• Title/Summary/Keyword: NO$_{3}^{-}$-N : NH$_{4}^{+}$-N 비율

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Assessment of Bottom Ash Amendment on Soil and Turfgrass Qualities in Golf Course (석탄바닥재의 골프장 토양 및 잔디생육 개량 영향평가)

  • Lee, Ju-Young;Choi, Hee-Youl;Shim, Gyu-Yul;Yang, Jae-E
    • Proceedings of the Turfgrass Society of Korea Conference
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    • 2011.02a
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    • pp.25-32
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    • 2011
  • 본 연구는 화력발전의 부산물로 발생하는 석탄바닥재가 골프장 사질 토양의 개량재로 사용 적합한지를 평가하기 위해 수행되었으며, 결과를 요약하면 다음과 같다. 1. 석탄바닥재의 화학성을 분석한 결과 총질소 0.34%, 가용성 인산 $52mgL^{-1}$, 치환성 칼륨 $51mgL^{-1}$ 뿐만 아니라 소량의 치환성 칼슘과 마그네슘을 함유하고 있어 식물생육에 이롭고, 유해중금속함량은 Cd, $Cr^{6+}$, Pb, Ni, As는 $1mgL^{-1}$ 이하, Cu 농도는 $1.25mgL^{-1}$ 검출되어 토양환경보전법의 토양오염우려기준 이하이므로 석탄바닥재 재활용으로 인한 토양오염 가능성은 매우 낮은 것으로 판단된다. 2. 모래 토양에 석탄바닥재를 부피비로 0~50% 비율로 혼합한 시료의 투수계수와 유효수분함량을 측정한 결과 석탄바닥재 혼합비율이 증가할수록 투수계수는 유의성 있게 감소하고 유효수분함량은 유의성 있게 증가해 석탄바닥재가 모래 토양의 낮은 수분보유력을 개선하는 효과가 있음을 확인하였다. 3. 모래 토양에 석탄바닥재를 부피비로 0~50% 비율로 혼합한 시료를 잔디식재층으로 조성한 라이시미터에 잔디종자 파종 후 약 4개월 뒤 잔디밀도가 완전히 형성된 후에 시비 후 3일 간격으로 채취한 용탈수를 분석한 결과 1일과 4일 후에 채취한 초기 용탈수에서는 석탄바닥재 혼합비율이 높을수록 $NO_3-N$, $NH_4-N$ 및 K함량이 유의성 있게 감소했으며, 대조구에 비해 석탄바닥재 혼합비율이 높은 처리구일수록 $NO_3-N$, $NH_4-N$ 및 K함량이 용탈수 채취기간 동안 지속적으로 용탈되었다. 이 결과로 석탄바닥재가 모래 토양의 낮은 양분 보유력을 개선하는데 효과적이고 석탄바닥재처리가 대조구에 비해 오랫동안 식물 생육에 필요한 양분을 공급하는 효과가 있음을 확인하였다. 4. 골프장 그린상구조와 동일한 시험포장을 만들고 모래 토양에 석탄바닥재 10%와 20% 그리고 피트, 액시스, 이소라이트를 부피비로 10% 비율로 혼합한 시료를 잔디식재층으로 조성하고 크리핑 벤트그래스(Agrostis paulstris Huds), Penn A-4 $10gm^{-2}$을 파종한 후에 처리구별로 잔디 품질을 평가하기 위해 잔디 밀도, 뿌리길이, 색상 및 시각적 품질을 조사한 결과 석탄바닥재 처리구는 기존에 사용하는 개량제인 피트, 액시스, 이소라이트 처리구와 동등한 잔디생육 촉진 효과가 있는 것으로 조사되었다. 5. 결론적으로 석탄바닥재는 골프장 토양의 물리적 특성과 화학적 특성을 개선하고 잔디생육에 필요한 양분을 공급하는데 효과적인 토양개량재라고 할 수 있다.

