• 제목/요약/키워드: NaCl solution

검색결과 1,388건 처리시간 0.028초

염분농도변화에 따른 TMCP강의 부식피로강도에 관한 실험적 연구 (An Experimental Study on Corrosion Fatigue Strength of TMCP Steel in Consideration of NaCl Salinity)

  • 강성원;김철현;이해우
    • 대한조선학회논문집
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    • 제40권3호
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    • pp.54-60
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    • 2003
  • Fatigue strength of offshore structures or ship structures is significantly decreased due to corrosive environment condition such as sea water and/or coal, crude oil of cargoes, compared to that of on shore structures. In corrosive environment, fatigue strength of structures also depends on characteristics of weld material heat affected zone(HAZ). In this research work, rotary bending fatigue tests of parent material and HAZ of TMCP steel were performed in order to investigate the initiation and propagation of cracks both in air and in NaCl solution. Comparison of fatigue strength In relation with the salinity of NaCl were carried out as well. According to the test results weld material or HAZ of TMCP steel showed higher fatigue strength than that of the parent material. The fatigue strength of TMCP steel decreases drastically in NaCl solution compared to that of in air environment. In particular, more reduced fatigue strength is observed in 1% NaCl solution than in 3% NaCl solution.

산과 염이 폴리에스터 직물의 알칼리 감량에 미치는 영향 (Effect of Acid and Salt on Weight toss of Polyester (PET) fabric by Sodium Hydroxide)

  • 도성국;조환
    • 한국염색가공학회지
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    • 제4권3호
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    • pp.65-73
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    • 1992
  • To control the hydrolysis rate of PET fabric with NaOH, HCl and $CH_3$COOH(HAc), as regulating reagent, were added to the 0.5 M NaOH solution. The concentrations of acids in 0.5 M NaOH were varied. PET fabrics were treated with aqueous solutions of acids in 0.5 M NaOH under different conditions. The weight loss of PET fabric, the rate of hydrolysis, the apparent activation energy (E$_{\alpha}$), the handle value, the etched surface of treated PET fabric, and the effect of salts such as NaCl, $CH_3$COONa(NaAc), and NH$_4$Cl on the weight loss were discussed. Acids in the aqueous 0.5 M NaOH solution decreased the weight loss of PET fabric bacause of neutralization of OH- and the weight loss of PET fabrics treated with corresponding concentration of aqueous NaOH solution to the concentrations of the aqueous solutions of acids in 0.5 M NaOH was lower than that of PET fabrics treated with aqueous solutions of acids in 0.5 M NaOH. The addition of NaCl to aqueous NaOH solution accelerated the reaction of OH- with PET greatly, the addition of NaAc increased the weight loss slightly, but the addition of NH$_4$Cl decreased the weight loss. It was thought that the very remarkable result that NaCl in aqueous NaOH solution promoted the hydrolysis of PET with NaOH would contribute to the conservation of energy and NaOH in the weight loss finishing process of PET fabric. The etched surface and the handle value of treated PET fabric were independent of the difference in the kinds of acids and salts added.nd salts added.

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RuO2를 양전극으로 사용한 무격막 전해셀에서의 이산화염소수 제조 (Preparation of Chlorine Dioxide Aqueous Solution by Un-divided Electrochemical Cell using RuO2 anode)

