• Bulletin of the Korean Chemical Society
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• v.21 no.4
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• pp.383-388
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• 2000

Multiblock copolymers consisting of poly( g-benzyl L-glutamate) (PBLG) as the hydrophobic part and poly(ethylene oxide) (PEO) as the hydrophilic part (GEG) were synthesized and characterized. GEG polymeric micelles were prepared by the dialysis technique. Particle size distributions based on intensity,volume, and number-average were 22.6 $\pm$ 11.9 nm, 23.5 $\pm$ 4.6 nm, and 23.7 $\pm$ 37 nm, respectively. It was observed that par-ticle size and size distribution of GEG polymeric micelles changed significantly with the choice of initial sol-vent. Transmission electron micrographs (TEM) showed the polymeric micelles to be spherically shaped, with sizes ranging from 20 nm to 40 nm in diameter. Fluorescence spectroscopy measurements suggested that GEG block copolymers wereassociated in water to form polymeric micelles, and the critical micelle concentrations (CMC) value of the block copolymers was 0.0094 g/L. Further evidenceof micelle formation of GEG block copolymers and limited mobility of the PBLG chain in the core ohe micelle was obtained with 1 H NMR in D2O.

• Transactions of Materials Processing
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• v.20 no.1
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• pp.23-28
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• 2011

For the fabrication of nano patterned products manufacturing a nano patterned mold is needed in advance. The nano patterned stamper was fabricated by electroforming the AAO master with nickel. The surface of nickel-plated stamper had nano-patterned holes with the diameter of 73 nm and the depth of 83 nm. Hot embossing was used for forming P3HT sheet and the process factors of hot embossing were closer as pressure, temperature and time. In the present paper hot embossing experiments were performed to find the main process conditions to affect the replication ratio of nano patterns on surface of P3HT sheet. As a result, main contributing factors for the replication ratio of hot embossed pattern could be sequentially enumerated as pressure, temperature and time.

• Korean Journal of Materials Research
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• v.23 no.6
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• pp.304-308
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• 2013

The effect of a sputter deposition sequence of Cu, Zn, and Sn metal layers on the properties of $Cu_2ZnSnS_4$ (CZTS) was systematically studied for solar cell applications. The set of Cu/Sn/Zn/Cu multi metal films was deposited on a Mo/$SiO_2$/Si wafer using dc sputtering. CZTS films were prepared through a sulfurization process of the Cu/Sn/Zn/Cu metal layers at $500^{\circ}C$ in a $H_2S$ gas environment. $H_2S$ (0.1%) gas of 200 standard cubic centimeters per minute was supplied in the cold-wall sulfurization reactor. The metal film prepared by one-cycle deposition of Cu(360 nm)/Sn(400 nm)/Zn(400 nm)/Cu(440 nm) had a relatively rough surface due to a well-developed columnar structure growth. A dense and smooth metal surface was achieved for two- or three-cycle deposition of Cu/Sn/Zn/Cu, in which each metal layer thickness was decreased to 200 nm. Moreover, the three-cycle deposition sample showed the best CZTS kesterite structures after 5 hr sulfurization treatment. The two- and three-cycle Cu/Sn/Zn/Cu samples showed high-efficient photoluminescence (PL) spectra after a 3 hr sulfurization treatment, wheres the one-cycle sample yielded poor PL efficiency. The PL spectra of the three-cycle sample showed a broad peak in the range of 700-1000 nm, peaked at 870 nm (1.425 eV). This result is in good agreement with the reported bandgap energy of CZTS.

• Proceedings of the Speleological Society Conference
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• 2001.06a
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• pp.3-29
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• 2001

