• Title/Summary/Keyword: Nano 입자

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Formation and Characterization of Red Phosphor Nano Powders (적색 형광체 나노 분말의 합성 및 특성 평가)

  • You, Young Chul;Kim, Ki Do;Lim, Hyung Sup;Kim, Hee Taik
    • Applied Chemistry for Engineering
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    • v.19 no.1
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    • pp.27-30
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    • 2008
  • Nano-sized phosphor powders were synthesized by the liquid phase method to confirm the size and morphology. By using the process, red phosphor particles with a size of 80 nm were obtained. The characteristic comparison of $Y_2O_3:Eu^{3+}$ and $YBO_3:Eu^{3+}$ was carried out and, as a result, $YBO_3:Eu^{3+}$ powders using boric salt showed an aggregated morphology and lower PL performance compared to $Y_2O_3:Eu^{3+}$.

Preparation of TiO2:Fe,V nanoparticles by flame spray pyrolysis and photocatalytic degradation of VOCs (화염분무열분해법을 이용한 TiO2:Fe,V 나노분말의 제조 및 VOCs 분해 특성)

  • Chang, Han Kwon;Jang, Hee Dong;Kim, Tae-Oh;Kim, Sun Kyung;Choi, Jin Hoon
    • Particle and aerosol research
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    • v.5 no.1
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    • pp.1-7
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    • 2009
  • Fe- and V-doped titanium dioxide nanoparticles consisting of spherical primary nanoparticles were synthesized from a mixed liquid precursor by using the flame spray pyrolysis. The effects of dopant concentration on the powder properties such as morphology, crystal structure, and light adsorption were analyzed by TEM, XRD, and UV-Vis spectrophotometer, respectively. As the V/Ti molar ratio increased, pure anatase particles were synthesized. On the contrary, rutile phase particles were synthesized as the Fe/Ti ratio increased. Photocatalytic property of as-prepared $TiO_2:Fe,V$ nanoparticles was investigated by measuring the removal efficiency for volatile organic compounds (VOCs) under the irradiation of visible light. After 2 hrs under visible light, the removal efficiencies of benzene, p-xylene, ethylbenzene, and toluene were reached to 21.9%, 21.4%, 19.8% and 17.6% respectively.

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Analysis of Nano-particle and Emissions Characteristics for FTP75 Mode in LPLi Vehicle (FTP75 모드에 의한 LPG액상분사자동차의 배출가스 및 나노입자배출특성)

  • Lee, Ho-Kil;Kim, Yong-Tae
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.2
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    • pp.161-167
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    • 2009
  • The regulation of the $CO_2$ emit from vehicles have become much more stringent in recent years. This stringent regulation is more request vehicle manufacturers to develop the alternative fuel vehicles for reducing exhaust emissions. LPG fuel is more clean energy compares with gasoline and diesel fuel. Especially, $CO_2$ emission of LPG Vehicle is less than gasoline vehicle and almost equal to diesel vehicle. For this reason, recently korean government is extending LPG fuel for hybrid car and light duty vehicle. In domestic, Propane is mixing $15{\sim}30%$ to butane for improvement of cold start at winter season. Therefore, In this paper was investigated that the characteristics of emissions according to propane mixing rate with 0, 10, 20, 30% were compared and analyzed by the vehicle test using LPG vehicle according to the FTP75 mode. It was also investigated the characteristics of nano-particle emit with propane mixing rate.

Inhibition effect of silica nanoparticle on the oxygen uptake rate of activated sludge (실리카 나노입자에 의한 활성슬러지 활성도 저해 효과 분석)

