• Title/Summary/Keyword: NOx Concentration

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NOx Gas Detecting Properties of the Nitrocellulose/MWCNT Thin Film Coated on the Glass Substrate (유리 기판 위에 제작된 Nitrocellulose/MWCNT 박막의 질소가스 검출특성)

  • Lee, Won Jae;Choi, Myung Kyu;Jang, Kyung Uk
    • Journal of the Semiconductor & Display Technology
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    • v.11 no.1
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    • pp.55-59
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    • 2012
  • NOx is one of the toxin gases, which is mainly causing the optic-chemical smog phenomena, and decreasing in the function of nose and taste. Especially, NO is easily reacting with $O_3$, and then becoming the $NO_2$. $NO_2$ is mainly causing the acidulation rain. So, we should develop the NOx gas sensing system to detect NOx gas. In this paper, we present the microstructure and the NOx gas detecting properties of the nitrocellulose/MWCNT thin film coated by the air-spray on the glass substrate. The nitrocellulose/MWCNT-based gas sensors have been studied detecting NOx molecules of a ppm-level at the temperature range of $30{\sim}120^{\circ}C$. The resistance of the sensors decreases when the sensors are exposed to NOx gas. As a results, we obtained the nitrocellulose/MWCNT sensors with the sensitivity of 0.6%/sec under the 0.8 ppm of NOx gas concetration. Also, we get the activation energy of 0.202eV from the sensor for the 0.3 ppm of NOx gas concentration.

A Study on Safety Treatment of NOx by Discharge Plasma Reaction (방전Plasma 반응에 의한 NOx의 안전처리에 관한 연구)

  • Choi, Jae-wook;Yamaguma, Mizuki
    • Journal of the Korean Society of Safety
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    • v.15 no.2
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    • pp.92-96
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    • 2000
  • In this experiment, we studied about concentration characteristics of $NO_x$ and generation of ozone in the reactor of corona discharge type by using mixed gas of $NO/N_2$ and $N_2/O_2$. In the case of the initial NO concentration increased, decrease rate of NO concentration was weakened and discharge input power of minimum NO concentration became high. When NO concentration was high, NO decomposition limit was appeared. And NO reduction rate was decreased, when initial NO concentration and discharge input power increased. When discharge input power was 5W, we could know the most proper energy value for treatment of NO. When the concentration of initial NO increased, generation of ozone decreased and in the case of same concentration of NO, according to discharge input power increase, generation of ozone increased.

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Prediction of the Combustion Performance in the Coal-fired Boiler using Response Surface Method (반응표면법을 이용한 석탄 화력 보일러 연소특성 예측)

  • Shin, Sung Woo;Kim, Sin Woo;Lee, Eui Ju
    • Journal of the Korean Society of Safety
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    • v.32 no.1
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    • pp.27-32
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    • 2017
  • The experimental design methodology was applied in the real scale coal-fired boiler to predict the various combustion properties according to the operating conditions and to assess the coal plant safety. Response surface method (RSM) was introduced as a design of experiment, and the database for RSM was provided with the numerical simulation of the coal-fired boiler. The three independent variables, high heating value of coal (HHV), overall stoichiometry excess air ratio (OST), and burner-side stoichiometry excess air ratio (BST), were set to characterize the cross section averaged NOx concentration and temperature distribution. The maximum NOx concentration was predicted accurately and mainly controlled by BST in the boiler. The parabola function was assumed for the zone averaged peak temperature distribution, and the prediction was in a fairly good agreement with the experiments except downstream. Also, the location of the peak temperature was compared with that of maximum NOx, which implies that thermal NOx formation is the main mechanism in the coal-fired boiler. These results promise the wide use of statistical models for the fast prediction and safety assessment.

A Study on the Flue Gas Mixing for the Performance Improvement of De-NOx plant (배연탈질설비의 성능향상을 휘한 가스혼합에 관한 연구)

  • 류병남
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.4
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    • pp.462-472
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    • 1999
  • De-NOx facility using Selective Catalytic Reduction method is the most widely applied one that removes NOx from flue gas emitted from combustion facility such as boiler for power generation engine incinerator etc. Reductant $NH_3\;or\;NH_4OH$ is sprayed into flue gas to convert NOx into $H_2O$ and $N_2.$ Good mixing between flue gas and $NH_3$ is the most important factor to increase reduction in catalytic layer and to reduce unreacted NH3 slip. Therefore the development of mixer device for mixing effect is one of the important part for SCR facility. Objectives of this study are to investigate the relation between flow and concentration field by observation at the wake of delta-wing type mixer. At the first stage qualitative measurement of flow field is conducted by flow visualization using laser light sheet in lab. scale wind tunnel. Also we have conducted the quantitative analysis by comparing flow field measurement using LDV with numerical simulation. On the basis of qualitative and quantitative analysis we investigate the dis-tribution of flow and concentration in flow model facility. The results of an experimental and compu-tational examination of the vortex structures shed from delta wing type vortex generator having $40^{\circ}$ angle of attack are presented, The effects of vortex structure on the gas mixing is discussed, too.

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The Study of Waste Treatment using Advanced Oxygen Enriched Combustion System (산소부하 연소 시스템을 이용한 폐기물 열처리에 관한 연구)

  • Lee, Keon-Joo
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.231-239
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    • 2003
  • In this study, the waste of landfill was treated using advanced enriched oxygen combustion system. The oxygen concentration of this study was 21%, 25%, 30% and 40% and the operating capacity was 200 g/min and the residence time was 10 minutes. As increased the oxygen concentration of combustion air. temperature of the incinerator was increased and the temperature was increased rapidly when the oxygen concentration was 30%. As increased the oxygen concentration, the NOx (ppm) of flue gas increase d for thermal NOx, however the CO (ppm) of flue gas decreased according to the increase of combustion efficiency . The optimum operation condition of incineration was obtained when the oxygen concentration is 30%${\sim}$40%. The unburned carbon of ash decreased from 10% to 4% when the oxygen concentration was increased from 21% to 30%, therefore the high combustion efficiency can be obtained if used the oxygen enriched combustion system.

