• Elastomers and Composites
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• v.31 no.5
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• pp.347-352
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• 1996

A natural rubber was blended with a butadiene rubber with different ratios. A natural rubber, along with three different blends, its ratio varying from 10 to 15 to 20 weight %, were prepared and tested. It was found that inclusion of the butadiene rubber increased cure time, compared to the natural rubber. It is speculated that increased free volume due to the inclusion of butadiene rubber contributed to this effect. Furthermore, inclusion of butadiene rubber led to increase hardness of a sphere, and as a result, the extent of rebound increased sharply.

• Elastomers and Composites
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• v.46 no.3
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• pp.186-194
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• 2011

Natural fiber/natural rubber composites were fabricated by uniformly compounding natural rubber and cellulose- based natural fiber kenaf and then by compression molding. The effect of kenaf fiber content on their vulcanization behavior, hardness, tensile properties, tear strength and static and dynamic properties was investigated. The contents of kenaf fiber in the composites were 0, 5, 10, 15, and 20 phr, compared to natural rubber and additives. The result indicated that various properties of natural rubber depended on the kenaf fiber content. With increasing kenaf fiber content, the torque for vulcanization of natural rubber was increased whereas the vulcanization time was reduced as well. The hardness, tensile modulus and tear strength of kenaf/natural rubber composites were gradually decreased with the fiber content whereas the tensile strength and elongation at break were decreased. Also, with increasing the kenaf fiber content the dynamic property of natural rubber was changed more greatly than the static property. The loss factor, which is closely related with the damping or absorption of the energy given to natural rubber, was proportionally increased with the fiber content.

• The Journal of Asian Finance, Economics and Business
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• v.8 no.11
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• pp.145-155
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• 2021

This study examines the export competitiveness of four major natural rubber exporters in the Belt and Road Initiative (BRI) region and investigates the factors affecting bilateral natural rubber export. This study utilized the revealed symmetric comparative advantage (RSCA) to measure export competitiveness. Next, this study employed the gravity model using the Poisson Pseudo Maximum Likelihood (PPML) estimation to analyze the factors affecting bilateral export from the four major natural rubber exporters to 46 countries in the region. The analysis is conducted by using annual data from 2001 till 2018. The findings showed that all four major exporters maintained their export competitiveness. Indonesia and Vietnam notably exhibited increasing trends in the early 2000s. Besides, the market share for Malaysia and Vietnam have increased from 2013 to 2015 with the BRI implementation in 2013. In addition, this study discovered that non-tariff measures (NTM) have a positive and significant impact on the bilateral export of natural rubber. The overall findings strongly indicate that the natural rubber export has increased post BRI announcement. The outcome highlighted the benefits of BRI implementation on the natural rubber export. This study is the first attempt to apply the gravity model on the natural rubber exports within the BRI region.

• Elastomers and Composites
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• v.19 no.3
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• pp.163-177
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• 1984

The effect of curing temperature increase and sulfur amount added were studied with natural and synthetic rubbers. Also, the effects of TMTD, MBTS and mixture of zinc soaps of high molecular fatty acids added to natural rubber were investigated respectively. The experimental results showed that, in the case of the conventional curing ($145^{\circ}C$), natural rubber, compared with synthetic rubber, gave higher values in elongation, tensile strength, cure rate, and lower values in modulus change. But, at high temperature curing ($180^{\circ}C$), natural rubber showed faster reversion rate, and higher heat build-up compared to synthetic rubber, than in the conventional curing. Also, natural rubber produced at high temperature showed severe degradation in hardness and tensile strength before heat-aging as well as in hardness, modulus and tensile strength after heat-aging. Improved reversion effect was obtained with natural rubber either by blending mixture of zinc soaps of high molecular acids or by applying semi-efficient vulcanization system.

• Elastomers and Composites
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• v.51 no.2
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• pp.106-112
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• 2016

Maleimidopropyltriethoxysilane grafted natural rubber (MISNR) was prepared by reaction of maleic anhydride grafted natural rubber and 3-aminopropyl triethoxysilane. MISNR was used as the compatibilizer of natural rubber/silica composites. The composites were prepared by two-step mixing procedures. The final mixtures were cured with optimum cure condition, which was established by a rheometer. Effects of the amounts of compatibilizer in the composites on the cure characteristics, morphology, thermal stability, and physical and mechanical behaviors were investigated. The composites having MISNR had shown cure characteristics and physical and mechanical properties superior to those without MISNR. Silica particles in the former appeared to be more uniform and reduced in size compared with the latter. The effects of the types of silica were also evaluated.