  • Lee, Soo Mi;Cho, Jin Woo
    • Journal of Korean Society of Water and Wastewater
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    • v.28 no.1
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    • pp.47-54
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    • 2014
  • Nanotechnology has become one of the fastest developing technologies and recently applied to a variety of industries. Thus, increasing number of nano materials including various nanoparticles would be discharged into wastewater and consequently entering a biological wastewater treatment process. However, the impact of the nano particles on biological wastewater treatment has not been estimated intensively. In this research, we investigated the effect of silica nanoparticle on the oxygen uptake rates (OURs) of activated sludge used in a conventional wastewater treatment process. The inhibition (%) values were estimated from the results of OURs experiments for the silica nanoparticles with various sizes of 10-15, 45-50, and 70-100 nm and concentrations of 50, 250, and 500 ppm. As results, the inhibition value was increased as the size of silica nano particles decreased and the injected concentration increased. The maximum inhibition value was investigated as 37.4 % for the silica nanoparticles with the size of 45-50 nm and concentration of 50 ppm. Additionally, the effect of size and concentration on the inhibition should be considered cautiously in case that the aggregation of particles occurred seriously so that the size of individual particles was increased in aquatic solution.

Classification and Condensation of Nano-sized Airborne Particles by Electrically Tuning Collection Size (포집크기의 전기적 튜닝 기술을 이용한 나노크기의 공기중 입자 분류 및 수농도 응축)

  • Kim, Yong-Ho;Kwon, Soon-Myoung;Park, Dong-Ho;Hwang, Jung-Ho;Kim, Yong-Jun
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1874-1879
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    • 2008
  • It is not easy to detect nano-sized airborne particles (< 100 nm in diameter) in air. Therefore, the condensation of the nanoparticles alongside of the size-classification is needed for their detection. This paper proposes a hybrid (aerodynamic+electrical) particle classification and condensation device using a micro virtual impactor (${\mu}VI$). The ${\mu}VI$ can classify the nanoparticles according to their size and condense the number concentration of nanoparticles interested. Firstly, the classification efficiency of the ${\mu}VI$ was measured for the particles, polystyrene latex (PSL), ranging from 80 to 250 nm in diameter. Secondly, the nanoparticles, NaCl of 50 nm in diameter, were condensed by 4 times higher. In consequence, the output signal was amplified by 4 times (before condensation: 4 fA, after condensation: 16 fA). It is expected that the proposed device will facilitate the detection of nanoparticles.

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Dielectric Characteristics of the Polymers Containing Nano-size Conductive Carbon Black Powders (전도성 나노 카본 블랙을 함유한 고분자 재료의 유전특성)

  • 진우석;이대길
    • Composites Research
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    • v.17 no.5
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    • pp.68-77
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    • 2004
  • The electromagnetic (EM) absorption or shielding characteristics of a material is an important issue not only for military purpose but also for commercial purposes such as radar, electric or telecommunication devices. In order to design the effective electromagnetic wave absorber, the electromagnetic characteristics of the constituents of the material should be available in target frequency band. Also, it must be possible to predict the electromagnetic properties of absorbers with respect to the content of lossy ingredients. In this study, the dielectric properties of unsaturated polyester resins containing nano-size conductive carbon black powder were measured with a free space method in the X-band frequency range and analyzed with respect to the content of carbon black. Finally, the method for estimating the dielectric properties of polymeric resin containing conductive carbon black with respect to the EM frequency was developed and verified.

Formation and Characterization of Green and Blue Phosphor Nano Powders (녹색과 청색 형광체 나노 분말의 합성 및 특성 평가)

  • Kwon, Oh Sung;You, Young Chul;Kim, Sang Min;Kim, Ki Do;Lim, Hyung Sup;Kim, Hee Taik
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.565-569
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    • 2009
  • Nano-sized green and blue phosphor powders were synthesized by liquid phase method to confirm the size and morphology. By using that process, the particle sizes of green and blue phosphor particles were 80 nm and 60 nm, respectively. The characteristic comparison of $Zn_2SiO_4$ : Mn and BAM : Eu was carried out and as a result, $Zn_2SiO_4$ : Mn powders showed an higher PL performance compared to BAM : Eu.