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A Convergence Study on the Effects of NH3/NOx Ratio and Catalyst Type on the NOx Reduction by Urea-SCR System of Diesel Engine (디젤엔진의 Urea-SCR 시스템에 의한 NH3/NOx 비율 및 촉매 방식이 NOx 저감에 미치는 영향에 관한 융합연구)

  • Yoon, Heung-Soo;Ryu, Yeon-Seung
    • Journal of the Korea Convergence Society
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    • v.10 no.4
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    • pp.131-138
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    • 2019
  • Diesel engines have important advantages over its gasoline counterpart including high thermal efficiency, high fuel economy and low emissions of CO, HC and $CO_2$. However, NOx reducing is more difficult on diesel engines because of the high $O_2$ concentration in the exhaust, marking general three way catalytic converter ineffective. Two method available technologies for continuous NOx reduction onboard diesel engines are Urea-SCR and LNT. The implementation of the Urea-SCR systems in design engines have made it possible for 2.5l and over engines to meet the tightened NOx emission standard of Euro-6. In this study, we investigate the characteristics of NOx reduction with respect to engine speed, load, types of catalyst and the $NH_3$/NOx ratio and present the conditions which maximize NOx reduction. Also we provide detailed experimental data on Urea-SCR which can be used for the preparation for standards beyond Euro-6.

A Study on NOx Removal by Using Plasma Discharge (플라즈마 방전을 이용한 NOx 제거에 관한 연구)

  • 김동욱;정영식
    • Journal of the Korean Society of Safety
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    • v.14 no.3
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    • pp.78-83
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    • 1999
  • This work is the experimental study for NO and NOx removal by utilizing non-thermal plasma. To apply to moving pollution source such as diesel automobile, we suggested the metal packed-helical wire reactor(MPHW) and measured properties of MPHW by varying the peak voltage, frequency, NOx concentration and flow rate for simulated NOx gas balanced with $N_2$. And then we compared these results with the results of cylinder-wire(CW) which was one of popularly used reactor in nonthermal plasma applications. The results of MPHW show fairly good NO and NOx removal rate compare with CW around above 20%. However. the power consumption of MPHW is larger than that of CW as much as around 2.5Watt in all range.

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Characteristics of NOx emission in lobed burner (로브형 버너에서의 NOx 배출특성)

  • Cho, H.C.;Cho, K.W.;Lee, Y.K.
    • 한국연소학회:학술대회논문집
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    • 2000.12a
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    • pp.140-147
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    • 2000
  • Using lobed burner, flame visualization and measurements of NOx and CO concentration in the combustor exit were carried out to evaluate the relation between the lobed structure in a burner and pollutant emission characteristics. The flame stability is enhanced by the lobed burner compared to conventional circular one. The correlation on fuel discharge velocity for flame blowout should be included on a variable related to the wall effect of the burner, because the flame blowout is observed at the burner having large perimeter. The burner having lobed structure in fuel discharge side compared to conventional burner reduces by 5% NOx emission due to lower flame intensity through flame elongation. Meanwhile the burner having lobed structure in air discharge side and both fuel and air discharge side increase the NOx emission.

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A Study on the Self Flue Gas Recirculating Flow of the Regenerative Low NOx Burner (축열식 저 NOx 연소기의 배기가스 내부 재순환 유동에 대한 연구)

  • Kim, Jong-Gyu;Kang, Min-Wook;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.17-26
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    • 2001
  • Self flue gas recirculation flow is an effective method for low NOx emission in the regenerative low NOx burner. The object of this study is to analyze the self flue gas recirculating flow by varying jet velocity of the combustion air. Fuel and air flow rates are fixed and combustion air jet nozzle diameters are 13, 6.5 and 5mm. The stoichiometric line is obtained from the concentration of the fuel using an acetone PLIF technique. It is found that the self flue gas recirculating flow is entrained into that line using a two color PIV technique. As the jet velocity of combustion air is increased, the flue gas entrainment rate into the stoichiometric line is increased. This result suggests that NOx emission can be reduced due to the effects of flue gas which is lowering the flame temperatures.

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NOx Emission Reduction and Mixing Enhancement of Turbulent Hydrogen Diffusion Flame by An Acoustic Excitation (음파가진에 의한 수소 확산 화염의 NOx 배출저감 및 혼합증진)

  • Han, Jeong-Jae;Kim, Mun-Ki;Yoon, Sang-Wook;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2005.10a
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    • pp.305-313
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    • 2005
  • Measurements of flame length, width and NOx emissions have been conducted to investigate the effect of an acoustic excitation on flame structure in turbulent hydrogen diffusion flames with coaxial air. The resonance frequency of oscillations was varied between 259 ,514 and 728 Hz with power rate of 0.405 and 2.88w. When these frequencies imposed to hydrogen flames, dramatic reduction of flame length and NOx emission was achieved. And acetone planar laser-induced fluorescence technique was used to measure a concentration of the near field of driven axisymmetric jet. The air-fuel stoichiometric line was plotted to investigate the mixing layer and development of air entrainment to fuel jet. Consequently, acoustic excitation on flame could enhance the air-fuel mixing resulting in abatement of NOx emission quantitatively.

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