• Title/Summary/Keyword: Natural free energy

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Estimation of Uncertainty in Critical Flow Function for Natural Gas (천연가스의 임계유동함수 불확도 평가)

  • Ha, Young-Cheol
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.7
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    • pp.625-638
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    • 2014
  • In this study, the uncertainties in the critical flow functions (CFFs) calculated by the AGA8-dc equation of state were estimated. To this end, the formulas for enthalpy, entropy, and speed of sound, which are used in calculating the CFF, were expressed in the form of dimensionless Helmholtz free energy and its derivatives, and the uncertainty in Helmholtz free energy was inferred. To consider the variations in the compressibility-dependent variables induced by the variation (i.e., uncertainty) in compressibility, the form of the AGA8-dc equation was modified to have a deviation equal to the uncertainty under each flow condition. For each independent uncertainty component of the CFF, a model for uncertainty contribution was developed. All these changes were applied to GASSOLVER, which is KOGAS's thermodynamic database. As a result, the uncertainties in the CFF were estimated to be 0.025, 0.055, and 0.112 % at 10, 50, and 100 bar, respectively, and are seen to increase with the increase in pressure. Furthermore, these results could explain the deviations in the CFFs across the different labs in which the CFF international comparison test was conducted under the ISO management in 1999.

Modelling Data Flow in Smart Claim Processing Using Time Invariant Petri Net with Fixed Input Data

  • Amponsah, Anokye Acheampong;Adekoya, Adebayo Felix;Weyori, Benjamin Asubam
    • International Journal of Computer Science & Network Security
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    • v.22 no.2
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    • pp.413-423
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    • 2022
  • The NHIS provides free or highly subsidized healthcare to all people by providing financial fortification. However, the financial sustainability of the scheme is threatened by numerous factors. Therefore, this work sought to provide a solution to process claims intelligently. The provided Petri net model demonstrated successful data flow among the various participant. For efficiency, scalability, and performance two main subsystems were modelled and integrated - data input and claims processing subsystems. We provided smart claims processing algorithm that has a simple and efficient error detection method. The complexity of the main algorithm is good but that of the error detection is excellent when compared to literature. Performance indicates that the model output is reachable from input and the token delivery rate is promising.

A Study on the Mechanical Properties of Organo-clay Filled NR/MMT Nanocomposites (Organo-Clay를 이용한 NR/MMT 나노복합체의 기계적 물성에 관한 연구)

  • Oh, Woo-Taek;Lee, Eun-Kyoung;Choi, Sei-Young
    • Elastomers and Composites
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    • v.44 no.4
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    • pp.455-465
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    • 2009
  • In this study, Organo-montmorillonite(MMT) was synthesized by intercalation of various amine(Octylamine, Dodecylamine, Dimethyldodecylamine, Octadecylamine) compounds into layered silicate. Natural Rubber(NR)/MMT nanocomposites were prepared by reinforcement of Organo-MMT. X-ray diffraction(XRD) and Scanning electron microscope(SEM) were employed to characterize the layer distance of Organo-MMT and the morphology of the NR/MMT nanocomposites. The structures of the synthesized Organo-MMTs were analyzed by the measurement of FT-IR. Cure characteristics, surface free energy and mechanical properties such as tensile strength, modulus and hardness of NR/MMT nanocomposites were carefully studied by contact angle meter, ODR, UTM, and hardness tester. FT-IR analysis showed a insertion of the alkyl and amine chains into the interlayers of the MMT. It was shown that the cure time of the organo-MMT was more decreased than that of $Na^+$-MMT. Surface free energy and tensile strength of the NR/DDA-MMT nanocomposite were the highest. NR/ODA-MMT nanocomposite was the highest in hardness.