Effects of Particle Measuring Conditions on Diesel Nanoparticles Distribution (입자측정조건이 디젤 나노입자의 입경분포에 미치는 영향)

  • Lee, Jin-Wook;Kim, Hong-Suk;Jeong, Young-Il
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.5
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    • pp.653-660
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    • 2006
  • Due to the stronger exhaust emission regulations and the introduction of advanced technology in Diesel engine, the specific Diesel particulate matters have decreased by about one order of magnitude since the 1980's. In recent years, particle number emissions rather than particulate mass emissions have become the subject of controversial discussions. Recent results from health studies imply that it is possible that particulate mass does not properly correlated with the variety of health effects attributed to Diesel exhaust. Concern is instead now focusing on nano-sized particles. This study has been performed for the better understanding about the Diesel nano-particle measurement and size distribution characteristics in the exhaust system of a turbo charged Diesel engine. A scanning mobility particle sizer(SMPS) system was applied to measure the particle number and size concentration of Diesel exhaust particles. As the experimental results, the number concentrations in the particle size (Dp<200 nm) were very sensitive to dilution conditions. Specially the changes in nano-particle number concentrations(Dp<50 nm) increased along the downstream of exhaust flow. Also we found the dilution conditions were influencing the condensation of SOF and $H_2O$ during dilution and cooling of hot exhaust.

Effect of ZnO Nano Particles on Thermal Stabilization of Polymers (고분자에 대한 산화아연(ZnO) 나노입자의 열안정화 효과)

  • ;;;R. W. Siegel;L. S. Schadler
    • Proceedings of the Korean Fiber Society Conference
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    • 2002.04a
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    • pp.171-172
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    • 2002
  • 나노미터 규모의 작은 충전제 입자는 마이크로 미터 규모의 일반적인 충전제 입자에 비해서 많은 다른 점이 발견되어 왔다. 이 연구에서는 최근에 알게된 입경이 100nm 이하인 ZnO 입자가 radical 중합된 고분자의 열안정성을 향상시키는 현상을 보다 자세하게 연구한 것이다. HDPE, LDPE, LLDPE, PP 및 PS를 열분해가 아주 느리게 일어나는 낮은 RPM으로 Haake사의 Torque Rheometer의 internal mixer 안에서 녹인 후 평균입경 49nm인 ZnO 나노입자를 약4분간 충부히 분산되도록 혼합하고 50 RPM으로 혼합속도를 높여서 시간에 따른 Trque의 변화를 측정하므로써 열안정성 효과를 관찰하였다. (중략)

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Improvement of Biological activities of Acer mono and Acer okamotoanum Saps by Nano-encapsulation Process (나노입자화 공정을 이용한 고로쇠 및 우산고로쇠 수액의 유용생리활성 증진)

  • Jeong, Myoung-Hoon;Ha, Ji-Hye;Oh, Sung-Ho;Kim, Seung-Seop;Jin, Ling;Lee, Hak-Ju;Kang, Ha-Young;Prak, Uk-Yeon;Lee, Hyeon-Yong
    • Journal of Korean Society of Forest Science
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    • v.98 no.4
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    • pp.399-408
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    • 2009
  • We investigated the improvement of immuno-modulatory activities of sap of Acer mono and A. okamotoanum encapsulated with edible polymers. Anticancer activities and immune activities such as human B and T cell growth, secretion of cytokines and natural killer cell growth were observed. Both human immune B and T cells were increased up to 30~50% by the addition of nano particle sap of Acer mono and A. okamotoanum. The secretion of Interleukin-6 (IL-6) and Tumor necrosis factor-a (TNF-a) from human immune B and T cells were also significantly increased compare to the control. Natural Killer (NK) cell growth was enhanced to $19.4{\times}10^5$ cells/mL in adding nano encapsulated sap of A.okamotoanum. The cytotoxicity of the sample on normal human lung cell (HEL299) was below 19.8% in adding 1.0 mg/mL of the nano particle sap of A. okamotoanum. Generally, the growth of all three human lung adenocarcinoma, human stomach adenocarcinoma and human liver adenocarcinama was inhibited up to 85% in adding 1.0 mg/mL of the encapsulated sap. Interestingly enough, the encapsulated sap was completely penetrated into human cancer cells within 30 min after addition. It showed that the encapsulation of the sap definitely increased its biological activities, which can expand its use to wide range of food industries.