• Title/Summary/Keyword: Natural Degradation

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Estimation of Welfare Change from Water Quality Degradation (수질 악화로 인한 후생변화의 추정)

  • Jeon, Chul-Hyun;Lee, Chung-Sun;Shin, Hio-Jung
    • Journal of Environmental Policy
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    • v.9 no.2
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    • pp.135-155
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    • 2010
  • The purposes of the paper are to estimate welfare change from water quality degradation by using contingent valuation method in Namdae stream of Gangrung and identify what factors of Namdae stream are important to Gangrun citizens. The study results show their total WTP per year and per household, \117,040 to improve Namdae stream quality from grade 3 to grade 1, including monetary WTP \87,502 plus opportunity cost of volunteering time for protection campaign, \29,538. The amount of total welfare change from water quality degradation based on the total WTP estimated above is calculated to be \27 billion of which the amount, as a sort of damage cost from water quality degraded, is so huge. All projects and policies related to natural environments, therefore, should consider both indirect and direct effects from them because natural environments have the irreversibility once degraded or deteriorated and would ultimately be influential on humans, both current and future generations, with tremendous amounts of time and costs beyond our imagination.

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Mild Isomerative Opening of Tetrahydrofuranyl Subunits in Steroids Using TFAT (trifluoroacetyl trifluoromethanesulfonate): Application to Synthesis of C17-OH Rockogenin Acetate

  • Lee, Jong-Seok;Kim, Byung-Sook;Shin, Jun-Ho;Lee, Yeon-Ju;Shin, Hee-Jae;Lee, Hyi-Seung
    • Bulletin of the Korean Chemical Society
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    • v.33 no.1
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    • pp.76-82
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    • 2012
  • A novel and efficient tetrahydrofuranyl ring opening method was developed using the highly reactive TFAT reagent in the presence of an acid scavenger, 2,6-di-tert-butyl-4-methylpyridine. Various acid sensitive groups are compatible with the reaction condition, making it generally applicable to many tetrahydrofuranyl steroids. Moreover, it is a synthetic equivalent of 'Marker degradation' affording an efficient synthesis of C17-OH rockogenin acetate.

A study on the change of physical properties of elastomer in high temperature curing (고온가황에 의한 탄성체의 물성변화에 관한 연구)

  • Lee, Jeung-Ho
    • Elastomers and Composites
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    • v.19 no.3
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    • pp.163-177
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    • 1984
  • The effect of curing temperature increase and sulfur amount added were studied with natural and synthetic rubbers. Also, the effects of TMTD, MBTS and mixture of zinc soaps of high molecular fatty acids added to natural rubber were investigated respectively. The experimental results showed that, in the case of the conventional curing ($145^{\circ}C$), natural rubber, compared with synthetic rubber, gave higher values in elongation, tensile strength, cure rate, and lower values in modulus change. But, at high temperature curing ($180^{\circ}C$), natural rubber showed faster reversion rate, and higher heat build-up compared to synthetic rubber, than in the conventional curing. Also, natural rubber produced at high temperature showed severe degradation in hardness and tensile strength before heat-aging as well as in hardness, modulus and tensile strength after heat-aging. Improved reversion effect was obtained with natural rubber either by blending mixture of zinc soaps of high molecular acids or by applying semi-efficient vulcanization system.

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Degradation of cis-Polyisoprene in Supercritical Tetrahydrofuran (Tetrahydrofuran의 초임계 상에서 cis-Polyisoprene의 분해)

  • Kim, H.J.;Hong, I.K.
    • Elastomers and Composites
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    • v.32 no.5
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    • pp.302-308
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    • 1997
  • Over 1953/54 Karl Ziegler and Giulio Natta independently discovered new types of catalyst. Thus it was able to produce synthetic cis-polyisoprene rubber which has same properties like natural rubber, since then the amount of consumption was increased rapidly. The problem of disposing of used rubbers has become acute in recent years. cis-Polyisoprene was degraded in supercritical tetrahydrofuran and degree of degradation and product were observed by GPC, FT-IR, GC-MS analyses. As a result, degradation of cis-polyisoprene had small dependency upon the operating pressure, and was inhibited in concentration increase. And cis-polyisoprene was degraded into narrow molecular weight distribution oligomer in 3 hours, and more than 10 organic compounds were produced.

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Effect of Degradation Processes on Optimal Remediation Design Sorption and First-Order Decay Rate

  • Park, Dong-Kyu;Ko, Nak-Youl;Lee, Kang-Kun
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.503-508
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    • 2004
  • Optimal remediation design using the pump and treat(P&T) method and natural attenuation was accomplished in consideration for degradation processes, such as sorption and first-order decay rate. Variation of both sorption and first-order decay rate has influence on design of optimal remediation application. When sorption effect increases, the more pumping rate and pumping wells are required. The location of operated wells is on the centerline of contaminant plume and wells near hot spot are mainly operated when sorption effect increases. The higher of first-order decay rate, the less pumping rate is required. These results show that the degradation processes have to be considered as one of the essential factors for optimal remediation design.

