• Title/Summary/Keyword: NO_X$

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Characteristics of Adsorption, Desorption of Exhaust Gases and Deactivation of LNT and SCR Catalysts for Diesel Vehicles (디젤 자동차용 LNT, SCR 촉매의 배출가스 흡착, 탈리 및 열화 특성)

  • Seo, C.K;Kim, H.N.;Choi, B.C.
    • Journal of Power System Engineering
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    • v.14 no.6
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    • pp.13-19
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    • 2010
  • 이 논문에서는 디젤자동차용 LNT와 SCR 촉매의 NO, $NH_3$ 흡착 및 탈리의 기본 특성과 수열화 온도와 시간 및 정량화된 황피독 농도에 대한 de-$NO_x$ 촉매의 내구성을 평가하였다. LNT 촉매는 열적으로 열화됨에 따라 Pt 및 Ba의 소결 및 응집으로 활성이 떨어져 $NO_x$ 전환율은 감소하였다. 반면에 Pt의 비활성화로 중간생성물인 $NH_3$ 생성량은 증가하였으며, 이때 생성된 $NH_3$는 LNT+SCR 복합시스템의 SCR 촉매의 환원제 역할을 담당한다. 1.0 g/L 이상의 황이 피독된 LNT 촉매는 탈황을 하여도 질소 산화물 흡장물질(Ba) 의 성능이 회복이 되지 않아 $NO_x$ 전환율은 회복되지 않았으며, 탈황 후 Pt 재활성화로 인해 NO2 및 SCR 환원제인 $NH_3$ 생성량은 증가하였다. SCR 촉매의 $NO_x$ 전환율은 $700^{\circ}C$ 36h, $800^{\circ}C$ 24h로 수열화 시킨 촉매는 전이금속 입자 성장 및 zeolite 구조 파괴로 인하여 급격하게 떨어졌으며, 0.36 g/L 황 피독된 촉매는 zeolite가 가지는 강산성 특정으로 내피독성이 강하여 탈황시 $NO_x$ 전환율은 회복되었다.

Characteristics of perovskite-structure Sr(Ti1-xFex)O3 thick film gas sensors (페롭스카이트 구조 Sr(Ti1-xFex)O3 후막 가스센서의 특성)

  • Jin, Guang-Hu;Lee, Woon-Young;Lee, Hyun-Gyu;Park, Jin-Seong
    • Journal of Sensor Science and Technology
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    • v.18 no.6
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    • pp.456-461
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    • 2009
  • Perovskite-structure $Sr(Ti_{1-x}Fe_x)O_3$ thick films, in which x is 0.4 or 0.6, were prepared by normal ceramic process on alumina substrate. Electrical resistance was measured as a function of thermal treatment condition including atmosphere, time, and temperature. The resistance of $Sr(Ti_{1-x}Fe_x)O_3$ films is lower than those of $SrTiO_3$ or $SrFeO_3$ films. The temperature coefficient of resistance over $550^{\circ}C$ was measured to be 0 for the $Sr(Ti_{1-x}Fe_x)O_3$ films after thermal treatment at $1100^{\circ}C$ in air. The sensing property of the films was also measured as a function of temperature and gas such as $O_2$, CO, $CO_2$, NO and $NO_2$. $Sr(Ti_{1-x}Fe_x)O_3$ films showed a good sensing property for $O_2$, but no sensing signal for CO, $CO_2$, NO and $NO_2$.

Electrical Property Changes of $\textrm{NO}_X$ Sensitive $\textrm{WO}_3$ Thin Films as Applied DC Voltages on 8YSZ Substrate (8YSZ 기판에 증착한 $\textrm{WO}_3$ 박막의 DC 전압에 따른 $\textrm{NO}_X$ 감지특성)

  • 전춘배;박기철
    • Journal of the Korean Institute of Telematics and Electronics T
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    • v.36T no.1
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    • pp.8-12
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    • 1999
  • $\textrm{WO}_3$ semiconductive film, which is known to have a sensitivity on $\textrm{NO}_X$ gas was prepared on 8YSZ (8% Yttria stabilized $\textrm{ZrO}_2$) ionic conductor substrate that has oxygen ion pumping effect. Microstructure and electrical properity, especially $\textrm{NO}_X$ sensitivity as a function of DC voltage applied to 8YSZ substrate was examined. When the $\textrm{WO}_3$ film was annealed, it showed amorphous structure, while crystallization was occurred at $600^{\circ}$C revealing orthorhombic phase of $\textrm{WO}_3$. As the annealing temperature increases, (111) and (001) peaks of $\textrm{WO}_3$ film was enhanced. At $400^{\circ}C$ when DC voltage was applied, comparing with no DC bias, more stable and large response characteristics was showed, and the best sensitivity was observed at 2V. Recovery characteristics of NO gas was much better that that of $\textrm{NO}_2$ gas.

