• Title/Summary/Keyword: NOx저감

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Effect of Nozzle Cap Geometry for Swirl-Type Two-Fluid Nozzle on the Spray Characteristics (선회형 이유체노즐의 노즐캡 형상에 따른 분무특성)

  • Choi, Y.J.;Kang, S.M.;Kim, D.J.;Lee, J.K.
    • Journal of ILASS-Korea
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    • v.13 no.3
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    • pp.134-142
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    • 2008
  • In the case of heavy duty diesel engines, the Urea-SCR system is currently considered to reduce the NOx emission as a proved technology, and it is widely studied to get the high performance and durability. However, the nozzles to inject the urea-water solution into the exhaust pipe occur some problems, including the nozzle clogging, deposition of urea-water solution on the inner wall of the exhaust pipe, resulting in the production of urea salt. In this study, a swirl-type twin-fluid nozzle to produce more fine droplets was used as a method to solve the problems. The effect of the nozzle cap geometry, including the length to diameter ratio ($l_o/d_o$) and chamfer, on the spray characteristics were investigated experimentally. The length to diameter ratio of nozzle cap were varied from 0.25 to 1.125. The chamfer angle of the nozzle cap was constant at 90o. The mean velocity and droplet size distributions of the spray were measured using a 2-D PDA (phase Doppler analyzer) system, and the spray half-width, AMD (arithmetic mean diameter) and SMD (Sauter mean diameter) were analyzed. At result, The larger length to diameter ratio of nozzle cap were more small SMD and AMD. The effect of the chamfer did increase the radial velocity, while it did not affect the atomization effect.

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A Study on Synthetic Method and Material Characteristics of Magnesium Ammine Chloride as Ammonia Transport Materials for Solid SCR (Solid SCR용 암모니아 저장물질인 Magnesium Ammine Chloride의 합성방법 및 물질특성 연구)

  • Shin, Jong Kook;Yoon, Cheon Seog;Kim, Hongsuk
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.11
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    • pp.843-851
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    • 2015
  • Among various ammonium salts and metal ammine chlorides used as solid materials for the sources of ammonia with solid SCR for lean NOx reduction, magnesium ammine chloride was taken up for study in this paper because of its ease of handling and safety. Lab-scale synthetic method of magnesium ammine chloride were studied for different durations, temperatures, and pressures with proper ammonia gas charged, as a respect of ammonia gas adsorption rate(%). To understand material characteristics for lab-made magnesium ammine chloride, DA, IC, FT-IR, XRD and SDT analyses were performed using the published data available in literature. From the analytical results, the water content in the lab-made magnesium ammine chloride can be determined. A new test procedure for water removal was proposed, by which the adsorption rate of lab-made sample was found to be approximately 100%.

Capacitance Characteristics of Fly Ash for Monitoring the Unburned Carbon Contained in Fly Ash (석탄회 미연탄소함량 동시측정을 위한 석탄회 정전용량 분석에 관한 연구)

  • 이재근;김장우;구재현;신진혁;김성찬;신희수;황유진
    • Journal of Energy Engineering
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    • v.11 no.1
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    • pp.67-73
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    • 2002
  • The carbon-in-ash system for simultaneously monitoring the unburned carbon in fly ash produced in a coal-fired power plan is designed and evaluated using the domestic fly ash produced in the coal-fired power plant. Real time monitoring is very important to control the combustion of the boiler in the coal-fired power plant and the purification system for fly ash recycling. The carbon-in-ash system based on the capacitance measurement consists of a LCR meter, a duct collector and an electrode cell. The capacitance of fly ash increases linearly with increasing fly ash carbon contents. The water content in fly ash plays an important role on the ash capacitance. The empirical equation for predicting the content of unburned carbon in fly ash produced in the domestic Boryung, Hadong and Samchenpo coal-fired power plants can be derived in the range of carbon content 0-20%.

Reduction of Exhaust Emissions Using Various Injector Configurations in Low Temperature Diesel Combustion (분사기 형상 변경을 통한 저온 디젤 연소의 배기 배출물 저감)

  • Jung, Yong-Jin;Jang, Jin-Young;Park, Jung-Seo;Bae, Choong-Sik;Kim, Duk-Sang
    • Transactions of the Korean Society of Automotive Engineers
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    • v.19 no.4
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    • pp.16-23
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    • 2011
  • Low temperature combustion is one of the advanced combustion technology in an internal combustion engine to reduce soot and nitrogen oxides simultaneously. In present experiment three kinds of injector were used to investigate the influence of injection angle and number of nozzle holes on the low temperature combustion in a heavy duty diesel engine. Low temperature diesel combustion is realized from the exhaust gas recirculation rate of 60%. Indicated mean effective pressure of low temperature combustion corresponds to the 70% level of conventional diesel engine combustion. Reduction of hydrocarbon and carbon monoxide, which are produced in low temperature combustion because of the low combustion temperature and a deficit of oxygen, was achieved by using various injector configuration. The result of experiment with $100^{\circ}$ injection angle and 8 holes showed that reductions in hydrocarbon and carbon monoxide could be achieved 58% and 27% respectively maintaining the 7% increased indicated mean effective pressure in low temperature diesel combustion compared with conventional injector.