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Effect of Incorporation Rate of Polyacrylamide Hydrogel on Changes in Chemical Properties of Root Media (Polyacrylamide 고흡수성 수지의 혼합 비율이 상토의 화학성에 미치는 영향)

  • Wang, Hyun-Jin;Choi, Jong-Myung;Lee, Jong-Suk
    • Journal of Bio-Environment Control
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    • v.14 no.3
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    • pp.190-195
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    • 2005
  • This research was conducted to investigate the changes in soil chemical properties of root media as influenced by incorporation rate of a polyacryl amide hydrogel, Stocksorb C. The pH at 5 weeks after treatment in four root media such as peatmoss + vermiculite (1:1, v/v; PV), peatmoss + composted rice hull (1:1; PR), peatmoss + composted saw dust (1:1; PD) and peatmoss + composted pine bark (1:1; PB) containing STSB were in the range from 7.04 to 7.30, which was too high. Elevated incorporation rate of STSB resulted in increase of EC in soil solution of four root media with linear and quadratic response. The concentrations of $NH_4^+-N,\;NO_3^--N,\;PO_4-P^{3-},\;K^+,\;Ca^{2+}and\;Mg^{2+}$ in four kinds of root media increased as incorporation rates of STSB were elevated. But the $NO_3^-$-N concentrations in PS media were lower than those in other there root media tested. The Fe concentrations in PV, PR and PS media increased as incorporation rates of STSB were elevated, but those in PB medium did not show significant different. The concentrations of $Fe^{2+},\;Mn^{2+},\;Zn^{2+}and\;Cu^{2+}$ in PS media were higher than those in other three root media.

Assessment of Water Quality in Pyeongtaek Reservoir and Its Main Tributaries (평택호와 유역 주요 하천의 수환경 및 오염도 평가)

  • Hwang, Soon-Jin;Cho, Kyung-Je;Shin, Jae-Ki
    • Korean Journal of Ecology and Environment
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    • v.36 no.1 s.102
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    • pp.38-47
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    • 2003
  • The water quality of the Pyeongtaek Reservoir and its main streams has been eval uated far water pollution state in March, June, September and December,2000. The following are the findings: $NH_4$ accounts for the majority of TN in the inflow streams. In the reservoir, TN and $NH_4$ are the more present in the winter season and less in the summer season, with $1.6{\sim}2.4$ times of $NO_3$ and $5.3{\sim}11.4$ times of $NO_2$ found in December and June compared with other seasons. The concentration of each component is different between streams: $NH_4$ among inorganic nitrogen has the highest concentration in the upstream, and $NO_3$ is more prevalent in the downstream. SRP accounts for $25{\sim}69%$ of TP in the stream. Unlike N component, P component in the reservoir rapidly decreases from upstream toward downstream, except in the summer. Average SRSi slightly increases in the fall, i.e., immediately after rainfall. In the streams, the average concentration of chlorophyll-a ranges from 9 to $33{\mu}g/l$, and is relatively high in the downstream. In contrast, in the reservoir, it is the highest in the upstream where $NH_4$ and SRP are frequently found. In particular, diatom and cryptomonad algae are bloomed in March, and blue-green algae in September; their maximum values are $108{\mu}g/l$ and $130{\mu}g/l$, respectively. Considering the concentration of N and P nutrients, pollution loads can affect the Pyeongtaek Reservoir in the downstream in this order: Ansong Stream

Optimization of Heteropolysaccharide-7 Production by Beijerinckia Indica (Beijerinckia Indica 배양을 통한 Heteropolysaccharide-7 생산 최적화)

