• Title/Summary/Keyword: Nano-composite

Search Result 1,051, Processing Time 0.026 seconds

Synthesis of Activated Carbon from a Bio Waste (Flower of Shorea Robusta) Using Different Activating Agents and Its Application as Supercapacitor Electrode

  • Ghosh, Souvik;Samanta, Prakas;Murmu, Naresh Chandra;Kim, Nam Hoon;Kuila, Tapas
    • Composites Research
    • /
    • v.35 no.1
    • /
    • pp.1-7
    • /
    • 2022
  • The activated carbon is a very good choice for using as supercapacitor electrode materials. Herein, the flower of Shorea robusta, a bio-waste material was successfully used to synthesize the activated carbons for application as supercapacitor electrode materials. The activated carbon was synthesized through chemical activation process followed by thermal treatment at 700℃ in presence of N2 atmosphere using KOH, ZnCl2 and H3PO4 as the activating agents. The physicochemical analyses demonstrate that the obtained activated carbons are graphitic in nature and the degree of disorder of the graphitic carbons is changed with the activating agents. The activated carbon obtained from Shorea robusta flower (ACSF-K) electrode shows the specific capacitance of ~610 F g-1 at 2 A g-1 current density, which is higher than ACSF-Z (560 F g-1) and ACSF-H (470 F g-1) electrode material under the identical current density. The synthesized graphitic carbons also demonstrated good rate capability and high electrochemical stability as supercapacitor electrode.

Facile Electrodeposition Technique for the Fabrication of MoP Cathode for Supercapacitor Application

  • Samanta, Prakas;Ghosh, Souvik;Murmu, Naresh Chandra;Lee, Joong Hee;Kuila, Tapas
    • Composites Research
    • /
    • v.34 no.6
    • /
    • pp.345-349
    • /
    • 2021
  • The continued environmental pollution caused by fossil fuel consumption has prompted researchers around the world to develop environmentally friendly energy technologies. Electrochemical energy storage is the significant area of research in this development process, and the research significance of supercapacitors in this field is increasing. Herein, a simple electrodeposition synthetic route was explored to develop the MoP layered cathode material. The layered structure provided a highly ion-accessible surface for smooth and faster ion adsorption/desorption. After Fe was doped into MoP, the morphology of MoP changes and the electrochemical performance was significantly improved. Specific capacitance value of the binder-free FeMoP electrode was found to be 269 F g-1 at 2 A g-1 current density in 6 M aqueous KOH electrolyte. After adding Fe to MoP, an additional redox contribution was observed in the redox conversion from Fe3+ to Fe2+ redox pair, and the charge transfer kinetics of MoP was effectively improved. This research can provide guidance for the development of supercapacitor electrode materials through simple electrodeposition technology.

Effect of moving load on dynamics of nanoscale Timoshenko CNTs embedded in elastic media based on doublet mechanics theory

  • Abdelrahman, Alaa A.;Shanab, Rabab A.;Esen, Ismail;Eltaher, Mohamed A.
    • Steel and Composite Structures
    • /
    • v.44 no.2
    • /
    • pp.255-270
    • /
    • 2022
  • This manuscript illustrates the dynamic response of nanoscale carbon nanotubes (CNTs) embedded in an elastic media under moving load using doublet mechanics theory, which not considered before. CNTs are modelled by Timoshenko beam theory (TBT) and a bottom to up modelling nano-mechanics is simulated by doublet mechanics theory to capture the size effect of CNTs. To explore the influence of the CNTs configurations on the dynamic behaviour, both armchair and zigzag configurations are considered. The governing equations of motion and the associated boundary conditions are obtained using the Hamiltonian principle. The Navier solution methodology is applied to obtain the solutions for both orientations. Free vibration and forced response under moving loads are considered. The accuracy of the developed procedure is verified by comparing the obtained results with available previous algorithms and good agreement is observed. Parametric studies are conducted to demonstrate effects of doublet length scale, CNTs configurations, moving load velocities as well as the elastic media parameters on the dynamic behaviours of CNTs. The developed procedure is supportive in the design and manufacturing of MEMS/NEMS made from CNTs.

