• Title/Summary/Keyword: Nano-level

Search Result 492, Processing Time 0.025 seconds

Durability Characteristics of Concrete with Nano Level Ceramic Based Coating (나노합성 세라믹계 도장재를 도포한 콘크리트의 내구성능)

  • Kim, Seong-Soo;Lee, Jeong-Bae;Han, Seung-Woo
    • Journal of the Korea Concrete Institute
    • /
    • v.19 no.5
    • /
    • pp.639-646
    • /
    • 2007
  • This study performed several tests for the durability of the concrete coated with nano synthesis ceramics which do not contain volatile organic compounds harmful to environment. The tests were adhesion test on dry and humid concrete, SEM test, MIP analysis, carbonation, chloride diffusion by electronic facilitation, freezing-thawing resistance, alkaline resistance, and brine resistance test. In the adhesion test on dry and humid concrete, nano synthesis ceramics coating produced the highest results among all the coatings tested. Nano synthesis ceramics adhered solidly on the concrete surface. The adhesive strength seemed to result from the hydrogen bond between nano synthesis ceramics which are inorganic and generated by hydrolysis and re-condensation reaction and the concrete's hydrates such as calcium silicate aluminate or calcium silicate hydrate. SEM test and MIP analysis results show surface structure with finest crevices pore in the nano synthesis ceramics coating applied concretes. In the carbonation, chloride diffusion, and freezing-thawing resistance tests, the concretes with nano synthesis ceramics coating indicated the best results. Based on these test results, further progress in application of nano synthesis ceramics coatings to various concrete structures including costal structures and sewerage arrangements can be expected.

Enhancement in the photocurrent of ZnO nanoparticles by thermal annealing

  • Byun, Kwang-Sub;Cho, Kyuong-Ah;Jun, Jin-Hyung;Seong, Ho-Jun;Kim, Sang-Sig
    • Journal of IKEEE
    • /
    • v.13 no.1
    • /
    • pp.57-64
    • /
    • 2009
  • The optoelectrical characteristics of the ZnO nanoparticles (NPs) annealed in vacuum or oxygen condition from $200^{\circ}C$ to $600^{\circ}C$ were examined. Increased on-off ratio (or, the ratio of photocurrent to dark current) was observed when they were annealed at $300^{\circ}C$, $400^{\circ}C$ and $500^{\circ}C$ with the values enhanced about 4 orders compared to the as-prepared ZnO NPs in both annealing conditions, while the maximum efficiency was shown at the annealing temperature of $600^{\circ}C$ for the ZnO NPs annealed in vacuum with the value of 29.8 mA/W and at the temperature of $500^{\circ}C$ for those annealed in oxygen condition with the value of 40.3 mA/W. Photoresponse behavior of the ZnO NPs annealed in oxygen showed the sharp increase right after the ir exposure to the light followed by the slow decay and saturation during steady illumination, differing from the ZnO NPs annealed in vacuum which only exhibited the gradual increase. This difference occurred due to the curing effect of the oxygen vacancies. SEM images indicated no change in their morphologies with annealing, indicating the change in their internal structures by annealing, and most remarkably at $600^{\circ}C$. As for their photoluminescence(PL) spectra, the decrease of the deep-level(DL) emission was observed when they were annealed in oxygen at $400^{\circ}C$, and not at $200^{\circ}C$ and $600^{\circ}C$.

  • PDF

Characteristics on Electroosmosis Ground Improvement Using Nano-geosynthetics (나노섬유를 이용한 동전기 지반개량에 관한 특성)

  • Ahn, Kwangkuk;Jeong, Kusic;Lee, JunDae
    • Journal of the Korean GEO-environmental Society
    • /
    • v.10 no.4
    • /
    • pp.59-63
    • /
    • 2009
  • In this study, Nano-geosynthetics with electroosmosis method was used and tried to verify the possibility of usage for soft ground improvement. Electroosmosis tests were performed with increasing the voltage level and changing distance between electrodes. The electrokinetic cell was assembled and a Nano-geosynthetics was inserted into the plastic drain board. And electroosmosis was applied to the disturbed kaolin clay. In order to study the effects of ground improvement, ground settlement, water content, collected pore water and shear strength were compared and analyzed with non-applied kaolin clay. Also, the electroosmosis tests were performed with changing the distance between electrodes and the voltage size. As a results of changing the distance and voltage between electrodes, the more voltage size was increased, the more the settlement of ground, shear strength and collected pore water were increased. As the distance between electrodes were increased, the settlement of ground, shear strength, water content and collected pore water were decreased. Finally, Nano-geosynthetics as a material of electrode have the sufficient potential to improve soft ground.