  • Wu Jian-Rong;Son Jeong Hwa;Kim Ki Myong;Nam Soo-Wan;Lee Jin-Woo;Kim Sung-Koo
    • Microbiology and Biotechnology Letters
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    • v.33 no.2
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    • pp.117-122
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    • 2005
  • Beijerinckia indica was cultured in mineral salts medium (MSM) medium with various carbon and nitrogen sources to improve the production yield of heteropolysaccharide-7 (PS-7). At high C/N ratio, the high concentration of PS-7 was produced until 40 h of the culture, whereas most of the glucose as a carbon source was used for the cell growth at low C/N ratio. However, at the high C/N ratio, PS-7 accumulation stopped at 48 h of the culture due to the increasing viscosity of the culture broth would inhibit the cell growth. Therefore, the optimized value of C/N ratio was 33.3 (20 g/L glucose, 7.5 mM $NH_{4}NO_3$) for the high production of PS-7. In the culture with various carbon sources, B. indica effectively used the hexoses or glucose-generating sugars for PS-7 formation. Especially, sucrose was the best carbon source for the high production of PS-7 (6.96 g/L) with a high viscosity (40772 cp). In the culture of B. indica with MSM medium containing 20 g/L glucose and 7.5 mM $NH_{4}NO_3$ in a 51 fermentor, the highest cell concentration was 2.5 g/L and the highest concentration of PS-7 was 7.5 g/L (35174 cp). The additional nitrogen sources of 7.5 mM $NH_{4}NO_3$, glutamine and glutamate at 12 h of the culture after exhaustion of a nitrogen source regulated the metabolism of carbon sources, therefore the nitrogen sources could control PS-7 synthesis.

Evaluation of Fate of $NH_4{^+}$ of Condensed Molasses Solubles(CMS) in Soil Using by $^{15}N$-Tracer Method (중질소 추적자법을 이용한 Condensed Molasses Solubles(CMS) 함유 $NH_4{^+}$의 토양 중 행동 연구)

  • Lee, Sang-Mo;Choi, Woo-Jung;Yun, Seok-In;Choi, Young-Dae;Ro, Hee-Myong;Park, Jee-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.2
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    • pp.69-76
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    • 2002
  • To study the behavior of $NH_4{^+}$ of CMS (condensed molasses solubles) in soil, a laboratory incubation experiment was conducted during a period of up to 21 days at $25^{\circ}C$. The $NH_4{^+}$ of CMS was labeled with $^{15}N$ and was applied to water-unsturated and water-saturated conditions. Soil pH was gradually decreased from 6.1 to 5.4 under unsaturated condition. However, soil pH was increased to 6.5 within 2 days under saturated condition and then was constant. The concentration of ammonium was decreased 3 times faster under unsaturated condition than under saturated condition. The concentration of nitrate was increased from 17.4 to $155.4mg\;kg^{-1}$ under unsaturated condition. But concentration of nitrate was kept with low(below $8.0mg\;kg^{-1}$) under saturated condition. During the incubation, 52.4% of $^{15}NH_4{^+}$ applied was existed in the form of $NO_3{^-}$ by nitrification under unsaturated condition. Most of applied nitrogen was immobilized within 4 days of incubation. On 21 days of the incubation the percentage of immobilized nitrogen derived from $^15NH_4{^+}$(NDFA) was 19.6% under unsaturated condition and 17.0% under saturated condition. The percentage of unaccounted N, which was lost by denitrification, was 28.4% under unsturated condition and 67.6% under saturated condition.

Vertical Flow Zeolite-Filled Reed Bed with Intermittent Feeding for Sewage Treatment (수직 흐름 제올라이트 갈대 여과상에 의한 생활하수 처리)