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Identification of the Actinomycetes Strain No.1372, A Producer of Actinomycin $X_2$ (Actinomycin $X_2$를 생산하는 방선균 분리주 No.1372의 동정)

  • 하상철;홍순덕
    • Microbiology and Biotechnology Letters
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    • v.22 no.2
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    • pp.164-168
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    • 1994
  • Identification of the Actinomycetes isolate strain No. 1372, a producer of Actinomycin X$_{2}$ was performed by using ISP method.l The strain, designated as No. 1372, was identified as Streptomyces floridae based on its morphological, physiological and biochemical characteristics. The highest production of the antibiotics by the strain was achieved in a fermentation medium containing soluble starch, yeast extract, (NH$_{4}$)SO$_{4}$, K$_{2}$HPO$_{4}$, NaCl$_{2}$, CaCO$_{3}$, and trace element.

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A Study on Nitric Oxide Formation & Reduction in Industrial Burner (I) -NO Concetration-Distribution in Double Swirling Diffusion Flame by LIF- (산업용 고부하버너 연소에서의 $NO_x$ 형성 및 저감에 관한 연구(I)-레이저 유도 형광법(LIF)를 이용한 이중선회 확산화염의 NO 농도 분포 측정-)

  • 박경석;김경수
    • Journal of Energy Engineering
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    • v.10 no.4
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    • pp.379-386
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    • 2001
  • This experimental study deals with on Nitric Oxide Formation & Reduction in Industrial Bunner. In this study, Laser-induced fluorescence (LIF) techniques have been used for quantitative measurements of Nitric Oxide. The NO A-X (0, 0) Vibrational band around 226 nm was excited using a XeCl excimer-pumped dye laser. And on-line excitation used $P_{21}+Q_1(14.5)/R_{12}+Q_2(20.5)/P_1(23.5)$ transition, for minimizing the other interferential effect. The measurements were taken NO concentration distribution in double swirling diffusion flame. In this swirl burner, NO concentration in downstream fo the flame decrease as primary/secondary air ratio increases.

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Air Pollutant Removal Rates of Concrete Permeable Blocks Produced with Coated Zeolite Beads (코팅된 제올라이트 비드를 이용한 콘크리트 투수블록의 대기전구물질 제거율 평가)

  • Park, Jun-Seo;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.2
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    • pp.153-164
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    • 2023
  • The objective of this study is to examine the removal rate of air pollutants, specifically sulfur oxides (SOx) and nitrogen oxides(NOx), using concrete permeable blocks containing zeolite beads coated with materials capable of eliminating these pollutants. Titanium dioxide(TiO2) powder and coconut shell powder were utilized for the removal of SOx and NOx and were applied as coatings on the zeolite beads. Concrete permeable block specimens embedded with the coated zeolite beads were produced using an actual factory production line. Test results demonstrated that the concrete permeable block containing zeolite beads coated with coconut shell powder in the surface layer achieved SOx and NOx removal rates of 12.5% and 99%, respectively, exhibiting superior performance compared to other blocks. Additionally, the flexural strength and slip resistance were 5.3MPa and 65BPN or higher, respectively, satisfying the requirements specified in KS F 4419 and KS F 4561. Conversely, the permeability coefficient exhibited low permeability, with grades 2 and 3 before and after contaminant pollution, according to the standard for 'design, construction, and maintenance of pavement using permeable block'. In conclusion, incorporating zeolite beads coated with coconut shell powder in the surface layer enables simultaneous removal of SOx and NOx, irrespective of ultraviolet rays, while maintaining adequate flexural strength and slip resistance. However, the permeability is significantly reduced, necessitating further improvements.

