• Structural Monitoring and Maintenance
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• v.11 no.2
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• pp.71-86
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• 2024

In this study, to reduce the amount of cement consumed in the production of cementitious composites, the effects of partial replacement of cement weight with nano-silica, silica fume, and copper slag on the mechanical properties of polypropylene fiber-reinforced cementitious composites are investigated. For this purpose, the effect of replacing cement weight by each of the aforementioned materials individually and in combination is studied. A total of 34 mix designs were prepared, and their compressive, tensile, and flexural strengths were obtained for each mix. Among the mix designs with one cement replacement material, the highest strength is related to the sample containing 2.5% nano-silica. In this mix design, the compressive, tensile, and flexural strengths improve by about 33%, 13%, and 15%, respectively, compared to the control sample. In the ones with two cement replacement materials, the highest strengths are related to the mix made with 10% silica fume along with 2% nano-silica. In this mix design, compressive, tensile, and flexural strengths increase by about 42%, 18%, and 20% compared to the control sample, respectively. Furthermore, in the mixtures containing three cement substitutes, the final optimal mix design for all three strengths has 15% silica fume, 10% copper slag, and 2% nano-silica. This mix design improves the compressive, tensile, and flexural strengths by about 57%, 23%, and 26%, respectively, compared to the control sample. Finally, two relationships have been presented that can be used to predict the values of tensile and flexural strengths of cementitious composites with very good accuracy only by determining the compressive strength of the composites.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.23 no.9
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• pp.741-746
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• 2010

Three-dimensionally ordered macro-porous Sn-C composites were prepared by using polystyrene microsphere as a template. The Sn-C composites were composed of well-interconnected pore with circular shape and wall structure with wall thickness of a few tens of nano-meters. This porous three-dimensional structure is readily and uniformly accessible to the electrolyte, which facilitates lithium ion diffusion during charge-discharge reactions. The wall thickness of the composites was increased as the increase of Sn content of the composite. From EDS analysis, it is confirmed that the Sn was dispersed uniformly in Sn-C composites. The capacity was increased as the Sn content increased, which is due to Sn anode with high capacity. The Sn-C composites with high Sn content showed superior cyclic performances. Such enhancement is ascribed to the thick wall thickness and small pore size of the sample with high Sn content. The Sn-C composite with Sn 30 wt% showed relatively high capacity and stable cycle life, however, the stability of the 3-dimensional structure should be enhanced by further work.

• Steel and Composite Structures
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• v.24 no.4
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• pp.499-512
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• 2017

This paper deals with nonlinear dynamic stability of embedded piezoelectric nano-composite separators conveying pulsating fluid. For presenting a realistic model, the material properties of structure are assumed viscoelastic based on Kelvin-Voigt model. The separator is reinforced with single-walled carbon nanotubes (SWCNTs) which the equivalent material properties are obtained by mixture rule. The separator is surrounded by elastic medium modeled by nonlinear orthotropic visco Pasternak foundation. The separator is subjected to 3D electric and 2D magnetic fields. For mathematical modeling of structure, three theories of classical shell theory (CST), first order shear deformation theory (FSDT) and sinusoidal shear deformation theory (SSDT) are applied. The differential quadrature method (DQM) in conjunction with Bolotin method is employed for calculating the dynamic instability region (DIR). The detailed parametric study is conducted, focusing on the combined effects of the external voltage, magnetic field, visco-Pasternak foundation, structural damping and volume percent of SWCNTs on the dynamic instability of structure. The numerical results are validated with other published works as well as comparing results obtained by three theories. Numerical results indicate that the magnetic and electric fields as well as SWCNTs as reinforcer are very important in dynamic instability analysis of structure.

