in this study should be about 42 g/L from the results of the NOx adsorption and the NOx reduction efficiency. The major reason in deactivation of the NSR catalyst is the decrease of the adsorption site owing to the agglomeration and sintering of Ba rather than PM aging by hydrothermal aging. It was confirmed by results of BET, SEM and TEM.

Study on the reduction of heterocyclic amines by marinated natural materials in pork belly

  • Hea Jin, Kang;Seung Yun, Lee;Da Young, Lee;Ji Hyeop, Kang;Jae Hyeon, Kim;Hyun Woo, Kim;Jae Won, Jeong;Dong Hoon, Oh;Sun Jin, Hur
    • Journal of Animal Science and Technology
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    • v.64 no.6
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    • pp.1245-1258
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    • 2022
  • This study was conducted to determine the effect of natural ingredient seasoning on the reduction of heterocyclic amine (HCA) production that may occur when pork belly is cooked at a very high temperature for a long time. Pork belly seasoned with natural ingredients, such as natural spices, blackcurrant, and gochujang, was cooked using the most common cooking methods, such as boiling, pan fry, and barbecue. HCAs in pork belly were extracted through solid-phase extraction and analyzed via high-performance liquid chromatography. For short-term toxicity, a mouse model was used to analyze weight, feed intake, organ weight, and length; hematology and serology analysis were also performed. Results revealed that HCAs formed only when heating was performed at a very high temperature for a long time, not under general cooking conditions. Although the toxicity levels were not dangerous, the method showing the relatively highest toxicity among various cooking methods was barbecue, and the natural material with the highest toxicity reduction effect was blackcurrant. Furthermore, seasoning pork belly with natural materials containing a large amount of antioxidants, such as vitamin C, can reduce the production of toxic substances, such as HCAs, even if pork belly is heated to high temperatures.

A Study on Roll Reduction Devices for FPSOs (FPSO의 횡요 감쇠 장치에 대한 고찰)

  • PARK IN-KYU;YANG JIN-HO;SHIN HYUN-SOO
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.30-35
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    • 2004
  • Several roll motion reduction devices are reviewed and suggested for the application in FPSO. The firstly suggested solution is the shape of the bilge. The next is a bilge keel. The last suggestion is the ART (anti-rolling tank). Typical U-tube type ART is designed for a FPSO and examined extensively by model experiment. The model section was made of transparent acryl. Free decay test, forced oscillation test and wave test were carried out at a two-dimensional wave flume. U-tube type ART is effective only when the natural periods of ART and ship are same. Therefore, the divided U-tube type ART with split plate is suggested for the reduction of the roll motion of a FPSO over the wide range of the roll period.

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Study on the noise reduction occurred to rotation in duct (덕트 회전체에서 발생하는 소음저감에 대한 연구)

  • Park, Hong-Ul;Kim, You-Jae;Park, Sung-Kwan
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.11a
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    • pp.875-879
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    • 2006
  • Noise reduction has become a major issue of the duct air-conditioners. This paper describes the reduction of noise and vibration of rotational slim duct system. The design of slim duct system is the most important point of noise reduction in terms of the motor of 2f line noise, resonance noise between forced frequency and natural frequency of Sirocco fan, unbalance noise of motor axis and the noise induced refrigerant. The noise of duct system is mainly measured from diffuser and bottom of duct. The optimal design was implemented after measuring the effect of noise and vibration in each part which is composed of duct system. In this paper, experimental results show that the main elements in air-conditioner duct design. These elements are anti-vibration rubber of motor, axis length of motor, rubber coupler, materials of sirocco fan and control method of motor which are the most vital factors in reducing noise.

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Polarographic Behavior of Azo Series Organic Compounds (II). Reduction of 1-(2-Pyridylazo)-2-naphthol in Acetonitrile (Azo계 유기화합물의 폴라로그래프법적 거동 (제2보). 아세토니트릴 중에서 1-(2-Pyridylazo)-2-naphthol의 환원)

  • Heung Lark Lee;Zun Ung Bae
    • Journal of the Korean Chemical Society
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    • v.27 no.1
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    • pp.24-30
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    • 1983
  • The polarographic behavior of 1-(2-pyridylazo)-2-naphthol (PAN) in acetonitrile as an aprotic solvent has been investigated. The reduction of PAN in $10^{-2}$ molarity of tetraethyl-ammonium perchlorate acetonitrile solution proceeds along two one-electron steps to give the corresponding hydrazo compound. Every reduction wave was diffusion controlled and considerably reversible. The reduction mechanism of PAN in acetonitrile is estimated as follows;

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Electrocatalytic Reduction of Dioxygen at Glassy Carbon Electrodes with Irreversible Self-assembly of N-hexadecyl-N'-methyl Viologen

  • Lee, Chi-Woo;Jang, Jai-Man
    • Bulletin of the Korean Chemical Society
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    • v.15 no.7
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    • pp.563-567
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    • 1994
  • The electroreduction of dioxygen at glassy carbon electrodes with irreversible self-assembly of N-hexadecyl-N'-methyl viologen $(C_{16}VC_1)$ proceeds at potentials more positive than those where the reduction occurs at bare electrodes. The electrocatalyzed reduction takes place at potentials well ahead of those where the catalyst is reduced in the absence of dioxygen and the limiting currents observed at rotating disk electrodes did not deviate from the thoretical Levich line up to 6400 rpm, indicating that the electrocatalysis is extremely rapid. The rate constant for the heterogeneous reaction between $C_{16}V^+C_1$ immobilized on the electrode surface and $O_2$ in solution was estimated to be ca. $10^8\;M^{-1}s^{-1}$. The half-wave potential of dioxygen reduction was independent of solution pH.