Methodology to Simultaneously Optimize the Inlet Ozone Concentration to Oxidize NO and Relative Humidity Composition for the $NO_x$ Degradation using Soil Bio-filter

  • Cho, Ki-Chul;Hwang, Kyung-Chul
    • Journal of Korean Society for Atmospheric Environment
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    • v.24 no.E2
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    • pp.83-91
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    • 2008
  • This work investigated the methodology to simultaneously optimize the ozone and relative humidity composition for the $NO_x$ degradation using soil biofilter. Experiments were made as a function of inlet ozone concentration ($0{\sim}1,770\;ppb$) and relative humidity ($38{\sim}81%$). Factorial design ($2^2+3$) and response surface methodology by central composite designs were used to examine the role of two factors and optimal response condition on $NO_x$ degradation. It was found that a second-order response surface model can properly interpret the experimental data with an $R^2$-value of 0.9730 and F-value of 71.83, based on which the maximum $NO_x$ degradation was predicted up to 92.8% within our experimental conditions.

A Study of Optimal Mixture Fraction of Soil Bio-Filter for Removing NOX (질소산화물 제거를 위한 최적 토양 바이오 필터 혼합비 도출에 관한 연구)

  • Cho, Ki-Chul;Lee, Nae-Hyun
    • Journal of Environmental Science International
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    • v.16 no.11
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    • pp.1247-1255
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    • 2007
  • Soil biofiltration is an environmentally-sound technology for elimination of VOCs, odorous and $NO_X$ compounds from a low concentration, high volume waste gas streams because of its simplicity and cost-effectiveness. This study investigated the optimal mixture fraction of briquet ash, compost, soil and loess for $NO_X$ degradation. Extreme vertices design was used to examine the role of four components on $NO_X$ degradation. Under our experimental conditions, 74.5% of $NO_X$ degradation was observed, using a model mixture(25% briquet ash, 10% compost, 30% soil and 40% loess) containing 100 ppb of NO. It was shown that experimental design analysis could allow selecting optimal conditions in such biodegradation processes in this study.

On the McShane integrability

  • Kim, Jin-Yee
    • Communications of the Korean Mathematical Society
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    • v.11 no.2
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    • pp.377-383
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    • 1996
  • For a given separable space X which contains no copy of $C_0$ and a weakly compact T, we show that a Dunford integrable function $f : [a,b] \to X$ is intrinsically-separable valued if and only if f is McShane integrable. Also, for a given separable space X which contains no copy of $C_0$, a weakly compact T and a Dunford integrable function f we show that if there exists a sequence $(f_n)$ of McShane integrable functions from [a,b] to X such that for each $x^* \in X^*, x^*f_n \to x^*f$ a.e., then f is McShane integrable. Finally, let X contain no copy of $C_0$. If $f : [a,b] \to X$ is McShane integrable, then F is a countably additive on $\sum$.

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Simultaneous Removal of SOx and NOx in Flue Gas of Oxy-fuel Combustion by Direct Contact Condenser (직접접촉식 응축기를 통한 가압순산소 연소 배가스 내 SOx, NOx 동시저감 연구)

  • Choi, Solbi;Mock, Chinsung;Yang, Won;Ryu, Changkook;Choi, Seuk-Cheon
    • Clean Technology
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    • v.25 no.3
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    • pp.245-255
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    • 2019
  • Pressurized oxy-fuel combustion is a promising technology for $CO_2$ capture with a benefit of improving power plant efficiency compared with atmospheric oxy-fuel combustion. Prior to $CO_2$ compression in this process, a flue gas condenser (FGC) is used to remove $H_2O$ while recovering the latent heat. At the same time, the FGC has a potential for high-efficiency removal of $SO_x$ and $NO_x$ by exploiting their good solubility in water. In this study, experiments were carried out in a lab-scale, direct contact FGC under different pressures varying between 1 and 20 bar to evaluate the removal efficiency of $SO_2$ and $NO_x$ for individual gases and their mixture. In the tests for individual gases, 20% and 76% of $NO_x$ was removed at 1 bar and 10 bar, respectively. Even higher removal efficiencies were achieved for $SO_2$, and also these were maintained for longer as the pressure increased. In the tests for $SO_2$ and $NO_x$ mixture, the removal efficiency of $NO_x$ increased from 13% at 1 bar to 56% at 20 bar because of higher solubility at elevated pressures. $SO_2$ in the mixture was initially dissolved almost completely and then increased by 1,219 ppm at 1 bar and by 165 ppm at 20 bar. Overall, the removal efficiency of $SO_2$ and $NO_x$ was increased at elevated pressures, but it was lower in the mixture compared with individual gases at identical conditions because of a lower pH and associated chemical reactions in water.