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Relationship between Infrared Peak Maximum Position and Molecular Interactions

  • Ryu, Soo-Ryeon;Noda, Isao;Jung, Young-Mee
    • Bulletin of the Korean Chemical Society
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    • v.32 no.11
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    • pp.4011-4015
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    • 2011
  • We explored the interpretation of the well-accepted correlation between the apparent peak maximum position shift and extent of molecular interactions, like hydrogen bonding and dipole-dipole interactions, based on the overlapped multiple band model. The simulation of two overlapped Lorentzian bands was carried out to interpret how the maximum position of a composite peak relates to the relative contributions of two species representing the different levels of molecular interactions, i.e., free (or very weekly bound) vs. strongly bound. To demonstrate the validity of our interpretation of the origin of the peak position shift, the temperaturedependent IR spectra of ethylene glycol were also analyzed. It was found through the analysis of simulated and experimental spectra that the apparent peak shift in certain case can be safely interpreted as the measure of the strength of hydrogen bonding. The result of this study gives a new insight to interpret molecular interactions probed by vibrational spectroscopy.

Species delimitation of the genus Champia (Rhodymeniales, Rhodophyta) from Korea using DNA barcoding

  • Koh, Young Ho;Cho, Ga Youn;Kim, Myung Sook
    • Journal of Ecology and Environment
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    • v.36 no.4
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    • pp.449-463
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    • 2013
  • DNA barcoding is becoming a widely applied tool to accurately discriminate red algae. We tested the effectiveness of DNA barcoding for identification and discovery of Champia species in Korea and clarified the phylogenetic relationships using the plastid rbcL gene. As results, we described four species of Champia such as C. inkyua sp. nov., C. recta Noda, C. bifida Okamura, and C. expansa Yendo. A new species, C. inkyua, is characterized by entangled thallus, terete and irregular branches, hooked apices, and longitudinal filaments running throughout the frond periphery only. Longitudinal filaments were composed of a complete cell with two half cells between diaphragms in the cavity. C. recta and C. bifida were reinstated with previously used names of C. parvula and C. compressa, respectively. C. recta is the first recorded species from Korea and is characterized by an erect thallus, terete and irregular branches, and straight apices. C. bifida is characterized by compressed thallus, pinnate or alternate branches, and bifid apices. C. expansa is characterized by flabellate thallus and dichotomous branches. Molecular analyses of COI and rbcL genes revealed sufficient sequence divergence to warrant species recognition in the genus Champia.

On overlapping territories satisfying cardinality constraints

  • Takashi Moriizumi;Shuji Tsukiyama;Shoji Shi Noda;Masakazu Sengoku;Isao Shirakawa
    • 제어로봇시스템학회:학술대회논문집
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    • 1987.10a
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    • pp.857-862
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    • 1987
  • Given a network with k specified vertices bi called centers, a cardinality constrained cover is a family {Bi} of k subsets covering the vertex set of a network, such that each subset Bi corresponds to and contains center bi, and satisfies a given cardinality constraint. A set of cardinality constrained overlapping territories is a cardinality constrained cover such that the total sum of T(B$_{i}$) for all subsets is minimum among all cardinality constrained covers, where T(B$_{i}$) is the summation of the shortest path lengths from center bi to every vertex in B$_{I}$. This paper considers a problem of finding a set of cardinality constrained overlapping territories. and proposes an algorithm for the Problem which has the time and space complexities are O(k$^{3}$$\mid$V$\mid$$^{2}$) and O(k$\mid$V$\mid$+$\mid$E$\mid$), respectively, where V and E are the sets of vertices and edges of a given network, respectively. The concept of overlapping territories has a possibility to be applied to a job assignment problem.oblem.

