• Journal of Advanced Marine Engineering and Technology
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• 제36권4호
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• pp.484-489
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• 2012

본 논문은 선박의 주 추진기관으로 사용가능한 육상 운송수단에 탑재되어있는 대형 디젤엔진에서 배출되는 입자상 물질과 질소산화물의 배출특성을 ESC mode에 적용시켜 분석하는데 초점을 두었다. 입자상 물질은 엔진의 고부하 영역에서 다량으로 배출되는 특성을 확인 할 수 있었으며 질소산화물의 경우 배기가스 온도 측정형태와 동일한 경향으로 배출되었다. 매연여과장치를 부착하여 입자상 물질의 배출특성을 분석한 결과 mode별 1/100~1/1,000배까지 저감되었다. 그러나 급격한 엔진 부하 변동 시 저감효과는 떨어졌으며 고속-고부하 영역에서는 매연여과장치내부의 온도상승으로 일부 재생현상이 발생하여 입자상 물질의 배출 증가 결과를 초래하는 현상이 발생하였다. 시험엔진에서 배출되는 입자상 물질의 입경분포를 분석한 결과 대부분 100nm 이하의 크기를 가지는 나노 입자가 배출되었으며 매연여과장치를 부착 및 탈착하여 측정한 결과 배출수준에는 차이가 있지만 입자상 물질의 입경분포는 비슷한 경향으로 분석되었다.

• Korean Chemical Engineering Research
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• 제57권5호
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• pp.730-734
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• 2019

열영동은 매질의 온도 구배에 의해 입자가 이동하는 현상이다. 본 논문에서는 미세유체 채널에서 입자의 열영동 현상에 대해서 논의한다. 흐름이 없는 비유동 채널에서 열원인 백금 와이어에 가해지는 전압에 비례해서 열영동에 의한 마이크로 입자의 이동이 더 크게 나타남을 확인하였다. 전압에 따른 백금 와이어 주변 온도 변화는 Callendar-van Dusen 식을 이용하여 예측하였다. 동일한 시스템에서 나노 입자의 열영동 현상을 관찰한 결과, 나노 입자도 마이크로 입자와 유사한 열영동 거동을 보임을 확인하였다. 마지막으로 Y 모양 미세유체 채널을 제작하고 백금 와이어 열원을 채널 내에 설치하여, 채널을 흐르는 현탁액 내의 입자의 열영동 현상을 구현하고, 이를 기반으로 현탁액의 흐름을 제어할 수 있음을 보인다.

• 문화기술의 융합
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• 제9권3호
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• pp.593-599
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• 2023

질산니켈육수화물염(nickel(II) nitrate hexahydrate) 수용액을 공업용 펄프에 함침시킨 전구체를 이용하여 세라믹스 분말을 제조하는 간단한 액상 합성법으로 산화니켈(NiO) 나노입자를 성공적으로 합성하였다. 질산니켈육수화물염 수용액이 함침된 전구체의 미세구조를 주사전자현미경(SEM)으로 확인하였고, 전구체의 열처리온도 증가에 따라 생성되는 산화니켈(NiO) 입자의 결정구조 및 입자크기를 X선회절분석(XRD) 및 SEM으로 분석하였다. 그 결과 전구체의 유기물질이 완전하게 열분해 되는 온도는 495-500℃이며, 열처리 온도의 증가에 따라 생성되는 산화니켈 입자의 크기 및 결정성이 증가하는 것을 XRD, SEM 분석을 통하여 확인하였다. 500-800℃에서 각각 1시간 동안 열처리하여 얻어진 산화니켈 입자의 크기는 50-200nm였다. 열처리 온도 380℃에서 NiO 결정상이 형성되고, 800℃까지는 NiO 단일상만 존재하며, 열처리 온도가 높아짐에 따라 생성되는 입자의 크기가 커지고 있음을 XRD 및 SEM 분석으로 확인하였다.

• 한국표면공학회지
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• 제50권3호
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• pp.212-218
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• 2017

$Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrite powders were prepared by self-propagating high temperature synthesis followed by classifying with an ultrasonic wet-magnetic separation unit to get high pure nano-sized particles. The $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ ferrites were well formed by using several powders like iron, nickel oxide, zinc oxide and magnesium oxide at 0.1 MPa of oxygen pressure. The ultrasonic wet-magnetic separation of pre-mechanical milled ferrite powders resulted in producing the powders with average size of 800 nm. The addition of a surfactant during the wet-magnetic separation process improved productivity more than twice. The coercive force, maximum magnetization and residual magnetization of the $Mg_xNi_yZn_{1-x-y}Fe_2O_4$ nano-powders with 800 nm size were 3651 A/m, $53.92Am^2/kg$ and $4.0Am^2/kg$, respectively.