Buckling and vibration of porous sandwich microactuator-microsensor with three-phase carbon nanotubes/fiber/polymer piezoelectric polymeric nanocomposite face sheets

  • Arani, Ali Ghorbanpour;Navi, Borhan Rousta;Mohammadimehr, Mehdi
    • Steel and Composite Structures
    • /
    • v.41 no.6
    • /
    • pp.805-820
    • /
    • 2021
  • In this research, the buckling and free vibration of three-phase carbon nanotubes/ fiber/ polymer piezoelectric nanocomposite face sheet sandwich microbeam with microsensor and micro-actuator surrounded in elastic foundation based on modified couple stress theory (MCST) is investigated. Three types of porous materials are considered for sandwich core. Higher order (Reddy) and sinusoidal shear deformation beam theories are employed for the displacement fields. Sinusoidal surface stress effects are extracted for sinusoidal shear deformation beam theory. The equations of motion are derived by Hamilton's principle and then the natural frequency and critical buckling load are obtained by Navier's type solution. The determined results are in good agreement with other literatures. The detailed numerical investigation for various parameters is performed for this microsensor-microactuator. The results reveal that the microsensor-microactuator enhanced by increasing of Skempton coefficient, carbon nanotubes diameter length to thickness ratio, small scale factor, elastic foundation, surface stress constants and reduction in porous coefficient, micro-actuator voltage and CNT weight fraction. The valuable results can be expedient for micro-electro-mechanical (MEMS) and nano-electro-mechanical (NEMS) systems.

Light Efficiency Enhancement Technology of OLED: Fabrication of Random Nano External Light Extraction Composite Layer (OLED의 광 효율 향상 기술: 랜덤 나노 외부 광 추출 복합 층 제작)

  • Choi, Geun Su;Jang, Eun Bi;Seo, Ga Eun;Park, Young Wook
    • Journal of the Semiconductor & Display Technology
    • /
    • v.21 no.3
    • /
    • pp.39-44
    • /
    • 2022
  • The light extraction technology for improving the light efficiency of OLEDs is the core technology for extracting the light inside the OLEDs to the outside. This study demonstrates a simple method to generate random nanostructures (RNSs) containing high refractive index nanoparticles to improve light extraction and viewing angle characteristics. A simple dry low-temperature process makes the nanostructured scattering layer on the polymer resin widely used in the industry. The scattering layer has the shape of randomly distributed nanorods. To control optical properties, we focused on changing the shape and density of RNSs and adjusting the concentration of high refractive index nanoparticles. As a result, the film of the present invention exhibits a perpendicular transmittance of 85% at a wavelength of 550 nm. This film was used as a scattering layer to reduce substrate mode loss and improve EL efficiency in OLEDs.

Vibration based energy harvesting performance of magneto-electro-elastic beams reinforced with carbon nanotubes

  • Arjun Siddharth Mangalasseri;Vinyas Mahesh;Sriram Mukunda;Vishwas Mahesh;Sathiskumar A Ponnusami;Dineshkumar Harursampath;Abdelouahed Tounsi
    • Advances in nano research
    • /
    • v.14 no.1
    • /
    • pp.27-43
    • /
    • 2023
  • This article investigates the energy harvesting characteristics of a magneto-electro-elastic (MEE) cantilever beam reinforced with carbon nanotubes (CNT) under transverse vibration. To this end, the well-known lumped parameter model is used to represent the coupled multiphysics problem mathematically. The proposed system consists of the MEE-CNT layer on top and an inactive substrate layer at the bottom. The substrate is considered to be made of either an isotropic or composite material. Basic laws such as Gauss's Law, Newton's Law and Faraday's Law are used to arrive at the governing equations. Surface electrodes across the beam are used to harvest the electric potential produced, together with a wound coil, for the generated magnetic potential. The influence of various distributions of the CNT and its volume fraction, substrate material, length-to-thickness ratio, and thickness ratio of substrate to MEE layer on the energy harvesting behaviour is thoroughly discussed. Further, the effect of external resistances and changes in substrate material on the response is analysed and reported. The article aims to explore smart material-based energy harvesting systems, focusing on their behaviour when reinforced with carbon nanotubes. The results of this study may lead to an improved understanding of the design and analysis of CNT-based smart structures.