HYDROELASTIC VIBRATION ANALYSIS OF TWO FLEXIBLE RECTANGULAR PLATES PARTIALLY COUPLED WITH A LIQUID

  • Jeong, Kyeong-Hoon;Kim, Jong-Wook
    • Nuclear Engineering and Technology
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    • v.41 no.3
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    • pp.335-346
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    • 2009
  • This paper deals with a hydroelastic vibration analysis of two rectangular plates partially coupled with a liquid, which is bounded by two plates and two rigid side walls. The wet displacement of each plate is assumed to be a combination of the modal functions of a dry uniform beam with a clamped boundary condition. As the liquid is assumed to be an ideal liquid, the displacement potential satisfying the Laplace equation is determined so that the liquid boundary conditions can meet the requirements at the rigid surfaces and the free liquid surface. The wet dynamic modal functions of each plate are expanded by using the finite Fourier transform to obtain an appropriate form of the compatibility requirement along the contacting surfaces between the plates and the liquid. The liquid-coupled natural frequencies of the plates are derived by using the Rayleigh-Ritz method. Finite element analyses using commercial software are carried out to verify the proposed theory. It is observed that the theoretical method agrees excellently with the three-dimensional finite element analyses results. The effects of the liquid depth and the liquid thickness on the normalized natural frequencies are investigated to identify the dynamic characteristics of the liquid coupled system.

Primary Current Generation for a Contactless Power Transfer System Using Free Oscillation and Energy Injection Control

  • Li, Hao Leo;Hu, Aiguo Patrick;Covic, Grant Anthony
    • Journal of Power Electronics
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    • v.11 no.3
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    • pp.256-263
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    • 2011
  • This paper utilizes free oscillation and energy injection principles to generate and control the high frequency current in the primary track of a contactless power transfer system. Here the primary power inverter maintains natural resonance while ensuring near constant current magnitude in the primary track as required for multiple independent loads. Such energy injection controllers exhibit low switching frequency and achieve ZCS (Zero Current Switching) by detecting the high frequency current, thus the switching stress, power losses and EMI of the inverter are low. An example full bridge topology is investigated for a contactless power transfer system with multiple pickups. Theoretical analysis, simulation and experimental results show that the proposed system has a fast and smooth start-up transient response. The output track current is fully controllable with a sufficiently good waveform for contactless power transfer applications.

Double Fourier Sine Series Method for The Free Vibration of a Rectangular Plate (이중 사인 시리즈법에 의한 직사각형 평판의 자유 진동해석)

  • 윤종욱;이장무
    • Journal of KSNVE
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    • v.6 no.6
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    • pp.771-779
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    • 1996
  • In this paper, double Fourier sine series is used as a modal displacement functions of a rectangular plate and applied to the free vibration analysis of a rectangular plate under various boundary conditions. The method of stationary potential energy is used to obtain the modal displacements of a plate. To enhance the flexibility of the double Fourier sine series, Lagrangian multipliers are utilized to match the geometric boundary conditions, and Stokes' transformation is used to handle the displacements that are not satisfied by the double Fourier sine series. The frequency parameters and mode shapes obtained by the present method are compared with those obtained by MSC/NASTRAN and other analysis.

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Free Vibration Analysis of a Simply-Supported Circular Plate with a Concentric Square Hole by the Independent Coordinate Coupling Method (독립좌표연성법을 이용한 정사각형 구멍을 갖는 단순지지 원판의 자유진동해석)

  • Heo, Seok;Kwak, Moon-Kyu
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.967-972
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    • 2008
  • This paper presents the free vibration analysis of a circular plate with a concentric square hole. The present problem deals with the numerical calculation of the natural frequencies and mode shapes of vibration of the structure by means of Independent Coordinate Coupling Method (ICCM). In this study, the boundary condition is the edge of the square hole is free and the outer circular plate is simply supported. Due to the geometric abnormality, this analysis does not permit an exact solution. Since the ICCM employs coordinate systems corresponding to each domain independently, the kinetic and potential energy expressions necessary for the Rayleigh-Ritz method can be easily obtained. Lastly, the kinematic relation is imposed. In this way, the eigenvalue problem can be easily set up. The numerical results show the efficacy of the ICCM and changes in natural frequencies and modes due to the square hole size.

