• Proceedings of the KSME Conference
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• 2008.11b
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• pp.1967-1972
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• 2008

Reburning is an efficient combustion technology to reduce nitrogen oxide by injecting hydro-carbon fuel to the downstream of the main combustion. In this paper LPG has been used not only as main fuel but also as reburn fuel and air was used as an oxidizer with 15kW swirl burner. Experimental studies have been done to evaluate effect of reburning for NOx reduction. Also to examine the effect of the amount of burnout air for complete combustion by reburn fuel on NOx reduction, test was conducted by reducing the amount of burnout air. Computational fluid dynamic (CFD) simulation was performed using the commercial CFD code FLUENT 6.3 to simulate experimental results and investigate the thermo-chemical characteristics. An evaluation of reaction models for swirl burner has been carried out for propane-air with two step finite-rate eddy-dissipation model in FLUENT.

• 한국연소학회:학술대회논문집
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• 2004.06a
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• pp.227-234
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• 2004

For gaseous fuel combustion with inherent $CO_2$ capture and low NOx emission, chemical-looping combustion(CLC) may yield great advantages of savings of energy to $CO_2$ separation and suppressing the effect on environment. In chemical-looping combustor, fuel is oxidized by metal oxide medium (oxygen carrier particle) in a reduction reactor. Reduced particles are transported to oxidation reactor and oxidized by air and recycled to reduction reactor. The fuel and the air are never mixed, and the gases from reduction reactor, $CO_2$ and $H_2O$, leave the system as separate stream. The $H_2O$ can be easily separated by condensation and pure $CO_2$ is obtained without any loss of energy for separation. The purpose of this study is to demonstrate inherent $CO_2$ separation and no NOx emission and to confirm high $CO_2$ selectivity, no side reaction (i.e., carbon deposition, hydrogen generation) by continuous reduction and oxidation experiment in a 50kWtb chemical-looping combustor. NiO/bentonite particle was used as a bed material and $CH_4$ and air were used as reacting gases for reduction and oxidation respectively.

• Advances in concrete construction
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• v.11 no.4
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• pp.307-314
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• 2021

Activated hwangtoh (ACT) is a natural resource abundant in South Korea, approximately 15.0% of soil. It is an efficient mineral admixture that has activated pozzolanic properties through high-temperature heating and rapid cooling. The purpose of this study is to improve a curb mixture that can reduce NOx outside and investigate durability performance. To this end, mortar curb specimens were manufactured by replacing OPC with ACT. The ACT substitution ratios of 0.0, 10.0, and 25.0% were considered, and mechanical and durability tests on the curb specimens were conducted at 28 and 91 days of age. Steam curing was carried out for three days for the production of curbs, which was very effective to strength development at early ages. The reduction in strength at early ages could be compensated through this process, and no significant performance degradation was evaluated in the tests on chloride attack, carbonation, and freezing and thawing. The mortar curb with an ACT of 10.0~25.0% replacement ratio exhibited clear NOx reduction through photocatalytic (TiO2) treatment. This is due to the increase in physical absorption through surface absorption and the photocatalyst-containing TiO2 coating. In this study, the reasonable range of the ACT replacement ratio for NOx reduction was quantitatively evaluated through a comprehensive analysis of each test.

• 한국연소학회:학술대회논문집
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• 2012.11a
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• pp.39-41
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• 2012

The influence of coal blending methods such as out-furnace (external or pre-mixed) blending and in-furnace (initially non-mixed) blending with different excess oxygen (highest, medium, and lowest stoichiometric conditions) on unburned carbon and NOx emissions of blend combustion in an entrained flow reactor (EFR) has been analyzed, using experimental and numerical approaches for binary coals used by Korean power plants. The results confirm that under the medium condition, contrasting processes such as reactive and un-reactive effects occur with SBRs in the out-furnace blending method. The in-furnace blending method results in an improvement in the efficiency of unburned carbon fractions and a further reduction in the NOx emission. Under the highest condition, the unburned carbon fraction in both the out-furnace and the in-furnace blending methods corresponds with the tendency under the medium condition with contrasting processes of lower magnitude, whereas the NOx emission in the highest condition increases slightly. Under the lowest conditions, the unburned carbon fraction in the out-furnace blending method gradually decreases as SBR decreases, without a competition effect. The reduction of NOx emission under the lowest conditions is more effective than those under other conditions for the two blending methods because of a homogeneous and heterogeneous NOx reduction mechanism.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.5
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• pp.693-700
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• 2006

The important factor for the development of burner is the achievement of low emissions with maintaining combustibility. In case of maintaining high temperature flame and excess air to increase the combustibility, it is possible to achieve high combustion efficiency, due to the reduction of UHC(unborn hydrocarbon), carbon monoxide and soot. However, it is difficult to reduce the thermal NOx produced in the high temperature flame. To solve this problem, we developed externally oscillated oil burner which is possible for the high efficiency combustion and low NOx emission, simultaneously. The experiment of flame characteristics and NOx reduction were achieved according to the variation of frequency, amplitude and air velocity. Frequency, amplitude and air velocity are the most important parameter. The optimum operating conditions are frequency 1,900 Hz, amplitude 3 $V_{pp.}$ and air velocity 6.8 m/s. Reduction of NOx and CO are 47% and 22%, respectively.