  • PDF

Color Stability of the Bioplastic containing Sorghum Extract Chelated by Fe(II) and Cu(II) (Fe(II)와 Cu(II)에 의해 킬레이트화 된 수수추출물 함유 바이오플라스틱의 색상 안정성)

  • Lee, Ga Hyun;Lee, Sung June;Jeong, Sang Won;Kim, Hyun-Chul;Choi, Jin Hyun;Bae, Do Gyu;Han, Sang Ik;Lee, Se Geun
    • Textile Coloration and Finishing
    • /
    • v.27 no.1
    • /
    • pp.62-69
    • /
    • 2015
  • To improve the color stability of the bioplastic containing sorghum extract, sorghum extract was chelated by a metal ion. The chelating activity was quantitatively evaluated under the various conditions. Chelation of sorghum extract by Cu(II) was determined by reaction with pyrocatechol violet, whereas Fe(II) chelation was investigated by forming complexes with ferrozine. Chelation of sorghum extract was increased rapidly with increasing concentrations of metal salt and sorghum extract. At a 0.1g/L metal salt addition level, the chelating activity of Fe(II) and Cu(II) were 66.7% and 54.2%, respectively. According to the chelation pH conditions, the sorghum extract was chelated almost 100% by Fe(II) above the pH 6.5. It was confirmed that Fe(II) was a strong chelator of sorghum extract than Cu(II). The sorghum extract chelated with metal salt exhibit higher thermal stability. The bioplastic containing chelated sorghum extract showed relatively less color change than the control.

A Programming Model for USN Applications based on Nano-Qplus (Nano-Qplus기반의 USN 응용 프로그래밍 모델)

  • Lee, Woo-Jin;Kim, Ju-Il;Lee, Kwang-Yong;Chong, Ki-Won
    • Journal of KIISE:Software and Applications
    • /
    • v.33 no.4
    • /
    • pp.378-387
    • /
    • 2006
  • A programming model for ubiquitous sensor network (USN) applications based on Nano-Qplus is proposed. USN applications mean programs of nodes which are components of sensor network such as sensor, router, sink and actuator. Developers can automatically generate programs of USN applications by setting attributes values of nodes using a script after they model a sensor network. A script for setting attributes values of a node is proposed in this paper. The algorithm of automatic code generation is also described. Developers can easily implement USN applications even if they do not know details of low-level communication, data sharing, and collective operations because the applications are automatically generated from a script. They set only attributes values of nodes using the script. Efforts for USN applications development also are reduced because of automatic code generation. Furthermore, developers can correct errors of applications in the early stage of development through ear]y test based on rapid code generation.

Fabrication of CuO/ZnO Nano-heterostructure by Photochemical Method and Their H2S Gas Sensing Properties

  • Kim, Jae-Hyun;Yong, Ki-Jung
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2011.08a
    • /
    • pp.359-359
    • /
    • 2011
  • This study reports the H2S gas sensing properties of CuO / ZnO nano-hetero structure bundle and the investigation of gas sensing mechanism. The 1-Dimensional ZnO nano-structure was synthesized by hydrothermal method and CuO / ZnO nano-heterostructures were prepared by photo chemical reaction. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) spectra confirmed a well-crystalline ZnO of hexagonal structure. In order to improve the H2S gas sensing properties, simple type of gas sensor was fabricated with ZnO nano-heterostructures, which were prepared by photo-chemical deposition of CuO on the ZnO nanorods bundle. The furnace type gas sensing system was used to characterize sensing properties with diluted H2S gas (50 ppm) balanced air at various operating temperature up to 500$^{\circ}C$. The H2S gas response of ZnO nanorods bundle sensor increased with increasing temperature, which is thought to be due to chemical reaction of nanorods with gas molecules. Through analysis of X-ray photoelectron spectroscopy (XPS), the sensing mechanism of ZnO nanorods bundle sensor was explained by well-known surface reaction between ZnO surface atoms and hydrogen sulfide. However at high sensing temperature, chemical conversion of ZnO nanorods becomes a dominant sensing mechanism in current system. Photo-chemically fabricated CuO/ZnO heteronanostructures show higher gas response and higher current level than ZnO nanorods bundle. The gas sensing mechanism of the heteronanostructure can be explained by the chemical conversion of sensing material through the reaction with H2S gas.

  • PDF

Ultra-Precise Polishing of Mica Glass Ceramics Using MR Fluids and Nano Abrasives (MR fluid를 이용한 Mica Glass Ceramics의 초정밀 연마)

  • Beak, Si-Young;Song, Ki-Hyeok;Kim, Ki-Beom;Kim, Byung-Chan;Kang, Dong-Sung;Hong, Kwang-Pyo
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.16 no.5
    • /
    • pp.85-90
    • /
    • 2017
  • Mica-glass ceramics has features such as micro-sized crystals, high strength, chemical resistance, semitransparent optical properties, etc. Due to its superior material properties, mica glass ceramics have increasing applications in dental and medical components, insulation boards, chemical devices, etc. In many applications, especially for dental and medical components, ultra-precise polishing is required. However, it is known to be a very difficult-to-grind material because of its high hardness and brittle properties. Thus, in this study, a newly developed ultra-precise polishing method is applied to obtain nano-level surface roughness of the mica glass ceramics using magnetorheological (MR) fluids and nano abrasives. Nano-sized ceria particles were used for the polishing of the mica glass ceramics. A series of experiments were performed under various polishing conditions, and the results were analyzed. A very fine surface roughness of Ra=6.127 nm could be obtained.