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Analysis of the Extracted Non-fibrous Matters from the Exhumed Textiles of Milchang-gun Burial of Mapo (마포 밀창군 묘 출토 복식유물의 섬유외 물질의 추출분석)

  • 안춘순
    • The Research Journal of the Costume Culture
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    • v.11 no.6
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    • pp.902-912
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    • 2003
  • The purpose of this research was two-folds; first, to investigate the type of soil contaminated in the Hunsang excavated from the Milchang-gun burial of Mapo for the purpose of proposing the adequate washing method, second, to utilize the chemical degradation result obtained from the previous research to identify the natural dye source used in the Hunsang textile. The application of KS K0251 test showed that the soil was more oleophilic than hydrophilic thus indicating that wet cleaning was more adequate that dry cleaning for the removal of Hunsang soil. The GC-MS result of the Hunsang extraction showed dimethyl phthalate and 2,4-di-tert-butylphenol as its degradation product and these coincided with the degradation products from the alizarin standard data of previous research. The comparison of the two suggested that it is likely that Hunsang was dyed with madder which has alizarin as its major chromophore.

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BMP-2-Enhanced Chondrogenesis Involves p38 MAPK-mediated Down-Regulation of Wnt-7a Pathway

  • Jin, Eun-Jung;Lee, Sun-Young;Choi, Young-Ae;Jung, Jae-Chang;Bang, Ok-Sun;Kang, Shin-Sung
    • Molecules and Cells
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    • v.22 no.3
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    • pp.353-359
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    • 2006
  • The bone morphogenetic protein (BMP) family has been implicated in control of cartilage development. Here, we demonstrate that BMP-2 promotes chondrogenesis by activating p38 mitogen-activated protein kinase (MAPK), which in turn downregulates $Wnt-7a/{\beta}$-catenin signaling responsible for proteasomal degradation of Sox9. Exposure of mesenchymal cells to BMP-2 resulted in upregulation of Sox9 protein and a concomitant decrease in the level of ${\beta}$-catenin protein and Wnt-7a signaling. In agreement with this, the interaction of Sox9 with ${\beta}$-catenin was inhibited in the presence of BMP-2. Inhibition of the p38 MAPK pathway using a dominant negative mutant led to sustained Wnt-7a signaling and decreased Sox9 expression, with consequent inhibition of precartilage condensation and chondrogenic differentiation. Moreover, overexpression of ${\beta}$-catenin caused degradation of Sox9 via the ubiquitin/26S proteasome pathway. Our results collectively indicate that the increase in Sox9 protein resulting from downregulation of ${\beta}$-catenin/Wnt-7a signaling is mediated by p38 MAPK during BMP-2 induced chondrogenesis in chick wing bud mesenchymal cells.

A Study on the Laboratory Scale Ultrasound Treatment System for Methyl tert-Butyl Ether Polluted Groundwater (Methyl tert-Butyl Ether 오염 지하수 처리를 위한 실험실 규모 초음파 분해 시스템 연구)

  • Kim, Heeseok;Yang, Inho;Cho, Hyeonjo;Her, Nam Guk;Jeong, Sangjo
    • Journal of Korean Society on Water Environment
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    • v.26 no.5
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    • pp.747-753
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    • 2010
  • A series of experiments with a laboratory scale ultrasound treatment system for MTBE polluted groundwater was performed to increase the efficiency of MTBE degradation in groundwater. This study evaluated several factors to increase the efficiency of MTBE treatment for artificial and natural groundwater. The treated volume of groundwater, ultrasound frequency and power, and pollutant concentrations have been changed to evaluate its effects on the degradation efficiency of MTBE in batch and continuous flow reactor. For the specific experimental conditions on this paper, MTBE degradations are more efficient at 580 kHz than those at 1 MHz. The efficiency of MTBE degradation is proportional to the intensity of ultrasound power per unit volume of MTBE polluted groundwater. The concentration of ions in groundwater does not much affect the efficiency of MTBE degradation. The $1^{st}$ order degradation constant of MTBE for different power per unit volume at 580 kHz shows linear relationship at same concentration. The $1^{st}$ order degradation constant for 0.1 mM MTBE solution is higher than that for 1 mM MTBE solution. These experimental results could be helpful to seek optimal conditions for relatively large volume of polluted groundwater treatment.

Isolation and Quantitative Determination of Costunolide from Saussurea Root (목향(Saussureae Radix)으로부터 Costunolide의 분리 및 함량분석)

  • Kim, Ju-Sun;Chi, Hyung-Joon;Chang, Seung-Yeup;Ha, Kwang-Won;Kang, Sam-Sik
    • Korean Journal of Pharmacognosy
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    • v.30 no.1
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    • pp.48-53
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    • 1999
  • Isolation and quantitative determination of costunolide from Saussurea lappa Clarke (Compositae) has been conducted by using HPLC method. Costunolide in an acetone extract from the crude drug was separated on a RP-18 column using a $MeOH-H_20$ mixture (65:35) as an eluent and the average content is about $1.32{\sim1.42%.$ The content of costunolide in dried extract was decreased by about 24% in seven days. However it showed a slight decrease in solution. It is highly recommended that quantitative determination of costunolide from Saussureae Radix should be conducted as early as possible after solvent extraction.

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