Axial frequency analysis of axially functionally graded Love-Bishop nanorods using surface elasticity theory

  • Nazemnezhad, Reza;Shokrollahi, Hassan
    • Steel and Composite Structures
    • /
    • v.42 no.5
    • /
    • pp.699-710
    • /
    • 2022
  • This work presents a comprehensive study on the surface energy effect on the axial frequency analyses of AFGM nanorods in cylindrical coordinates. The AFGM nanorods are considered to be thin, relatively thick, and thick. In thin nanorods, effects of the inertia of lateral motions and the shear stiffness are ignored; in relatively thick nanorods, only the first one is considered; and in thick nanorods, both of them are considered in the kinetic energy and the strain energy of the nanorod, respectively. The surface elasticity theory which includes three surface parameters called surface density, surface stress, and surface Lame constants, is implemented to consider the size effect. The power-law form is considered for variation of the material properties through the axial direction. Hamilton's principle is used to derive the governing equations and boundary conditions. Due to considering the surface stress, the governing equation and boundary condition become inhomogeneous. After homogenization of them using an appropriate change of variable, axial natural frequencies are calculated implementing harmonic differential quadrature (HDQ) method. Comprehensive results including effects of geometric parameters and various material properties are presented for a wide range of boundary condition types. It is believed that this study is a comprehensive one that can help posterities for design and manufacturing of nano-electro-mechanical systems.

Finite element computer simulation of twinning caused by plastic deformation of sheet metal

  • Fuyuan Dong;Wang Xu;Zhengnan Wu;Junfeng Hou
    • Steel and Composite Structures
    • /
    • v.47 no.5
    • /
    • pp.601-613
    • /
    • 2023
  • Numerous methods have been proposed in predicting formability of sheet metals based on microstructural and macro-scale properties of sheets. However, there are limited number of papers on the optimization problem to increase formability of sheet metals. In the present study, we aim to use novel optimization algorithms in neural networks to maximize the formability of sheet metals based on tensile curve and texture of aluminum sheet metals. In this regard, experimental and numerical evaluations of effects of texture and tensile properties are conducted. The texture effects evaluation is performed using Taylor homogenization method. The data obtained from these evaluations are gathered and utilized to train and validate an artificial neural network (ANN) with different optimization methods. Several optimization method including grey wolf algorithm (GWA), chimp optimization algorithm (ChOA) and whale optimization algorithm (WOA) are engaged in the optimization problems. The results demonstrated that in aluminum alloys the most preferable texture is cube texture for the most formable sheets. On the other hand, slight differences in the tensile behavior of the aluminum sheets in other similar conditions impose no significant decreases in the forming limit diagram under stretch loading conditions.

Optimal sensor placement of retrofitted concrete slabs with nanoparticle strips using novel DECOMAC approach

  • Ali Faghfouri;Hamidreza Vosoughifar;Seyedehzeinab Hosseininejad
    • Smart Structures and Systems
    • /
    • v.31 no.6
    • /
    • pp.545-559
    • /
    • 2023
  • Nanoparticle strips (NPS) are widely used as external reinforcers for two-way reinforced concrete slabs. However, the Structural Health Monitoring (SHM) of these slabs is a very important issue and was evaluated in this study. This study has been done analytically and numerically to optimize the placement of sensors. The properties of slabs and carbon nanotubes as composite sheets were considered isotopic and orthotropic, respectively. The nonlinear Finite Element Method (FEM) approach and suitable optimal placement of sensor approach were developed as a new MATLAB toolbox called DECOMAC by the authors of this paper. The Suitable multi-objective function was considered in optimized processes based on distributed ECOMAC method. Some common concrete slabs in construction with different aspect ratios were considered as case studies. The dimension and distance of nano strips in retrofitting process were selected according to building codes. The results of Optimal Sensor Placement (OSP) by DECOMAC algorithm on un-retrofitted and retrofitted slabs were compared. The statistical analysis according to the Mann-Whitney criteria shows that there is a significant difference between them (mean P-value = 0.61).

Microstructure Characteristics of Conductive Cement Mortar with Deterioration Damage (열화손상이 발생된 전도성시멘트모르타르의 미세구조 특성)

  • Kim, Young-Min;Lee, Gun Cheol;Yun, Hyun Do;Kwon, Hyun Woo
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2021.05a
    • /
    • pp.195-196
    • /
    • 2021
  • The pore distribution of the cement mortar mixed with carbon nanotubes was found to have a large number of pores at (370~80)㎛, and the distribution ratio was larger as the carbon nanotubes were mixed. However, the pores with a fine particle diameter of (10-0.5) ㎛ were found to be larger as the carbon nanotubes were incorporated. However, the distribution of pores of the test specimens of conductive cement mortar with deterioration damage was found to be distributed in a number of particle diameters of (500 to 100) ㎛ and (10 to 0.5) ㎛. It is judged that the particle diameter of the internal pores increased due to the damage. However, as the mixing ratio of the test specimen with carbon nanotubes increased, the distribution of voids was relatively lower than that of plain, and it was judged to have excellent resistance to deterioration damage.

  • PDF