Electrical Transport Properties and Magnetoresistance of (1-x)La0.7Sr0.3MnO3/xZnFe2O4 Composites

  • Seo, Yong-Jun;Kim, Geun-Woo;Sung, Chang-Hoon;Lee, Chan-Gyu;Koo, Bon-Heun
    • Korean Journal of Materials Research
    • /
    • v.20 no.3
    • /
    • pp.137-141
    • /
    • 2010
  • The $(1-x)La_{0.7}Sr_{0.3}MnO_3(LSMO)/xZnFe_2O_4$(ZFO) (x = 0, 0.01, 0.03, 0.06 and 0.09) composites were prepared by a conventional solid-state reaction method. We investigated the structural properties, magnetic properties and electrical transport properties of (1-x)LSMO/xZFO composites using X-ray diffraction (XRD), scanning electron microscopy (SEM), field-cooled dc magnetization and magnetoresistance (MR) measurements. The XRD and SEM results indicate that LSMO and ZFO coexist in the composites and the ZFO mostly segregates at the grain boundaries of LSMO, which agreed well with the results of the magnetic measurements. The resistivity of the samples increased by the increase of the ZFO doping level. A clear metal-to-insulator (M-I) transition was observed at 360K in pure LSMO. The introduction of ZFO further downshifted the transition temperature (350K-160K) while the transition disappeared in the sample (x = 0.09) and it presented insulating/semiconducting behavior in the measured temperature range (100K to 400K). The MR was measured in the presence of the 10kOe field. Compared with pure LSMO, the enhancement of low-field magnetoresistance (LFMR) was observed in the composites. It was clearly observed that the magnetoresistance effect of x = 0.03 was enhanced at room temperature range. These phenomena can be explained using the double-exchange (DE) mechanism, the grain boundary effect and the intrinsic transport properties together.

Preventive effects of nano-graphene oxide against Parkinson's disease via reactive oxygen species scavenging and anti-inflammation

  • Hee-Yeong Kim;Hyung Ho Yoon;Hanyu Seong;Dong Kwang Seo;Soon Won Choi;Jaechul Ryu;Kyung-Sun Kang;Sang Ryong Jeon
    • BMB Reports
    • /
    • v.56 no.3
    • /
    • pp.202-207
    • /
    • 2023
  • We investigated the neuroprotective effects of deca nano-graphene oxide (daNGO) against reactive oxygen species (ROS) and inflammation in the human neuroblastoma cell line SH-SY5Y and in the 6-hydroxydopamine (6-OHDA) induced Parkinsonian rat model. An MTT assay was performed to measure cell viability in vitro in the presence of 6-OHDA and/or daNGO. The intracellular ROS level was quantified using 2',7'-dichlorofluorescein diacetate. daNGO showed neuroprotective effects against 6-OHDA-induced toxicity and also displayed ROS scavenging properties. We then tested the protective effects of daNGO against 6-OHDA induced toxicity in a rat model. Stepping tests showed that the akinesia symptoms were improved in the daNGO group compared to the control group. Moreover, in an apomorphine-induced rotation test, the number of net contralateral rotations was decreased in the daNGO group compared to the control group. By immunofluorescent staining, the animals in the daNGO group had more tyrosine hydroxylase-positive cells than the controls. By anti-Iba1 staining, 6-OHDA induced microglial activation showed a significantly decrease in the daNGO group, indicating that the neuroprotective effects of graphene resulted from anti-inflammation. In conclusion, nano-graphene oxide has neuroprotective effects against the neurotoxin induced by 6-OHDA on dopaminergic neurons.

Thermal Design and On-Orbit Thermal Analysis of 6U Nano-Satellite High Resolution Video and Image (HiREV) (6U급 초소형 위성 HiREV(High Resolution Video and Image)의 광학 카메라의 열 설계 및 궤도 열 해석)

  • Han-Seop Shin;Hae-Dong Kim
    • Journal of Space Technology and Applications
    • /
    • v.3 no.3
    • /
    • pp.257-279
    • /
    • 2023
  • Korea Aerospace Research Institute has developed 6U Nano-Satellite high resolution video and image (HiREV) for the purpose of developing core technology for deep space exploration. The 6U HiREV Nano-Satellite has a mission of high-resolution image and video for earth observation, and the thermal pointing error between the lens and the camera module can occur due to the high temperature in camera module on mission mode. The thermal pointing error has a large effect on the resolution, so thermal design should solve it because the HiREV optical camera is developed based on commercial products that are the industrial level. So, when it operates in space, the thermal design is needed, because it has the best performance at room temperature. In this paper, three passive thermal designs were performed for the camera mission payload, and the thermal design was proved to be effective by performing on-orbit thermal analysis.