  • Seo, Jeoung-Yoon
    • KSBB Journal
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    • v.22 no.2
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    • pp.102-108
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    • 2007
  • A sewage was treated using a vertical flow zeolite-filled reed bed. The sewage from the student dormitory of Changwon National University was fed into the reed bed for 10 minutes every 6 hours at the hydraulic load of $314L/m^3{\cdot}$day. The filtering height of the reed bed was 100 em and the zeolite mixture was filled in the reed bed. The mixture consisted of the same volume of two types of zeolite: 0.5$\sim$1 mm and 1$\sim$3 mm in diameter. Annual average removal efficiency was 88 89.9%, $COD_{Cr}$ 86.1 %, $COD_{Mn}$ 81.2%, T-N 34.0%, $NH_4^+$-N 97.3% and T-P 34.6%. T-N of effluent was mostly $NO_3^-$-N and the concentration of $NO_2^-$-N in effluent was lower than 0.1 mg/L. All removal efficiencies did not show a remarkable seasonal change. The ranking of phosphorous fractions fixed to the zeolite in column test was Ca-P > Fe-P > reductant soluble Fe-P > occluded P > saloid P > AI-P at all depths of the filter. All phosphorous fractions except for AI-P reduced at deeper filter layer, while their content ratios increased at deeper filter layer. Organic matter content was the highest at the highest layer (0$\sim$5 cm from the top of the filter) and only small differences were observed at the deeper filter layer than 5 em from the top. Organic matter content increased at all depths of the filter with the operating time.

Developments of Water Treatment System by Biological Fluidized Bed for Water Reuse Aquaculture (생물학적 유동층을 이용한 어류양식 순환수의 처리씨스템 개발)

  • LEE Ki-Wan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.26 no.4
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    • pp.380-391
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    • 1993
  • The experimental study was made to propose the treatment method of wastewater in the high-density fish culture system. The BOD to COD ratios of effluents were almost same to 0.65 in the eel-farm, but were various in the farm rearing together with tilapia etc. A BOD rate curve of the eel-farm effluent could be described mathematically by the equation, $BODu=14.1(1-10^{-0.222t})+30.9(1-10^{-0.035(t-8)})$. Nitrification in Biological Fluidized Bed(BFB) system to treat the fish-farm wastewater could be reduce ammonium level up to $65{\sim}79\%$ when ammonium loading rates were between 0.014 and 0.075g $NH_4/g$ BVS-day. Nitrification efficiency was decreased by organic matters in the wastewater when ammonium loading was low(0.014 g $NH_4/g$ BVS-day). T-N removal ratios were decreased to increase loading in denitrification process, because of low C/N ratio. Based on much higher biological mass concentrations, BFB system takes many advantages of a practical viewpoint, such as stability of treatment efficiency and reduction of necessary site area for the facility, as compared with conventional treatment systems.

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Irrigation Water Qualities along Dong-Jin River Watershed during 1994-1998 (동진강 수계 농업용수 수질평가)

  • Uhm, Mi-Jeong;Choi, Jeong-Sik;Han, Soo-Gon;Kim, Kab-Cheol;Moon, Young-Hun
    • Korean Journal of Environmental Agriculture
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    • v.19 no.2
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    • pp.110-115
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    • 2000
  • This study was conducted to monitor the irrigation water qualities along Dong-Jin river watershed. The water quality was surveyed at 6 sites from April to september during $1994{\sim}1998$. And the results were as follows : In July and August, water quality was better than that of any other months due to dilution with rainwater. Whereas, it became worse in April but it involved lower contents than limitted contents affected to the crop damage. Content of inorganic components was higher at Jeong-up and Won-pyeong stream. The reason for it that Jeong-up stream was deteriorated with sewage water from Jeong-up city, and Won-pyeong stream has narrow width. Water quality in upstream of Dong-Jin river, was evaluated best conditions in all sampling sites. For investigated period, water quality got worse from 1994 to 1995 but it was getting better to 1998 after 1995, especially at Jeong-up stream. The total equivalent of cation and anion was the highest at April through all months and at Jeong-up stream in sampling sites. Equivalent ratio of cation to $anions({\Sigma}C/{\Sigma}A)$ was higher at May than any other months and lower at Won-pyeong streams than any other sites. The value of most inorganic components was highly correlated with those of other components. But the value of $NO_3\;^--N$ was not correlated with that of most components, and $PO_4\;^{3-}-P$ was not correlated with COD, $NH_4\;^+-N$, $NO_3\;^--N$, $SO_4\;^{2-}$.

