• Title/Summary/Keyword: NO-NO$_2$ 변환

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Effect of Propene($C_3H_6$) ON NO-$NO_2$ Conversion Process in a Pulsed Corona Discharge (펄스코로나 방전에서 프로핀($C_3H_6$)이 NO-$NO_2$ 변환에 미치는 영향에 관한 연구)

  • 박광서;전배혁;전광민
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.5
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    • pp.67-77
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    • 2000
  • Investigated was the effect of propene(C3H6) on the NO-NO2 conversion in dry exhaust gases from lean burn engine using a pulsed corona discharge. A kinetic model was developed to characterize the plasma chemistry in simulated exhausts containing propene. The model uses ELENDIF program to solve Boltzmann equation for electron energy distribution function, and CHEMKIN-II program to solve stiff ODE(ordinary differential equation) problems for species concentrations. The corona discharge energy per pulse and the time-space averaged E/N were obtained by fitting the model to experimental data. The model calculation shows good agreement for NO and NO2 concentrations with the experimental data, and predicts the formation of byproducts such as CH2O, CH3HCO, CO AND CH3NO2 Propene enhances the NOx conversion enormously at lower energy density and the NOx conversion increases with the increase of initial propene and oxygen concentration, and temperature.

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라군슬러지 처리 공정 평가 및 개선

  • 황두성;오종혁;김연구;이규일;최윤동;황성태;박진호
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.06a
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    • pp.238-238
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    • 2004
  • 우라늄 변환시설은 중수로용 $UO_2$ 분말 제조 시설로서 2001년도부터 제염 해체를 통한 변환시설 환경복원사업을 시작하였다. 변환 공정의 운전 중 발생하여 라군(lagoon)에 저장되어 있는 방사성 슬러지 폐액의 처리는 시설의 해체과정에서 매우 중요한 업무중의 하나이다. 라군 슬러지의 주성분은 $NH_4NO_3$, $NaNO_3$, $Ca(NO_3)_3$, $CaCO_3$ 및 U 화합물과 소량의 Fe, Mg, Al, Si 및 P 화합물로 구성되어 있다.(중략)

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Photochemical Conversion of NOX in Atmosphere by Photocatalyst Coated Mortar (광촉매 코팅한 모르타르를 이용한 대기 중 NOX의 광화학적 변환)

  • Hyeon Jin;Kyong Ku Yun;Hajin Choi;Kyo-Seon Kim
    • Korean Chemical Engineering Research
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    • v.61 no.2
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    • pp.240-246
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    • 2023
  • This study was performed to convert NOx in atmosphere by photochemical reaction utilizing the eco-friendly solar energy. The mortar specimen coated with photocatalyst was fabricated and the photochemical conversion efficiency of NOx was analyzed. The photocatalyst coated concrete was fabricated by first adding TiO2 photocatalyst on the bottom of mold first and next adding cement mortar and, then, curing the concrete mortar. The grease was sprayed on the bottom of mold in advance so that the concrete can be demolded easily after curing. The conversion efficiencies of NOx by photochemical reactions were investigated systematically by changing the process variable conditions of amount of TiO2 coating, UV-A light intensity, total gas flow rate, relative humidity and initial NOx concentration. It was confirmed that the photocatalyst coated concrete fabricated in this study could convert NOx successfully for various process conditions in atmosphere. In future, we believe this research result can be utilized as basic data to design the infrastructure of building, tunnel and road for controlling efficiently the air pollutants such as NOx, SOx, and VOCs.

SA-Based Test Scheduling to Reduce the Test Time of NoC-Based SoCS (SA 기법 응용 NoC 기반 SoC 테스트 시간 감소 방법)

  • Ahn, Jin-Ho;Kim, Hong-Sik;Kim, Hyun-Jin;Park, Young-Ho;Kang, Sung-Ho
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.2
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    • pp.93-100
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    • 2008
  • In this paper, we address a novel simulated annealing(SA)-based test scheduling method for testing network-on-chip (NoC)-based systems-on-chip(SoCs), on the assumption that the test platform proposed in [1] is installed. The proposed method efficiently mixed the rectangle packing method with SA and improved the scheduling results by locally changing the test access mechanism(TAM) widths for cores and the testing orders. Experimental results using ITC'02 benchmark circuits show that the proposed algorithm can efficiently reduce the overall test time.

Implementation of Data Protocol Conversion System for High-end CMOS Image Sensors Equipped with SMIA CCP2 Serial Interface (SMIA CCP2 직렬 인터페이스를 가지는 고기능 이미지 센서를 위한 데이터 프로토콜 변환 시스템의 구현)

  • Kim, Nam-Ho;Park, Hyun-Sang
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.10 no.4
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    • pp.753-758
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    • 2009
  • Recently the high-end CMOS image sensors are developed, conforming to the SMIA CCP2 specification, which is a high-speed low-power serial interface based on LVDS technology. But this kind of technology trend makes the existing equipments are no longer useful, although their capability is still good enough to handle the recent image sensors if there was no interfacing problem. In this paper, we propose and realize a data protocol conversion system that translates the SMIA CCP2 serial signals into the existing 10-bit parallel signals. The proposed system is composed of a de-serializer and a FPCA chip, and thus can be constructed on a small PCB which enables easy integration between the existing equipments and the new high-end image sensors. Besides, the maximum transfer rate by the SMIA specification is also achieved on the implemented system. So it is expected that the implemented system can be used as a general-purpose protocol converter in a variety of sensor-related application fields.

