• 제목/요약/키워드: Nano-bio technology

검색결과 533건 처리시간 0.033초

가수분해된 PAN 중공사 PVA 복합막을 이용한 물-에탄올 계의 투과증발 분리 (Hydrolyzed PAN Hollow Fiber PVA Composite Membrane for Pervaporation Separation of Water-ethanol Mixtures)

  • 강수연;김소연;정성일;서창희;박헌휘;임지원
    • 멤브레인
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    • 제23권4호
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    • pp.283-289
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    • 2013
  • Poly(vinyl alcohol) (PVA)에 대하여 가교제로써 glutaraldehyde (GA), maleic anhydride (MA)를 이용하여 제조한 코팅용액을 알칼리로 가수분해 시킨 poly acrylonitrile (PAN) 중공사 막표면에 코팅하여 막을 제조하였다. 제조된 막의 투과특성평가를 위해서 물/에탄올 혼합액에 대한 투과증발 실험을 수행하였다. $60^{\circ}C$의 90 wt%의 물/에탄올 혼합액에 대하여 반응온도 및 가교제의 농도변화에 따른 투과도 및 선택도를 측정하였다. 일반적으로 반응온도, 가교제 농도가 증가할 경우 투과도는 낮아지고, 선택도는 증가하는 경향을 보여주었다. 가교제로 GA의 대표적 결과는 반응온도 $120^{\circ}C$, GA 11 wt%로 투과도는 $165g/m^2hr$ 선택도는 81이고, MA는 반응온도 $120^{\circ}C$, MA 11 wt%로 투과도는 $174g/m^2hr$ 선택도는 73의 결과를 얻을 수 있었다.

역삼투막 표면에 폴리비닐알코올 코팅을 통한 파울링 현상 감소연구 (Studies on the Fouling Reduction through the Coating of Poly (vinyl alcohol) on Polyamide Reverse Osmosis Membrane Surfaces)

  • 김일형;지은희;임지원;정성일
    • 멤브레인
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    • 제22권4호
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    • pp.272-279
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    • 2012
  • 본 연구에서는 폴리아마이드 역삼투 복합막 표면에 중성 친수성 고분자인 poly (vinyl alcohol) (PVA)를 코팅한 후 모델 오염물질인 bovine serum albumin (BSA), humic acid (HA), sodium alginate (SA)에 대하여 파울링 개선 효과가 있는지를 알아보고자 하였다. 고분자의 파울링 유도를 위해 모델 오염물질인 BSA, HA, SA 등이 100 ppm으로 용해된 공급원액을 2, 4, 8 atm 조건에서 PVA 코팅된 막과 코팅되지 않은 막에 대하여 파울링 실험을 수행한 결과. 압력이 증가함에 모든 오염물질에 대해서 파울링은 심화되었다. 파울링 심화 현상은 BSA > HA > SA의 순으로 일어났으며, PVA가 코팅된 막에 대해 파울링 개선효과는 HA > BSA > SA의 순으로 나타났다. 전자현미경 사진 결과에서도 같은 경향을 보여주고 있다. 결국, PVA가 코팅된 역삼투막은 어느 경우에서나 파울링 개선효과는 뚜렷하게 있었으며 HA의 경우에서 가장 두드러졌다.

PEBAX 3533과 PEG의 혼합막에 대한 기체투과 연구 (Gas Separation Study of PEBAX 3533 and PEG Blended Membranes)

  • 김광배;조은혜;정성일;이형근;임지원
    • 멤브레인
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    • 제23권2호
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    • pp.144-150
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    • 2013
  • 본 연구에서는 Poly (ether block amides)(PEBAX) 3533을 이용하여 $N_2$, $O_2$, $CH_4$, $CO_2$, $SO_2$에 대하여 투과도를 측정하였다. 투과선택도를 향상시키기 위하여 분자량 400의 Poly (ethylene glycol) (PEG)를 PEBAX 대비 20%, 40%, 50% 첨가하여 막을 제조한 후 $N_2$, $O_2$, $CH_4$, $CO_2$, $SO_2$ 순으로 투과도 및 순수 기체에 대하여 확산도 및 용해도를 각각의 막에 대하여 Time-lag법을 이용하여 측정하였다. 예상한 바와 같이 PEG 함량의 증가에 따라 순수 기체에 대한 투과도는 증가하였으며, 이상선택도의 경우 PEBAX 3533이 지니는 값과 큰 차이를 나타내지 않았으며 PEG 함량 증가에 따라 투과도의 증가는 각 기체의 PEG에 대한 용해도 증가때문인 것으로 밝혀졌으며 이에 대해서 본문에서 자세히 설명하고자 한다.

