• Title/Summary/Keyword: NOx

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A Study on the NOx Emission Status and Reduction Technologies of Domestic Marine Engine (국내 선박 엔진의 NOx 배출현황 및 저감기술 개발에 관한 고찰)

  • Kang K. J.;Kim S. H.;Kim E. C.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.2
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    • pp.57-63
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    • 2004
  • In this paper, the NOx emission and the reduction technologies of NOx emission for domestic marine diesel engine were investigated. At first, the present production status of domestic marine diesel engines was investigated. In the next, the NOx emission of domestic marine diesel engines was investigated. Finally, the present status of a reduction technologies of NOx emission was investigated. From this investigation, It could be founded that the domestic marine diesel engines satisfied the IMO current NOx regulations, however the higher technologies must be studied to prepare the more severe IMO regulations of the near future.

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Characteristics of NOx Reduction on NSR(NOx Storage and Reduction) Catalyst Supported by Ni, Ru-ZSM-5 Additives (Ni, Ru-ZSM-5를 첨가한 NSR 촉매의 NOx 정화 특성)

  • Choi, Byung-Chul;Lee, Choon-Hee;Jeong, Jong-Woo
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.5
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    • pp.105-111
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    • 2007
  • In this study, we investigated the conversion performance of de-NOx catalyst for lean-burn natural gas engine. As a de-NOx catalyst, NOx storage reduction catalyst was composed of Pt, Pd and Rh with washcoat including Ba and Ni, Ru-ZSM-5. Ni, Ru-ZSM-5, which was regarded as a NOx direct decomposition catalyst, was made up of ion exchanged ZSM-5 by 5wt.% Ni or Ru. The performance of de-NOx catalyst was evaluated by NOx storage capacity and catalytic reduction in air/fuel, $\lambda=1.6$. The catalytic reaction was also observed when the added fuel was supplied to fuel rich atmosphere by fuel spike period of 5 seconds. The NOx conversion of the catalysts with Ni-ZSM-5 or Ru-ZSM-5 was mainly caused by the effect of NOx adsorption of Ba rather than the catalytic reduction of Ni, Ru-ZSM-5. Ni, Ru-ZSM-5 catalysts can not use for the NSR catalyst because they have quick process in thermal deactivation.

The Study for Designs of Lean-Premixed low NOx Combustor (희박-예혼합 저 NOx 연소기 설계에 대한 연구)

  • Lim, Am-Ho;Kim, Han-Suck;Ann, Kuk-Young;Lee, Sang-Min;Kim, Yong-Mo
    • 한국연소학회:학술대회논문집
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    • 2003.12a
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    • pp.83-88
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    • 2003
  • The concept of lean-premixed combustion in gas turbine combustor operation has become a standard in recent years as an effective means to meet stringent environmental standards on NOx emissions. Various types of air-fuel premixer, which affect greatly NOx emission and stability of lean-premixed low NOx combustor, were investigated experimentally to reduce the NOx emission. One type of the premixers is selected by experiments and applied it to 70kW class lean-premixed gas turbine combustor. The exit temperature and emissions of CO and NOx were measured with equivalence ratios at ambient pressure. From the results, the emissions of CO and NOx were influenced by the type of air-fuel premixer. As the mixing length of air and fuel is longer, the NOx and CO emission were decreased in the primary reaction zone. Compared with of conventional combustor, the lean-premixed low NOx combustor has low NOx emission characteristics.