• 한국세라믹학회지
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• 제42권9호
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• pp.607-612
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• 2005

The effect of MgO diluents in combustion synthesis of $TiB_2$ nano particles was investigated. The reaction $TiO_2\;+\;B_2O_3\;+\;xMg\;{\rightarrow}\;TiB_2\;+\;5MgO$ was used to synthesize $TiB_2$ nano particles. The combustion velocity was measured to examine the relation between the reaction temperature and the morphologies of particles. The diluent MgO did not react with the reactants and played a role to decrease combustion temperature. As the MgO diluents contents increased, the particles with the smaller size and the narrower size distribution were synthesized. At the condition of 6 mole of MgO, the combustion wave velocity was about 5 cm/see and the synthesized particles showed the size of 60 nm with narrow size distribution.

• 한국정밀공학회지
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• 제31권9호
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• pp.799-804
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• 2014

Hard turning is a machining process for hardened materials with high surface quality so that grinding process can be eliminated. Therefore, the hard turning is capable of reducing machining time and improving productivity. In this study, hardened AISI4140 (high-carbon chromium steel) that has excellent yield strength, toughness and wear resistance was finish turned using CBN tools. Wear characteristics of CBN tool was analyzed in dry and MQL mixed with nano-particle (Nano-MQL). The dominant fracture mechanism of CBN tool is diffusion and dissolution wear on the rake surface resulting in thinner cutting edge. Abrasive wear by hard inclusion in AISI4140 was dominant on the flank surface. Nano-MQL reduced tool wear comparing with the dry machining but chip evacuation should be considered. A cryogenically treated tool showed promising result in tool wear.

• 수산해양기술연구
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• 제51권3호
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• pp.454-460
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• 2015

The present study is undertaken to evaluate the effect of volume fraction on the results of Charpy impact test for the rubber matrix filled with nano sized silica particles composites. The Charpy impact tests are conducted in the temperature range $0^{\circ}C$ and $-10^{\circ}C$. The range of volume fraction of silica particles tested are between 11% to 25%. The critical energy release rate $G_{IC}$ of the rubber matrix composites filled with nano sized silica particles is affected by silica volume fraction and it is shown that the value of $G_{IC}$ decreases as volume fraction increases. In regions close to the initial crack tip, fracture processes such as matrix deformation, silica particle debonding and delamination, and/or pull out between particles and matrix which is ascertained by SEM photographs of Charpy impact fracture surfaces.

• KSBB Journal
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• 제28권4호
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• pp.249-253
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• 2013

In this study, we analyzed the attachment amount and the surface properties, such as shape and attachment aspect of silver nanoparticles on the surface of salt and sucrose. In addition, we investigated the antimicrobial activity of silver nanoparticles by measuring total colony counts and total coliforms in sewage according to the time and the amount of silver nanoparticles. As a result, it is found that silver nanoparticles are attached on the surface of salt and sucrose from the SEM images and there is no microorganisms on the surface of salt and sucrose. Silver nanoparticles on salt were rod shape but silver nanoparticles on sucrose were round shape. Also, the content of silver was 0.735 mg/g on salt and 0.885 mg/g on sucrose. In all experiments, total colony counts and total coliforms sharply declined initially, and it decreased gradually as change the time. When injection amount of nano silver sucrose and salt increased, the width of decline was greater. The amount of total colony counts and total coliforms of nano silver salt was much lower and the disinfection efficiency was higher comparing with nano silver sucrose. That means the case of nano silver salt is much better at the antimicrobial activity.

• 설비공학논문집
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• 제18권7호
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• pp.549-555
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• 2006

In the present study, sterilizing and antibacterial performance tests of Polybutylene pipe with nano-silver were carried out in the testing bench of water supply facilities. Experimental results show that the average sterilizing and antibacterial rate of two micro-biological samples such as E. coli and S. aureus is about 90% in case of stillness experimental condition and 99% in case of flowing experimental condition, when elapsed time is 120 hours and 3 hours, respectively. Experimental results also show that the supply water velocity in nano-silver Polybutylene pipe varies from 1 m/s to 1.5 m/s, the elapsed time needed sterilizing rate reach to 100% decreases.

• 한국분말재료학회지
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• 제15권2호
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• pp.148-155
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• 2008

Nano magnetite particles have been prepared by two step reaction consisting of urea hydrolysis and ammonia addition at certain ranges of pH. Three different concentrations of aqueous solution of ferric ($Fe^{3+}$) and ferrous ($Fe^{2+}$) chloride (0.3 M-0.6 M, and 0.9 M) were mixed with 4 M urea solution and heated to induce the urea hydrolysis. Upon reaching at a certain pre-determined pH (around 4.7), 1 M ammonia solution were poured into the heated reaction vessels. In order to understand the relationship between the concentration of the starting solution and the final size of magnetite, in-situ pH measurements and quenching experiments were simultaneous conducted. The changes in the concentration of starting solution resulted in the difference of the threshold time for pH uprise, from I hour to 3 hours, during which the akaganeite (${\beta}$-FeOOH) particles nucleated and grew. Through the quenching experiment, it was confirmed that controlling the size of ${\beta}$-FeOOH and the attaining a proper driving force for the reaction of ${\beta}$-FeOOH and $Fe^{2+}$ ion to give $Fe_3O_4$ are important process variables for the synthesis of uniform magnetite nanoparticles.