• Title/Summary/Keyword: Natural gas

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Basic Design of 36 MTD Class Natural Gas BOG Re-Liquefaction System (36 MTD급 천연가스 BOG 재액화 플랜트 기본설계)

  • Ko, Junseok;Park, Seong-Je;Kim, Ki-Duck;Hong, Yong-Ju;Koh, Deuk-Yong;Kim, Hyobong;Yeom, Hankil
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.99-105
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    • 2013
  • In this paper, we carried out the basic design of 36 MTD natural gas BOG re-liquefaction system to recover the generated natural gas during performance test of LNG pump and natural gas compressor. The re-liquefaction process of natural gas is designed to have 1500 kg/h of liquefaction rate with reverse Brayton refrigeration cycle. With the designed process, the variation of liquefaction rate is calculated for various inlet conditions of feed gas. From results, the liquefaction rate is more sensitive for inlet temperature than gas composition. The specifications of equipments such as gas blower, natural gas compressor, cryogenic heat exchanger and nitrogen compander are determined on the basis of the designed process. The requirement of power consumption and cooling water are also determined through the basic design.

Retention Behaviors of Natural Gas Components on a Single Column by Gas Chromatography (기체 크로마토그래피에 의한 단일 컬럼상에서 천연가스 성분의 머무름 거동)

  • Choi, Yong-Wook;Choe, Kun-Hyung;Lee, Dai-Woon
    • Analytical Science and Technology
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    • v.7 no.3
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    • pp.329-338
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    • 1994
  • The retention behaviors of natural gas components were studied on a single column by gas chromatography. The dead time, $t_0$ was obtained by using extrapolation of homologous series to determine capacity factors. The plots of retention data for homologous series and carbon number at different temperatures were shown to converge into a single point, which point was determined as a dead time. The results of the effect of temperature on the column efficiency for n-butane exhibited the plate number, N incerased with temperature, but the resolution among the fast eluted components decreased. The adsorption enthalpy (${\Delta}H^0{_{ads}}$) for each component on 28% DC 200 stationary phase was determined, and in order to investigate the retention behaviors of natural gas components the regression analysis of log $t_R$, log k' and log ${\alpha}$ vs. van der Waals volume(Vw), molecular connectivity index(X) and hydrophobic fragmental constant(f) were carred out. Good correlation was found between log k' vs. Vw, and log k' vs. f. The correlations between the physical properties of natural gas and the physical parameters were investigated by the linear regression analysis. The relationships between Vw vs. molecular weight and heating value(${\Delta}H_{comb}$), X vs. boiling point, and f vs. molecular weight, boiling point and heating value exhibited the high correlation coefficient more than 0.99. Using the regression equation between the heating value of natural gas and Vw the predicted heating values from $C_6$ to $C_{10}$ showed good agreement with those reported in the literature within 0.2% relative error.

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Dynamic Performance of Natural Gas Injection Valve for Heavy-Duty Power Generation Engine - Part I (발전용 대형엔진용 천연가스 분사밸브 동특성 연구 (I))

  • Choi, Young;Kim, Yong-Rae;Lee, Seok-Whan;Kim, Chang-Gi
    • Journal of the Korean Institute of Gas
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    • v.19 no.6
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    • pp.15-21
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    • 2015
  • Natural gas fuel has known to be very promising in terms of abundancy and economic value. Therefore it is widely treated as research topics in a variety field of production, storage and utilization. Natural gas has become one of the major sources for the power generation by using internal combustion engines(ICE). Development of natural gas fuel injection device should be preceded to realize a reliable natural gas fuel supply system for a MW class power generation reciprocating ICE. In this research, an injection valve which consists of solenoid and body part with a moving plate was designed and its dynamic performance was experimented in the engine-like environment. As a result of the experiments, linearity of flow rate was obtained and overall around 2ms of response time was observed at the pressure difference of 1bar. In addition, more than 100Liter/min(@2Hz) of gas flow rate was witnessed, which is expected to be adequate for the fuel supply system of a MW class natural gas engine.