An Experimental Study on $NO_x$ Reduction Efficiency and $NH_3$ Conversion Efficiency under Various Conditions of Reductant Injection on SCR and AOC (SCR 촉매와 AOC 촉매에서 환원제 분사에 따른 $NO_x$ 저감효율과 $NH_3$ 변환효율에 관한 실험적 연구)

  • Dong, Yoon-Hee;Choi, Jung-Hwang;Cho, Yong-Seok;Lee, Seang-Wock;Lee, Seong-Ho;Oh, Sang-Ki;Park, Hyun-Dae
    • Transactions of the Korean Society of Automotive Engineers
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    • v.18 no.5
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    • pp.85-90
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    • 2010
  • As the environmental regulation of vehicle emission is strengthened, investigations for $NO_x$ and PM reduction strategies are popularly conducted. Two current available technologies for continuous $NO_x$ reduction onboard diesel vehicles are Selective Catalytic Reduction (SCR) using aqueous urea and lean $NO_x$ trap (LNT) catalysts. The experiments were conducted to investigate the $NO_x$ reduction performance of SCR system which can control the ratio of $NO/NO_2$, temperature and SV(space velocity), and the model gas was used which is similar to a diesel exhaust gas. The maximum reduction efficiency is indicated when the $NO:NO_2$ ratio is 1:1 and the SV is 30,000 $h^{-1}$ in $300^{\circ}C$. Generally, ammonia slip from SCR reactors are rooted to incomplete conversion of $NH_3$ over the SCR. In this research, slip was occurred in 6cases (except low SV and $NO:NO_2$ ratio is 1:1) after SCR. Among 6 case of slip occurrence, the maximum conversion efficiency is observed when SV is 60,000 $h^{-1}$ in $400^{\circ}C$.

The Availability of Automobile Catalytic Convert of Copper Based on the DFT Calculations of Cu-NO Complexes (Cu-NO 복합체에 대한 DFT 계산에 따른 Cu의 자동차 촉매변환기 적합성)

  • Ha, Kwanga;Lee, Min-Joo
    • Journal of the Korean Chemical Society
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    • v.62 no.5
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    • pp.358-363
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    • 2018
  • The purpose of this study is to show the possibility of using Cu catalyst in removal of $NO_x$ from automobile exhaust which is regarded as the primary source of fine dust PM2.5. The energy and the bond lengths of the three possible structures of Cu-NO complex, which is formed by binding NO molecule to Cu, and the changes in IR and Raman spectra are calculated using MPW1PW91 method on the level of 6-311(+)G(d,p) of basis sets with Gaussian 09 program. As a result, the enthalpy of formation of the Cu-NO complexes are obtained as ${\Delta}H=104.89$, 91.98, -127.48 kJ/mol for the linear, bent, and bridging forms of them, respectively. And the bond lengths between N and O in NO complexes, which becomes longer than NO molecule, indicates that O is easily reduced from Cu-NO. In addition, the Cu-NO complexes using Cu catalyst can be easily measured by infrared or Raman spectroscopy because in the IR and Raman spectra of the NO and Cu-NO complexes the positon and the intensity of bands are definitely different in each vibration mode.

A Study of the characteristics of NOx measurement and analysis methods of the SCR system for ships (선박용 SCR 시스템 NOx 측정 및 분석 방식의 특성 연구)

  • Kim, Sung-Yoon;Lee, Young-Ho;Kim, Min;Park, Sam-Sik
    • Journal of Advanced Marine Engineering and Technology
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    • v.39 no.4
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    • pp.387-392
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    • 2015
  • A method for measuring and analyzing the $NO_x$ in ships is described in $NO_x$ Technical Code 2008. The analysis device, as required by the Code, has been to use a Chemi-luminescence detection method or Heated Chemi-luminescence detection. on the other hand, selective catalytic reduction using $NH_3$ as a reducing agent has an interference effect on the analyzer, and causes measurement error. In this study, the Chemi-luminescence detection method was examined according to how it affects the concentration of $O_2$, CO, $SO_2$, $NH_3$. Fourier transform infrared spectrometry analysis equipment and measurement methods were compared. In order to confirm the effect of the physical interference of the measuring device, it was confirmed by decomposing a measuring device. Consequently, white precipitate and moisture were generated inside the chemiluminescence detection system and I found that affecting interference. The influence of interference highlights the need to consider the minimized $NO_x$ measurement method.

Determination of Physical Camera Parameters from DLT Parameters (직접선형변환 매개변수로부터 물리적 사진기 매개변수의 산정)

  • Jeong, Soo;Lee, Chang-No;Oh, Jae-Hong
    • Journal of Korean Society for Geospatial Information Science
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    • v.13 no.2 s.32
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    • pp.39-43
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    • 2005
  • In this study, we analyzed the accuracy of the conversion from DLT parameters to physical camera parameters and optimized the use of DLT model for non-metric cameras in photogrammetric tasks. Using the simulated data, we computed two sets of physical camera parameters from DLT parameters and Bundle adjustment for various cases. Comparing two results based on the RMSE values of check points, we optimized the arrangement of GCPs for DLT.

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