파파리반딧불이(H papariensis)의 생태학적 특성을 규명하고자 서식처 환경, 개체군, 고도별 출현양상과 지역별 분포양상, 발광양상, 교미행동을 조사하였다. 춘천시 서면 지암리에서 H. papariensis 성충의 개체군 밀도를 1998년 5월부터 7월에 걸쳐 조사하였으며, 전체 채집 개체수는 703개체였다. 이중 수컷은 680개체, 암컷은 23개체를 채집하였다. 지암리에서 전체 출현기간은 50여 일로 추정되었다. 처음 출현한 날로부터 2주에서 3주 사이에 최대 정점을 나타내었으며, 이후 점진적으로 감소하는 출현양상을 나타내었다. 수컷 680개체중 47개체는 재 포획되었으며, 이로서 추정된 최대수명은 6일 이상, 평균수명은 3.26일로 나타났으며, 수컷과 암컷의 상대적인 성비는 27.5/l로 나타났다. 한국산 Hotaria속 반딧불이 2종의 고도별 출현 및 지역별 분포양상에 대하여 1999년 5월부터 7월까지 18개 지역을 선정하여 조사하였다. 전체 채집개체수는 1096개체였으며 이중 H. papariensis는 584개체, H unmunsana는 512개체였다 두 종은 제주도를 제외한 전 조사지역에서 공서 하고 있었으며 H. papariensis는 북쪽지역에 우세하게 분포하였고 H. unmunsana는 남쪽지역에 우세하게 분포하는 양상을 나타내었다. 성충 반딧불이의 최고 출현성기는 고도가 높아질수록 늦어지는 경향을 나타내었다. 고도별로 200m 이하 지역에서는 6월 초순에서 중순, 200-400m 지역에서는 6월 중순에서 말경, 400-600m 지역에서는 6월말 경부터 7월 초순, 600-800m 지역에서는 7월 초순부터 중순에 각각 최고 성기를 나타내었다. H. papariensis의 암컷과 수컷의 발광양상을 분석하고자 정지발광과 구애 발광을 구분하여 조사하였고 각각의 발광지속시간과 발광주기를 구분하여 측정하였다. 수컷의 발광지속시간은 정지발광(0.12초)보다 구애발광(0.17초)에서 1.4배 증가하였으며 암컷의 발광지속시간은 정지발광(0.15초)보다 구애발광(0.19초)에서 1.5배 증가하였다. 발광주기는 수컷에서 정지발광(1.26초)보다 구애발광(1.12초)에서 0.88배 감소하였고, 암컷에서 정지발광(2.99초)보다 구애발광(1.06초)에서 0.35배 감소하였다. 발광양상에서 발광주파수는 수짓의 정지발광에서 0.8 Hz, 수컷 구애발광에서 0.9 Hz, 암컷의 정지발광에서 0.3 Hz, 암컷의 구애발광에서 0.9 Hz로 각각 나타났다. H. papariensis의 발광파장영역은 400 nm에서 700 nm에 이르는 모든 영역에서 확인되었으며 가장 높은 첨두치는 600 nm에 있고 500에서 600 nm 사이의 파장대가 가장 두드러지게 나타났다. 발광양상과 어우러진 교미행동은 Hp system과 같은 결과를 얻었다.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.23 no.7
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• pp.539-544
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• 2010

We have synthesized new blue electroluminescent polyalkylfluorene-based copolymers [poly(F-co-Py)x:y, where x:y = 99:1 or 95:5 mole ratios] containing the hole-injecting pyrazole derivative [3,3'-(4,6-bis(octyloxy)-1,3-phenylene)bis(1,5-diphenyl-4,5-dihydro-1H-pyrazole] through Ni(0) mediated polymerization, and their electroluminescent properties were investigated. Electroluminescent (EL) devices were fabricated with ITO / PEDOT:PSS (110 nm) / copolymers or PF homopolymer (80 nm) / Ca (50 nm) / Al (200 nm) configuration. Each EL device constructed from the copolymer exhibited significantly enhanced brightness and efficiency compared with a device constructed from the PF homopolymer. The EL device constructed with poly(F-co-Py)99:1 exhibited the highest luminous efficiency and brightness (0.95 cd/A and $2,907\;cd/m^2$, respectively). The achieved luminous efficiency was an excellent result, providing almost a 4-fold improvement on the efficiency obtainable with the a PF homopolymer device. This enhanced efficiency of the copolymer devices results from their improved hole injection and more efficient charge carrier balance, which arises from the HOMO level (~5.83 eV) of the poly(F-co-Py)99:1 copolymer, which is higher than that of the PF homopolyme (~5.90 eV).

• Applied Biological Chemistry
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• v.23 no.2
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• pp.123-130
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• 1980

Thiamine derivatives of thiamine tetrahydrofurfuryl disulfide (TTFD) and thiamine propyl disulfide (TPD) were obtained in a good yield and purity by use of thiothiamine $(SB_1)$ and also described in details for the preparing sodium tetrahydrofurfuryl thiosulphate (Bunte's salt) with and without KI. The optimum reaction conditions for the preparation of TTFD was set in which the Box-Wilson plan was applied. The reaction conditions are as follows; 1. pH value of aqueous solution of thiol type of $B_1{\cdot}HCl;12.09$ 2. Quantity of Bunte's salt (to $B_1{\cdot}HCl\;20G$); 35.01g 3. Reaction temperature; $15.59^{\circ}C$ Studies on ultraviolet absorption were made at various pH and showed that the absorption maxima are shifted with change of pH. The absorption maxima are at $244{\sim}246nm,\;234{\sim}235nm$ in TTFD, and $245{\sim}246nm,\;233{\sim}235nm$ in TPD. The structure was proved by the infrared spectral evidence. Quantitative determination was studied.