N3S-ligated Copper(II) Complex Catalyzed Selective Oxidation of Benzylic Alcohols to Aldehydes under Mild Reaction Conditions

  • Dharmalingam, Sivanesan;Koo, Eunhae;Yoon, Sungho;Park, Gyoosoon
    • Bulletin of the Korean Chemical Society
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    • 제35권3호
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    • pp.715-720
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    • 2014
  • A Cu(II) complex with an three nitrogens and one sulfur coordination environment was synthesized and characterized. Its redox potential was observed at 0.483 V vs. NHE, very similar to that of a Cu-containing fungal enzyme, galactose oxidase, which catalyzes the oxidation of alcohols to corresponding aldehydes with the concomitant reduction of molecular oxygen to water. The Cu(II) complex selectively oxidizes the benzylic alcohols using TEMPO/$O_2$ under mild reaction conditions to corresponding aldehydes without forming any over-oxidation product. Moreover, the catalyst can be recovered and reused multiple times for further oxidation reactions, thus minimizing the waste generation.

Cellulose Nanocrystals as Advanced "Green" Materials for Biological and Biomedical Engineering

  • Sinha, Arvind;Martin, Elizabeth M.;Lim, Ki-Taek;Carrier, Danielle Julie;Han, Haewook;Zharov, Vladimir P.;Kim, Jin-Woo
    • Journal of Biosystems Engineering
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    • 제40권4호
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    • pp.373-393
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    • 2015
  • Background: Cellulose is a ubiquitous, renewable and environmentally friendly biopolymer, which has high promise to fulfil the rising demand for sustainable and biocompatible materials. Particularly, the recent progress in the synthesis of highly crystalline cellulose-based nanoscale biomaterials, namely cellulose nanocrystals (CNCs), draws significant attention from many research communities, ranging from bioresource engineering, to materials science and engineering, to biological and biomedical engineering to bionanotechnology. The feasibility of harnessing CNCs' unique biophysicochemical properties has inspired their basic and applied research, offering much promise for new biomaterials with diverse advanced functionalities. Purpose: This review focuses on vital issues and topics on the recent advances in CNC-based biomaterials with potential, in particular, for bionanotechnology and biological and biomedical engineering. The challenges and limitations of CNC technology are discussed as well as potential strategies to overcome them, providing an essential source of information in the exploration of possible and futuristic applications of the CNC-based functional "green" nanomaterials. Conclusion: CNCs offer exciting possibilities for advanced "green" nanomaterials, driving innovative research and development in a wide range of fields, including biological and biomedical engineering.

보이차(Pu-erh tea)의 항산화 효과 (Antioxidant activities of Pu-erh tea)

  • 소은미;정은주;신장철;김성현;백순옥;김영만;김일광
    • 분석과학
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    • 제19권1호
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    • pp.39-44
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    • 2006
  • 보이차를 물로 추출하고, 항산화성 물질을 얻기위해 n-hexane, ethyl acetate(EA), butanol(BuOH)로 분획하였다. 분획은 자유라티칼 소거 활성과 환원력 측정의 두가지 방법으로 항산화활성 정도를 조사하였다. 이들 항산화활성을 butylated hydroxyanisole(BHA), butylated hydroxytoluene(BHT) 그리고 ${\alpha}$-tocopherol 같은 비교표준 항산화제와 비교하였다. 보이차의 EA분획은 BHA와 BHT 보다 더 높은 항산화활성을 보였다.

중국의 재료과학분야 연구현황과 우리의 대응방안 (Chinese Research Trends in Materials Science and the Korean Countermeasure)

  • 노경란;길상철;남수우
    • 한국재료학회지
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    • 제23권12호
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    • pp.745-756
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    • 2013
  • Recent rapid development of the Chinese economy based on science and technology is challenging Korean industries and economy. Since the driving force for this rapid development of China is known to be scientific technologies, the purpose of this research is to confirm the current status of Chinese scientific research in the field of "Materials Science and Engineering" and propose a strategy for competition with China. Even though there are numerous journals of "Materials Science and Engineering", the 10 most popular journals with high impact factors were selected to cover general materials, nano materials, bio materials, and electronic materials. It was found that the number of scientific papers written by Chinese scientists for the materials field in the 10 journals was slowly increasing from the year 2000 until 2005, but has been rapidly increasing since 2005. This research found that Chinese research activities in the traditional metallic materials and nano materials have tremendously increased to occupy around 30 % or more papers published in several major journals related with materials science and engineering. On the other hand, bio materials and electronic materials research has not been pursued so actively; however, very recently the number of publications in these fields is also beginning to increase. To compete with this tremendously growing Chinese scientific development, Korea should have a policy of "selection and concentration" in materials-related fields, including basic science in nano, bio, and electronic materials.

Crystallization of amorphous Si by pulse annealing with Ni ferritins

  • Tojo, Yosuke;Miura, Atsushi;Fuyuki, Takashi;Yamashita, Ichiro;Uraoka, Yukiharu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.553-556
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    • 2009
  • We investigated an application of supramolecular protein, and demonstrated the metal induced lateral crystallization utilizing ferritins with Ni nanoparticles, named the "bio-nano-crystallization". So far, this method has required long time, because of this method condition based on the conventional solid phase crystallization. In this study, we applied the pulsed rapid thermal annealing to bio-nanocrystallization. As a result, we succeeded in the crystallization for a short time. We found that the TFTs characteristics were improved with decrease metal impieties in poly-Si thin films by this method.

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