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A Study on the Removal of Ammonia by Using Peat Biofilter (미생물 활성토탄을 이용한 암모니아 제거에 관한 연구)

  • Choung, Youn Kyoo;Ahn, Jun Seong
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.3
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    • pp.655-668
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    • 1994
  • Conventional deodorization filters using soil and compost reach the capacity limitation of deodorization in short period, because its removal mechanism primarily depends on adsorption. Therefore, in this study the experiment was performed on the removal of ammonia which is a strong inorganic malodor, frequently emitted from night soil treatment plants and sewage treatment plants, by seeding activated sludges on the bio-peat containing higher organic contents, water conservation capacity, permeability and lower pressure drop. As a result, in raw peat filter natural ammonia outlet was observed in consequence of pH increase resulted from ammonia ionizing in liquid phase. Ammonia removal mechanism primarily depended on the adsorption onto the anion colloidal substances in peat. In peat bio-filter, theoretical ammonium salts ratio was higher than that of raw peat, resulted from slight pH increase by microorganism activity, however, the experimetal value of ammonia-nitrogen accumulated in bio-peat was lower than that of raw peat because of nitrification by nitrifying bacteria. In the initial reaction period, adsorption was predominant in the ammonia removal mechanism, but nitrification was conspicuous after the middle period. Mass balance of nitrogen was established using experimental data of input $NH_3$ loading, output $NH_3$ loading, $NH_4{^+}$-N, $NO_x$-N, and Org-N. The critical time of unsteady state, which is the maximum activating point of microorganism in bio-filter, was determined using experimental data, and the ammonia adsorption curve was computed using regression analysis. On the basis of the results obtained by above analysis, the delay days for the saturation of adsoption capacity in peat bio-filter was calculated.

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Fertilizer Effect of Waste Nutrient Solution in Greenhouses for Young Radish Cultivation (열무 재배를 위한 시설하우스 폐양액의 비료 효과)

  • Hong, Youngsin;Moon, Jongpil;Park, Minjung;Son, Jinkwan;Yun, Sungwook
    • Journal of Bio-Environment Control
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    • v.31 no.4
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    • pp.460-467
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    • 2022
  • The purpose of this study is to enhance utilization of the waste nutrient solution (WNS) disposed at the hydroponic greenhouse. Several sets of testing were conducted to examine the effects of WNS: (a) a fertilizer effect, (b) soil column leaching, and (c) crop cultivation. The fertilizer effect test was applied in young radish cultivation by examining the growth characteristics of young radish and soil based on inorganic nitrogen according to the soil treatment of the nitrogen fertilizer (NF) and the WNS. The fertilizer effects and crop cultivation test were conducted with five treatments (A-E): A, non-treatment (water); B, 100% of NF; C, 70% of NF + 30% of WNS; D, 50% of NF + 50% of WNS; and E, 30% of NF + 70% of WNS. The soil column leaching test was conducted with three treatments: non-treatment (water), 100% of NF, 50% of WNS + 50% of NF. As a result, the chemical properties of the WNS were pH 6.0, EC 2.4dS·m-1, total phosphorus (T-P) 28mg·L-1, ammonium nitrogen (NH4-N) 5.0mg·L-1, and nitrate nitrogen (NO3-N) 301mg·L-1. The chemical properties of the soil were pH 5.51, EC 0.31dS/m, organic matter 2.08g·kg-1, NO3-N 9.64mg·kg-1, and NH4-N 3.20mg·kg-1. The results of fertilizer effects showed that the ratio of 50% or less of NF and 50% or more of WNS was high in young radish growth. There was no statistically significant difference between the soil chemistry in the C-E treatments where WNS was mixed with NF and the B treatment where only NF was applied. As a result of the soil column leaching test, there was no significant difference in the concentrations of NO3 and NH4 in the treatment of 100% of NF and 50% of NF + 50% of WNS. The study indicates, if the mixed fertilizer of WNS and NF is applied in the soil cultivation of young radish, it will reduce the use of NF and environmental pollution. This also helps reduce production costs on farmers and increase the yield of young radish.