  • 권태옥;박보배;노현철;문일식
    • 공업화학
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    • 제20권3호
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    • pp.296-300
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    • 2009
  • $RuO_2/Ti$를 양전극으로 사용한 무격막 전해셀(un-divided electrochemical cell) 시스템에서의 이산화염소수($ClO_2$) 제조 연구를 수행하였다. 이산화염소의 전구체로는 아염소산나트륨($NaClO_2$)이 사용되었으며, 무격막 전해셀에서 전구체 용액의 전해셀 주입유량, 전구체 용액 초기 pH, 아염소산나트륨과 전해질인 염화나트륨의 주입농도 그리고 전류밀도(current density)가 생성된 이산화염소수의 농도 및 pH에 미치는 영향을 조사하였다. 생성된 이산화염소수의 농도와 pH는 초기 전구체 용액의 pH와 전해셀 주입유량에 큰 영향을 받는 것으로 나타났으며, 전해질로 사용된 염화나트륨은 전해질로서의 역할 뿐만 아니라 이산화염소의 전구체로도 작용함을 알 수 있었다. 이산화염소수 제조를 위한 무격막 전해셀에서의 전구체용액의 최적 주입유량은 90 mL/min, 전구체 용액의 초기 pH는 2.3, 아염소산나트륨 주입농도는 4.7 mM, 염화나트륨 주입농도는 100 mM 그리고 전류밀도는 $5A/dm^2$로 나타났으며, 이때 발생된 이산화염소수의 pH는 약 3, 이산화염소 농도는 약 350 mg/L이었다.

염지액농도, 염지시간 및 염지압력에 따른 계란의 염 침투효과 (Permeation Effect of NaCl into Shell Egg with Concentration of NaCl Solution, Salting Time and Salting Pressure)

  • 전기홍;유익종;장윤희;강통삼
    • 한국가금학회지
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    • 제20권3호
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    • pp.125-131
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    • 1993
  • 본 시험은 계란의 껍질을 파괴하지 않고 적절한 압력을 이용하여 적절한 농도의 염지액이 단시간 내에 계란의 난백 및 난황층으로 이동되어 염분이 가미된 계란을 제조한 다음 이를 열처리 과정을 거쳐서 반숙 또는 완숙된 계란으로 제조하거나 또는 열처리하지 않은 가염된 생계란을 제조하여 편리하게 식용할 수 있는 계란의 가미 가공방법에 관한 것이다. 염지계란의 염도에 영향을 주는 요소는 염지액 농도(0~40%, wt/vol), 염지시간(O~45h), 그리고 염지압력(O~4.5kg/$\textrm{cm}^2$) 등으로 이들 조건에 따른 계란의 소금 험하였다. 계란의 소금농도는 염지액농도, 염지시산, 염지압력에 비례하여 증가하는 경향을 보였으며 처리구 중 난백내에서 0.70~l.00%, 그리고 난황내에서 0.40~0.45%가 가장 바람직한 염농도임을 알 수 있었다. 한편 염지계란의 품질을 측정하기 위한 관능검사는 염지액농도(20~40%) 염지시간(12~20h), 그리고 염지압력(3~4.5kg/$\textrm{cm}^2$)에서 가장 우수한 결과를 보였다. 위 시험의 결과, 염지계란을 제조하는 조건으로 염지액농도 30%, 염지시간 16h 그리고 염지압력 4.0kg/$\textrm{cm}^2$에서 가장 우수한 결과를 보였다.

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EPDM 소재의 수용액으로부터의 외관 오염 (Appearance Contamination of EPDM Article from Water Solution)

  • 최성신;정혜승;주용태;양경모;이성훈
    • Elastomers and Composites
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    • 제45권2호
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    • pp.100-105
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    • 2010
  • EPDM 소재를 공기 중, 수돗물, 3차 증류수, NaCl/$CaCl_2$ 혼합 수용액, $CaCl_2/FeCl_3$ 혼합 수용액에서 7일간 노화시켰다. 노화 온도는 $90^{\circ}C$였다. 공기와 3차 증류수에서 노화된 시험편은 백화가 발생하지 않았으나, 수돗물, NaCl/$CaCl_2$ 혼합 수용액, $CaCl_2/FeCl_3$ 혼합 수용액에서 노화된 시험편은 백화가 발생하였다. 백화 물질을 규명하기 위해 GC/MS를 이용하여 가용성 유기물을 분석하였으며, 영상 분석기와 SEM을 이용하여 표면 형태를 조사하였으며, EDX를 이용하여 표면 적층물의 원소 분석을 실행하였다. 백화의 주요 원인으로는 금속 이온과 지방산과의 반응에 의한 지방산 금속염의 형성을 들 수 있다.