• Elastomers and Composites
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• v.21 no.3
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• pp.205-212
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• 1986

The dielectric properties of natural rubber are very important to investigate the molecular structure. The charcteristics of the dielectric absorption in aging natural rubber were studied in the range of frequency from $1{\times}10^3Hz\;to\;3.2{\times}10^7Hz$ at the temperature of $23^{\circ}C$. As the results, it has been confirmed that in the case of aged NR vulcanized specimen with contained sulfur 2 phr above the specimens exhibit two kind of dielectic losses due to the the dipole polarization by impurities and sulfurs, and of raw rubber exhibit the kind of losses due the to dipole polarization. Particularly, it has been affirmed that the dielectric loss spectrum of the aging natural rubber is larger than that the natural rubber, and the dielectric strength of the aging natural rubber drop depreciate respctively.

• Macromolecular Research
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• v.13 no.1
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• pp.30-38
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• 2005

Sulfur-cured gum natural rubber vulcanizates were devulcanized using two different concentrations of diallyl disulfide. The devulcanization process was performed at $110^{\circ}C$ min in an open two-roll cracker-cum-mixing mill. Natural rubber vulcanizates having various sulfur/accelerator ratios were used to study the cleavage of monosulfide, disulfide, and polysulfide bonds. The properties of devulcanized natural rubber increased upon increasing the disulfide concentration and the mechanical properties of the revulcanized natural rubber increased upon decreasing the sulfur content in the original rubber vulcanizates. The scorch time and the maximum state of cure both increased when the ground vulcanizates were treated with higher amounts of disulfide. TGA and DMA were conducted to study the effects of the devulcanization on the thermal stability and the $T_g$ behavior of the vulcanizates. SEM analysis was conducted to study how the failure mechanism was affected by the devulcanization process. It was possible to recover $70-80\%$ of the original gum rubber properties by using this process. From IR spectroscopic analysis, we observed that the oxidation of the main chains did not occur during high-temperature milling.

• Elastomers and Composites
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• v.58 no.4
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• pp.173-178
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• 2023

Recently, there has been a significant focus on the development of flexible and stretchable sensors, driven by advancements in electronic devices and the robotics industry. Among these sensors, tactile sensors stand out as the most actively researched, playing a crucial role in facilitating interaction between humans and electronic devices, particularly in robotics and medical applications. This study specifically involves the manufacturing of a capacitive tactile sensor using a relatively straightforward process and sensor structure. Natural rubber and Nitrile butadiene rubber, commonly employed in the rubber industry, were utilized. The dielectric material in the manufactured tactile sensor possesses a porous structure. Notably, the resulting tactile sensor demonstrated excellent sensitivity, approximately 1%/kPa, and exhibited the capability to detect pressures up to 212 kPa.

• Journal of the Korean Society of Industry Convergence
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• v.2 no.1
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• pp.97-103
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• 1999

The power curve during rubber mixing presents useful information for the understanding of rubber mixing process, because the power curve is determined the mixing state of rubber at the point. The time to the second peak on the power curve is known as carbon black incorporation time, BIT. This study gets the quantity relationship of BIT and viscosity of natural rubber, so by determining the mixing time of the compound on the ground of viscosity of the raw rubber. The mixing with natural rubber and carbon black is examined for various grade natural rubbers, encompassing a wide range of Mooney viscosity. Alter smoothing the mixing power curve using a polynomial, the carbon black incorporation time, BIT, was determined time to second power peak on the curve, The BIT's versus specific values on Mooney viscometer test curve show a linear relation, Especially, the peak of initial maximum torque on Mooney viscometer curve, PMT, is most relevant property relating to the BIT. PMT is useful index for determined optimum mixing time, To apply this results at the mixing, we effectively control the natural rubber mixing but can also know the grading of natural rubber upon processability.

• Advances in materials Research
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• v.12 no.1
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• pp.1-13
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• 2023

The combination of cobalt ferrite and natural rubber has a potential to enhance the functional properties of rubber ferrite composites available on the market. In this study, cobalt ferrite was synthesized by the sol-gel method with tapioca starch as a cheating agent and then incorporated into natural rubber using an internal mixer. The curing characteristics, magnetic hysteresis, complex permeability, and permittivity of the rubber ferrite composites were studied as a function of the loading from 0 to 25 phr. The cure time and scorch time tended to reduce with the addition of non-reinforced cobalt ferrite fillers. The remanent and saturation magnetizations were linearly proportional to the cobalt ferrite loading, consistent with the rule of mixture. On the other hand, the increase in cobalt ferrite loading from 5 to 25 phr slightly affected the coercive field and the complex permeability. Using the maximum loading of 25 phr, both real and imaginary parts of the permittivity were significantly raised and reduced with the frequency in the 10-300 MHz range.