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Effect of $NH_3$/NOx ratio and Catalyst Temperature on DeNOx Performance in the $NH_3$-SCR reactor ($NH_3$-SCR 반응기 내에서의 $NH_3$/NOx 및 SCR 촉매 온도가 DeNOx 성능에 미치는 영향)

  • Hong, Kil-Hwa;Gong, Ho-Jeong;Hwang, In-Goo;Park, Sim-Soo
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.3096-3101
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    • 2008
  • Selective Catalytic Reduction (SCR) technology is well-known to be effective for the reduction of NOx emission. So car manufacturers has adopted Ures-SCR system to be satisfied with emission regulation. This paper discusses the effective of $NH_3/NOx$ ratio and SCR catalyst temperature in the $NH_3$-SCR reactor on DeNOx performance. So it is shown the characteristic of NOx conversion and ammonia slip using the $NH_3$ instead of Urea-Solution. From the result of this study, it is found to optimize $NH_3/NOx$ ratio to have the best case of high NOx conversion and low ammonia slip at variable SCR catalyst temperatures. Lastly, it is also found the characteristics of NOx conversion and ammonia slip with compared with Urea.

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Role of Nox4 in Neuronal Differentiation of Mouse Subventricular Zone Neural Stem Cells (쥐의 뇌실 하 영역(SVZ) 신경 줄기 세포의 신경 세포로의 분화 과정에서 Nox4의 역할)

  • Park, Ki-Youb;Na, Yerin;Kim, Man Su
    • Journal of Life Science
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    • v.26 no.1
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    • pp.8-16
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    • 2016
  • Reactive oxygen species (ROS), at appropriate concentrations, mediate various normal cellular functions, including defense against pathogens, signal transduction, cellular growth, and gene expression. A recent study demonstrated that ROS and ROS-generating NADPH oxidase (Nox) are important in self-renewal and neuronal differentiation of subventricular zone (SVZ) neural stem cells in adult mouse brains. In this study, we found that endogenous ROS were detected in SVZ neural stem cells cultured from postnatal mouse brains. Nox4 was predominantly expressed in cultured cells, while the levels of the Nox1 and Nox2 transcripts were very low. In addition, the Nox4 gene was highly upregulated (by up to 10-fold) during neuronal differentiation. Immunocytochemical analysis detected the Nox4 protein mainly in neurons positive for the neuronal specific tubulin Tuj1. After differentiation, endogenous ROS were detected exclusively in neuron-like cells with processes. In addition, perturbation of the cellular redox state with N-acetyl cysteine, a ROS scavenger, during neuronal differentiation greatly inhibited neurogenesis. Lastly, knockdown of Nox4 using short hairpin RNA decreased neurogenesis. These findings suggest that Nox4 may be a major ROS-generating enzyme in postnatal SVZ neural stem cells, and Nox4-mediated ROS generation may be important in their neuronal differentiation.

Characteristics of UBC and NOx Emission in Air Staging Combustion (공기 다단 연소 기법 적용에 따른 미연탄소분 및 질소산화물 배출특성)

  • Kim, Jeong Woo;Lim, Ho;Go, Young Gun;Jeon, Chung Hwan
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.40 no.10
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    • pp.637-644
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    • 2016
  • The purpose of this study is to understand the characteristics of unburned carbon (UBC) and NOx emissions for pulverized coal when air staging combustion is applied. A two-staged drop tube furnace capable of applying air staging combustion was designed and installed. The combustion of sub-bituminous (Tanito) has been investigated. UBC and the NOx concentration were measured under various temperatures and stoichiometric ratios in unstaged and staged combustion. As a result, UBC decreased and the NOx concentration increased with an increase in stoichiometric ratio and temperature. In particular, the NOx reduction mechanism was activated when the temperature in the fuel rich zone increased. Both UBC and the NOx concentration decreased as the temperature increased in the fuel rich zone. A high NOx reduction effect was obtained, compared to the UBC increase, when the air staging technique was applied.