호 알칼리성 Alcaligenes sp.가 생산하는 ${\gamma}$-Polyglutamic Acid의 용액 특성 (Solution Properties of ${\gamma}$-Polyglutamic Acid Produced by Alkalophilic Alcaligenes sp.)

  • 이신영;강태수김갑수
    • KSBB Journal
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    • 제10권4호
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    • pp.386-392
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    • 1995
  • The high viscous ${\gamma}$-polyglutamic acid(${\gamma}$-PGA) from alkalophilic Alcaligenes sp. was purified and its solution property was investigated. The intrinsic viscosities for Na+ form and H+ form of ${\gamma}$-PGA were 31.1 and 0.38d$\ell$/g, respectively. The viscosity of H+-PGA was not influenced by pH or salts while that of Na+-PGA was influenced. The intrinsic viscosity of Na+-PGA solution decreased remarkably at the alkaline or acidic pH and showed the sharp decrease when salts were added. ${\gamma}$-PGA exhibited the property of the polyelectrolyte showing the .sharp decrease of intrinsic viscosity by the addition of NaCl, and intrinsic viscosity of dilute solution with the low concentration of NaCl was exponentially dependent on temperature and its temperature dependency increased with increasing NaCl concentration. The chain stiffness, coil overlap parameter and critical concentration of Na+-PGA were 0.08, 5.25 and 0.07g/d$\ell$, respectively.

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Effect of Different Conditions of Sodium Chloride Treatment on the Characteristics of Kenaf Fiber-Epoxy Composite Board

  • SETYAYUNITA, Tamaryska;WIDYORINI, Ragil;MARSOEM, Sri Nugroho;IRAWATI, Denny
    • Journal of the Korean Wood Science and Technology
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    • 제50권2호
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    • pp.93-103
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    • 2022
  • Currently, biofibers are used as a reinforcement in polymer composites for structural elements and construction materials instead of the synthetic fibers which cause environmental problems and are expensive. One of the chemicals with a pH close to neutral that can be potentially used as a modified fiber material is sodium chloride (NaCl). Therefore, this study aims to investigate the characteristics of a composite board made from NaCl-treated kenaf fiber. A completely randomized design method was used with consideration of two factors: the content of NaCl in the treatment solution (1 wt%, 3 wt%, and 5 wt%) and the duration of immersion of fibers in the solution (1 h, 2 h, and 3 h). The NaCl treatment was conducted by soaking the fibers in the solution for different durations. The fibers were then rinsed with water until the pH of the water reached 7 and subsequently dried inside an oven at 80℃ for 6 h. Kenaf fiber and epoxy were mixed manually with the total loading of 20 wt% based on the dry weight of the fiber. Physical and mechanical properties of the fibers were then evaluated based on JIS A 5908 particleboard standards. The results showed that increasing NaCl content in the fiber treatment solution can increase the physical and mechanical properties of the composite board. The properties of fibers treated with 5 wt% NaCl for 3 h were superior with a modulus of elasticity of 2.085 GPa, modulus of rupture of 19.77 MPa, internal bonding of 1.8 MPa, thickness swelling of 3%, and water absorption of 10.9%. The contact angle of untreated kenaf fibers was 104°, which increased to 80° and 73° on treatment with 1 wt% and 5 wt% NaCl for 3 h, respectively.