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Prediction of Wave-Induced Current Using Time-Dependent Wave Model (쌍곡선형 파랑모형을 이용한 해빈류 예측)

  • 이정만;김재중
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 1998.10a
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    • pp.189-199
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    • 1998
  • Wave-induced current model is developed in our study and this model is composed with wave transform model and current model. Two types of wave model are used in our study, one is Copeland(1985) type which is applied in the offshore region and the other is Watanabe and Maruyama(1984) type which is applied in the surf zone. The depth-integrated and time-averaged governing equation of an unsteady nonlinear form is used in the wave induced current model. Lateral mising, radiation stresses, surface and bottom stresses are considered in our current model. Copeland's(1985) relult is used to calculate radiation stress and Berkmeir & Darlymple's(1976) is used as a surface friction formula. Numerical solutions are obtained by Leendertse scheme and compared with Noda's(1974) experimental results for the uniform slope coastal region test and Nishimura & Maruyama's(1985) experimental relults and numerical simulation results for the detached breakwater test. The results from our wave model show good agreement with the others and also show nonlinear effects around the detached breakwater. Wave induced current model is developed in this study and this model shows nonlinear effects around the detached breakwater and can be applied in the surf zone and also consider the friction stresses.

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Relationship of IGF-I mRNA Levels to Tissue Development in Chicken Embryos of Different Strains

  • Kita, K.;Noda, C.;Miki, K.;Kino, K.;Okumura, J.
    • Asian-Australasian Journal of Animal Sciences
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    • v.13 no.12
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    • pp.1653-1658
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    • 2000
  • Insulin-like growth factor-I (IGF-I) mRNA levels in the eyes, heart, liver and breast muscle removed from dwarf egg-type, normal egg-type and normal meat-type chicken embryos at 7, 14 and 20 days of incubation were measured. There was no influence of chicken strain on IGF-I gene expression in the eyes and liver. The IGF-I gene expression in eyes increased significantly along with the incubation period. In the liver, IGF-I gene expression at 20 days of incubation was significantly higher than that at 14 days of incubation. In the muscle, the lowest value for IGF-I gene expression was observed in meat-type chicken embryos. Regression analysis revealed that IGF-I gene expression was significantly correlated to the weights of the eyes and liver, but not the muscle. We conclude that there is little influence of strain on tissue IGF-I gene expression in chicken embryos during incubation but that tissue development in chicken embryos is nevertheless at least partly regulated by the change in IGF-I gene expression.

Analysis of Phonological Reduction in Conversational Japanese (현대일본어의 회화문에 나타난 축약형의 음운론적 분석)

  • Choi Young-sook;Sato Shigeru;Pahk Hy-tay
    • Proceedings of the KSPS conference
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    • 1996.10a
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    • pp.198-206
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    • 1996
  • Using eighteen text materials from various goners of present-day Japanese, we collected phonologically reduced forms frequently observed in conversational Japanese, and classified them in search of unified explanation of phonological reduction phenomena. We found 7,516 cases of reduced forms which we divided into 43 categories according to the types of phonological changes they have undergone. The general tendencies ale that deletion and fusion of a phoneme or an entire syllable takes place frequently, resulting in the decrease in the number of syllable. Typical examples frequently observed throughout the materials are : $~/noda/{\rightarrow}~/nda/,{\;}-/teiru/{\rightarrow}~/teru/,{\;}~/dewa/{\rightarrow}~/zja/,{\;}~/tesimau/{\rightarrow}~/cjau/$. From morphosyntactic point of view phonological reduction often occurs at the NP and VP morpheme boundaries. The following findings are drawn from phonological observations of reduction. (1) Vowels are more easily deleted than consonants. (2) Bilabials(/m/, /b/, and /w/ are the most likely candidates for deletion. (3) In a concatenation of vowels, closed vowels are absorbed into open vowels, or two adjacent vowels come to create another vowel, in which case reconstruction of the original sequence is not always predictable. (4) Alveolars are palatalized under the influence of front vowels. (5) Regressive assimilation takes place in a syllable starting with ill, changing the entire syllable into phonological choked sound or a syllabic nasal, depending on the voicing of following phoneme.