Effect of Water on the Kinetics of Nitric Oxides Reduction by Ammonia over V-based Catalyst (바나듐계 촉매상에서 암모니아를 이용한 질소산화물의 환원반응속도에 수분이 미치는 영향에 관한 연구)

  • Kim, Young-Deuk;Jeong, Soo-Jin;Kim, Woo-Seung
    • Transactions of the Korean Society of Automotive Engineers
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    • v.20 no.6
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    • pp.73-82
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    • 2012
  • The main and side reactions of the three selective catalytic reduction (SCR) reactions with ammonia over a vanadium-based catalyst have been investigated using synthetic gas mixtures in the temperature range of $170{\sim}590^{\circ}C$. The three SCR reactions are standard SCR with pure NO, fast SCR with an equimolar mixture of NO and $NO_2$, and $NO_2$ SCR with pure $NO_2$. Vanadium based catalyst has no significant activity in NO oxidation to $NO_2$, while it has high activity for $NO_2$ decomposition at high temperatures. The selective catalytic oxidation of ammonia and the formation of nitrous oxide compete with the SCR reactions at the high temperatures. Water strongly inhibits the selective catalytic oxidation of ammonia and the formation of nitrous oxide, thus increasing the selectivity of the SCR reactions. However, the presence of water inhibits the SCR activity, most pronounced at low temperatures. In this study, the experimental results are analyzed by means of a dynamic one-dimensional isothermal heterogeneous plug-flow reactor (PFR) model according to the Eley-Rideal mechanism.

Characteristics Diagnosis of Supersonic Air Plasma by 0.4 MW Class Segmented Type Arc Torch (0.4 MW급 분절형 아크 토치에 의한 초음속 공기 플라즈마의 특성 진단)

  • Kim, Min-Ho;Lee, Mi-Yeon;Choe, Chae-Hong;Kim, Jeong-Su;Seo, Jun-Ho;Hong, Bong-Geun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.194-195
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    • 2013
  • 초음속 공기 플라즈마 환경을 모사할 수 있는 0.4 MW급 Enhanced Huels형 초음속 공기 플라즈마 발생 장비가 2012년에 전북대학교에 설치 완료되었다. 초음속 공기 플라즈마 시험장비는 대기권으로 reentry 할 수 있는 비행체의 열차폐체 시험평가를 주목적으로 개발되었으며, 핵융합장치용 고온 내열체 소재개발에도 활용될 예정이다. 분절형 아크 플라즈마 토치는 전극부식에 의한 오염도를 적으면서 고출력의 안정적인 플라즈마를 발생시키며, 일반적인 직류 토치로는 얻을 수 없는 초고엔탈피 플라즈마 열유동을 얻을 수 있는 특징이 있다. 구축된 장비는 최대 직류 출력 1,200 kW의 DC 전원공급장치, 0.4 MW급의 분절형 아크 플라즈마 토치, ${\phi}1.5m{\times}2m$ 크기의 진공쳄버, 1 MW의 냉각 능력을 갖춘 디퓨저와 열교환기, 진공 용량 $100m^3$/min의 진공펌프 9대, 88 g/s의 공기유량에서 NOx를 50,000 ppm에서 100 ppm으로 저감할 수 있는 후처리 시스템, 4 bar 15 g/s의 공기를 공급할 수 있는 가스 공급장치, 30 bar 600 lpm의 저전도수와 4 bar 560 lpm의 일반수를 공급할 수 있는 냉각수 공급장치로 구성되어 있다. 초음속 공기 플라즈마의 발생 특성을 시험하기 위해 플라즈마 발생 조건으로 토치공급전력 350 kW와 410 kW, 토치 공기 공급 유량 16.3 g/s, 토치 내부압력 3.9~4.2 bar, 챔버압력 40 mbar으로 시험을 수행하였다. 발생된 플라즈마 상태를 진단하기 위해 속도는 쇄기 탐침기, 열유속은 Gardon 게이지, 엔탈피와 토치 효율은 토치의 공급전력과 냉각수에 의한 손실 전력으로 각각 측정하였다.