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Dynamic behaviour of stiffened and damaged coupled shear walls

  • Meftah, S.A.;Tounsi, A.;Adda-Bedia, E.A.
    • Computers and Concrete
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    • v.3 no.5
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    • pp.285-299
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    • 2006
  • The free vibration of stiffened and damaged coupled shear walls is investigated using the mixed finite element method. The anisotropic damage model is adopted to describe the damage extent of the reinforced concrete shear wall element. The internal energy of a locally damaged shear wall element is derived. Polynomial shape functions established by Kwan are used to present the component of displacements vector on each point within the wall element. The principle of virtual work is employed to deduce the stiffness matrix of a damaged shear wall element. The stiffened system is reinforced by an additional stiffening beam at some level of the structure. This induces additional axial forces, and thus reduces the bending moments in the walls and the lateral deflection, and increases the natural frequencies. The effects of the damage extent and the stiffening beam on the free vibration characteristics of the structure are studied. The optimal location of the stiffening beam for increasing as far as possible the first natural frequency of vibration is presented.

Standard Transfer Free Energy of Sodium and Cupric Ions in Water-Acetylacetone Solvent System (물-아세틸아세톤 용매계에서 나트륨이온과 구리이온의 표준이동 자유에너지)

  • Lee Heung Lark;Park Jong-Taek
    • Journal of the Korean Chemical Society
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    • v.36 no.5
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    • pp.632-637
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    • 1992
  • Standard transfer free energies of sodium and cupric perchlorates in water-acetylacetone solvent system have been determined by electromotive force measurements of galvanic cell and these energies of sodium and cupric ions in this solvent system have been evaluated by the tetrabutylammonium tetraphenylborate assumption as the extrathermodynamic procedure. Standard transfer free energy values of sodium and cupric ions from water to acetylacetone solvent were 5.09 and 4.16 kcal/mol at 25${\circ}C$, respectively. These values mean that acetylacetone is much weaker donor solvent to sodium and cupric ions than water. The standard transfer free energy value of cupric ion from water to mixture solvents which contain small amount of acetylacetone is changed by an unusual form. This is because of the chelate formation effect of acetylacetone to cupric ion.

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Template-free Hydrothermal Synthesis of High Phase Purity Mordenite Zeolite Particles Using Natural Zeolite Seed for Zeolite Membrane Preparation (제올라이트 분리막 제조를 위한 유기주형 없는 고순도 모데나이트 제올라이트 입자 수열합성에 관한 연구)

  • Lee, Du-Hyoung;Alam, Syed Fakhar;Lee, Hye-Rheon;Sharma, Pankaj;Cho, Churl-Hee;Han, Moon-Hee
    • Membrane Journal
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    • v.26 no.5
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    • pp.381-390
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    • 2016
  • In this study, the natural mordenite (MOR) zeolite seeds were used for the synthesis of high purity mordenite crystals. The effect of seed concentration and crystallization time on the phase purity and surface morphology of MOR crystals has also been reported. The diffraction, elemental and scanning analysis of MOR zeolite particles obtained from 100 g hydrothermal solution batch containing 3 g natural seed, hydrothermally treated at $140^{\circ}C$ for 72 h reveal the high phase-purity of as-synthesized sample having crystals of uniform size ($1-2{\mu}m$). Moreover, high seed concentration leads to the production of mesoporous MOR particles composed of needle shape primary nano crystallites. The gases adsorption performances of as-synthesized MOR particle were carried out at $25^{\circ}C$ and 0-1 bar. Surprisingly, MOR particles show good adsorption potential for $CO_2$ (97.19 mg/g) compared to other gases. Thus it confirms that high purity MOR particles can be synthesized without using any organic template which gives an advantage of separation performance at lower price.