• 제목/요약/키워드: Natural reduction

검색결과 2,165건 처리시간 0.03초

Reduction of cement consumption by producing smart green concretes with natural zeolites

  • Trung, Nguyen Thoi;Alemi, Nima;Haido, James H.;Shariati, Mahdi;Baradaran, Seyedata;Yousif, Salim T.
    • Smart Structures and Systems
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    • 제24권3호
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    • pp.415-425
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    • 2019
  • This study was carried out to evaluate the natural zeolite in producing green concrete as an effort to prevent global warming and environmental impact problems of cement industries. To achieve this target, two types of natural zeolites applied to study physical, chemical and compressive strength of concrete containing different percentages of zeolites. The results in comparison with control samples indicate that compressive strength of zeolites mixes increases with the 15% replacement of zeolite instead of cement in all types of samples. In the water-cement ratio of 0.6, results showed an increase in the compressive strength of all percentages of replacement. This results indicate that using natural zeolites could be produced a green concrete by a huge reduction and saving in the consumption of cement.

Fe(II)을 이용한 Cr(Ⅵ) 환원시 천연유기물의 영향 (Effects of Natural Organic Matter (NOM) on Cr(Ⅵ) reduction by Fe(II))

  • 한인섭
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 1999년도 추계학술발표회
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    • pp.81-84
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    • 1999
  • The aqueous geochemical characteristics of Cr(III) and Cr(Ⅵ) in environmental systems are very different from one another: Cr(Ⅵ) is highly soluble, mobile and toxic relative to Cr(III) Reduction of Cr(Ⅵ) to Cr(III) are beneficial in aquatic systems because of the transformation of a highly mobile and toxic species to one having a low solubility in water, thus simultaneously decreasing chromium mobility and toxicity. Fe(II) species are excellent reductants for transforming Cr(Ⅵ) to Cr(III), and in addition, keeping Cr(III) concentrations below the drinking water standard of 52 ppb at pH values between 5 and 11. Investigations of the effects of NOM on Cr(Ⅵ) reduction are for examining the feasibility of using ferrous iron to reduce hexavalent chromium in subsurface environments. Experiments in the presence of soils, however, showed that the solid phase consumes some of the reducing capacity of Fe(II) and makes the overall reduction kinetics slower. The soil components bring about consumption of the ferrous iron reductant. Particular attention is devoted to the complexation of Fe(II) by NOM and the subsequent effect on Cr(Ⅵ) reduction. Cr(Ⅵ) reduction rate by Fe(II) was affected by the presence of NOM (humic acid), The effects of humic acid was different from the solution pH values and the concentration of humic acid. It was probably due to the reactions between humic acid and Cr(Ⅵ), humic acid and Fe(II), and between Cr(Ⅵ) and Fe(II), at each pH.

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고유진동수의 감소율과 신경망을 이용한 보의 손상평가 (Damage Detection of Beam by Using the Reduction Ratio of Natural Frequency and the Neural Network)

  • 최혁;이규원
    • 한국구조물진단유지관리공학회 논문집
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    • 제10권2호
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    • pp.153-165
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    • 2006
  • 구조물이 손상을 받으면 그 구조물의 동적특성인 고유진동수, 감쇠비, 모드형상 등이 변한다. 본 논문에서는 구조물이 손상을 받을 때 고유진동수의 감소율에 대한 특성을 알아보고 그 감소율을 이용한 구조물의 손상평가를 다룬다. 손상의 유무뿐만 아니라 손상의 위치와 정도까지도 고유진동수의 감소율만으로 파악하고자 하였으며 인공신경망을 이용하였다. 신경망에 사용되는 자료는 다른 연구와 달리 해석 자료로부터 얻어지는 오차 없는 자료뿐만 아니라 실측자료를 가상하여 오차를 포함하는 자료를 대상으로 하였으며, 고유진동수의 감소율로 훈련된 인공신경망을 활용하여 구조물의 손상 위치와 정도를 파악할 수 있었다.

린번 천연가스자동차용 NOx 흡장촉매의 열화특성 (Aging Characteristics of NOx Storage and Reduction Catalyst for Lean-bum Natural Gas Vehicles)

  • 최병철;이춘희
    • 한국자동차공학회논문집
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    • 제15권3호
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    • pp.147-152
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    • 2007
  • This study investigates the aging characteristics of NOx storage and reduction(NSR) catalyst on the emission conditions of lean burn natural gas vehicles. We designed various NSR catalysts using by the double-layer washcoat technology to increase of a surface area and a thermal durability performance of the catalysts. The experiments were conducted with 3 kinds of the NSR catalysts, which were manufactured using by a honeycomb cordierite substrate. It was found that Ba is weak in the thermal aging because it has lower melting temperature than that of precious metals (PMs). The suitable loading amount of Ba in this study should be about 42 g/L from the results of the NOx adsorption and the NOx reduction efficiency. The major reason in deactivation of the NSR catalyst is the decrease of the adsorption site owing to the agglomeration and sintering of Ba rather than PM aging by hydrothermal aging. It was confirmed by results of BET, SEM and TEM.