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Numerical study of a conical MILD combustor with varing the fuel flow rate (연료유량 변화에 따른 원추형 MILD 연소로의 수치적 해석)

  • Kim, Tae Kwon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3370-3375
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    • 2014
  • MILD combustion is a highly favored technology for solving the trade-off relation between high thermal efficiency and low pollutant emissions. The system has low NOx concentration in high temperature combustion by recirculating the combustion gas, as well as improving the thermal efficiency by making the internal temperature in a combustion furnace uniform. This study describes the combustion characteristics of a conical MILD combustor in a laboratory-scale furnace by adjusting the equivalence ratio with the fuel gas flow rate while maintaining a constant air flow rate of the furnace. The MILD regime in the furnace is well characterized and the in-furnace temperature and emissions were predicted, respectively, for the range of equivalence of 0.69 - 0.83. For the range of equivalence ratios, this study confirmed the existence of a stable flame region that has an approximately $300^{\circ}C$ temperature difference between the maximum flame temperature region and main reaction region.

A Study on Installation of Removal Device for Volatile Organic Compounds from Petrochemical Plant (석유화학 공장에서 VOCs 제거시설 설치사례 연구)

  • 김석택
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.95-101
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    • 2000
  • High growth of economy and industrial development was produced every air pollutants, that is, SOx, NOx, dust, VOCs and malodorous gas was produced. Recently, volatile organic compounds(VOCs) was bring about very serious environmental problems. Ulsan petrochemical complex was densely a large scale of petrochemical plant. This study was carried out to select treatment equipment of VOCs produced from petrochemical plant, and has compared with Carbon filter, Regenerative thermal oxidation(RCO) and Flare stack for technical merit and demerit but also initial investment and operating cost.

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Reduction of Nitrous Oxide Emission by EGR Method on Diesel Engine (디젤엔진에서 배기가스 재순환 방법을 이용한 아산화질소의 배출률 저감)

  • Yoo, Dong-Hoon
    • Journal of Power System Engineering
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    • v.19 no.3
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    • pp.16-21
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    • 2015
  • Nitrous oxide($N_2O$) concentration in the atmosphere has been constantly increased by the human activities with industrial growth after the industrial revolution. One of factors to increase $N_2O$ concentration in the atmosphere is the $N_2O$ emission caused by the combustion of marine fuel. Especially, a sulfur component included in marine fuel oils is known as increasing the $N_2O$ formation in diesel combustion. Form this point of view, $N_2O$ emission from a ship is not negligible. On the other hand, Exhaust gas recirculation(EGR) that have thermal, chemical and dilution effect is effective method for reducing the NOx emission. In this study, an author investigated $N_2O$ reduction by using EGR on a direct injection diesel engine. The test engine was a 4-stroke diesel engine with maximum output of 12 kW at 2600rpm, and operating condition of the engine was a fixed load of 75%. The experimental oil was a blend-fuel that were adjusted with sulfur ratio of 3.5%, and EGR ratio of 0%, 10%, 20% and 30%. In conclusion, diesel fuel that contained 3.5% sulfur component increased $SO_2$ emission in exhaust gas, and increment of EGR ratio reduced NO emission. Moreover, $N_2O$ emission was decreased as over 50% at EGR ratio of 10% and reduced 100% at EGR ratio of 30% compared with $N_2O$ emission of 0% EGR ratio.

A Study on the Emission Characteristics of LNG-diesel Dual-fuel Engine for Euro 2 Standard (Euro 2 기준 LNG-경유 혼소엔진의 배출가스 특성에 관한 연구)

  • Cho, Gyu-Baek;Kim, Chong-Min;Kim, Dong-Sik;Kim, Hong-Suk
    • Journal of the Korean Institute of Gas
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    • v.15 no.1
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    • pp.9-14
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    • 2011
  • Heavy duty diesel engine has relatively small portion of whole vehicles due to long drive distance and large engine displacement, but largely influences atmosphere environment. City buses changed to CNG (Compressed Natural Gas) bus with Korea-Japan Worldcup. Heavy duty truck and intercity bus, however, were impossible to use CNG because those kinds of vehicles had long drive distance and CNG station was installed mainly at the around of the bus garage of city. Insulation container storing the natural gas as a liquid makes heavy duty truck and intercity bus possible to use the natural gas. Drive using diesel is possible where is hard to recharge the gas. With LNG (Liquefied Natural Gas), the dependence on oil is largely decreased, PM (Particulate Matter) and NOx which is chronic disadvantage of diesel is remarkably reduced and finally $CO_2$, the representative green house gas, is reduced over 10%.