• Proceedings of the Korean Vacuum Society Conference
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• 2016.02a
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• pp.199-199
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• 2016

본 연구에서는 고상반응법을 사용하여 제조한 MgWO4:Dy,Na 형광체의 광학특성과 결정구조를 조사하였다. Fig.1 XRD 주 피크는 $23.9^{\circ}$에서 관측 되었으며 (110) 면에서 발생한 회절신호이다. 결정구조는 단사정계임을 알 수 있었다. Dy,Na의 함량비를 0 mol, 0.02 mol, 0.04 mol, 0.06 mol, 0.08 mol, 0.10 mol로 변화시켜 합성했으나, 함량비와는 관계없이 동일한 XRD 회절 피크 패턴이 관측되었다. Fig.2. 그림의 220-340 nm에서 관찰되는 넓은 밴드는 $O2-{\rightarrow}W6+$에 의해 발생한 LMCT(ligand to metal charge transfer)이고, Dy에서 WO42- 그룹으로 에너지 전달에 의해서 생긴 CTB 이다. 합성한 형광체를 295 nm로 여기 시킨 모든 형광체 분말의 발광 스펙트럼은 Dy 이온의 $4F9/2{\rightarrow}6H15/2$ 전이에 의한 487 nm, $4F9/2{\rightarrow}6H13/2$ 전이에 의한 577 nm, $4F9/2{\rightarrow}6H11/2$ 전이에 의한 668 nm의 발광 스펙트럼이 관측되었다. Dy 이온이 0.02 mol일 때, 발광 세기가 가장 강하였으며, 몰 비가 증가함에 따라 발광의 세기는 감소하는 농도 소광현상이 관측되었다.

• Analytical Science and Technology
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• v.17 no.1
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• pp.23-28
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• 2004

Trace amount of uranyl (II) has been determined spectrophotometrically by measuring the optical density of the light blue yellowish coloured solutions formed by reaction between the metal ion and nicotinohydroxamic acid (NHx) in presence of different secondary ligands in strong isoamyl alcohol alkaline medium. The absorption maxima for both aqueous and extracted systems measured at their respective optimum pH were found to be 360 and 559 nm (DETA), 375 and 358 nm (EDA), 369 and 362 nm (piperidine), 354 and 341 nm (pyridine) and 363 and 336 nm (3 piperidine), 354 and 341 nm (pyridine) and 363 and 336 nm (3 - picoline), respectively at which Beer's law was obeyed. Effect of pH, reagent concentration, order of addition of reagent, time, temperature and solvent media on the absorption spectra have also been studied. Among the different systems studied, the shortest concentration range of uranyl(II) adhering to Beer's Law was 2.4 - 10.5 ppm observed for $UO_2(II)$ - NHx - DETA system in aqueous medium and also for iso amyl alcohol(IAA) extracted $UO_2$ - NHx - pyridine system was 2.4 - 7.8.

• Korean Journal of Materials Research
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• v.23 no.1
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• pp.47-52
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• 2013

Graphene has been synthesized on 100- and 300-nm-thick Ni/$SiO_2$/Si substrates with $CH_4$ gas (1 SCCM) diluted in mixed gases of 10% $H_2$ and 90% Ar (99 SCCM) at $900^{\circ}C$ by using inductively-coupled plasma chemical vapor deposition (ICP-CVD). The film morphology of 100-nm-thick Ni changed to islands on $SiO_2$/Si substrate after heat treatment at $900^{\circ}C$ for 2 min because of grain growth, whereas 300-nm-thick Ni still maintained a film morphology. Interestingly, suspended graphene was formed among Ni islands on 100-nm-thick Ni/$SiO_2$/Si substrate for the very short growth of 1 sec. In addition, the size of the graphene domains was much larger than that of Ni grains of 300-nm-thick Ni/$SiO_2$/Si substrate. These results suggest that graphene growth is strongly governed by the direct formation of graphene on the Ni surface due to reactive carbon radicals highly activated by ICP, rather than to well-known carbon precipitation from carbon-containing Ni. The D peak intensity of the Raman spectrum of graphene on 300-nm-thick Ni/$SiO_2$/Si was negligible, suggesting that high-quality graphene was formed. The 2D to G peak intensity ratio and the full-width at half maximum of the 2D peak were approximately 2.6 and $47cm^{-1}$, respectively. The several-layer graphene showed a low sheet resistance value of $718{\Omega}/sq$ and a high light transmittance of 87% at 550 nm.

• Proceedings of the Zoological Society Korea Conference
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• 1997.10b
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• pp.302.1-302
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• 1997

No Abstract, See Full Text