• 한국연소학회:학술대회논문집
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• 1999.10a
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• pp.149-154
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• 1999

The influences of air staging on NOx emission and burnout of coal flames were investigated using 1MWth combustion test facility. The experiments showed that variation of overall excess air ratio led to a relatively higher NOx emission level for ${\lambda}=1.2.$ When air staging was applied to the combustion air, it was confirmed that a fuel rich primary combustion zone was established and unburned char was burened completely by mixing with the staged air supplied radially around the flame. The NOx emissions were redued by increasing the staged air flow rate, and staging air was suggested to be more than 40% of the total combustion air for the substantial NOx reduction.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.6
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• pp.645-653
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• 2005

The effects of a WI(Water Injection) at the intake Pipe and an urea injection at the exhaust pipe for a 4-cylinder DI(Direct Injection) diesel engine were investigated experimentally The water quantity was controlled by temperature of intake manifold and MAF(Manifold Air Flow). In addition, the urea quantify was controlled by NOx quantify and MAF. Effects of WI system, urea-SCR system and tandem system were investigated for with and without EGR(Exhaust Gas Recirculation). As the results. the SUF(Stoichiometric Urea Flow) and NOx map were obtained. In addition, NOx results can be visualized with engine speed and engine load. It was concluded. therefore, that the NOx reduction effects of the tandem system without the EGR were more than those with the EGR base engine.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 1997.04a
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• pp.30-34
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• 1997

This paper Describe a modelling method for SCR(selective Catalytic reduction) system in refuse incineration plant. We consider the SCR system as a single input single output system. For modelling the SCR system, an auto regressive exogeneous(ARX) modelling method is used. In this case, we should design the white noise input for modelling and put it on the system as an input (.NH/sap2/.), and taken an outlet NOx as an output. From these two relations, we design the ARX model with 45 second delay time and transform to discrete system with 0.5 sampling time. Using the obtained SCR model, we simulate the SCR system to reduce the outlet NOx content by a conventional PID control method.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.876-885
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• 2018

Utilization of spent RHDM(Residue Hydrodemetallation) catalyst as de-NOx SCR(Selective Catalytic Reduction) catalyst was studied by conducting by heptane cleaning and high-temperature roasting for removal of deposited carbon and sulfur. Followed by oxalic acid leaching was carried out for controlling excess vanadium deposited on spent RHDM catalyst in search of appropriate vanadium loadings for the best SCR performance and the leaching conditions are 5~15wt% concentration of oxalic acid and 5min leaching time at $50^{\circ}C$ with the ultra-sonic agitator. De-NOx activities of prepared and commercial SCR catalyst were measured by the atmospheric SCR catalyst performance test unit, their residual content were also carried out by ICP, C&S Analysis and XRF. Acid leaching (AL-10) catalyst showed the highest de-NOx efficiency of all prepared catalysts and the de-NOx efficiency over wash coated catalyst(WC-AL-10) was equivalent to that of commercial SCR catalyst. Therefore the possibility of using as SCR catalyst for each application by adjusting treatment conditions of spent RHDM catalyst was found and further research will be needed in detail for the its commercialization.

• Journal of the Korean Society for Marine Environment & Energy
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• v.6 no.3
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• pp.16-25
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• 2003

In this paper, the reduction of green house effect gas CO₂ emission and NOx gas emission by using the RORO ship coastal transport of import-export container cargo was investigated. At first, the domestic CO₂ gas emission and the transportation of import-export container cargo were Investigated. Next, the characteristic of a RORO ship and CO₂ emission standard and NOx emission standard were investigated. And also, the reduction of CO₂ emission and NOx emission by the shift of coastal transport from land transport for the transportation of import-export container cargo between Kyongin area and Pusan Port were calculated. Finally, the change of CO2 and NOx gas emission due to the change of the share of coastal transportation and the load efficiency of RORO ship are investigated. The research results show that the shift of RORO ship coastal transport from land transport was very effective to reduce the CO₂ emission but it was no good to reduce the NOx emission.