A Convergence Study on the Effects of NH3/NOx Ratio and Catalyst Type on the NOx Reduction by Urea-SCR System of Diesel Engine (디젤엔진의 Urea-SCR 시스템에 의한 NH3/NOx 비율 및 촉매 방식이 NOx 저감에 미치는 영향에 관한 융합연구)

  • Yoon, Heung-Soo;Ryu, Yeon-Seung
    • Journal of the Korea Convergence Society
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    • v.10 no.4
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    • pp.131-138
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    • 2019
  • Diesel engines have important advantages over its gasoline counterpart including high thermal efficiency, high fuel economy and low emissions of CO, HC and $CO_2$. However, NOx reducing is more difficult on diesel engines because of the high $O_2$ concentration in the exhaust, marking general three way catalytic converter ineffective. Two method available technologies for continuous NOx reduction onboard diesel engines are Urea-SCR and LNT. The implementation of the Urea-SCR systems in design engines have made it possible for 2.5l and over engines to meet the tightened NOx emission standard of Euro-6. In this study, we investigate the characteristics of NOx reduction with respect to engine speed, load, types of catalyst and the $NH_3$/NOx ratio and present the conditions which maximize NOx reduction. Also we provide detailed experimental data on Urea-SCR which can be used for the preparation for standards beyond Euro-6.

STATIC CHARACTERISTICS OF A UREA-SCR SYSTEM FOR NOx REDUCTION IN DIESEL ENGINES

  • Nam, J.G.
    • International Journal of Automotive Technology
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    • v.8 no.3
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    • pp.283-288
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    • 2007
  • This paper presents the static characteristics of a urea-SCR system. The static characterization of the urea-SCR system was generated by sweeping urea flow rates at common engine torque/speed operating points. Several experiments were performed using engine operating points at different raw NOx emission levels, space velocities, and SCR catalyst temperatures. The recorded NOx emissions from the engine exhaust outlet and engine tailpipe are then compared. The urea-SCR static system results indicated that a $50{\sim}60%$ NOx conversion is achievable at most engine operating points using the stoichiometric $NH_3/NOx$ ratio, and a high 98% NOx conversion is possible by exceeding the stoichiometric $NH_3/NOx$ ratio. The effect of the pre-oxidation catalyst volume was also investigated and found to have a profound impact on experimental results, particularly the static NOx conversion.

NOx Reduction Characteristics of Air Staging Burner for Pulverized-coal Combustion (공기 다단공급식 미분탄 버너의 NOx 저감 특성)

  • Park, Chu-Sik;Kim, Sung-Won;Choi, Snag-Il
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.153-160
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    • 2001
  • The combustion test used DTF was performed to obtain the characteristics of NOx emission and reduction. In this test, major factor of NOx emission was a stoichiometric air ratio. At the onset of combustion to be rich oxygen, NOx was produced rapidly. Optimum condition for NOx reduction was formed under about AR:0.7 in the combustion test of Alaska coal. Investigations were undertaken with 200KW(th) test combustor. In combustion test, the major variables were coal feed ratio of center/outer, stoichiometric air ratio at the onset of combustion. The lowest NOx emission, 182ppm(6% O2 base), was achieved at about AR:0.6 of the first combustion stage with low NOx burner. Also, unburned carbon content of char collected in this combustion condition was about 1wt%.

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Experimental Study on DeNOx Characteristics of Urea-SCR System (Urea-SCR 시스템의 DeNOx 특성에 관한 실험적 연구)

  • Ham, Yun-Young;Lee, Seong-Ho;Jung, Hong-Seok;Shin, Dong-Hyun
    • Transactions of the Korean Society of Automotive Engineers
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    • v.17 no.2
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    • pp.180-186
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    • 2009
  • To meet the NOx limit without a penalty of fuel consumption, urea SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, as a basic research to develop an algorithm for urea injection control, the characteristics of engine out NOx emission and behavior of NOx reduction during steady-state and transient conditions were investigated using 2L DI diesel engine. Test results show that on increasing the catalyst temperature the variations in the outlet NOx concentration are faster and maximal allowable $NH_3$ storage exponentially decreases. For change from a low to high engine load, it can be seen that a few seconds after load-step is required to reach full NOx conversion and the adsorbed amount of $NH_3$ at lower temperature desorb during the next temperature increase, causing $NH_3$ slip. Engine out NOx emission needs to be corrected because NOx emissions just after step load is lower than that of steay state condition.