Analysis of Gas Emissions and Power Generation for Co-firing Ratios of NG, NH3, and H2 Based on NGCC (NGCC 기반 천연가스, 암모니아, 수소 혼소 발전 비율에 따른 CO2와 NOx 배출량 및 전력 생산량 분석)

  • Inhye Kim;Jeongjae Oh;Taesung Kim;Minsuk Im;Sunghyun Cho
    • Korean Chemical Engineering Research
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    • v.62 no.3
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    • pp.225-232
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    • 2024
  • The reduction of CO2 emissions in the energy production sector, which accounts for 86.8% of total greenhouse gas emissions, is important to achieve carbon-neutrality. At present, 60% of total power generation in South Korea is coal and natural gas. Replacing fossil fuel with renewable energy such as wind and solar has disadvantages of unstable energy supply and high costs. Therefore, this study was conducted through the co-firing of natural gas, ammonia and hydrogen utilizing the natural gas combined cycle process. The results demonstrated reduction in CO2 emissions and 34%~238% of the power production compared to using only natural gas. Case studies on mass fractions of natural gas, ammonia and hydrogen indicated that power production and NOx emissions were inversely proportional to the ammonia ratio and directly proportional to the hydrogen ratio. This study provides guidelines for the use of various fuel mixtures and economic analysis in co-firing power generation.

Hydrocarbon generation and indicator in the western Ulleung Basin (울릉분지 서부에서의 탄화수소 생성 및 지표)

  • Ryu, Byong-Jae;Kim, Ji-Hoon;Lee, Young-Joo;Riedel, M.;Hyndman, R.D.;Kim, Il-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.507-510
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    • 2007
  • Piston cores retrieved from the western Ulleung Basin, East Sea were analyzed to examine the potential for hydrocarbon generation and to determine the hydrocarbon indicators. 2D multi-channel reflection seismic and Chirp data were also investigated for mapping and characterizing the geophysical hydrocarbon indicators such as BSR (bottom simulating reflector), blank zone, pock-mark etc. High organic carbon contents and sedimentation rates that suggest good condition for hydrocarbon generation. High pressure and low temperature condition, and high residual hydrocarbon concentrations are favor the formation of natural gas hydrate. In the piston cores, cracks generally oriented to bedding may indicate the gas expansion. The seismic data show several BSRs that are associated with natural gas hydrates and underlying free gas. A number of vertical to sub-vertical blank zones were well identified in the seismic sections. They often show the seismic pull-up structures, probably indicating the presence of high velocity hydrates. Numerous pockmarks were also observed in the Chirp profiles. They may indicate the presence of free gas below the hydrate stability zone as well.

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A Study on Ammonia Formation with Nitrogen Impurity at a Natural Gas Steam Reforming Catalytic Process (소량의 질소를 포함한 천연가스 수증기 개질 반응에서 GHSV 변화에 따른 암모니아 생성 반응에 관한 연구)

  • KIM, CHUL-MIN;PARK, SANG-HYOUN;LEE, JUHAN;LEE, SANGYONG
    • Journal of Hydrogen and New Energy
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    • v.30 no.6
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    • pp.601-607
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    • 2019
  • Ammonia would be formed in natural gas containing small amount of nitrogen reforming process in the process natural gas, which might damage the Pt catalyst and Prox catalyst. In the article, the effect of nitrogen contents on the formation of ammonia in the reforming process has been studied. In the experiments, Ru based and Ni based catalysts were used and the concentration of ammonia in the reformate gas at various gas hourly space velocity was measured. Experimental result shows that relatively higher ammonia concentration was measured with Ru based catalyst than with Ni based catalyst. It also shows that the concentration of ammonia increased rapidly after most of the methane converted into hydrogen. Based on the experimental results to reduce ammonia concentration it might be better to finish methane conversion at the exit position of the reforming reactor to minimize the contact time of catalyst and nitrogen with high concentration of hydrogen.