Study on the reduction of heterocyclic amines by marinated natural materials in pork belly

  • Hea Jin, Kang;Seung Yun, Lee;Da Young, Lee;Ji Hyeop, Kang;Jae Hyeon, Kim;Hyun Woo, Kim;Jae Won, Jeong;Dong Hoon, Oh;Sun Jin, Hur
    • Journal of Animal Science and Technology
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    • 제64권6호
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    • pp.1245-1258
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    • 2022
  • This study was conducted to determine the effect of natural ingredient seasoning on the reduction of heterocyclic amine (HCA) production that may occur when pork belly is cooked at a very high temperature for a long time. Pork belly seasoned with natural ingredients, such as natural spices, blackcurrant, and gochujang, was cooked using the most common cooking methods, such as boiling, pan fry, and barbecue. HCAs in pork belly were extracted through solid-phase extraction and analyzed via high-performance liquid chromatography. For short-term toxicity, a mouse model was used to analyze weight, feed intake, organ weight, and length; hematology and serology analysis were also performed. Results revealed that HCAs formed only when heating was performed at a very high temperature for a long time, not under general cooking conditions. Although the toxicity levels were not dangerous, the method showing the relatively highest toxicity among various cooking methods was barbecue, and the natural material with the highest toxicity reduction effect was blackcurrant. Furthermore, seasoning pork belly with natural materials containing a large amount of antioxidants, such as vitamin C, can reduce the production of toxic substances, such as HCAs, even if pork belly is heated to high temperatures.

FPSO의 횡요 감쇠 장치에 대한 고찰 (A Study on Roll Reduction Devices for FPSOs)

  • 박인규;양진호;신현수
    • 한국해양공학회:학술대회논문집
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    • 한국해양공학회 2004년도 학술대회지
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    • pp.30-35
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    • 2004
  • Several roll motion reduction devices are reviewed and suggested for the application in FPSO. The firstly suggested solution is the shape of the bilge. The next is a bilge keel. The last suggestion is the ART (anti-rolling tank). Typical U-tube type ART is designed for a FPSO and examined extensively by model experiment. The model section was made of transparent acryl. Free decay test, forced oscillation test and wave test were carried out at a two-dimensional wave flume. U-tube type ART is effective only when the natural periods of ART and ship are same. Therefore, the divided U-tube type ART with split plate is suggested for the reduction of the roll motion of a FPSO over the wide range of the roll period.

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덕트 회전체에서 발생하는 소음저감에 대한 연구 (Study on the noise reduction occurred to rotation in duct)

  • 박홍을;김유재;박성관
    • 한국소음진동공학회:학술대회논문집
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    • 한국소음진동공학회 2006년도 추계학술대회논문집
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    • pp.875-879
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    • 2006
  • Noise reduction has become a major issue of the duct air-conditioners. This paper describes the reduction of noise and vibration of rotational slim duct system. The design of slim duct system is the most important point of noise reduction in terms of the motor of 2f line noise, resonance noise between forced frequency and natural frequency of Sirocco fan, unbalance noise of motor axis and the noise induced refrigerant. The noise of duct system is mainly measured from diffuser and bottom of duct. The optimal design was implemented after measuring the effect of noise and vibration in each part which is composed of duct system. In this paper, experimental results show that the main elements in air-conditioner duct design. These elements are anti-vibration rubber of motor, axis length of motor, rubber coupler, materials of sirocco fan and control method of motor which are the most vital factors in reducing noise.

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Azo계 유기화합물의 폴라로그래프법적 거동 (제2보). 아세토니트릴 중에서 1-(2-Pyridylazo)-2-naphthol의 환원 (Polarographic Behavior of Azo Series Organic Compounds (II). Reduction of 1-(2-Pyridylazo)-2-naphthol in Acetonitrile)

  • 이흥락;배준웅
    • 대한화학회지
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    • 제27권1호
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    • pp.24-30
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    • 1983
  • 반양성자성 용매인 아세토니트릴 중에서 1-(2-pyridylazo)-2-naphthol (PAN)의 폴라로그래프법적 거동을 조사하였다. $10^{-2}$몰농도의 과염소산 테트라에틸암모늄 아세토니트릴 용액에서 PAN은 1전자 2단계의 환원과정을 거쳐 hydrazo화합물이 되었다. 각 환원파는 확산지배적이었고 가역성도 비교적 좋았다. 아세토니트릴에서 PAN의 환원반응 메카니즘은 아래와 같이 결론지을 수 있다.

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Electrocatalytic Reduction of Dioxygen at Glassy Carbon Electrodes with Irreversible Self-assembly of N-hexadecyl-N'-methyl Viologen

  • Lee, Chi-Woo;Jang, Jai-Man
    • Bulletin of the Korean Chemical Society
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    • 제15권7호
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    • pp.563-567
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    • 1994
  • The electroreduction of dioxygen at glassy carbon electrodes with irreversible self-assembly of N-hexadecyl-N'-methyl viologen $(C_{16}VC_1)$ proceeds at potentials more positive than those where the reduction occurs at bare electrodes. The electrocatalyzed reduction takes place at potentials well ahead of those where the catalyst is reduced in the absence of dioxygen and the limiting currents observed at rotating disk electrodes did not deviate from the thoretical Levich line up to 6400 rpm, indicating that the electrocatalysis is extremely rapid. The rate constant for the heterogeneous reaction between $C_{16}V^+C_1$ immobilized on the electrode surface and $O_2$ in solution was estimated to be ca. $10^8\;M^{-1}s^{-1}$. The half-wave potential of dioxygen reduction was independent of solution pH.