• 한국전기전자재료학회논문지
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• 제29권12호
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• pp.829-834
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• 2016

Coil specimens were prepared by continuous coating on a copper wire with flexible PAI (polyamideimide) and PAI/nanosilica (5 wt%) varnish and thermally aged at 150, 200 and $250^{\circ}C$ for 5, 10 and 15 days, respectively. AC insulation breakdown voltage was investigated under inverter surge condition at 60 Hz and 1,000 Hz and insulation breakdown voltage decreased with increasing aging temperature and aging time at each 60 and 1,000 Hz.

• 한국전기전자재료학회논문지
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• 제25권10호
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• pp.798-804
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• 2012

This paper focuses on thermal properties of a newly prepared composite material by nano-silica and micro-silica mixture. Nano-silica and micro-silica mixture composites were made by dispersing surface treated nano-silica(average radius: 10 nm) and micro-size silica in epoxy resin. To investigate the effects of nano-silica and micro-size silica mixture(ENMC), the glass transition temperature (Tg), coefficients of thermal expansion(CTE) and elastic modulus of DMA properties by DSC, TMA and DMA devices were measured for the ENMC according to increase nano-silica addition contents and EMC. All properties of the neat epoxy were improved by the addition of micro-silica, which was improved much further by the addition of surface treated nano-silica to the EMC system.

• Computers and Concrete
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• 제21권6호
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• pp.649-659
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• 2018

Adaptive neuro-fuzzy inference systems (ANFIS) can be efficient in modelling non-linear, complex and ambiguous behavior of cement-based materials undergoing combined damage factors of different forms (physical and chemical). The current work investigates the use of ANFIS to model the behavior (time of failure (TF)) of a wide range of concrete mixtures made with different types of cement (ordinary and portland limestone cement (PLC)) without or with supplementary cementitious materials (SCMs: fly ash and nanosilica) under various exposure regimes with the most widely used chloride-based de-icing salts (individual and combined). The results show that predictions of the ANFIS model were rational and accurate, with marginal errors not exceeding 3%. In addition, sensitivity analyses of physical penetrability (magnitude of intruding chloride) of concrete, amount of aluminate and interground limestone in cement and content of portlandite in the binder showed that the predictive trends of the model had good agreement with experimental results. Thus, this model may be reliably used to project the deterioration of customized concrete mixtures exposed to such aggressive conditions.

• Computers and Concrete
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• 제32권6호
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• pp.607-613
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• 2023

The objective of this work is to determine the compressive strength of geopolymer concrete utilizing four distinct machine learning approaches. These techniques are known as gradient boosting machine (GBM), generalized linear model (GLM), extremely randomized trees (XRT), and deep learning (DL). Experimentation is performed to collect the data that is then utilized for training the models. Compressive strength is the response variable, whereas curing days, curing temperature, silica fume, and nanosilica concentration are the different input parameters that are taken into consideration. Several kinds of errors, including root mean square error (RMSE), coefficient of correlation (CC), variance account for (VAF), RMSE to observation's standard deviation ratio (RSR), and Nash-Sutcliffe effectiveness (NSE), were computed to determine the effectiveness of each algorithm. It was observed that, among all the models that were investigated, the GBM is the surrogate model that can predict the compressive strength of the geopolymer concrete with the highest degree of precision.

• 한국건설순환자원학회논문집
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• 제11권4호
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• pp.332-340
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• 2023

이 연구는 나노 입자의 혼입이 시멘트 모르타르의 파괴인성치에 미치는 영향을 조사하였다. 탄소나노튜브 (carbon nanotube, CNT), 나노실리카 (nanosilica. NS), 그리고 나노 탄산칼슘 (nano calcium carbonate, NC)가 각각 혼입된 시멘트 모르타르의 3점 재하 휨강도, 압축강도, 슬럼프 실험을 수행하였다. 물시멘트비, 잔골재시멘트비가 각각 0.45, 1.5인 모르타르에 19.5 mm 강섬유가 0, 2 vol.% 혼입된 시멘트 모르타르를 사용하였다. 나노 입자 혼입은 시멘트 모르타르의 파괴인성치와 압축강도를 일부 향상시켰다. 그러나 강섬유가 보강된 시멘트 모르타르의 경우 나노 입자 혼입은 모르타르 유동성을 저하하여 강섬유의 분산도에 부정적 영향을 초래하여 오히려 파괴인성치를 감소시키는 결과를 확인할 수 있었다. 나노 입자의 혼입으로 인한 모르타르의 유동성 저하를 개선할 수 있는 추가적인 연구가 필요하다.

• Transactions on Electrical and Electronic Materials
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• 제17권3호
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• pp.163-167
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• 2016

Inverter surge resistant enameled wire was prepared with an organic/inorganic hybrid nanocomposite, and the effect of ambient temperature on the insulation lifetime of the enameled wire in the form of twisted pair was studied by a withstanding voltage tester. The organic polymer was Polyesterimide-polyamideimide (EI/AI) and the inorganic material was a Nano-sized silica (average particle size : 15 nm). The enamel thickness was 50 μm and the ambient temperature was 100, 150, 200, and 250, respectively. Transmission electron microscopy (TEM) observation showed that Nano-sized Silica were evenly dispersed in EI/AI. There were many air gaps in a twisted pair, therefore, when voltage was applied to the twisted pair, enamel erosion took place in the air gap area because of partial discharge accordi, ng to Paschen’s law. As ambient temperature increased, insulation lifetime decreased according to Arrhenius relationship, which was explained by the increasing mobility of polymer chains in EI or AI. And insulation breakdown voltage value at 10 kHz was 1,864.5 sec (31.1 min), which is 1.9 times higher than at 20 kHz, 981.6 sec (16.4 min).