A Study on the Estimation of Carbon Dioxide Generation During High Purity Hydrogen Production According to Natural Gas Composition (천연가스 조성에 따른 수소 생산 시에 발생하는 이산화탄소 배출량 산출에 대한 연구)

  • CHO, JUNGHO;NOH, JAEHYUN;KIM, DONG SUN
    • Journal of Hydrogen and New Energy
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    • v.30 no.6
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    • pp.485-489
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    • 2019
  • Hydrogen is known to be a clean fuel which does not generate a green house gas during the combustion. However, about 8 kg of carbon dioxide is generated during the course of producing 1 kg of hydrogen through reforming, water gas shift reaction and pressure swing adsorption in order to obtain a high purity hydrogen over 99.999% by volume. In this work, carbon dioxide generation is estimated according to four kinds of natural gas compositions supplied by Korea Gas Corporation and regarding natural gas as pure methane. For the simulation of the modeling, PRO/II with PROVISION V10.2 at AVEVA was utilized and Peng-Robinson equation of state with Twu's alpha function was selected.

Development of Gasoline Engine Renewal CNG Generator and a Study on Exhaust Gas Characteristics of Equivalent Diesel Engine (가솔린 엔진개조 CNG 발전기 개발과 동급 디젤엔진의 배출가스 특성 연구)

  • Lee, Jung-Cheon;Kim, Ki-Ho;Lee, Jung-Min;Park, An-Young
    • Journal of Power System Engineering
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    • v.22 no.6
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    • pp.74-79
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    • 2018
  • Compressed natural gas has a high octane number and low particulate emission characteristics as compared with petroleum-based fuels, so it can respond to exhaust gas regulations positively. A natural gas engine has been introduced to improve the quality of the atmosphere, a diversity of fuel, a stable supply, and it has widely been used in city buses and garbage trucks. Recently, the natural gas engine has received attention by overcoming the disadvantage of the theoretical air-fuel ratio method through the development of EGR cooler and engine parts with the development of LP-EGR technology. In this study, we try to develop the cogeneration system that can simultaneously generate electric power and heat by remodeling the gasoline engine to the mixer type CNG engine. As a result, it was able to reduce the NOx (approximately 77%) compared to the diesel engines with same displacement.

Application of Target Reliability Levels for Maintenance of Domestic Natural Gas Pipelines (국내 천연가스배관 유지관리를 위한 목표신뢰도 적용사례)

  • Lee, Jin-Han;Kim, Jeong-Hwan;Jo, Young-Do;Kim, Lae Hyun
    • Journal of the Korean Institute of Gas
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    • v.22 no.3
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    • pp.1-6
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    • 2018
  • Reliability based design and assessment (RBDA) methodology is one of the newest directions of natural gas pipeline design method. Reliability targets are used to ensure that safety levels are met relevant limit states in the stage of design and maintenance. The target reliability for ultimate limit states such as large leak and rupture were developed using tolerable risk criteria for individual and societal risk. This paper shows the reliability target can be met through the implementation of periodic maintenance measures during the life cycle of the pipelines. The case study involves the calculation of the failure probability due to equipment impact, the calculation of the failure probability due to corrosion, and the estimation the re-inspection interval for domestic natural gas transmission pipelines.

Determination of Fucosterol in the Marine Algae Pelvetia siliquosa by Gas Chromatography

  • Lee, Sang-Hyun;Lee, Yeon-Sil;Jung, Sang-Hoon;Lee, Hye-Seung;Kang, Sam-Sik;Shin, Kuk-Hyun
    • Natural Product Sciences
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    • v.10 no.1
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    • pp.29-31
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    • 2004
  • A new method for the quantitative determination of fucosterol in the marine algae Pelvetia siliquosa by gas chromatography was established. A HP-1 column programmed as $200^{\circ}C\;(5\;min)\;{\rightarrow}\;5/min\;{\rightarrow}\;280^{\circ}C\;(10\;min)$ was developed. The analysis of fucosterol in P. siliquosa was successfully carried out within 30 min.