• 제목/요약/키워드: Nanostructured

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적층구조 촉매층(Al/Fe/Al)을 이용한 탄소나노튜브의 합성에서 최상층 알루미늄 층의 역할 (Role of Aluminum Top-layer on Synthesis of Carbon Nanotubes using Laminated Catalyst(Al/Fe/Al) layer)

  • 송우석;최원철;전철호;류동헌;이승엽;신용숙;박종윤
    • 한국진공학회지
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    • 제16권5호
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    • pp.377-382
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    • 2007
  • 적층구조 촉매층(Al/Fe/Al)을 이용하여 열 화학기상증착(thermal chemical vapor deposition ; TCVD)법을 통해 탄소 나노튜브를(carbon nanotubes ; CNTs)를 합성하였다. Raman spectroscopy, SEM 및 HR-TEM 분석결과, G/D는 22.7이며, 직경이 $1.14\;{\sim}\;1.32\;nm$인 금속성의 단일벽 탄소 나노튜브(single-walled CNTs ; SWCNTs)의 다발(bundle)들이 기판 전체에 network 구조로 형성되어 있는 것을 확인할 수 있었다. 이는 최상층의 Al이 촉매인 Fe의 응집현상(agglomeration)을 막아주는 역할을 하여 작고 균일한 핵 생성 사이트(nucleation site)를 통해 좁은 직경분포를 가진 단일벽 탄소 나노튜브가 합성되었음을 알 수 있다.

Development of Nanostructured Light-Absorbers for Ultrasound Generation by Using a Solution-Based Process

  • Sang, Pil Gyu;Heo, Jeongmin;Song, Ju Ho;Thakur, Ujwal;Park, Hui Joon;Baac, Hyoung Won
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.377-377
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    • 2016
  • Under nanosecond-pulsed laser irradiation, light-absorbing thin films have been used for photoacoustic transmitters for ultrasound generation. Especially, nanostructured absorbers are attractive due to high optical absorption and efficient thermoacoustic energy conversion: for example, 2-dimensional (2-D) gold nanostructure array, synthetic gold nanoparticles, carbon nanotubes (CNTs), and reduced graphene oxides. Among them, CNT has been used to fabricate a composite film with polydimethylsiloxane (PDMS) that exhibits excellent photoacoustic conversion performance for high-frequency, high-amplitude ultrasound generation. Previously, CNT-PDMS nanocomposite films were made by using a high-temperature chemical vapor deposition (HTCVD) process for CNT growth. However, this approach is not suitable to fabricate large-area CNT films (>several cm2). This is because a chamber dimension of HTCVD is limited and also the process often causes nonuniform CNT growth when the film area increases. As an alternative approach, a solution-based process can be used to overcome these issues. We develop PDMS composite transmitters, based on the solution process, using several nanostructured light-absorbers such as CNTs, nanoink powders, and imprinted regular arrays of gold nanostructure. We compare fabrication processes of each composite transmitters and photoacoustic output performance.

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다공성 알루미나 필터 표면에 형성된 나노구조물의 형상에 따른 찢어짐에 의한 세포파쇄 특성 평가 (Evaluation of Mechanical Tearing based Cell Disruption Capability to Shape Nanostructures formed on Nanoporous Alumina Filter)

  • 이용훈;한의돈;김병희;서영호
    • 한국생산제조학회지
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    • 제26권1호
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    • pp.1-5
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    • 2017
  • This study investigated the mechanical tearing of a cell membrane using a nanostructured alumina filter for easy and quick mechanical cell disruption. Nanostructured alumina filters were prepared by a multi-step aluminum anodizing process and nanopore etching process. Six different types of nanostructures were formed on the surface of the nanoporous alumina filters to compare the mechanical cell disruption characteristics according to the shape of the nanostructure. The prepared alumina filter was assembled in a commercial filter holder, and then, NIH3T3 fibroblast cells in a buffer solution were passed through the nanostructured alumina filter at a constant pressure. By measuring the concentration of proteins and DNA, the characteristics of mechanical cell disruption of the nanostructured alumina filter were investigated.

수소환원법으로 제조된 나노구조 Fe-Co 합금분말의 미세구조 및 자성특성 (Micro Structures and Magnetic Properties of Nanostructured Fe-Co Alloy Powders Produced by Hydrogen Reduction Process)

  • 안봉수;이백희;이규환;김영도
    • 한국재료학회지
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    • 제12권6호
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    • pp.488-492
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    • 2002
  • Magnetic properties of nanostructured materials are affected in complicated manner by their microstructure such as grain size, internal strain and crystal structure. Thus, studies on the synthesis of nanostructured materials with controlled microstructure are necessary for a significant improvement in magnetic properties. It is well known that when Fe-Co alloy undergoes ordering transformation, soft magnetic properties could be obtained. There are many reports that the magnetic properties of the materials can be changed with variation of grain size. In the present work, nanostructured Fe-50at.%Co alloy powder produced by hydrogen reduction process (HRP) starting with two oxide powder mixtures of $Fe_2O_3\;and\; Co_3O_4$. The mean grain size of the HRP powders was about 40 nm and coercivity of the: powders was about 43 Oe.