• Bulletin of the Korean Chemical Society
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• 제32권5호
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• pp.1534-1538
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• 2011

Uniform, hollow nanosilica spheres were prepared by the chemical coating of cationic polystyrene (cPS) with tetraethylorthosilicate (TEOS), followed by calcination at 600 $^{\circ}C$ under air. cPS was synthesized by surfactant-free emulsion polymerization using 2,2'-azobis (2-methyl propionamidine) dihydrochloride as the cationic initiator, and poly(vinyl pyrrolidone) as a stabilizer. The resulting cPS spheres were 280 nm in diameter, and showed monodispersion. After coating, the hollow silica product was spherically shaped, and 330 nm in diameter, with a narrow distribution of sizes. Dispersion was uniform. Wall thickness was 25 nm, and surface area was 96.4 $m^2/g$, as determined by BET. The uniformity of the wall thickness was strongly dependent upon the cPS surface charge. The effects of TEOS and ammonia concentrations on shape, size, wall thickness, and surface roughness of hollow $SiO_2$ spheres were investigated. We observed that the wall thicknesses of hollow $SiO_2$ spheres increased and that silica size was simultaneously enhanced with increases in TEOS concentrations. When ammonia concentrations were increased, the irregularity of rough surfaces and aggregation of spherical particles were more severe because higher concentrations of ammonia result in faster hydrolysis and condensation of TEOS. These changes caused the silica to grow faster, resulting in hollow $SiO_2$ spheres with irregular, rough surfaces.

• 한국수소및신에너지학회논문집
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• 제28권2호
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• pp.144-149
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• 2017

A proton-conducting bisphenylpropaned sulfonated fluorinated blockcopolymer (BPSFBC) was synthesized. Five kinds of polymer electrolyted composite membranes were preparated by incorporating silica ($SiO_2$) with various weight ratio. And their characteristics were investigated by FT-IR (fourier transform infrared), $^1H-NMR$ ($^1H$ nuclear magnetic resonance), TGA (thermogravimetric analysis), water uptake, FE-SEM (field emission scanning electron microscopes), and ion conductivity properties. The water uptake and ion conductivity were increased until 9 wt% $SiO_2$, and then decreased. The maximum proton conductivity equal to $52mScm^{-1}$ was measured for the BPSFBC/$SiO_2$-9 composite membrane at $90^{\circ}C$ and 100% relative humidity. From the measured results, it is distinct that the manufactured composite membrane BPSFBC/$SiO_2$-9 can be considered as a polymer membrane suitable for a fuel cell electrolyte.

• Advances in aircraft and spacecraft science
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• 제1권1호
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• pp.1-14
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• 2014

Physico-chemical changes of the plasma modified titanium alloy [Ti-6Al-4V] surface were studied with respect to their crystallographic changes by X-Ray Diffraction (XRD) and Scanning Electron Microscope (SEM).The plasma-treatment of surface was carried out to enhance adhesion of high performance nano reinforced epoxy adhesive, a phenomenon that was manifested in subsequent experimental results. The enhancement of adhesion as a consequence of improved spreading and wetting on metal surface was studied by contact angle (sessile drop method) and surface energy determination, which shows a distinct increase in polar component of surface energy. The synergism in bond strength was established by analyzing the lap-shear strength of titanium laminate. The extent of enhancement in thermal stability of the dispersed nanosilica particles reinforced epoxy adhesive was studied by Thermo Gravimetric Analysis (TGA), which shows an increase in onset of degradation and high amount of residuals at the high temperature range under study. The fractured surfaces of the joint were examined by Scanning electron microscope (SEM).

• 한국재료학회지
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• 제25권4호
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• pp.209-213
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• 2015

Synthesis of nano-silica using water glass in a Sol-Gel process is one of several methods to manufacture nano-silica. In nano-silica synthesized from water glass, there are various metal impurities. However, synthesis of nano-silica using water glass in a Sol-Gel process is an interesting method because it is relatively simple and cheap. In this study, nano-silica was synthesized from water glass; we investigated the effect of pH on the synthesis of nano-silica. The morphology of the nanosilica with pH 2 was flat, but the surface of the nano-silica with pH 10 had holes similar to small craters. As a result of ICP-OES analysis, the amount of Na in the nano-silica with pH 2 was found to be 170 mg/kg. On the other hand, the amount of Na in the nano-silica with pH 10 was found to be 56,930 mg/kg. After calcination, the crystal structure of the nano-silica with pH 2 was amorphous. The crystal structure of the nano-silica with pH 10 transformed from amorphous to tridymite. This is because elemental Na in the nano-silica had the effect of decreasing the phase transformation temperature.