• Advances in nano research
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• v.5 no.2
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• pp.69-97
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• 2017

In this study, nonlinear response of laminated functionally graded carbon nanotube reinforced composite (FG-CNTRC) plate under low-velocity impact based on the Eshelby-Mori-Tanaka approach in thermal conditions is studied. The governing equations are derived based on higher-order shear deformation plate theory (HSDT) under von $K\acute{a}rm\acute{a}n$ geometrical nonlinearity assumptions. The finite element method with 15 DOF at each node and Newmark's numerical integration method is applied to solve the governing equations. Four types of distributions of the uniaxially aligned reinforcement material through the thickness of the plates are considered. Material properties of the CNT and matrix are assumed to be temperature dependent. Contact force between the impactor and the laminated plate is obtained with the aid of the modified nonlinear Hertzian contact law models. In the numerical example, the effect of layup (stacking sequence) and lamination angle as well as the effect of temperature variations, distribution of CNTs, volume fraction of the CNTs, the mass and the velocity of the impactor in a constant energy level and boundary conditions on the impact response of the CNTRC laminated plates are investigated in details.

• Computers and Concrete
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• v.25 no.4
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• pp.283-291
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• 2020

The present paper researches post-buckling behaviors of geometrically imperfect concrete beam resting on elastic foundation reinforced with graphene oxide powders (GOPs) based on finite element method (FEM). Distribution of GOPs are considered as uniform and linearly graded through the thickness. Geometric imperfection is considered as first buckling mode shape of the beam, the GOP reinforced beam is rested in initial position. The material properties of GOP reinforced composite have been calculated via employment of Halpin-Tsai micromechanical scheme. The provided refined beam element verifies the shear deformation impacts needless of any shear correction coefficient. The post-buckling load-deflections relations have been calculated via solving the governing equations having cubic non-linearity implementing FEM. Obtained findings indicate the importance of GOP distributions, GOP weight fraction, matrix material, geometric imperfection, shear deformation and foundation parameters on nonlinear buckling behavior of GOP reinforced beam.

• Composites Research
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• v.28 no.5
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• pp.260-264
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• 2015

In this paper, molecular dynamics (MD) simulation was carried to predict thermo-mechanical behaviors for carbon nanotube (CNT) reinforced epoxy composites and to analyze the trends. Total of six models having the volume fractions of CNT from 0 to 25% in epoxy were constructed. To predict thermal behaviors, temperature was increased constantly from 300 to 600 K, and the glass transition temperature ($T_g$) and coefficient of thermal expansion (CTE) analyzed using the relationship between temperature and specific volume. The elastic moduli that represented to the mechanical behaviors were also predicted by constant strain. Additionally, the effects of functionalization of CNT on mechanical behaviors of composite were analyzed. Models were constructed to represent CNTs functionalized by nitrogen doping and COOH groops, and interfacial behaviors and elastic moduli were analyzed. Results showed that the agglomerations of CNTs in epoxy cause by perturbations of thermo-mechanical behaviors, and the functionalization of CNTs improved the interfacial response as well as mechanical properties.

• Korean Chemical Engineering Research
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• v.59 no.3
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• pp.326-332
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• 2021

In this study, a spherical carbon composite material containing nano-silicon was synthesized using hydrothermal synthesis, and coated with petroleum pitch to prepare an anode material to investigate the electrochemical characteristics. Hydrothermal synthesis was performed by varying molar concentration, and the pitch was coated using THF as an organic solvent to prepare a composite material. The physical properties of anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances were investigated by cycle, C-rate, cyclic voltammetry and electrochemical impedance tests in 1.0 M LiPF₆ electrolyte (EC : DMC : EMC = 1 : 1 : 1 vol%). The pitch-coated silicon/carbon composite (Pitch@Si/C-1.5) with sucrose of 1.5 M showed a spherical shape. In addition, a high initial capacity of 1756 mAh/g, a capacity retention ratio of 82% after 50 cycles, and an excellent rate characteristic of 81% at 2 C/0.1 C were confirmed.