Thermal Stability of Nanostructured Synthetic Ferrimagnets under Applied Magnetic Fields in the 45˚ Direction

  • Han, C.W.;Han, J.K.;Lim, S.H.
    • Journal of Magnetics
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    • 제15권3호
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    • pp.116-122
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    • 2010
  • An accurate analytical equation for the total energy in the framework of the single domain model is used to study the thermal stability of nanostructured synthetic ferrimagnets. Elliptical cells are considered that have lateral dimensions of 160 nm (long axis)$\times$80 nm (short axis) and varying values of thickness asymmetry for the two magnetic layers. The direction of the applied magnetic field, which points to the $45^{\circ}$ direction, is in the opposite direction to the thicker layer magnetization. A significant difference is observed in the applied magnetic field dependencies of the equilibrium magnetic configuration and the magnetic energy barrier when using the simplifying assumption that the self-demagnetizing field is identical in magnitude to the dipole field. At a small thickness asymmetry of 0.2 nm, for example, the magnetic energy barrier is reduced from 68 kT (T=300 K) to 6 kT at the remanent state and a progressive switching behavior changes into a critical behavior, as the simplifying assumption is used. The present results clearly demonstrate the need for an accurate analytical equation for the total energy in predicting the thermal stability of nanostructured synthetic ferrimagnets.

Cyclosporin A가 봉입된 nanostructured lipid carriers의 물리적 특성연구 (Physical properties of cyclosporin A-loaded nanostructured lipid carriers)

  • 송충길;정석재;심창구;김대덕
    • Journal of Pharmaceutical Investigation
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    • 제38권1호
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    • pp.39-43
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    • 2008
  • Cyclosporin A (CyA), a potent immunosuppressive drug used in allogeneic transplants and autoimmune disease, is a typical water-insoluble drug. Recently, nanoparticle carriers were investigated to improve the intestinal absorption of drugs. In this study, CyA-loaded nanostructured lipid carriers (NLCs) were prepared from a hot o/w emulsion using the high pressure homogenization method. The NLCs were consisted of cationic lipids, solid lipids, liquid lipids (oils), surfactant and stabilizer. Encapsulation efficiency of CyA in NLCs was approximately 71%. The average particle size and zeta potential of NLCs were below 250 nm and above +40 mV, respectively. The morphology of NLCs was confirmed by transmission electron microscopy (TEM) analysis. Compared to the CyA powder, higher in vitro release of CyA from NLCs was observed after burst release within 30 min. Thus, CyA-loaded NLCs could be applied not only for parenteral route but also for gastrointestinal administration, which needs further investigation.

오스템퍼링 시간에 따른 초고강도 나노 베이나이트강의 미세조직과 기계적 특성 (Effect of Austempering Time on the Microstructure and Mechanical Properties of Ultra-High Strength Nanostructured Bainitic Steels)

  • 이지민;황병철
    • 한국재료학회지
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    • 제30권2호
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    • pp.87-92
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    • 2020
  • This study deals with the effects of austempering time on the microstructure and mechanical properties of ultra-high strength nanostructured bainitic steels with high carbon and silicon contents. The steels are composed of bainite, martensite and retained austenite by austempering and quenching. As the duration of austempering increases, the thickness of bainitic ferrite increases, but the thickness of retained austenite decreases. Some retained austenites with lower stability are more easily transformed to martensite during tensile testing, which has a detrimental effect on the elongation due to the brittleness of transformed martensite. With increasing austempering time, the hardness decreased and then remained stable because the transformation to nanostructured bainite compensates for the decrease in the volume fraction of martensite. Charpy impact test results indicated that increasing austempering time improved the impact toughness because the formation of brittle martensite was prevented by the decreased fraction and increased stability of retained austenite.

기계적 합금 및 펄스전류 활성 소결에 의한 나노구조 TiCo 합금의 제조 (Mechanical Synthesis and Fabrication of Nanostructured TiCo Alloy by Pulsed Current Activated Sintering)

  • 손인진;송하영;조성욱;김원백;서창열
    • 대한금속재료학회지
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    • 제50권1호
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    • pp.39-44
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    • 2012
  • Nanopowders of TiCo were synthesized from Ti and Co by high energy ball milling. Highly dense nanostructured TiCo compounds were consolidated at low temperature by pulsed current activated sintering within 3 minutes from the mechanical synthesis of the powders (TiCo) and horizontal milled Ti+Co powders under 100 Mpa pressure. This process allows very quick densification to near theoretical density and prohibits grain growth in nanostructured materials. The grain sizes of the TiCo compounds were calculated. Finally, the average hardness values of the nanostructured TiCo compounds were investigated.

산화갈륨 나노구조 광촉매 특성을 이용한 이산화탄소 저감 및 에틸렌 생성 작용 (CO2 Reduction and C2H4 Production Using Nanostructured Gallium Oxide Photocatalyst)

  • 서다희;류희중;서종현;황완식
    • 한국전기전자재료학회논문지
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    • 제35권3호
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    • pp.308-310
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    • 2022
  • Ultrawide bandgap gallium oxide (Ga2O3) semiconductors are known to have excellent photocatalytic properties due to their high redox potential. In this study, CO2 reduction is demonstrated using nanostructured Ga2O3 photocatalyst under ultraviolet (254 nm) light source conditions. After the CO2 reduction, C2H4 remained as a by-product in this work. Nanostructured Ga2O3 photocatalyst also showed an excellent endurance characteristic. Photogenerated electron-hole pairs boosted the CO2 reduction to C2H4 via nanostructured Ga2O3 photocatalyst, which is attributed to the ultrawide and almost direct bandgap characteristics of the gallium oxide semiconductor. The findings in this work could expedite the realization of CO2 reduction and a simultaneous C2H4 production using a low cost and high performance photocatalyst.