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QUALITY IMPROVEMENT OF COMPRESSED COLOR IMAGES USING A PROBABILISTIC APPROACH

  • Takao, Nobuteru;Haraguchi, Shun;Noda, Hideki;Niimi, Michiharu
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2009.01a
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    • pp.520-524
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    • 2009
  • In compressed color images, colors are usually represented by luminance and chrominance (YCbCr) components. Considering characteristics of human vision system, chrominance (CbCr) components are generally represented more coarsely than luminance component. Aiming at possible recovery of chrominance components, we propose a model-based chrominance estimation algorithm where color images are modeled by a Markov random field (MRF). A simple MRF model is here used whose local conditional probability density function (pdf) for a color vector of a pixel is a Gaussian pdf depending on color vectors of its neighboring pixels. Chrominance components of a pixel are estimated by maximizing the conditional pdf given its luminance component and its neighboring color vectors. Experimental results show that the proposed chrominance estimation algorithm is effective for quality improvement of compressed color images such as JPEG and JPEG2000.

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OPTIMAL SPUTTERING CONDITIONS FOR HIGH-DENSITY MAGNETIC RECORDING MEDIA BY FTS

  • Noda, Kohki;Kawanabe, Takashi;Naoe, Masahiko
    • Journal of Surface Science and Engineering
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    • v.29 no.6
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    • pp.824-828
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    • 1996
  • Co-based alloy thin films ddeposited by fcing targets sputtering(FTS) were investigated for use in high-density magnetic recording media to determine how their magnetic properties are dependent on the sputtering conditions, and thus to find appropriate parameters that allow the sputtering and thin films to meet the specificiations for magnetic properties. FTS can discharge at lower working gas pressure than other sputtering methods such as dcmagnetron sputteing because the plasma is sufficiently confined by a magnetic field applied perpendicular to both of the target planes, which results in plasma-free substrates. Co-Cr-Ta films were deposited by FTS on glass and silicon substrates at substrate temperature between room temperature and $350^{\circ}C$, and at argon gas pressure between 0.1 and 10mTorr. The films were also deposited on polyimide tapes at substrate temperature of $130^{\circ}C$ and argon gas pressure of 1 mTorr. The effective advantages of Ta as an additional element were investigated, using the same films on the tapes. As a result of the experiment, it was found that better magnetic properties were obtained in the ranges of higher temperature and lower argon gas pressure with background pressure in thr range of $1.5 \times 10^{-6}$ Torr. Ta addition at 2 to 4 atomic percent almost havled the Co-Cr grain sizes, indicating that Ta addition at an appropriate atomic percent is effective for improving the microstructure and characteristics of Co-Cr films.

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Solar Wind Observations Using STELab-IPS Array In Japan

  • Fujiki, Ken'ichi;Tokumaru, Munetoshi;Iju, Tomoya;Hirota, Maria;Noda, Momotaro;Kojima, Masayoshi
    • The Bulletin of The Korean Astronomical Society
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    • v.36 no.2
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    • pp.93.1-93.1
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    • 2011
  • Radio wave from a compact radio source such as a quasar are scattered by irregularities of electron density. The scattered waves interfere with each other as they propagate to the Earth producing diffraction patterns on the ground. This phenomenon is called interplanetary scintillation (IPS). The IPS pattern contains the information of solar wind velocities and density fluctuations passing across a line-of-sight (LOS) from an observer to a radio source. The IPS is a useful tool which allows us to measure the solar wind in three dimensional space inaccessible to in situ observations. Although the IPS measurement is an integral of solar wind velocities and density fluctuations along the LOS, which causes degradation of accuracy, we have succeeded to develop computer assisted tomography (CAT) analysis to remove the effect of LOS integration. These techniques greatly improved the accuracy of determinations of solar wind velocity structures. In this talk we present our IPS observation system and long-term variation of global solar wind structures from 1980-2009, then we focus on recent peculiar solar wind properties.

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A flexible OTFT-OLED display using solution-processed organic dielectrics

  • Hirai, Nobukazu;Katsuhara, Mao;Yagi, Iwao;Yasuda, Ryoichi;Ushikura, Shin-Ich;Noda, Makoto;Moriwaki, Toshiki;Imaoka, Ayaka;Yoneya, Nobuhide;Yumoto, Akira;Nomoto, Kazumasa;Urabe, Tetsuo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.131-134
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    • 2009
  • We have developed a flexible OTFT backplane in which all the dielectrics are formed by solutionprocess in order to achieve low-cost and highthroughput manufacturing. The backplane successfully drives a flexible AM-OLED display with peak brightness of > 200 nit and the contrast ratio of > 1000:1 with great mechanical flexibility.

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