AA1100의 부식에 미치는 Na2S, NaCl, H2O2 농도의 영향 (Effects of Na2S, NaCl, and H2O2 Concentrations on Corrosion of Aluminum)

  • 이주희;장희진
    • Corrosion Science and Technology
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    • 제18권6호
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    • pp.312-317
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    • 2019
  • The objective of this study was to investigate the corrosion behavior of aluminum (AA1100) in a mixed solution of 0 ~ 0.1 g/L Na2S + 0.3 ~ 3 g/L NaCl + 0 ~ 10 mL/L H2O2. Potentiodynamic polarization tests were performed. Effects of solution compositions on corrosion potential, corrosion rate, and pitting potential of aluminum were statistically analyzed with a regression model. Results suggested that localized corrosion susceptibility of aluminum was increased in the solution with increasing concentration of NaCl because the pitting potential was lowered linearly with increasing NaCl concentration. On the contrary, H2O2 mitigated the galvanic corrosion of aluminum by increasing the corrosion potential. It also mitigated localized corrosion by increasing the pitting potential of aluminum. Na2S did not exert a noticeable effect on the corrosion of aluminum. These effects of different chemical species at various concentrations were independent of each other. Synergy or offset effect was not observed.

Corrosion Behavior of Rapidly Solidified Mg-Zn-Y Alloys in NaCl Solution

  • Izumi, Shogo;Yamasaki, Michiaki;Sekigawa, Takahiro;Kawamura, Yoshihito
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
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    • pp.1043-1044
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    • 2006
  • Compositional dependence of corrosion behavior of rapidly solidified Mg-rich Mg-Zn-Y alloys in NaCl aqueous solution has been investigated. Mg-Zn-Y ternary alloys containing small amounts of Zn exhibited low corrosion rate, although the $Mg_{98}Y_2$ (at. %) binary alloy showed severe corrosion with violet evolution of hydrogen. The alloy with highest corrosion-resistance was $Mg_{97.25}Zn_{0.75_Y_2$, its corrosion rate was about 1 mm year-1 in 0.17 M (1.0 wt. %) NaCl solution. $Mg_{97.25}Zn_{0.75}Y_2$ alloy exhibited passive region in anodic polarization curves when immersed in NaCl solution. Rapidly solidification and small amount of Zn addition may bring about an increase in electrochemical homogeneity of Mg-Zn-Y alloys, resulting in enhancement of corrosion resistance.

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조리방법에 따른 채소류의 품질 변화 (Quality Changes of Vegetables by different Cooking Methods)

  • 김병철;황진영;우현정;이세미;조형용;유영미;신해헌;조은경
    • 한국조리학회지
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    • 제18권1호
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    • pp.40-53
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    • 2012
  • $90^{\circ}C$의 물, 0.5% NaCl 용액, 1.0% Nacl 용액, $400^{\circ}C$ 과열수증기 등을 사용하여 가열 조리한 오이, 애호박, 당근, 무, 양파 등의 채소류의 품질변화를 살펴보았다. 가열에 의한 채소류의 pH는 증가하는 경향을 보였다. 가열조리한 채소류의 색 변화를 Hunter 색차계를 사용하여 L값(밝기), a값(적색도), b값(황색도)을 측정한 결과 $400^{\circ}C$ 과열수증기로 30초간 처리한 채소류의 색변화가 $90^{\circ}C$의 물, 0.5% NaCl 용액, 1.0% Nacl 용액에서 처리한 것보다 L값(밝기), a값(적색도), b값(황색도)등의 변화가 적어 변색이 적게 일어난 결과를 나타내었다. 채소류에 존재하는 오염 미생물은 $400^{\circ}C$ 과열수증기로 30초간 처리한 채소류에서 매우 효과적으로 생육이 억제되었다. 가열조리에 의한 비타민C의 함량 변화는 조리방법과 채소류의 종류에 따라 비타민C 잔존율에 차이가 있었다. 고온의 과열수증기를 이용한 단시간 조리법은 $900^{\circ}C$의 물, 0.5% NaCl 용액, 1.0% NaCl 용액 등에서 처리한 일반 가열조리법에 비하여 pH, 색, 세포연화, 비타민C 감소율 등의 변화가 적게 나타났다. 본 논문의 연구 자료는 앞으로 진행될 가정 대용식(HMR, Home Meal Replacement)의 개발에 이용될 것이다.

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