• The Journal of Korean Academy of Prosthodontics
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• v.46 no.2
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• pp.105-115
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• 2008

Statement of problem: Proper finishing and polishing enhance both the esthetics and the longevity of restored teeth. Blade finishing technique would be suited for smoothing and finishing. Evaluation of this technique are necessary. Purpose: The purpose of this study was to evaluate the blade finishing and polishing procedures on the surface profile and roughness of ormocer-based composite resin and nanohybrid composite resin. Material and methods: The material included a ormocer-based composite resin ($Admira^{(R)}$ & $Admira^{(R)}$ Flow); a nanohybrid composite resin ($Grandio^{(R)}$ & $Grandio^{(R)}$ Flow). One hundred forty specimens of each group were prepared using a mylar strip and randomly divied into blade finishing and rubber polishing groups (n=10). The average surface roughness (Ra) in micrometers was measured and the surface profile was examined by scanning electron microscopy (SEM) (Magnification ${\times}$ 200). The data were analyzed by Mann-Whitney Test at 0.05 significance level. Conclusion: The results of this study indicated that the mylar strip produced the smoothest surface on all materials and among the finishing-polishing methods was not significanct difference (P>0.05). Ormocer-based flowable composite resin performedthe lowest variability in initial surface roughness among the tested materials.

• Journal of Powder Materials
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• v.9 no.6
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• pp.441-448
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• 2002

Dispersions of non-soluble ceramic particles in a metallic matrix can enhance the strength and heat resistance of materials. With the advent of mechanical alloying it became possible to put the theoretical concept into practice by incorporating very fine particles in a flirty uniform distribution into often oxidation- and corrosion- resistant metal matrices. e.g. superalloys. The present paper will give an overview about the mechanical alloying technique as a dry, high energy ball milling process for producing composite metal powders with a fine controlled microstructure. The common way is milling of a mixture of metallic and nonmetallic powders (e.g. oxides. carbides, nitrides, borides) in a high energy ball mill. The heavy mechanical deformation during milling causes also fracture of the ceramic particles to be distributed homogeneously by further milling. The mechanisms of the process are described. To obtain a homogeneous distribution of nano-sized dispersoids in a more ductile matrix (e.g. aluminium-or copper based alloys) a reaction milling is suitable. Dispersoid can be formed in a solid state reaction by introducing materials that react with the matrix either during milling or during a subsequent heat treatment. The pre-conditions for obtaining high quality materials, which require a homogeneous distribution of small dis-persoids, are: milling behaviour of the ductile phase (Al, Cu) will be improved by the additives (e.g. graphite), homogeneous introduction of the additives into the granules is possible and the additive reacts with the matrix or an alloying element to form hard particles that are inert with respect to the matrix also at elevated temperatures. The mechanism of the in-situ formation of dispersoids is described using copper-based alloys as an example. A comparison between the in-situ formation of dispersoids (TiC) in the copper matrix and the milling of Cu-TiC mixtures is given with respect to the microstructure and properties, obtained.

• Journal of the Korean Ceramic Society
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• v.45 no.4
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• pp.226-231
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• 2008

The dense sintered bodies with >95% theoretical densities were successfully obtained from the $BaZrO_3,\;BaCeO_3,\;Ba(Zr_{0.7}Ce_{0.3})O_3$ solid solution, and core-shell structured $0.7BaZrO_3-0.3BaCeO_3$ composite powders prepared by sol-gel methods. The activation energy of $Ba(Zr_{0.7}Ce_{0.3})O_3$ solid solution calculated from the Arrhenius plot of the proton conductivities was similar to that of $BaZrO_3$. The activation energy of core-shell structured $0.7BaZrO_3-0.3BaCeO_3$ composite, however, was much lower than that of $BaZrO_3$ or $Ba(Zr_{0.7}Ce_{0.3})O_3$ solid solution, and was very similar to that $BaCeO_3$. These results could be assigned to the Ce-rich grain boundary which was clearly observed by EDX in core-shell structured $0.7BaZrO_3-0.3BaCeO_3$ composite.